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1. 发明申请

WO2004007657A1 USE OF METAL COMPLEX COMPOUNDS AS OXIDATION CATALYSTS 审中-公开
标题翻译：使用金属复合化合物作为氧化催化剂
公开(公告)号：WO2004007657A1
公开(公告)日：2004-01-22
申请号：PCT/EP2003/007121
申请日：2003-07-03
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , SCHLINGLOFF, Gunther , WIEPRECHT, Torsten , BACHMANN, Frank , DANNACHER, Josef , DUBS, Marie-Josée , HAZENKAMP, Menno , HEINZ, Uwe , FREY, Markus , SCHNEIDER, Albert
发明人： SCHLINGLOFF, Gunther , WIEPRECHT, Torsten , BACHMANN, Frank , DANNACHER, Josef , DUBS, Marie-Josée , HAZENKAMP, Menno , HEINZ, Uwe , FREY, Markus , SCHNEIDER, Albert
IPC分类号： C11D3/395
CPC分类号： C11D3/168 , C07D213/68 , C07D213/74 , C11D3/3932
摘要： Use of metal complex compounds of formula (1) [L n Me m X p ] z Y q wherein Me is manganese, titanium, iron, cobalt, nickel or copper, X is a coordinating or bridging radical, n and m are each independently of the other an integer having a value of from 1 to 8, p is an integer having a value of from 0 to 32, z is the charge of the metal complex, Y is a counter-ion, q = z/(charge Y), and L is a ligand of formula (2) wherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , R 10 and R 11 are each independently of the others hydrogen; unsubstituted or substituted C 1 -C 18 alkyl or aryl; cyano; halogen; nitro; -COOR 12 or -SO 3 R 12 wherein R 12 is in each case hydrogen, a cation or unsubstituted or substituted C 1 -C 18 alkyl or aryl; -SR 13 , -SO 12 R 13 or -OR 13 wherein R 13 is in each case hydrogen or unsubstituted or substituted C 1 -C 18 alkyl or aryl; -NR 14 R 15 ; -(C 1 -C 6 alkylene)-NR 14 R 15 ; -N o R 14 R 15 R 16 ; -(C 1 -C 6 alkylene)-N o R 14 R 15 R 16 ; -N(R 13 )-(C 1 -C 6 alkylene)-NR 14 R 15 ; -N[(C 1 -C 6 alkylene)-NR 14 R 15 ] 2 ; -N(R 13 )-(C 1 -C 6 alkylene)-N o R 14 R 15 R 16 , -N[C 1 -C 6 alkylene)-N o R 14 R 15 R 16 ] 2 ; -N(R 13 )-N-R 14 R 15 or -N(R 13 )-N o R 14 R 15 R 16 , wherein R 13 is as defined above and R 14 , R 15 and R 16 are each independently of the other(s) hydrogen or unsubstituted or substituted C 1 -C 18 alkyl or aryl, or R 14 and R 15 together with the nitrogen atom bonding them form an unsubstituted or substituted 5-, 6- or 7-membered ring which may optionally contain further heteroatoms; with the proviso that (i) at least one of the substituents R 1 -R 11 contains a quaternized atom which is not directly bonded to one of the three pyridine A, B or C and that (ii) Y is neither I' nor CI' in the case that Me is Mn(II), R 1 -R 5 and R 7 -R 11 are hydrogen and R 6 is formula (III) as catalysts for oxidation reactions, and the novel metal complex compounds of formula (1), the novel ligands of formula (2) and their starting materials.
摘要翻译：使用式（1）的金属络合物[LnMemXp] zq其中Me是锰，钛，铁，钴，镍或铜，X是配位或桥键基团，n和m各自独立地为整数值为1〜8，p为0〜32的整数，z为金属络合物的电荷，Y为抗衡离子，q = z /（电荷Y），L为是式（2）的配体，其中R 1，R 2，R 3，R 4，R 5，R 6，R 7，R 8，R 9，R 10和R 11各自独立地为氢; 未取代或取代的C 1 -C 18烷基或芳基; 氰基; 卤素; 硝基; -COOR 12或-SO 3 R 12，其中R 12在各种情况下为氢，阳离子或未取代或取代的C 1 -C 18烷基或芳基; -SR 13，-SO 12 R 13或-OR 13，其中R 13各自为氢或未取代或取代的C 1 -C 18烷基或芳基; -NR14R15; - （C 1 -C 6亚烷基）-NR 14 R 15; -N R14R15R16; - （C 1 -C 6亚烷基）-N R14R15R16; -N（R13） - （C 1 -C 6亚烷基）-NR 14 R 15; -N [（C1-C6亚烷基）-NR 14 R 15] 2; -N（R 13） - （C 1 -C 6亚烷基）-N 14 R 15 R 16，-N [C 1 -C 6亚烷基）-N R 14 R 15 R 16] 2; -N（R 13）-N-R 14 R 15或-N（R 13）-N R 14 R 15 R 16，其中R 13如上所定义，R 14，R 15和R 16各自独立地为氢或未取代或取代的C1- C 18烷基或芳基，或R 14和R 15与与它们键合的氮原子一起形成未取代或取代的5-，6-或7-元环，其可以任选地含有其它杂原子; 条件是（i）至少一个取代基R 1 -R 11含有不直接与三个吡啶A，B或C中的一个键合的季铵化原子，并且（ii）Y不是I'和Cl' Me是Mn（II），R1-R5和R7-R11是氢的情况，R6是作为氧化反应的催化剂的式（III），式（1）的新型金属络合物，式 2）及其起始材料。

