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1. 发明申请

WO02088289A3 USE OF METAL COMPLEX COMPOUNDS AS OXIDATION CATALYSTS 审中-公开
标题翻译：使用金属复合化合物作为氧化催化剂
公开(公告)号：WO02088289A3
公开(公告)日：2003-02-27
申请号：PCT/EP0204572
申请日：2002-04-25
申请人： CIBA SC HOLDING AG , SCHLINGLOFF GUNTHER , WIEPRECHT TORSTEN , BACHMANN FRANK , DANNACHER JOSEPH , DUBS MARIE-JOSEE , HAZENKAMP MENNO , RICHTER GRIT , SCHMIDT BRIGITTE , SCHNEIDER ALBERT , WEINGARTNER PETER
发明人： SCHLINGLOFF GUNTHER , WIEPRECHT TORSTEN , BACHMANN FRANK , DANNACHER JOSEPH , DUBS MARIE-JOSEE , HAZENKAMP MENNO , RICHTER GRIT , SCHMIDT BRIGITTE , SCHNEIDER ALBERT , WEINGARTNER PETER
IPC分类号： C07D213/53 , A01N25/00 , A01N59/00 , B01J23/34 , B01J31/18 , B01J31/22 , C07B61/00 , C07D213/30 , C07D213/61 , C07D213/68 , C07D213/70 , C07D213/74 , C07D213/77 , C07D301/12 , C07F1/08 , C07F7/28 , C07F13/00 , C07F15/02 , C07F15/04 , C07F15/06 , C11D3/39 , C11D3/395 , D06L3/02 , D06P5/02 , D06P5/15 , D21C9/10 , D21C9/16
CPC分类号： B01J31/1815 , B01J23/34 , B01J2231/70 , B01J2231/72 , B01J2531/16 , B01J2531/46 , B01J2531/72 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C07D213/61 , C07D213/68 , C07D213/74 , C07F13/005 , C11D3/3932 , D06L4/10 , D06L4/12 , D06P5/02 , D06P5/153 , D21C9/1036 , D21C9/163
摘要： Use of metal complex compounds of formula (1): [L>n m p Yq wherein Me is manganese, titanium, iron, cobalt, nickel or copper, X is a coordinating or bridging radical, n and m are each independently of the other an integer having a value of from 1 to 8, p is an integer having a value of from 0 to 32, z is the charge of the metal complex, y is a counter-ion, q=z/(charge Y), and L is a ligand of formula (2) wherein R1, R2, R3, R4, R5, R6, R7, R8, R9, R10 and R11 are each independently of the others hydrogen; unsubstituted or substituted C1-C18 alkyl or aryl; cyano; halogen; nitro; -COOR12 or -SO3R12 wherein R12 is in each case hydrogen, a cation or unsubstituted or substituted C1-C18alkyl or aryl; -SR13, -SO2R13 or -OR13 wherein R13 is in each case hydrogen or unsubstituted or substituted C1-C18alkyl or aryl;-N(R13)-NR'13R"13 wherein R13, R'13 and R"13 are as defined above for R13; -NR14R15 or -N R14R15R16 wherein R14, R15 and R16 are each independently of the other(s) hydrogen or unsubstituted or substituted C1-C18alkyl or aryl, or R14 and R15 together with the nitrogen atom bonding them form an unsubstituted or substituted 5-, 6- or 7-membered ring which may optionally contain further hetero atoms; with the proviso that R1, R2, R3, R4, R5, R6, R7, R8, R9, R10, and R11 are not simultaneously hydrogen, as catalysts for oxidation reactions, and the novel metal complex compounds of formula (1) and the novel ligands of formula (2).
摘要翻译：使用式（1）的金属络合物：其中Me是锰，钛，铁，钴，镍或铜，X是配位或桥接基团，n和m各自独立地为具有1至8的整数，p为0至32的整数，z为金属络合物的电荷，y为抗衡离子，q = z /（电荷Y），L是式（2）的配体，其中R 1，R 2，R 3，R 4，R 5，R 6，R 7，R 8，R 9，R 10和R 11各自独立地为氢; 未取代或取代的C 1 -C 18烷基或芳基; 氰基; 卤素; 硝基; -COOR 12或-SO 3 R 12，其中R 12在各种情况下为氢，阳离子或未取代或取代的C 1 -C 18烷基或芳基; -SR 13，-SO 2 R 13或-OR 13，其中R 13各自为氢或未取代或取代的C 1 -C 18烷基或芳基; -N（R 13）-NR 13 R 13，其中R 13，R 13和R 13如上定义对于R13; -NR14R15或-N + R14R15R16，其中R14，R15和R16各自独立地为氢或未取代或取代的C1-C18烷基或芳基，或者R14和R15与键合氮原子一起形成未取代或未取代的取代的5-，6-或7-元环，其可以任选地含有另外的杂原子; 条件是R 1，R 2，R 3，R 4，R 5，R 6，R 7，R 8，R 9，R 10和R 11不同时为氢，作为氧化反应的催化剂，并且新的式（1）金属络合物和式（2）的新配体。

