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1. 发明申请

WO2011038857A8 ALKOXYLATED GLYCEROL ACETALS AND THEIR DERIVATIVES 审中-公开
标题翻译：烷氧基甘氨酸及其衍生物
公开(公告)号：WO2011038857A8
公开(公告)日：2012-01-05
申请号：PCT/EP2010005825
申请日：2010-09-23
申请人： COGNIS IP MAN GMBH , FLEUTE-SCHLACHTER INGO , HELDT SANDRA , KEMPERS PETER , SCHOERKEN ULRICH , PAETZOLD ECKHARD , KRAGL UDO
发明人： FLEUTE-SCHLACHTER INGO , HELDT SANDRA , KEMPERS PETER , SCHOERKEN ULRICH , PAETZOLD ECKHARD , KRAGL UDO
IPC分类号： C07D317/18 , A01N35/02 , C07D319/06
CPC分类号： C07D317/18 , A01N43/28 , A01N43/32 , C07D319/06 , C08G65/2606 , C08G2650/44
摘要： Suggested are alkoxylated glycerol acetals according to formulae (Ia) and (Ib) in which R1 stands for a linear or branched, saturated or unsaturated and optionally substituted hydrocarbyl residue comprising 6 to 22 carbon atoms and O or 1 to 3 double bonds, a benzyl or furfuryl radical, R2 stands for hydrogen, an alkyl, alkenyl or hydroxyalkyl group having 6 to 22 carbon atoms or an acyl group having 6 to 22 carbon atoms and 0 or 1 to 3 double bonds, AO represents an ethylene oxide, an propylene oxide, an butylene oxide unit or their mixtures, and n stands for an integer of about 1 to about 100.
摘要翻译：建议根据式（Ia）和（Ib）的烷氧基化甘油缩醛，其中R 1表示直链或支链，饱和或不饱和和任选取代的包含6至22个碳原子和O或1至3个双键的烃基，苄基或糠基，R 2表示氢，具有6至22个碳原子的烷基，烯基或羟烷基或具有6至22个碳原子的酰基和0或1至3个双键，AO表示环氧乙烷，环氧丙烷，环氧丁烷单元或其混合物，n表示约1至约100的整数。

2. 发明申请

WO2011038857A3 ALKOXYLATED GLYCEROL ACETALS AND THEIR DERIVATIVES 审中-公开
标题翻译：烷氧基化甘油乙缩醛及其衍生物
公开(公告)号：WO2011038857A3
公开(公告)日：2011-08-25
申请号：PCT/EP2010005825
申请日：2010-09-23
申请人： COGNIS IP MAN GMBH , FLEUTE-SCHLACHTER INGO , HELDT SANDRA , KEMPERS PETER , SCHOERKEN ULRICH , PAETZOLD ECKHARD , KRAGL UDO
发明人： FLEUTE-SCHLACHTER INGO , HELDT SANDRA , KEMPERS PETER , SCHOERKEN ULRICH , PAETZOLD ECKHARD , KRAGL UDO
IPC分类号： C07D317/18 , A01N35/02 , C07D319/06
CPC分类号： C07D317/18 , A01N43/28 , A01N43/32 , C07D319/06 , C08G65/2606 , C08G2650/44
摘要： Suggested are alkoxylated glycerol acetals according to formulae (Ia) and (Ib) in which R1 stands for a linear or branched, saturated or unsaturated and optionally substituted hydrocarbyl residue comprising 6 to 22 carbon atoms and O or 1 to 3 double bonds, a benzyl or furfuryl radical, R2 stands for hydrogen, an alkyl, alkenyl or hydroxyalkyl group having 6 to 22 carbon atoms or an acyl group having 6 to 22 carbon atoms and 0 or 1 to 3 double bonds, AO represents an ethylene oxide, an propylene oxide, an butylene oxide unit or their mixtures, and n stands for an integer of about 1 to about 100.
摘要翻译：建议的是根据式（Ia）和（Ib）的烷氧基化甘油缩醛，其中R 1代表包含6至22个碳原子和0或1至3个双键的直链或支链，饱和或不饱和和任选取代的烃基残基，或糠基，R2代表氢，具有6-22个碳原子的烷基，烯基或羟烷基或具有6-22个碳原子和0或1-3个双键的酰基，AO代表环氧乙烷，环氧丙烷，环氧丁烷单元或它们的混合物，并且n代表约1至约100的整数。