2. 发明申请

WO2002088289A2 USE OF METAL COMPLEX COMPOUNDS AS OXIDATION CATALYSTS 审中-公开
标题翻译：使用金属复合化合物作为氧化催化剂
公开(公告)号：WO2002088289A2
公开(公告)日：2002-11-07
申请号：PCT/EP2002/004572
申请日：2002-04-25
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , SCHLINGLOFF, Gunther , WIEPRECHT, Torsten , BACHMANN, Frank , DANNACHER, Joseph , DUBS, Marie-Josée , HAZENKAMP, Menno , RICHTER, Grit , SCHMIDT, Brigitte , SCHNEIDER, Albert , WEINGARTNER, Peter
发明人： SCHLINGLOFF, Gunther , WIEPRECHT, Torsten , BACHMANN, Frank , DANNACHER, Joseph , DUBS, Marie-Josée , HAZENKAMP, Menno , RICHTER, Grit , SCHMIDT, Brigitte , SCHNEIDER, Albert , WEINGARTNER, Peter
IPC分类号： C11D3/39
CPC分类号： B01J31/1815 , B01J23/34 , B01J2231/70 , B01J2231/72 , B01J2531/16 , B01J2531/46 , B01J2531/72 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C07D213/61 , C07D213/68 , C07D213/74 , C07F13/005 , C11D3/3932 , D06L4/10 , D06L4/12 , D06P5/02 , D06P5/153 , D21C9/1036 , D21C9/163
摘要： Use of metal complex compounds of formula (1): [L n Me m X p ] z Y q wherein Me is manganese, titanium, iron, cobalt, nickel or copper, X is a coordinating or bridging radical, n and m are each independently of the other an integer having a value of from 1 to 8, p is an integer having a value of from 0 to 32, z is the charge of the metal complex, y is a counter-ion, q=z/(charge Y), and L is a ligand of formula (2) wherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , R 10 and R 11 are each independently of the others hydrogen; unsubstituted or substituted C 1 -C 18 alkyl or aryl; cyano; halogen; nitro; -COOR 12 or -SO 3 R 12 wherein R 12 is in each case hydrogen, a cation or unsubstituted or substituted C 1 -C 18 alkyl or aryl; -SR 13 , -SO 2 R 13 or -OR 13 wherein R 13 is in each case hydrogen or unsubstituted or substituted C 1 -C 18 alkyl or aryl;-N(R 13 )-NR' 13 R" 13 wherein R 13 , R' 13 and R" 13 are as defined above for R 13 ; -NR 14 R 15 or -N + R 14 R 15 R 16 wherein R 14 , R 15 and R 16 are each independently of the other(s) hydrogen or unsubstituted or substituted C 1 -C 18 alkyl or aryl, or R 14 and R 15 together with the nitrogen atom bonding them form an unsubstituted or substituted 5-, 6- or 7-membered ring which may optionally contain further hetero atoms; with the proviso that R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , R 10 , and R 11 are not simultaneously hydrogen, as catalysts for oxidation reactions, and the novel metal complex compounds of formula (1) and the novel ligands of formula (2).
摘要翻译：使用式（1）的金属络合物：其中Me是锰，钛，铁，钴，镍或铜，X是配位或桥接基团，n和m各自独立地为具有1至8的整数，p为0至32的整数，z为金属络合物的电荷，y为抗衡离子，q = z /（电荷Y），L是式（2）的配体，其中R 1，R 2，R 3，R 4，R 5，R 6，R 7，R 8，R 9，R 10和R 11各自独立地为氢; 未取代或取代的C 1 -C 18烷基或芳基; 氰基; 卤素; 硝基; -COOR 12或-SO 3 R 12，其中R 12在各种情况下为氢，阳离子或未取代或取代的C 1 -C 18烷基或芳基; -SR 13，-SO 2 R 13或-OR 13，其中R 13各自为氢或未取代或取代的C 1 -C 18烷基或芳基; -N（R 13）-NR 13 R 13，其中R 13，R 13和R 13如上定义对于R13; -NR14R15或-N + R14R15R16，其中R14，R15和R16各自独立地为氢或未取代或取代的C1-C18烷基或芳基，或者R14和R15与键合氮原子一起形成未取代或未取代的取代的5-，6-或7-元环，其可以任选地含有另外的杂原子; 条件是R 1，R 2，R 3，R 4，R 5，R 6，R 7，R 8，R 9，R 10和R 11不同时为氢，作为氧化反应的催化剂，并且新的式（1）金属络合物和式（2）的新配体。

