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    • 2. 发明申请
    • USE OF METAL COMPLEX COMPOUNDS AS OXIDATION CATALYSTS
    • 使用金属复合化合物作为氧化催化剂
    • WO2004039932A1
    • 2004-05-13
    • PCT/GB2003/004625
    • 2003-10-28
    • RECKITT BENCKISER N.V.RECKITT BENCKISER (UK) LIMITEDWIEDEMANN, RalfBACHMANN, FrankDANNACHER, JosephDUBS, Marie-JoseeHAZENKAMP, MennoRICHTER, GritSCHLINGLOFF, GuntherSCHMIDT, BrigitteSCHNEIDER, AlbertWEINGARTNER, PeterWIEPRECHT, Torsten
    • WIEDEMANN, RalfBACHMANN, FrankDANNACHER, JosephDUBS, Marie-JoseeHAZENKAMP, MennoRICHTER, GritSCHLINGLOFF, GuntherSCHMIDT, BrigitteSCHNEIDER, AlbertWEINGARTNER, PeterWIEPRECHT, Torsten
    • C11D3/39
    • C11D3/3932C11D3/168
    • An automatic dishwasher detergent formulation comprising: - (a) a metal complex compounds of formula (1) [ L n Me m ,X p ] z Y q wherein Me is manganese, titanium, iron, cobalt, nickel or copper, X is a co-ordinating or bridging radical, n and m are each independently of the other an integer having a value of from 1 to 8, p is an integer having a value of from 0 to 32, z is the charge of the metal complex, Y is a counter-ion, q = z / (charge Y), and L is a ligand of formula (2); wherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , R 1O and R 11 are each independently of the others hydrogen; unsubstituted or substituted C 1 -C 18 alkyl or aryl; cyano; halogen; nitro; -COOR 12 or -SO 3 R 12 wherein R 12 is in each case hydrogen, a cation or unsubstituted or substituted C 1 -C 18 alkyl or aryl; SR 13 , -SO 2 R 13 or -OR 13 wherein R 13 is in each case hydrogen or unsubstituted or substituted C 1 -C 18 alkyl or aryl; -N(R 13 ) -NR' 13 R ' ' 13 wherein R 13 , R ' 13 and R ' ' 13 are as defined above for R 13 ; -NR 14 NR 15 or - N ⊕ R 14 R 15 R 16 wherein R 14 , R 15 and R 16 are each independently of the other(s) hydrogen or unsubstituted or substituted C 1 -C 18 alkyl or aryl, or R 14 and R 15 together with the nitrogen atom bonding them from an unsubstituted or substituted 5-, 6- or 7-membered ring which may optionally contain further hetero atoms; with the proviso that R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , R 10 and R 11 are not simultaneously hydrogen, as a catalyst for oxidation reactions; and (b) an enzyme.
    • 一种自动洗碗机洗涤剂配方,其包含:(a)式(1)的金属络合物[LnMem,Xp] zq其中Me是锰,钛,铁,钴,镍或铜,X是配位的 或桥接基团,n和m各自独立地为具有1至8的整数的整数,p为0至32的整数,z为金属络合物的电荷,Y为计数器 - ,q = z /(电荷Y),L是式(2)的配体; 其中R1,R2,R3,R4,R5,R6,R7,R8,R9,R1O和R11各自独立地为氢; 未取代或取代的C 1 -C 18烷基或芳基; 氰基; 卤素; 硝基; -COOR 12或-SO 3 R 12,其中R 12在各种情况下为氢,阳离子或未取代或取代的C 1 -C 18烷基或芳基; SR13,-SO2R13或-OR13,其中R13各自为氢或未取代或取代的C1-C18烷基或芳基; -N(R 13)-NR 13 R 13,其中R 13,R'13和R“13如上文对R 13所定义; -NR14NR15或-N4R15R16,其中R14,R15和R16各自独立地为氢或未取代或取代的C1-C18烷基或芳基,或者R14和R15与氮原子一起与未取代或未取代的 取代的5-,6-或7-元环,其可以任选地含有另外的杂原子; 条件是作为氧化反应的催化剂,R1,R2,R3,R4,R5,R6,R7,R8,R9,R10和R11不同时为氢; 和(b)酶。