3. 发明申请

WO2008003420A3 PROCESS FOR PRODUCTION OF FATTY ACIDS, FATTY ACID ESTERS AND STEROLESTERS FROM SOAPSTOCK 审中-公开
标题翻译：用于生产脂肪酸，脂肪酸酯和皂甙的脱水剂的方法
公开(公告)号：WO2008003420A3
公开(公告)日：2008-02-28
申请号：PCT/EP2007005663
申请日：2007-06-27
申请人： COGNIS IP MAN GMBH , KEMPERS PETER , SCHOERKEN ULRICH , WOLF THOMAS , SATO SETSUO , BUENO DE ALMEIDA WANDERSON , SILVA BIZZARRI PABLO , SHIGUERU ARAUJO ALEXSSANDER
发明人： KEMPERS PETER , SCHOERKEN ULRICH , WOLF THOMAS , SATO SETSUO , BUENO DE ALMEIDA WANDERSON , SILVA BIZZARRI PABLO , SHIGUERU ARAUJO ALEXSSANDER
IPC分类号： C11B13/02 , A23K1/16 , C11C3/10
CPC分类号： C11B13/02 , A23L33/11 , C10G2300/1011 , C11C1/045 , C11C1/10 , C11C3/003 , Y02E50/13 , Y02P30/20 , Y02W30/74
摘要： The invention relates to a first process for production of fatty acids directly from any soapstock generated in the alkali refining process comprising of a) adding a lipase directly to the alkaline soapstock to facilitate hydrolysis of mono-,di- and triglycerides without prior neutralisation b) neutralizing and splitting the soaps with strong acids until reaching pH 1-6, c) separating the fatty acid phase from the aqueous by settling and/or centrifugation. In a second embodiment a second process for production of fatty acids directly from any soapstock is subject of the invention. This process comprises i) neutralizing and splitting the soaps with strong acids until reaching pH 1-6 ii) adding a lipase to facilitate mono-/di-/triglyceride hydrolysis iii) separating the fatty acid phase from the aqueous by settling and / or centrifugation In a further subject matter the invention deals with the use of said fatty acids for enzymatic or chemical synthesis of C1 to C6 alcanol esters and / or for chemical dimerisation of the fatty acids. As a consequence the invention also refers to a process for obtaining sterolesters and/or fatty acid esters characterized in that the fatty acids obtained according to the processes for production of fatty acids directly from any soapstock as aforementioned described are a) esterified with C1 to C6 alkanol with a Lipase that is selective for fatty acids and does not transesterify the sterolesters b) the fatty acid esters are separated from the sterolesters by distillation The use of said sterolesters for animal feed, food, health foods and as pharmaceutical agent for lowering cholesterol and/or as precursor for steroid synthesis as well as the use of said fatty acid esters as solvent, for the production of fatty alcohols, as biofuel, and biodiesel, as plastisicer or for dimerization is also subject of the invention.
摘要翻译：本发明涉及直接从碱炼油工艺中产生的任何皂料生产脂肪酸的第一种方法，包括a）将脂肪酶直接加入到碱性皂脚中以促进单甘油酯，二甘油酯和甘油三酯的水解，而无需事先中和b）用强酸中和和分解肥皂直至达到pH1-6，c）通过沉降和/或离心将脂肪酸相与水分离。在第二个实施方案中，直接从任何皂脚生产脂肪酸的第二种方法是本发明的主题。该方法包括i）用强酸中和和分解肥皂直至达到pH 1-6，ii）加入脂肪酶以促进甘油一酯/甘油二酯/甘油三酯水解，iii）通过沉降和/或离心将脂肪酸相与水分离在另一主题中，本发明涉及所述脂肪酸用于酶促或化学合成C 1至C 6烷醇酯和/或用于化学二聚化脂肪酸的用途。因此，本发明还涉及用于获得胆固醇酯和/或脂肪酸酯的方法，其特征在于根据如前所述的任何皂料直接生产脂肪酸的方法获得的脂肪酸a）用C 1至C 6酯化链烷醇与对脂肪酸具有选择性且不使胆固醇酯交换酯基的脂肪酶反应b）通过蒸馏将脂肪酸酯与胆固醇酯分离所述胆固醇酯用于动物饲料，食品，保健食品和作为药物用于降低胆固醇和 /或作为类固醇合成的前体以及所述脂肪酸酯作为溶剂的用途，用于生产脂肪醇，生物燃料和生物柴油，作为增塑剂或用于二聚化也是本发明的主题。