3. 发明申请

WO2004039934A1 USE OF METAL COMPLEX COMPOUNDS AS OXIDATION CATALYSTS 审中-公开
标题翻译：使用金属复合化合物作为氧化催化剂
公开(公告)号：WO2004039934A1
公开(公告)日：2004-05-13
申请号：PCT/EP2003/011636
申请日：2003-10-21
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , SCHLINGLOFF, Gunther , WIEPRECHT, Torsten , HEINZ, Uwe , SCHNEIDER, Albert , DUBS, Marie-Josée , BACHMANN, Frank , HAZENKAMP, Menno , EHLIS, Thomas , VINCENZI, Cornelia , DANNACHER, Josef
发明人： SCHLINGLOFF, Gunther , WIEPRECHT, Torsten , HEINZ, Uwe , SCHNEIDER, Albert , DUBS, Marie-Josée , BACHMANN, Frank , HAZENKAMP, Menno , EHLIS, Thomas , VINCENZI, Cornelia , DANNACHER, Josef
IPC分类号： C11D3/395
CPC分类号： C07D401/14 , C11D3/168 , C11D3/3932
摘要： Use of metal complex compounds of formula (1) and/or (1') [L n Me m X p ] z Y q (1), [L' n Me m X p ] z Y q (1'), wherein all substituents are as defined in the claims, as catalysts for oxidation reactions, and also novel metal complex compounds and novel ligands.
摘要翻译：使用式（1）和/或（1'）[LnMemXp] yq（1），[L'nMemXp] zq（1'）的金属络合物，其中所有取代基如作为氧化反应的催化剂，还有新的金属络合物和新配体。