2. 发明专利

BR0209292B1 未知
公开(公告)号：BR0209292B1
公开(公告)日：2014-04-29
申请号：BR0209292
申请日：2002-04-25
申请人： CIBA SC HOLDING AG
发明人： SCHLINGLOFF GUNTHER , WIEPRECHT TORSTEN , BACHMANN FRANK , DANNACHER JOSEPH , DUBS MARIE-JOSEE , HAZENKAMP MENNO , HAENSLER GRIT , SCHMIDT BRIGITTE , SCHNEIDER ALBERT , WEINGARTNER PETER
IPC分类号： C07D213/53 , C11D3/39 , A01N25/00 , A01N59/00 , B01J23/34 , B01J31/18 , B01J31/22 , C07B61/00 , C07D213/30 , C07D213/61 , C07D213/68 , C07D213/70 , C07D213/74 , C07D213/77 , C07D301/12 , C07F1/08 , C07F7/28 , C07F13/00 , C07F15/02 , C07F15/04 , C07F15/06 , C11D3/395 , D06L3/02 , D06L4/10 , D06L4/12 , D06P5/02 , D06P5/15 , D21C9/10 , D21C9/16
摘要： The present invention relates to the use of metal complex compounds with terpyridine ligands as oxidation catalysts. The present invention relates also to formulations comprising such metal complex compounds, to novel metal complex compounds, and to novel ligands. The metal complex compounds are used especially tor improving the action of peroxides, for example in the treatment of textile material, without at the same time causing any appreciable damage to fibres and dyeings.

3. 发明专利

DE60304200T2 未知
公开(公告)号：DE60304200T2
公开(公告)日：2006-08-17
申请号：DE60304200
申请日：2003-07-03
申请人： CIBA SC HOLDING AG
发明人： SCHLINGLOFF GUNTHER , WIEPRECHT TORSTEN , BACHMANN FRANK , DANNACHER JOSEF , DUBS MARIE-JOSEE , HAZENKAMP MENNO , HEINZ UWE , FREY MARKUS , SCHNEIDER ALBERT
IPC分类号： C11D3/395 , D06L3/02 , B01J31/22 , C07B61/00 , C07D213/68 , C07D213/74 , C07F13/00 , C11D3/16 , C11D3/39

4. 发明专利

AT328057T 未知
公开(公告)号：AT328057T
公开(公告)日：2006-06-15
申请号：AT02740514
申请日：2002-04-25
申请人： CIBA SC HOLDING AG
发明人： SCHLINGLOFF GUNTHER , WIEPRECHT TORSTEN , BACHMANN FRANK , DANNACHER JOSEPH , DUBS MARIE-JOSEE , HAZENKAMP MENNO , HAENSLER GRIT , SCHMIDT BRIGITTE , SCHNEIDER ALBERT , WEINGARTNER PETER
IPC分类号： C07D213/53 , A01N25/00 , A01N59/00 , B01J23/34 , B01J31/18 , B01J31/22 , C07B61/00 , C07D213/30 , C07D213/61 , C07D213/68 , C07D213/70 , C07D213/74 , C07D213/77 , C07D301/12 , C07F1/08 , C07F7/28 , C07F13/00 , C07F15/02 , C07F15/04 , C07F15/06 , C11D3/39 , C11D3/395 , D06L3/02 , D06L4/10 , D06L4/12 , D06P5/02 , D06P5/15 , D21C9/10 , D21C9/16
摘要： The present invention relates to the use of metal complex compounds with terpyridine ligands as oxidation catalysts. The present invention relates also to formulations comprising such metal complex compounds, to novel metal complex compounds, and to novel ligands. The metal complex compounds are used especially tor improving the action of peroxides, for example in the treatment of textile material, without at the same time causing any appreciable damage to fibres and dyeings.