4. 发明申请

WO2007017167A2 METHOD FOR THE CHEMOENZYMATIC PRODUCTION OF FATTY ACID ESTERS 审中-公开
标题翻译：方法脂肪酸酯的化学 - 酶法生产
公开(公告)号：WO2007017167A2
公开(公告)日：2007-02-15
申请号：PCT/EP2006007633
申请日：2006-08-02
申请人： COGNIS IP MAN GMBH , BOTH SABINE , SCHOERKEN ULRICH , MEYER CAROLIN
发明人： BOTH SABINE , SCHOERKEN ULRICH , MEYER CAROLIN
CPC分类号： B01J31/003 , B01J31/0225 , B01J31/08 , C12P7/62
摘要： Disclosed is a method for producing fatty acid esters, in which (a) fatty acids are treated with aqueous aliphatic alcohols having a boiling point ranging between 60 and 120 °C in the presence of esterases so as to obtain a pre-esterification product, (b) water and non-reacted alcohol are separated from the pre-esterification product, (c) the pre-esterification product is subjected to a second, chemically catalyzed esterification process, the same aliphatic alcohol being added as in step (a), and (d) the separated aqueous alcohol from step (c) is reused for the enzymatic pre-esterification process in stage (a).
摘要翻译：公开了一种用于脂肪酸酯的制备方法，其中（a）脂肪酸酯酶与具有含水脂肪醇的沸点60〜120℃之间，并由此产生一个Vorveresterungsprodukt，（b）从所述Vorveresterungsprodukt水和未反应的处理的存在醇相同的脂族醇的重复加入如在步骤下分离，（c）该Vorveresterungsprodukt（a）使经化学催化的第二酯化，和（d）步骤（c）的分离的含水醇为在步骤酶促预酯化（一）重新开始。

5. 发明申请

WO2012031933A3 DERIVATIZATION OF HYDROXYACETALS AND HYDROXYACETAL MIXTURES 审中-公开
标题翻译：衍生化hydroxyacetals和HYDROXYACETALGEMISCHEN的
公开(公告)号：WO2012031933A3
公开(公告)日：2012-06-14
申请号：PCT/EP2011064844
申请日：2011-08-29
申请人： COGNIS IP MAN GMBH , BELLER MATTHIAS , KRAGL UDO , SCHOERKEN ULRICH , PAETZOLD ECKHARD , JACKSTELL RALF
发明人： BELLER MATTHIAS , KRAGL UDO , SCHOERKEN ULRICH , PAETZOLD ECKHARD , JACKSTELL RALF
IPC分类号： C07D317/22 , C07D319/06
CPC分类号： C07D317/22 , C07D319/06
摘要： A method is described in which hydroxyacetals or hydroxyacetal mixtures are used for catalytic C-O-C linking reactions to form ethers, especially by telomerizing diene systems, wherein palladium-(0) complexes are used as catalysts, carbonylating olefins with rhodium-(0) complexes and reacting the same with the hydroxyacetals or hydroxyacetal mixtures, and dimerizing the hydroxyacetals or hydroxyacetal mixtures with ruthenium-(0) complexes while eliminating water. The method allows the carbon chain of the hydroxyacetal or hydroxyacetal mixture used to be extended by several C atoms, the calorific value of the products to be increased, and the evaporation temperature to be lowered. The products can be used as fuels, solvents, detergents, cosmetics, softeners, stabilizers, pharmaceuticals, fungicides and microbicides, flavors, intermediate products, and as additives in various fields of application.
摘要翻译：描述了从hydroxyacetals或Hydroxyacetalgemischen催化COC-键形成于醚形成反应，尤其是由二烯系统，其中，钯（0）配合物用作催化剂，烯烃与铑（0）配合物和羰基化的调聚反应开始的处理他们的与hydroxyacetals或共混物反应是还有hydroxyacetals的二聚化或 - 与钌的混合物（0）同时消除水络合物。该方法允许使用的羟基缩醛或的碳链的延伸 - 几个C原子的混合物，并增加了产品的热值的和在蒸发温度的降低。该产品可以用作燃料，溶剂，洗涤剂，化妆品，增塑剂，稳定剂，药物，杀真菌剂和杀微生物剂，香料物质，中间体和作为添加剂用于各种应用。

