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    • 3. 发明申请
    • PROCESS FOR PRODUCTION OF FATTY ACIDS, FATTY ACID ESTERS AND STEROLESTERS FROM SOAPSTOCK
    • 用于生产脂肪酸,脂肪酸酯和皂甙的脱水剂的方法
    • WO2008003420A3
    • 2008-02-28
    • PCT/EP2007005663
    • 2007-06-27
    • COGNIS IP MAN GMBHKEMPERS PETERSCHOERKEN ULRICHWOLF THOMASSATO SETSUOBUENO DE ALMEIDA WANDERSONSILVA BIZZARRI PABLOSHIGUERU ARAUJO ALEXSSANDER
    • KEMPERS PETERSCHOERKEN ULRICHWOLF THOMASSATO SETSUOBUENO DE ALMEIDA WANDERSONSILVA BIZZARRI PABLOSHIGUERU ARAUJO ALEXSSANDER
    • C11B13/02A23K1/16C11C3/10
    • C11B13/02A23L33/11C10G2300/1011C11C1/045C11C1/10C11C3/003Y02E50/13Y02P30/20Y02W30/74
    • The invention relates to a first process for production of fatty acids directly from any soapstock generated in the alkali refining process comprising of a) adding a lipase directly to the alkaline soapstock to facilitate hydrolysis of mono-,di- and triglycerides without prior neutralisation b) neutralizing and splitting the soaps with strong acids until reaching pH 1-6, c) separating the fatty acid phase from the aqueous by settling and/or centrifugation. In a second embodiment a second process for production of fatty acids directly from any soapstock is subject of the invention. This process comprises i) neutralizing and splitting the soaps with strong acids until reaching pH 1-6 ii) adding a lipase to facilitate mono-/di-/triglyceride hydrolysis iii) separating the fatty acid phase from the aqueous by settling and / or centrifugation In a further subject matter the invention deals with the use of said fatty acids for enzymatic or chemical synthesis of C1 to C6 alcanol esters and / or for chemical dimerisation of the fatty acids. As a consequence the invention also refers to a process for obtaining sterolesters and/or fatty acid esters characterized in that the fatty acids obtained according to the processes for production of fatty acids directly from any soapstock as aforementioned described are a) esterified with C1 to C6 alkanol with a Lipase that is selective for fatty acids and does not transesterify the sterolesters b) the fatty acid esters are separated from the sterolesters by distillation The use of said sterolesters for animal feed, food, health foods and as pharmaceutical agent for lowering cholesterol and/or as precursor for steroid synthesis as well as the use of said fatty acid esters as solvent, for the production of fatty alcohols, as biofuel, and biodiesel, as plastisicer or for dimerization is also subject of the invention.
