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    • 6. 发明申请
    • USE OF METAL COMPLEX COMPOUNDS AS OXIDATION CATALYSTS
    • 使用金属复合化合物作为氧化催化剂
    • WO2004007657A1
    • 2004-01-22
    • PCT/EP2003/007121
    • 2003-07-03
    • CIBA SPECIALTY CHEMICALS HOLDING INC.SCHLINGLOFF, GuntherWIEPRECHT, TorstenBACHMANN, FrankDANNACHER, JosefDUBS, Marie-JoséeHAZENKAMP, MennoHEINZ, UweFREY, MarkusSCHNEIDER, Albert
    • SCHLINGLOFF, GuntherWIEPRECHT, TorstenBACHMANN, FrankDANNACHER, JosefDUBS, Marie-JoséeHAZENKAMP, MennoHEINZ, UweFREY, MarkusSCHNEIDER, Albert
    • C11D3/395
    • C11D3/168C07D213/68C07D213/74C11D3/3932
    • Use of metal complex compounds of formula (1) [L n Me m X p ] z Y q wherein Me is manganese, titanium, iron, cobalt, nickel or copper, X is a coordinating or bridging radical, n and m are each independently of the other an integer having a value of from 1 to 8, p is an integer having a value of from 0 to 32, z is the charge of the metal complex, Y is a counter-ion, q = z/(charge Y), and L is a ligand of formula (2) wherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , R 10 and R 11 are each independently of the others hydrogen; unsubstituted or substituted C 1 -C 18 alkyl or aryl; cyano; halogen; nitro; -COOR 12 or -SO 3 R 12 wherein R 12 is in each case hydrogen, a cation or unsubstituted or substituted C 1 -C 18 alkyl or aryl; -SR 13 , -SO 12 R 13 or -OR 13 wherein R 13 is in each case hydrogen or unsubstituted or substituted C 1 -C 18 alkyl or aryl; -NR 14 R 15 ; -(C 1 -C 6 alkylene)-NR 14 R 15 ; -N o R 14 R 15 R 16 ; -(C 1 -C 6 alkylene)-N o R 14 R 15 R 16 ; -N(R 13 )-(C 1 -C 6 alkylene)-NR 14 R 15 ; -N[(C 1 -C 6 alkylene)-NR 14 R 15 ] 2 ; -N(R 13 )-(C 1 -C 6 alkylene)-N o R 14 R 15 R 16 , -N[C 1 -C 6 alkylene)-N o R 14 R 15 R 16 ] 2 ; -N(R 13 )-N-R 14 R 15 or -N(R 13 )-N o R 14 R 15 R 16 , wherein R 13 is as defined above and R 14 , R 15 and R 16 are each independently of the other(s) hydrogen or unsubstituted or substituted C 1 -C 18 alkyl or aryl, or R 14 and R 15 together with the nitrogen atom bonding them form an unsubstituted or substituted 5-, 6- or 7-membered ring which may optionally contain further heteroatoms; with the proviso that (i) at least one of the substituents R 1 -R 11 contains a quaternized atom which is not directly bonded to one of the three pyridine A, B or C and that (ii) Y is neither I' nor CI' in the case that Me is Mn(II), R 1 -R 5 and R 7 -R 11 are hydrogen and R 6 is formula (III) as catalysts for oxidation reactions, and the novel metal complex compounds of formula (1), the novel ligands of formula (2) and their starting materials.
    • 使用式(1)的金属络合物[LnMemXp] zq其中Me是锰,钛,铁,钴,镍或铜,X是配位或桥键基团,n和m各自独立地为 整数值为1〜8,p为0〜32的整数,z为金属络合物的电荷,Y为抗衡离子,q = z /(电荷Y),L为 是式(2)的配体,其中R 1,R 2,R 3,R 4,R 5,R 6,R 7,R 8,R 9,R 10和R 11各自独立地为氢; 未取代或取代的C 1 -C 18烷基或芳基; 氰基; 卤素; 硝基; -COOR 12或-SO 3 R 12,其中R 12在各种情况下为氢,阳离子或未取代或取代的C 1 -C 18烷基或芳基; -SR 13,-SO 12 R 13或-OR 13,其中R 13各自为氢或未取代或取代的C 1 -C 18烷基或芳基; -NR14R15; - (C 1 -C 6亚烷基)-NR 14 R 15; -N R14R15R16; - (C 1 -C 6亚烷基)-N R14R15R16; -N(R13) - (C 1 -C 6亚烷基)-NR 14 R 15; -N [(C1-C6亚烷基)-NR 14 R 15] 2; -N(R 13) - (C 1 -C 6亚烷基)-N 14 R 15 R 16,-N [C 1 -C 6亚烷基)-N R 14 R 15 R 16] 2; -N(R 13)-N-R 14 R 15或-N(R 13)-N R 14 R 15 R 16,其中R 13如上所定义,R 14,R 15和R 16各自独立地为氢或未取代或取代的C1- C 18烷基或芳基,或R 14和R 15与与它们键合的氮原子一起形成未取代或取代的5-,6-或7-元环,其可以任选地含有其它杂原子; 条件是(i)至少一个取代基R 1 -R 11含有不直接与三个吡啶A,B或C中的一个键合的季铵化原子,并且(ii)Y不是I'和Cl' Me是Mn(II),R1-R5和R7-R11是氢的情况,R6是作为氧化反应的催化剂的式(III),式(1)的新型金属络合物,式 2)及其起始材料。
    • 8. 发明授权
    • USE OF METAL COMPLEX COMPOUNDS AS OXIDATION CATALYSTS
    • 金属络合物作为氧化催化剂使用
    • EP1521820B1
    • 2006-03-22
    • EP03763699.0
    • 2003-07-03
    • Ciba Specialty Chemicals Holding Inc.