6. 发明申请

WO2009021641A2 LIPOPHILIC PREPARATIONS 审中-公开
标题翻译：亲脂性筹备工作
公开(公告)号：WO2009021641A2
公开(公告)日：2009-02-19
申请号：PCT/EP2008006338
申请日：2008-08-01
申请人： COGNIS IP MAN GMBH , GUTSCHE BERNHARD , SCHOERKEN ULRICH , WEISS ALBRECHT , FABRY BERND
发明人： GUTSCHE BERNHARD , SCHOERKEN ULRICH , WEISS ALBRECHT , FABRY BERND
IPC分类号： C12P7/64 , C11C3/00
CPC分类号： C12P7/6463 , C11C3/003
摘要： What are proposed are novel lipophilic preparations comprising (a) from 20 to 40% by weight of myristic acid or esters thereof, (b) from 20 to 40% by weight of palmitic acid or esters thereof, (c) from 0.1 to 5% by weight of aliphatic and/or cycloaliphatic hydrocarbons and (d) less than 20% by weight of carboxylic acids or esters thereof having 12 and fewer carbons in the acyl radical and (e) less than 20% by weight of carboxylic acids or esters thereof having 16 and more carbons in the acyl radical, with the proviso that all percentages add up to 100% by weight.
摘要翻译：含有（a）20至40重量％的肉豆蔻酸或其酯提出了新的亲脂性制剂，（b）中20至40重量％的棕榈酸或其酯，（C）0.1〜5重量脂肪的％和 /或脂环族烃，和（d）少于20个重量％的羧酸或具有12和酰基中更少的碳原子和（e）它们的酯低于20个重量％的羧酸或酰基含16个或更多的烃它们的酯，与条件是所有的百分比合计达100重量％。