4. 发明申请

WO2004039933A1 USE OF METAL COMPLEX COMPOUNDS AS CATALYSTS FOR OXIDATION USING MOLECULAR OXYGEN OR AIR 审中-公开
标题翻译：使用金属复合化合物作为催化剂使用分子氧或空气进行氧化
公开(公告)号：WO2004039933A1
公开(公告)日：2004-05-13
申请号：PCT/EP2003/011635
申请日：2003-10-21
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , WIEPRECHT, Torsten , SCHLINGLOFF, Gunther , XIA, Juntao , HEINZ, Uwe , SCHNEIDER, Albert , DUBS, Marie-Josée , BACHMANN, Frank , HAZENKAMP, Menno , DANNACHER, Josef
发明人： WIEPRECHT, Torsten , SCHLINGLOFF, Gunther , XIA, Juntao , HEINZ, Uwe , SCHNEIDER, Albert , DUBS, Marie-Josée , BACHMANN, Frank , HAZENKAMP, Menno , DANNACHER, Josef
IPC分类号： C11D3/395
CPC分类号： C11D3/3932 , C11D3/168
摘要： Use, as a catalyst for oxidation reactions using molecular oxygen and/or air, of at least one metal complex compound of formula (1) wherein Me is manganese, titanium, iron, cobalt, nickel or copper, X is a coordinating or bridging radical, n and m are each independently of the other an integer having a value of from 1 to 8, p is an integer having a value of from 0 to 32, z is the charge of the metal complex, Y is a counter-ion, q = z/(charge of Y), and L is a ligand of formula (2) wherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , R 10 and R 11 are each independently of the others hydrogen; unsubstituted or substituted C 1 -C 18 alkyl or aryl; cyano; halogen; nitro; -COOR 12 or -S0 3 R 12 wherein R 12 is in each case hydrogen, a cation or unsubstituted or substituted C 1 -C 18 alkyl or aryl; -SR 13 , -S0 2 R 13 or -OR 13 wherein R 13 is in each case hydrogen or unsubstituted or substituted C 1 -C 18 alkyl or aryl; -NR 14 R 15 ; -(C 1 -C 6 alkylene)-NR 14 R 15 ; -N (+) R 14 R 15 R 16 ; -(C 1 -C 6 alkylene)-N (+) R I4 R 15 R 16 ; -N(R 13 )-(C 1 -C 6 alkylene)-NR 14 R l5 ; -N[(C 1 -C 6 alkylene)-NR 14 R 15 ] 2 ; -N(R 13 )-(C I -C 6 alkylene)-N (+) R 14 R 15 R 16 ; -N[(C 1 -C 6 alkylene)-N (+) R 14 R 15 R16]2; -N(R l3 )-N-R l4 R 15 or -N(R 13 )N"R l4 R 15 R 16 , wherein R 13 is as defined above and R 14 , R 15 and R 16 are each independently of the other(s) hydrogen or unsubstituted or substituted C 1 -C 18 alkyl or aryl, or R 14 and R 15 , together with the nitrogen atom linking them, form an unsubstituted or substituted 5-, 6- or 7-membered ring which may contain further hetero atoms.
摘要翻译：使用至少一种式（1）的金属络合物（其中Me是锰，钛，铁，钴，镍或铜）作为氧化反应的催化剂，使用分子氧和/或空气，X是配位或桥接基团，n和m各自独立地为具有1至8的整数，p为0至32的整数，z为金属络合物的电荷，Y为抗衡离子， q = z /（Y的电荷），L是式（2）的配体，其中R1，R2，R3，R4，R5，R6，R7，R8，R9，R10和R11各自独立地为氢; 未取代或取代的C 1 -C 18烷基或芳基; 氰基; 卤素; 硝基; -COOR 12或-SO 3 R 12，其中R 12在各种情况下为氢，阳离子或未取代或取代的C 1 -C 18烷基或芳基; -SR 13，-SO 2 R 13或-OR 13，其中R 13各自为氢或未取代或取代的C 1 -C 18烷基或芳基; -NR14R15; - （C 1 -C 6亚烷基）-NR 14 R 15; -N <（+）> R14R15R16; - （C 1 -C 6亚烷基）-N <（+）> RI4R15R16; -N（R13） - （C 1 -C 6亚烷基）-NR14Rl5; -N [（C1-C6亚烷基）-NR 14 R 15] 2; -N（R13） - （C 1 -C 6亚烷基）-N <（+）> R14R15R16; -N [（C1-C6亚烷基）-N <（+）> R14R15R16] 2; -N（R13）-N-R14R15或-N（R13）N“R14R15R16，其中R13如上所定义，R14，R15和R16各自独立地为氢或未取代或取代的C1-C18烷基或芳基或R 14和R 15与连接它们的氮原子一起形成未含或取代的可含有其它杂原子的5-，6-或7-元环。