    • SCHLINGLOFF, GuntherWIEPRECHT, TorstenBACHMANN, FrankDANNACHER, JosefDUBS, Marie-JoséeHAZENKAMP, MennoHEINZ, UweFREY, MarkusSCHNEIDER, Albert
    • C11D3/395C11D3/16C07D213/68C07D213/74C11D3/39
    • C11D3/168C07D213/68C07D213/74C11D3/3932
    • Use of metal complex compounds of formula (1) [LnMemXp]zYq wherein Me is manganese, titanium, iron, cobalt, nickel or copper, X is a coordinating or bridging radical, n and m are each independently of the other an integer having a value of from 1 to 8, p is an integer having a value of from 0 to 32, z is the charge of the metal complex, Y is a counter-ion, q = z/(charge Y), and L is a ligand of formula (2) wherein R1, R2, R3, R4, R5, R6, R7, R8, R9, R10 and R11 are each independently of the others hydrogen; unsubstituted or substituted C1-C18alkyl or aryl; cyano; halogen; nitro; -COOR12 or -SO3R12 wherein R12 is in each case hydrogen, a cation or unsubstituted or substituted C1-C18alkyl or aryl; -SR13, -SO12R13 or -OR13 wherein R13 is in each case hydrogen or unsubstituted or substituted C1-C18alkyl or aryl; -NR14R15; -(C1-C6alkylene)-NR14R15; -NoR14R15R16; -(C1-C6alkylene)-NoR14R15R16; -N(R13)-(C1-C6alkylene)-NR14R15; -N[(C1-C6alkylene)-NR14R15]2; -N(R13)-(C1-C6alkylene)-NoR14R15R16, -N[C1-C6alkylene)-NoR14R15R16]2; -N(R13)-N-R14R15 or -N(R13)-NoR14R15R16, wherein R13 is as defined above and R14, R15 and R16 are each independently of the other(s) hydrogen or unsubstituted or substituted C1-C18alkyl or aryl, or R14 and R15 together with the nitrogen atom bonding them form an unsubstituted or substituted 5-, 6- or 7-membered ring which may optionally contain further heteroatoms; with the proviso that (i) at least one of the substituents R1-R11 contains a quaternized atom which is not directly bonded to one of the three pyridine A, B or C and that (ii) Y is neither I' nor CI' in the case that Me is Mn(II), R1-R5 and R7-R11 are hydrogen and R6 is formula (III) as catalysts for oxidation reactions, and the novel metal complex compounds of formula (1), the novel ligands of formula (2) and their starting materials.
    • 9. 发明公开
    • USE OF METAL COMPLEX COMPOUNDS AS OXIDATION CATALYSTS
    • 金属络合物作为氧化催化剂使用
    • EP1521820A1
    • 2005-04-13
    • EP03763699.0
    • 2003-07-03
    • Ciba Specialty Chemicals Holding Inc.
    • SCHLINGLOFF, GuntherWIEPRECHT, TorstenBACHMANN, FrankDANNACHER, JosefDUBS, Marie-JoséeHAZENKAMP, MennoHEINZ, UweFREY, MarkusSCHNEIDER, Albert
    • C11D3/395C11D3/16C07D213/68C07D213/74C11D3/39
    • C11D3/168C07D213/68C07D213/74C11D3/3932
    • Use of metal complex compounds of formula (1) [LnMemXp]zYq wherein Me is manganese, titanium, iron, cobalt, nickel or copper, X is a coordinating or bridging radical, n and m are each independently of the other an integer having a value of from 1 to 8, p is an integer having a value of from 0 to 32, z is the charge of the metal complex, Y is a counter-ion, q = z/(charge Y), and L is a ligand of formula (2) wherein R1, R2, R3, R4, R5, R6, R7, R8, R9, R10 and R11 are each independently of the others hydrogen; unsubstituted or substituted C1-C18alkyl or aryl; cyano; halogen; nitro; -COOR12 or -SO3R12 wherein R12 is in each case hydrogen, a cation or unsubstituted or substituted C1-C18alkyl or aryl; -SR13, -SO12R13 or -OR13 wherein R13 is in each case hydrogen or unsubstituted or substituted C1-C18alkyl or aryl; -NR14R15; -(C1-C6alkylene)-NR14R15; -NoR14R15R16; -(C1-C6alkylene)-NoR14R15R16; -N(R13)-(C1-C6alkylene)-NR14R15; -N[(C1-C6alkylene)-NR14R15]2; -N(R13)-(C1-C6alkylene)-NoR14R15R16, -N[C1-C6alkylene)-NoR14R15R16]2; -N(R13)-N-R14R15 or -N(R13)-NoR14R15R16, wherein R13 is as defined above and R14, R15 and R16 are each independently of the other(s) hydrogen or unsubstituted or substituted C1-C18alkyl or aryl, or R14 and R15 together with the nitrogen atom bonding them form an unsubstituted or substituted 5-, 6- or 7-membered ring which may optionally contain further heteroatoms; with the proviso that (i) at least one of the substituents R1-R11 contains a quaternized atom which is not directly bonded to one of the three pyridine A, B or C and that (ii) Y is neither I' nor CI' in the case that Me is Mn(II), R1-R5 and R7-R11 are hydrogen and R6 is formula (III) as catalysts for oxidation reactions, and the novel metal complex compounds of formula (1), the novel ligands of formula (2) and their starting materials.