5. 发明专利

AU2003253026A1 USE OF METAL COMPLEX COMPOUNDS AS OXIDATION CATALYSTS 未知
公开(公告)号：AU2003253026A1
公开(公告)日：2004-02-02
申请号：AU2003253026
申请日：2003-07-03
申请人： CIBA SC HOLDING AG
发明人： HEINZ UWE , FREY MARKUS , SCHNEIDER ALBERT , SCHLINGLOFF GUNTHER , WIEPRECHT TORSTEN , BACHMANN FRANK , DANNACHER JOSEF , DUBS MARIE-JOSEE , HAZENKAMP MENNO
IPC分类号： D06L3/02 , B01J31/22 , C07B61/00 , C07D213/68 , C07D213/74 , C07F13/00 , C11D3/16 , C11D3/39 , C11D3/395

6. 发明专利

BR0312694A 未知
公开(公告)号：BR0312694A
公开(公告)日：2005-04-26
申请号：BR0312694
申请日：2003-07-03
申请人： CIBA SC HOLDING AG
发明人： SCHLINGLOFF GUNTER , WIEPRECHT TORSTEN , BACHMANN FRANK , DANNACHER JOSEF , DUBS MARIE-JOSEE , HAZENKAMP MENNO , HEINZ UWE , FREY MARKUS , SCHNEIDER ALBERT
IPC分类号： D06L3/02 , B01J31/22 , C07B61/00 , C07D213/68 , C07D213/74 , C07F13/00 , C11D3/16 , C11D3/39 , C11D3/395

7. 发明专利

ES2268440T3 UTILIZACION DE COMPUESTOS DE COMPLEJOS METALICOS COMO CATALIZADORES DE OXIDACION. 未知
公开(公告)号：ES2268440T3
公开(公告)日：2007-03-16
申请号：ES03769428
申请日：2003-10-21
申请人： CIBA SC HOLDING AG
发明人： SCHLINGLOFF GUNTHER , WIEPRECHT TORSTEN , HEINZ UWE , SCHNEIDER ALBERT , DUBS MARIE-JOSEE , BACHMANN FRANK
IPC分类号： C11D3/395 , C07D401/14 , C11D3/16 , C11D3/39
摘要： La utilización como catalizador en reacciones de oxidación de al menos un compuesto de complejo metálico de fórmula (1) (Ver fórmula) Me sea manganeso, titanio, hierro, cobalto, níquel o cobre, X sea un radical coordinante o formador de puentes, n y m sean, independientemente entre sí, un número entero con un valor de 1 a 8, P sea un número entero con un valor de 0 a 32, z sea la carga del complejo metálico, y sea un contra-ión, q = z/(carga de Y), y L sea un ligando de fórmula (2) (Ver fórmula) en el que Q sea N o CR10, R1, R2, R3, R4, R5, R6, R7, R8, R9 y R10 sean, cada uno independientemente entre sí, hidrógeno; alquilo-C1-C18 sustituido o no sustituido o arilo sustituido o no sustituido; ciano; halógeno; nitro; -COOR11 o -SO3R11 en el que R11 sea, en cada caso, hidrógeno, un catión o alquilo-C1-C18 sustituido o no sustituido o arilo sustituido o no sustituido; -SR12, -SO2R12 o -OR12 en el que R12 sea, en cada caso, hidrógeno o alquilo-C1-C18 sustituido o no sustituido o arilo sustituidoo no sustituido; -NR13R14; -(alquileno-C1-C6)-NR13R14; -N+R13R14R15; -(alquileno-C1-C6)-NR13R14R15; -N(R12)-(alquileno-C1-C6)NR13R14; -N[(alquileno-C1-C6)-NR13R14]2; -N(R12)-(alquileno-C1-C6)-N+R13R14R15; -N[(alquileno-C1-C6)-N+R13R14 R15]2; -N(R12)-N-R13R14 o -N(R12)-N+R13R14R15 en el que R12 sea como se define anteriormente y R13, R14 y R15 sean, independientemente entre sí, hidrógeno o alquilo-C1C18 sustituido o no sustituido o arilo sustituido o no sustituido, o R13 y R14, junto con el átomo de nitrógeno al que están unidos, formen un anillo de 5, 6 o 7 miembros, sustituido o no sustituido, que pueda contener otros heteroátomos.