    • 本发明涉及直接从碱炼油工艺中产生的任何皂料生产脂肪酸的第一种方法,包括a)将脂肪酶直接加入到碱性皂脚中以促进单甘油酯,二甘油酯和甘油三酯的水解,而无需事先中和b) 用强酸中和和分解肥皂直至达到pH1-6,c)通过沉降和/或离心将脂肪酸相与水分离。 在第二个实施方案中,直接从任何皂脚生产脂肪酸的第二种方法是本发明的主题。 该方法包括i)用强酸中和和分解肥皂直至达到pH 1-6,ii)加入脂肪酶以促进甘油一酯/甘油二酯/甘油三酯水解,iii)通过沉降和/或离心将脂肪酸相与水分离 在另一主题中,本发明涉及所述脂肪酸用于酶促或化学合成C 1至C 6烷醇酯和/或用于化学二聚化脂肪酸的用途。 因此,本发明还涉及用于获得胆固醇酯和/或脂肪酸酯的方法,其特征在于根据如前所述的任何皂料直接生产脂肪酸的方法获得的脂肪酸a)用C 1至C 6酯化 链烷醇与对脂肪酸具有选择性且不使胆固醇酯交换酯基的脂肪酶反应b)通过蒸馏将脂肪酸酯与胆固醇酯分离所述胆固醇酯用于动物饲料,食品,保健食品和作为药物用于降低胆固醇和 /或作为类固醇合成的前体以及所述脂肪酸酯作为溶剂的用途,用于生产脂肪醇,生物燃料和生物柴油,作为增塑剂或用于二聚化也是本发明的主题。
    • 4. 发明申请
    • USE OF FATTY ALCOHOLS AS PLASTICIZER TO IMPROVE THE PHYSICAL-MECHANICAL PROPERTIES AND PROCESSABILITY OF PHB AND ITS CO-POLYMERS
    • 使用脂肪醇作为增塑剂,以提高PHB及其共聚物的物理机械性能和可加工性
    • WO2006012917A1
    • 2006-02-09
    • PCT/EP2004/008874
    • 2004-08-06
    • COGNIS BRASIL LTDA.PHB INDUSTRIAL S/ACOGNIS DEUTSCHLAND GMBH & CO. KGBUENO DE ALMEIDA, WandersonSILVA BIZZARRI, PabloSERTORI DURAO, AntônioDO NASCIMENTI, Jefter, Fernandes
    • BUENO DE ALMEIDA, WandersonSILVA BIZZARRI, PabloSERTORI DURAO, AntônioDO NASCIMENTI, Jefter, Fernandes
    • C12P7/62
    • C08K5/05C08K5/10C08L67/04
    • The invention relates a plasticized polymeric composition comprising (i) PHB with the pro­viso that the PHB and its co-polymers of PHB are produced by a bio-polymer extraction proc­ess, characterized by the fact that the concentrated cellular material, previously dried or not, is mixed to an adequate solvent, specifically superior alcohol, preferably with a chain with more than 3 carbon atoms, or any other of its acetates, preferably the isoamyl alcohol, amyl acetate, isoamyl acetate or the fusel oil as described by the Brazilian Patent PI 9302312-0 published in 04/30/2002 (ii) a) Fatty alcohols of chain length from 6 to 30 carbon (C6-C30) with the proviso that the fatty alcohols can be saturated or olefinically unsaturated linear or branched and b) glycerol esters of fatty acids with 6 to 24 carbon atoms with the proviso that the fatty acids can be saturated or olefinically unsaturated, linear or branched and optional (iii) additives with the proviso that the additives are composed by thermal stabilization system, constituted by: primary antioxidant as Phenol hindered; secondary antioxidant as organic phosphites; thermal stabilizers as lactone; sorbitol and sodium benzoate as nucleants and starch, wood powder, cane bagasse fibers, rice pod fibers and sisal fibers as fillers.
    • 本发明涉及增塑的聚合物组合物,其包含(i)PHB,条件是PHB及其PHB的共聚物通过生物聚合物提取方法生产,其特征在于先前干燥或未干燥的浓缩的细胞材料, 混合到足够的溶剂,特别优选的醇,优选具有多于3个碳原子的链,或其任何其它乙酸酯,优选异戊醇,乙酸戊酯,乙酸异戊酯或杂醇油,如巴西专利PI 9302312-0发表于04/30/2002(ii)a)链长为6至30碳(C6-C30)的脂肪醇,条件是脂肪醇可以是饱和的或烯属不饱和的直链或支链和b)甘油 具有6至24个碳原子的脂肪酸的酯,条件是脂肪酸可以是饱和或烯属不饱和的,直链或支链的和任选的(iii)添加剂,条件是添加剂组成 由热稳定系统构成:主要抗氧化剂作为苯酚受阻; 二次抗氧化作为有机亚磷酸盐; 热稳定剂为内酯; 山梨醇和苯甲酸钠作为成核剂和淀粉,木粉,甘蔗渣纤维,稻荚纤维和剑麻纤维作为填料。
    • 6. 发明申请
    • PROCESS FOR PRODUCTION OF FATTY ACIDS, FATTY ACID ESTERS AND STEROLESTERS FROM SOAPSTOCK
    • 生产脂肪酸,脂肪酸酯和甾醇酯的方法
    • WO2008003420A2
    • 2008-01-10
    • PCT/EP2007/005663
    • 2007-06-27