5. 发明公开

EP1383857A2 USE OF METAL COMPLEX COMPOUNDS AS OXIDATION CATALYSTS 有权
标题翻译： VERWENDUNG VON METALLKOMPLEXVERBINDUNGEN ALS氧化剂KATALYSATOREN
公开(公告)号：EP1383857A2
公开(公告)日：2004-01-28
申请号：EP02740514.1
申请日：2002-04-25
申请人： Ciba Specialty Chemicals Holding Inc.
发明人： SCHLINGLOFF, Gunther , WIEPRECHT, Torsten , BACHMANN, Frank , DANNACHER, Joseph , DUBS, Marie-Josée , HAZENKAMP, Menno , HÄNSLER, Grit , SCHMIDT, Brigitte , SCHNEIDER, Albert , WEINGARTNER, Peter
IPC分类号： C11D3/39 , B01J31/18 , D21C9/10 , D21C9/16 , C07D213/70 , C07D213/61 , C07D213/77 , C07D213/74 , C07D213/30 , C07D301/12 , C07F13/00
CPC分类号： B01J31/1815 , B01J23/34 , B01J2231/70 , B01J2231/72 , B01J2531/16 , B01J2531/46 , B01J2531/72 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C07D213/61 , C07D213/68 , C07D213/74 , C07F13/005 , C11D3/3932 , D06L4/10 , D06L4/12 , D06P5/02 , D06P5/153 , D21C9/1036 , D21C9/163
摘要： Use of metal complex compounds of formula (1): [LnMemXp]zYq wherein Me is manganese, titanium, iron, cobalt, nickel or copper, X is a coordinating or bridging radical, n and m are each independently of the other an integer having a value of from 1 to 8, p is an integer having a value of from 0 to 32, z is the charge of the metal complex, y is a counter-ion, q=z/(charge Y), and L is a ligand of formula (2) wherein R1, R2, R3, R4, R5, R6, R7, R8, R9, R10 and R11 are each independently of the others hydrogen; unsubstituted or substituted C1-C18 alkyl or aryl; cyano; halogen; nitro; -COOR12 or -SO3R12 wherein R12 is in each case hydrogen, a cation or unsubstituted or substituted C1-C18alkyl or aryl; -SR13, -SO2R13 or -OR13 wherein R13 is in each case hydrogen or unsubstituted or substituted C1-C18alkyl or aryl;-N(R13)-NR'13R'13 wherein R13, R'13 and R'13 are as defined above for R13; -NR14R15 or -N+R14R15R16 wherein R14, R15 and R16 are each independently of the other(s) hydrogen or unsubstituted or substituted C1-C18alkyl or aryl, or R14 and R15 together with the nitrogen atom bonding them form an unsubstituted or substituted 5-, 6- or 7-membered ring which may optionally contain further hetero atoms; with the proviso that R1, R2, R3, R4, R5, R6, R7, R8, R9, R10, and R11 are not simultaneously hydrogen, as catalysts for oxidation reactions, and the novel metal complex compounds of formula (1) and the novel ligands of formula (2).
摘要翻译：使用式[LnMemXp] zYq（1）的金属络合物，其中Me是锰，钛，铁，钴，镍或铜，X是配位或桥连基团，n和m各自独立地是另一个具有值为1〜8，p为0〜32的整数，z为金属络合物的电荷，Y为抗衡离子，q = z /（电荷Y），L为其中R 1，R 2，R 3，R 4，R 5，R 6，R 7，R 8，R 9，R 10和R 11各自独立地为氢; 未取代或取代的C 1 -C 18烷基或芳基; 氰基; 卤素; 硝基; -COOR 12或-SO 3 R 12，其中R 12各自为氢，阳离子或未取代或取代的C 1 -C 18烷基或芳基; -SR 13，-SO 2 R 13或-OR 13，其中R 13各自为氢或未取代或取代的C 1 -C 18烷基或芳基; -N（R 13）-NR'13R“13其中R 13，R 13和R 13如上述R 13所定义; -NR14R15或-N⊕R14R15R16，其中R14，R15和R16各自独立地为氢或未取代或取代的C1-C18烷基或芳基，或者R14和R15与其键合的氮原子一起形成未取代或取代的5 - ，6或7元环，其可以任选地含有另外的杂原子; 条件是R 1，R 2，R 3，R 4，R 5，R 6，R 7，R 8，R 9，R 10和R 11不同时为氢，作为氧化反应的催化剂，并且式（1）和新颖的新型金属络合物式（2）的配体。