8. 发明专利

DE60306672D1 未知
公开(公告)号：DE60306672D1
公开(公告)日：2006-08-17
申请号：DE60306672
申请日：2003-10-21
申请人： CIBA SC HOLDING AG
发明人： SCHLINGLOFF GUNTHER , WIEPRECHT TORSTEN , HEINZ UWE , SCHNEIDER ALBERT , DUBS MARIE-JOSEE , BACHMANN FRANK , HAZENKAMP MENNO , EHLIS THOMAS , VINCENZI CORNELIA , DANNACHER JOSEF
IPC分类号： C11D3/395 , C07D401/14 , C11D3/16 , C11D3/39
摘要： Use of metal complex compounds of formula (1) and/or (1') [LnMemXp]zYq (1), [L'nMemXp]zYq (1'), wherein all substituents are as defined in the claims, as catalysts for oxidation reactions, and also novel metal complex compounds and novel ligands.

9. 发明专利

DE60304200D1 未知
公开(公告)号：DE60304200D1
公开(公告)日：2006-05-11
申请号：DE60304200
申请日：2003-07-03
申请人： CIBA SC HOLDING AG
发明人： SCHLINGLOFF GUNTHER , WIEPRECHT TORSTEN , BACHMANN FRANK , DANNACHER JOSEF , DUBS MARIE-JOSEE , HAZENKAMP MENNO , HEINZ UWE , FREY MARKUS , SCHNEIDER ALBERT
IPC分类号： C11D3/395 , D06L3/02 , B01J31/22 , C07B61/00 , C07D213/68 , C07D213/74 , C07F13/00 , C11D3/16 , C11D3/39

10. 发明专利

BR0315926A 未知
公开(公告)号：BR0315926A
公开(公告)日：2005-09-20
申请号：BR0315926
申请日：2003-10-21
申请人： CIBA SC HOLDING AG
发明人： WIEPRECHT TORSTEN , SCHLINGLOFF GUNTHER , XIA JUNTAO , HEINZ UWE , SCHNEIDER ALBERT , DUBS MARIE-JOSEE , BACHMANN FRANK , HAZENKAMP MENNO , DANNACHER JOSEF
IPC分类号： C11D3/16 , C11D3/39 , C11D3/395
摘要： Use, as a catalyst for oxidation reactions using molecular oxygen and/or air, of at least one metal complex compound of formula (1) wherein Me is manganese, titanium, iron, cobalt, nickel or copper, X is a coordinating or bridging radical, n and m are each independently of the other an integer having a value of from 1 to 8, p is an integer having a value of from 0 to 32, z is the charge of the metal complex, Y is a counter-ion, q=z/(charge of Y), and L is a ligand of formula (2) wherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , R 10 and R 11 are each independently of the others hydrogen; unsubstituted or substituted C 1 -C 18 alkyl or aryl; cyano; halogen; nitro; -COOR 12 or -SO 3 R 12 wherein R 12 is in each case hydrogen, a cation or unsubstituted or substituted C 1 -C 18 alkyl or aryl; -SR 13 , -SO 2 R 13 or -OR 13 wherein R 13 is in each case hydrogen or unsubstituted or substituted C 1 -C 18 alkyl or aryl; -NR 14 R 15 ; -(C 1 -C 6 alkylene)-NR 14 R 15 ; -N (+) R 14 R 15 R 16 ; -(C 1 -C 6 alkylene)-N (+) R 14 R 15 R 16 ; -N(R 13 )-(C 1 -C 6 alkylene)-NR 14 R 15 ; -N[(C 1 -C 6 alkylene)-NR 14 R 15 ] 2 ; -N(R 13 )-(C 1 -C 6 alkylene)-N (+) R 14 R 15 R 16 ; -N[(C 1 -C 6 alkylene)-N (+) R 14 R 15 R 16]2 ; -N(R 13 )-N-R 14 R 15 or -N(R 13 )N''R 14 R 15 R 16 , wherein R 13 is as defined above and R 14 , R 15 and R 16 are each independently of the other(s) hydrogen or unsubstituted or substituted C 1 -C 18 alkyl or aryl, or R 14 and R 15 , together with the nitrogen atom linking them, form an unsubstituted or substituted 5-, 6- or 7-membered ring which may contain further hetero atoms. [L n Me m X p ] z Y q (1)

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