    • COGNIS IP MANAGEMENT GMBHKEMPERS, PeterSCHÖRKEN, UlrichWOLF, ThomasSATO, SetsuoBUENO DE ALMEIDA, WandersonSILVA BIZZARRI, PabloSHIGUERU ARAUJO, Alexssander
    • KEMPERS, PeterSCHÖRKEN, UlrichWOLF, ThomasSATO, SetsuoBUENO DE ALMEIDA, WandersonSILVA BIZZARRI, PabloSHIGUERU ARAUJO, Alexssander
    • C11B13/02A23K1/16C11C3/10
    • C11B13/02A23L33/11C10G2300/1011C11C1/045C11C1/10C11C3/003Y02E50/13Y02P30/20Y02W30/74
    • The invention relates to a first process for production of fatty acids directly from any soapstock generated in the alkali refining process comprising of a) adding a lipase directly to the alkaline soapstock to facilitate hydrolysis of mono-,di- and triglycerides without prior neutralisation b) neutralizing and splitting the soaps with strong acids until reaching pH 1-6, c) separating the fatty acid phase from the aqueous by settling and/or centrifugation. In a second embodiment a second process for production of fatty acids directly from any soapstock is subject of the invention. This process comprises i) neutralizing and splitting the soaps with strong acids until reaching pH 1-6 ii) adding a lipase to facilitate mono-/di-/triglyceride hydrolysis iii) separating the fatty acid phase from the aqueous by settling and / or centrifugation In a further subject matter the invention deals with the use of said fatty acids for enzymatic or chemical synthesis of C1 to C6 alcanol esters and / or for chemical dimerisation of the fatty acids. As a consequence the invention also refers to a process for obtaining sterolesters and/or fatty acid esters characterized in that the fatty acids obtained according to the processes for production of fatty acids directly from any soapstock as aforementioned described are a) esterified with C1 to C6 alkanol with a Lipase that is selective for fatty acids and does not transesterify the sterolesters b) the fatty acid esters are separated from the sterolesters by distillation The use of said sterolesters for animal feed, food, health foods and as pharmaceutical agent for lowering cholesterol and/or as precursor for steroid synthesis as well as the use of said fatty acid esters as solvent, for the production of fatty alcohols, as biofuel, and biodiesel, as plastisicer or for dimerization is also subject of the invention.
    • 本发明涉及直接从碱精制方法中生产的任何皂液生产脂肪酸的第一种方法,包括:a)直接向碱性皂料中加入脂肪酶,以促进甘油单酯,甘油二酯和甘油三酯的水解,而无需预先中和b) 用强酸中和和分解肥皂直至pH达到1-6,c)通过沉降和/或离心将脂肪酸相与水相分离。 在第二个实施方案中,直接从任何皂片生产脂肪酸的第二种方法是本发明的主题。 该方法包括:i)用强酸中和并分离肥皂直到达到pH 1-6 ii)加入脂肪酶以促进单 - /二 - /甘油三酯水解iii)通过沉降和/或离心将脂肪酸相与水相分离 在另一主题中,本发明涉及所述脂肪酸用于C1至C6烷醇酯的酶或化学合成和/或用于脂肪酸的化学二聚化的用途。 因此,本发明还涉及一种获得甾体和/或脂肪酸酯的方法,其特征在于根据如上所述直接从任何皂片生产脂肪酸的方法获得的脂肪酸是a)用C1至C6酯化 链烷醇具有对脂肪酸选择性且不酯交换酯基的脂肪酶b)脂肪酸酯通过蒸馏与甾体分离使用所述甾体为动物饲料,食品,保健食品和用作降低胆固醇的药剂, /或作为类固醇合成的前体以及使用所述脂肪酸酯作为溶剂,用于生产作为生物燃料的脂肪醇和作为增塑剂的生物柴油或二聚体也是本发明的主题。