6. 发明公开

EP1521820A1 USE OF METAL COMPLEX COMPOUNDS AS OXIDATION CATALYSTS 有权
标题翻译：金属络合物作为氧化催化剂使用
公开(公告)号：EP1521820A1
公开(公告)日：2005-04-13
申请号：EP03763699.0
申请日：2003-07-03
申请人： Ciba Specialty Chemicals Holding Inc.
发明人： SCHLINGLOFF, Gunther , WIEPRECHT, Torsten , BACHMANN, Frank , DANNACHER, Josef , DUBS, Marie-Josée , HAZENKAMP, Menno , HEINZ, Uwe , FREY, Markus , SCHNEIDER, Albert
IPC分类号： C11D3/395 , C11D3/16 , C07D213/68 , C07D213/74 , C11D3/39
CPC分类号： C11D3/168 , C07D213/68 , C07D213/74 , C11D3/3932
摘要： Use of metal complex compounds of formula (1) [LnMemXp]zYq wherein Me is manganese, titanium, iron, cobalt, nickel or copper, X is a coordinating or bridging radical, n and m are each independently of the other an integer having a value of from 1 to 8, p is an integer having a value of from 0 to 32, z is the charge of the metal complex, Y is a counter-ion, q = z/(charge Y), and L is a ligand of formula (2) wherein R1, R2, R3, R4, R5, R6, R7, R8, R9, R10 and R11 are each independently of the others hydrogen; unsubstituted or substituted C1-C18alkyl or aryl; cyano; halogen; nitro; -COOR12 or -SO3R12 wherein R12 is in each case hydrogen, a cation or unsubstituted or substituted C1-C18alkyl or aryl; -SR13, -SO12R13 or -OR13 wherein R13 is in each case hydrogen or unsubstituted or substituted C1-C18alkyl or aryl; -NR14R15; -(C1-C6alkylene)-NR14R15; -NoR14R15R16; -(C1-C6alkylene)-NoR14R15R16; -N(R13)-(C1-C6alkylene)-NR14R15; -N[(C1-C6alkylene)-NR14R15]2; -N(R13)-(C1-C6alkylene)-NoR14R15R16, -N[C1-C6alkylene)-NoR14R15R16]2; -N(R13)-N-R14R15 or -N(R13)-NoR14R15R16, wherein R13 is as defined above and R14, R15 and R16 are each independently of the other(s) hydrogen or unsubstituted or substituted C1-C18alkyl or aryl, or R14 and R15 together with the nitrogen atom bonding them form an unsubstituted or substituted 5-, 6- or 7-membered ring which may optionally contain further heteroatoms; with the proviso that (i) at least one of the substituents R1-R11 contains a quaternized atom which is not directly bonded to one of the three pyridine A, B or C and that (ii) Y is neither I' nor CI' in the case that Me is Mn(II), R1-R5 and R7-R11 are hydrogen and R6 is formula (III) as catalysts for oxidation reactions, and the novel metal complex compounds of formula (1), the novel ligands of formula (2) and their starting materials.

7. 发明公开

EP1556467A1 USE OF METAL COMPLEX COMPOUNDS AS OXIDATION CATALYSTS 有权
标题翻译：金属络合物作为氧化催化剂的用途
公开(公告)号：EP1556467A1
公开(公告)日：2005-07-27
申请号：EP03769428.8
申请日：2003-10-21
申请人： Ciba Specialty Chemicals Holding Inc.
发明人： SCHLINGLOFF, Gunther , WIEPRECHT, Torsten , HEINZ, Uwe , SCHNEIDER, Albert , DUBS, Marie-Josée , BACHMANN, Frank , HAZENKAMP, Menno , EHLIS, Thomas , VINCENZI, Cornelia , DANNACHER, Josef
IPC分类号： C11D3/395 , C11D3/16 , C07D401/14 , C11D3/39
CPC分类号： C07D401/14 , C11D3/168 , C11D3/3932
摘要： Use of metal complex compounds of formula (1) and/or (1') [LnMemXp]zYq (1), [L'nMemXp]zYq (1'), wherein all substituents are as defined in the claims, as catalysts for oxidation reactions, and also novel metal complex compounds and novel ligands.
摘要翻译：作为氧化催化剂，使用式（1）和/或（1'）[LnMemXp] zYq（1），[L'nMemXp] zYq（1'）的金属配合物化合物，其中所有取代基如权利要求书中所定义反应，以及新的金属络合物化合物和新型配体。