7. 发明申请

WO2006077023A3 COMPOSITIONS WHICH CAN BE USED AS BIOFUEL 审中-公开
标题翻译：组合物的生物燃料
公开(公告)号：WO2006077023A3
公开(公告)日：2008-02-28
申请号：PCT/EP2006000121
申请日：2006-01-10
申请人： COGNIS IP MAN GMBH , SCHOERKEN ULRICH , MEYER CAROLIN , HOF MATTHIAS , COOBAN NIGEL , STUHLMANN DIANA
发明人： SCHOERKEN ULRICH , MEYER CAROLIN , HOF MATTHIAS , COOBAN NIGEL , STUHLMANN DIANA
IPC分类号： C11C3/00 , A23L27/00 , A23L27/60 , C07C69/003 , C10L1/10 , C12P7/64
CPC分类号： C12P7/62 , C10G2300/1003 , C10G2300/1014 , C10L1/026 , C10L1/18 , C10L1/1817 , C10L1/1826 , C10L1/19 , C10L1/191 , C11C3/003 , C12P7/649 , Y02E50/13 , Y02P30/20
摘要： The invention relates to a composition which contains an alkylester which is provided with an alkyl radical containing 1 - 8 carbon atoms and partial glycerides which have a glycerine content of free glycerine upto a maximum of 2 wt.% in relation to the total amount of the composition. The invention also relates to a first method for producing the inventive composition, wherein triglycerides are enzymatically reacted with an esterase in the presence of alcohols which are provided with a plurality of carbon atoms having 1 - 8 C atoms, said esterase being activated by adding alkaline salts. In an additional method, the esterases are immobilised and / or chemically modified. The invention further relates to a method, wherein the inventive composition is produced by chemical partial tranesterfication. The invention subsequently relates to a composition which can be obtained according to said method, in addition to the use of the inventive compositions as biodiesel or additives in fuel compositions.
摘要翻译：公开的是含有具有最大的2重量％的游离甘油与烷基基团含有1至8个碳的组合物的总量的原子和偏甘油酯甘油基于内容的烷基酯的组合物。另外，制造本发明的组合物的第一方法，提出了在其中甘油三酯的醇的存在下与多个1个碳原子的 - 与酯酶，这是通过加入碱性盐的激活酶反应8个碳原子。在另一种方法中，酯酶可以被固定和/或化学改性使用。此外，提出一种方法，其中本发明的组合物是通过化学Partialumesterung制备。此外该组合物可用由新方法和使用本发明组合物的生物柴油或作为燃料组合物的添加剂提出。

8. 发明专利

DE502008000886D1 Ein Gemisch enthaltend Fettsäureglyceride 未知
公开(公告)号：DE502008000886D1
公开(公告)日：2010-08-19
申请号：DE502008000886
申请日：2008-03-20
申请人： COGNIS IP MAN GMBH
发明人： SCHOERKEN ULRICH , KEMPERS PETER , SANDER ANDREAS , HORLACHER PETER
IPC分类号： C12P7/64 , A23L1/30 , A23L33/00 , C07C69/587 , C11C1/04

9. 发明专利

BRPI0606422A2 未知
公开(公告)号：BRPI0606422A2
公开(公告)日：2009-06-30
申请号：BRPI0606422
申请日：2006-01-10
申请人： COGNIS IP MAN GMBH
发明人： SCHOERKEN ULRICH , HOF MATTHIAS , COOBAN NIGEL , MEYER CAROLIN , STUHLMANN DIANA
IPC分类号： C11C3/00 , A23L27/00 , A23L27/60 , C07C69/003 , C10L1/10 , C12P7/64
摘要： A composition comprising alkyl esters, with a C1-C8 alkyl group, and partial glycerides, with a free glycerol content of, at most, 2%, by weight, based on the weight of the composition, derived in an enzymatically-catalyzed reaction from saturated or unsaturated, straight or branched C8-C22 fatty acids of vegetable oils, and useful, inter alia, in biofuels, such as biodiesel, and as an additive for improving the lubricating performance of fuel compositions.

10. 发明专利

CA2595235C PRODUCTION AND USE OF MONOGLYCERIDES 未知
公开(公告)号：CA2595235C
公开(公告)日：2014-12-30
申请号：CA2595235
申请日：2006-01-10
申请人： COGNIS IP MAN GMBH
发明人： SCHOERKEN ULRICH , BOTH SABINE , BONGARDT FRANK , STUHLMANN DIANA
IPC分类号： C12P7/64 , A61Q90/00
摘要： The invention relates to a method which is used to produce monoglycerides, wherein triglycerides are enzymatically reacted with an esterase in the presence of alcohols provided with a plurality of carbon atoms having 1 - 8 C-atoms, said esterase being activated by adding alkaline salts. The invention also relates to the use of said monoglycerides which are produced according to said method and which are separated or can be used as a mixture with the reaction components as lubricating additives, as an additive for fuel or as emulsifying components in food, cosmetic and/or pharmaceutical formulations.

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