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    • 1. 发明公开
    • Procédé de fabrication d'un circuit intégré et notamment d'une mémoire eprom comportant deux composants distincts isolés électriquement.
    • 具有两个不同,电绝缘部件制造集成电路,特别是EPROM存储器的方法。
    • EP0206929A1
    • 1986-12-30
    • EP86401321
    • 1986-06-17
    • COMMISSARIAT ENERGIE ATOMIQUE
    • HARTMANN JOELMARTIN FRANCOIS
    • H01L27/112H01L21/28H01L21/8246H01L21/8247H01L27/10H01L29/78H01L29/788H01L29/792H01L21/82H01L29/60
    • H01L27/11526H01L21/28273H01L27/11536
    • 1. Process for the production, on a semiconductor substrate (8), of an integrated circuit having at least two separate electrically insulated components, a first component (2) having a first insulant (10) surmounted by first (12) and second (14) stacked gates, which are separated by a second insulant (16), and a second component (22) having a third insulant (30) surmounted by a third gate (28), the first (10), second (16) and third (30) insulants having different, clearly defined thicknesses, characterized in that it comprises the following stages : a) producing a first insulant layer (110) on the substrate (8), b) covering the first insulant layer (110) with a first conductive layer (112), in which the first gate (12) will be formed, c) formation of a second insulant layer (112) on the first conductive layer (116), d) carrying out a first etching of the second insulant layer (116) and the first conductive layer (112) so as to only retain said second insulant and said conductive material in the region in which the first component will be produced, e) elimination of the first insulant layer (110) region located at the point where the second component will be produced, f) producing a third insulant layer (130) in said location, g) covering the structure obtained with a second conductive layer (114), h) producing the second (14) and third (28) gates by etching the second conductive layer (114) and i) producing the first gate (12) with the aid of a second etching of the second insulant layer (116) and the first conductive layer (112).
    • 1.工艺进行生产,在具有至少两个分开的电绝缘部件,第一部件(2)具有由第一(12)顶上的第一绝缘材料(10)和第二集成电路的半导体衬底(8)( 14)层叠栅,其通过由第三栅极(28顶上的第二绝缘材料(16),和一个第二部件(22)具有第三隔热材料(30)),所述第一(10分离),第二(16)和 第三(30)insulants具有不同的,明确定义的厚度,dadurch gekennzeichnet,DASS它包括以下阶段:a)制备(8),b)盖着与所述第一绝缘材料层(110)在所述衬底上的第一绝缘材料层(110) 第一导电层(112),其中所述第一栅极(12)将形成,c)将第一导电层(116)上的第二绝缘材料层(112)的形成,d)进行所述第二绝缘材料的第一蚀刻 层(116)和所述第一导电层(112),以便只保留所述第二绝缘材料和所述导电材料钓鱼 人,(在其中,所述第一组件将被产生,E的区域)位于其中,所述第二组件将被产生的点消除所述第一绝缘材料层(110)的区域中,f)产生第三绝缘材料层130)的所述位置 ,G)覆盖产生所述第二(14)和第三(28)门通过蚀刻所述第二导电层(114与第二导电层(114)获得的结构中,h))和i)的制造第一栅极(12)与 所述第二绝缘材料层(116)和所述第一导电层(112)的第二蚀刻的帮助。
    • 10. 发明专利
    • Preparation of a coating on a substrate, e.g. metal oxides on silicon-based substrates, involves chemical atomic layer deposition using a deuterated reactant
    • FR2810791A1
    • 2001-12-28
    • FR0007932
    • 2000-06-21
    • COMMISSARIAT ENERGIE ATOMIQUE
    • MARTIN FRANCOISMUR PIERREBARON THIERRY
    • C23C16/30C23C16/40C23C16/44C30B25/02H01L21/3205H01L21/324
    • A layer of at least one metal or a deuterated compound of at least one metal is deposited on a substrate by chemical atomic layer deposition (ALD) using at least a non-deuterated precursor of the metal or metal compound and a deuterated reagent, which, for a silicon substrate, avoids the growth of parasitic SiO2 under a layer of, e.g., a high-K dielectric metal oxide. Preferred Features: The substrate is selected from pure Si, SiGe, SiC, polycrystalline silicon and substrates having an ALD-deposited monolayer of a compound selected from MoSi2, MoGe2, MoSixNy, and MoGexNy, starting from deuterated reactants such as SiD4, GeD4 and ND3. The metal is selected from Hf, Zr, Ti, Nb, Mo, W, Ta, Al, Mg, Si and Ge. The metal compound is selected from oxides, nitrides, germanides, silicides and ternary compounds of the metal with Si, or Ge and N. The deuterated reactant is selected from heavy water (D2O), D2O2, ND3, SiD4 and GeD4. Deposition is carried out at 500 degrees C or lower, preferably 200-400 degrees C, and the coating can comprise a single layer or many layers. The deuterated compound of at least one metal is a deuterated oxide of a metal having higher electropositivity than Si, such as Al or Mg. Preferably, the deuterated oxide is a mixed oxide of Al or Mg and another metal having lower electropositivity than Mg, such as Hf, or it can be a high permittivity (High-K) oxide, and it is impermeable to hydrogen. The metal oxide can be selected from oxides of Al, Ti, Zr and Hf and oxides having greater permittivity than that of SiO2. A layer of metal selected from Mo, Ti, Ta and Nb can be deposited on the deuterated metal oxide layer by ALD using a chlorinated or brominated metal precursor and the deuterated reagent.