8. 发明授权

EP1383857B1 USE OF METAL COMPLEX COMPOUNDS AS OXIDATION CATALYSTS 有权
标题翻译：金属络合物作为氧化催化剂的用途
公开(公告)号：EP1383857B1
公开(公告)日：2006-05-31
申请号：EP02740514.1
申请日：2002-04-25
申请人： Ciba Specialty Chemicals Holding Inc.
发明人： SCHLINGLOFF, Gunther , WIEPRECHT, Torsten , BACHMANN, Frank , DANNACHER, Joseph , DUBS, Marie-Josée , HAZENKAMP, Menno , HÄNSLER, Grit , SCHMIDT, Brigitte , SCHNEIDER, Albert , WEINGARTNER, Peter
IPC分类号： C11D3/39 , B01J31/18 , D21C9/10 , D21C9/16 , C07D213/70 , C07D213/61 , C07D213/77 , C07D213/74 , C07D213/30 , C07D301/12 , C07F13/00
CPC分类号： B01J31/1815 , B01J23/34 , B01J2231/70 , B01J2231/72 , B01J2531/16 , B01J2531/46 , B01J2531/72 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C07D213/61 , C07D213/68 , C07D213/74 , C07F13/005 , C11D3/3932 , D06L4/10 , D06L4/12 , D06P5/02 , D06P5/153 , D21C9/1036 , D21C9/163
摘要： Use of metal complex compounds of formula (1): [LnMemXp]zYq wherein Me is manganese, titanium, iron, cobalt, nickel or copper, X is a coordinating or bridging radical, n and m are each independently of the other an integer having a value of from 1 to 8, p is an integer having a value of from 0 to 32, z is the charge of the metal complex, y is a counter-ion, q=z/(charge Y), and L is a ligand of formula (2) wherein R1, R2, R3, R4, R5, R6, R7, R8, R9, R10 and R11 are each independently of the others hydrogen; unsubstituted or substituted C1-C18 alkyl or aryl; cyano; halogen; nitro; -COOR12 or -SO3R12 wherein R12 is in each case hydrogen, a cation or unsubstituted or substituted C1-C18alkyl or aryl; -SR13, -SO2R13 or -OR13 wherein R13 is in each case hydrogen or unsubstituted or substituted C1-C18alkyl or aryl;-N(R13)-NR'13R'13 wherein R13, R'13 and R'13 are as defined above for R13; -NR14R15 or -N+R14R15R16 wherein R14, R15 and R16 are each independently of the other(s) hydrogen or unsubstituted or substituted C1-C18alkyl or aryl, or R14 and R15 together with the nitrogen atom bonding them form an unsubstituted or substituted 5-, 6- or 7-membered ring which may optionally contain further hetero atoms; with the proviso that R1, R2, R3, R4, R5, R6, R7, R8, R9, R10, and R11 are not simultaneously hydrogen, as catalysts for oxidation reactions, and the novel metal complex compounds of formula (1) and the novel ligands of formula (2).
摘要翻译：式（1）的金属配合物的用途：[LnMemXp] zYq其中Me是锰，钛，铁，钴，镍或铜，X是配位或桥连基团，n和m各自独立地是具有 1至8的值，p是具有0至32的值的整数，z是金属络合物的电荷，y是反离子，q = z /（电荷Y），并且L是（2）的配体，其中R 1，R 2，R 3，R 4，R 5，R 6，R 7，R 8，R 9，R 10和R 11各自彼此独立地为氢; 未取代或取代的C 1 -C 18烷基或芳基; 氰基; 卤素; 硝基; -COOR 12或-SO 3 R 12，其中R 12在每种情况下为氢，阳离子或未取代或取代的C 1 -C 18烷基或芳基; -SR 13，-SO 2 R 13或-OR 13，其中R 13各自为氢或未取代或取代的C 1 -C 18烷基或芳基; -N（R 13）-NR'13 R 13，其中R 13，R 13和R 13如上所定义对于R13; -NR 14 R 15或-N + R 14 R 15 R 16，其中R 14，R 15和R 16各自独立地为氢或未取代或取代的C 1 -C 18烷基或芳基，或者R 14和R 15与它们连接的氮原子一起形成未取代或取代的 - 可任选地含有另外的杂原子的6-或7-元环; 条件是R1，R2，R3，R4，R5，R6，R7，R8，R9，R10和R11不同时为氢，用作氧化反应的催化剂，以及式（1）的新型金属配合物化合物和式（2）的新型配体。

9. 发明授权

EP1521820B1 USE OF METAL COMPLEX COMPOUNDS AS OXIDATION CATALYSTS 有权
标题翻译：金属络合物作为氧化催化剂使用
公开(公告)号：EP1521820B1
公开(公告)日：2006-03-22
申请号：EP03763699.0
申请日：2003-07-03
申请人： Ciba Specialty Chemicals Holding Inc.
发明人： SCHLINGLOFF, Gunther , WIEPRECHT, Torsten , BACHMANN, Frank , DANNACHER, Josef , DUBS, Marie-Josée , HAZENKAMP, Menno , HEINZ, Uwe , FREY, Markus , SCHNEIDER, Albert
IPC分类号： C11D3/395 , C11D3/16 , C07D213/68 , C07D213/74 , C11D3/39
CPC分类号： C11D3/168 , C07D213/68 , C07D213/74 , C11D3/3932
摘要： Use of metal complex compounds of formula (1) [LnMemXp]zYq wherein Me is manganese, titanium, iron, cobalt, nickel or copper, X is a coordinating or bridging radical, n and m are each independently of the other an integer having a value of from 1 to 8, p is an integer having a value of from 0 to 32, z is the charge of the metal complex, Y is a counter-ion, q = z/(charge Y), and L is a ligand of formula (2) wherein R1, R2, R3, R4, R5, R6, R7, R8, R9, R10 and R11 are each independently of the others hydrogen; unsubstituted or substituted C1-C18alkyl or aryl; cyano; halogen; nitro; -COOR12 or -SO3R12 wherein R12 is in each case hydrogen, a cation or unsubstituted or substituted C1-C18alkyl or aryl; -SR13, -SO12R13 or -OR13 wherein R13 is in each case hydrogen or unsubstituted or substituted C1-C18alkyl or aryl; -NR14R15; -(C1-C6alkylene)-NR14R15; -NoR14R15R16; -(C1-C6alkylene)-NoR14R15R16; -N(R13)-(C1-C6alkylene)-NR14R15; -N[(C1-C6alkylene)-NR14R15]2; -N(R13)-(C1-C6alkylene)-NoR14R15R16, -N[C1-C6alkylene)-NoR14R15R16]2; -N(R13)-N-R14R15 or -N(R13)-NoR14R15R16, wherein R13 is as defined above and R14, R15 and R16 are each independently of the other(s) hydrogen or unsubstituted or substituted C1-C18alkyl or aryl, or R14 and R15 together with the nitrogen atom bonding them form an unsubstituted or substituted 5-, 6- or 7-membered ring which may optionally contain further heteroatoms; with the proviso that (i) at least one of the substituents R1-R11 contains a quaternized atom which is not directly bonded to one of the three pyridine A, B or C and that (ii) Y is neither I' nor CI' in the case that Me is Mn(II), R1-R5 and R7-R11 are hydrogen and R6 is formula (III) as catalysts for oxidation reactions, and the novel metal complex compounds of formula (1), the novel ligands of formula (2) and their starting materials.

10. 发明授权

EP1556467B1 USE OF METAL COMPLEX COMPOUNDS AS OXIDATION CATALYSTS 有权
公开(公告)号：EP1556467B1
公开(公告)日：2006-07-05
申请号：EP03769428.8
申请日：2003-10-21
申请人： Ciba Specialty Chemicals Holding Inc.
发明人： SCHLINGLOFF, Gunther , WIEPRECHT, Torsten , HEINZ, Uwe , SCHNEIDER, Albert , DUBS, Marie-Josée , BACHMANN, Frank , HAZENKAMP, Menno , EHLIS, Thomas , VINCENZI, Cornelia , DANNACHER, Josef
IPC分类号： C11D3/395 , C11D3/16 , C07D401/14 , C11D3/39
CPC分类号： C07D401/14 , C11D3/168 , C11D3/3932
摘要： Use of metal complex compounds of formula (1) and/or (1') [LnMemXp]zYq (1), [L'nMemXp]zYq (1'), wherein all substituents are as defined in the claims, as catalysts for oxidation reactions, and also novel metal complex compounds and novel ligands.

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