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1. 发明申请

WO2009013163A1 USE OF METAL COMPLEX COMPOUNDS AS OXIDATION CATALYSTS 审中-公开
标题翻译：使用金属复合化合物作为氧化催化剂
公开(公告)号：WO2009013163A1
公开(公告)日：2009-01-29
申请号：PCT/EP2008/059151
申请日：2008-07-14
申请人： CIBA HOLDING INC. , WAGNER, Barbara , ROHWER, Hauke , DUBS, Marie-Josée , END, Nicole , HAZENKAMP, Menno , MARQUAIS-BIENEWALD, Sophie
发明人： WAGNER, Barbara , ROHWER, Hauke , DUBS, Marie-Josée , END, Nicole , HAZENKAMP, Menno , MARQUAIS-BIENEWALD, Sophie
IPC分类号： B01J31/18 , C07D215/14 , C07D215/26 , C11D3/39 , C11D3/395
CPC分类号： B01J31/1815 , B01J31/1825 , B01J31/2217 , B01J2231/70 , B01J2531/0238 , B01J2531/0258 , B01J2531/16 , B01J2531/46 , B01J2531/72 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C07D213/81 , C07D213/88 , C07D215/38 , C07D401/12 , C11D3/0021 , C11D3/168 , C11D3/3932 , C11D3/3935 , C11D3/48
摘要： The present invention relates to the use of metal complex compounds having hydrazide ligands as oxidation catalysts. Further aspects of the invention are formulations comprising such metal complex compounds, novel metal complex compounds and novel ligands. The metal complex compounds are used especially for enhancing the action of peroxides, for example in the treatment of textile material, without at the same time causing any appreciable damage to fibres and dyeings. There is also no appreciable damage to fibres and dyeings if these metal complexes are used in combination with an enzyme or a mixture of enzymes.
摘要翻译：本发明涉及具有酰肼配位体的金属络合物作为氧化催化剂的用途。本发明的其它方面是包含这种金属络合物，新型金属络合物和新型配体的制剂。金属络合物特别用于增强过氧化物的作用，例如在纺织材料的处理中，而不会同时对纤维和染色造成明显的损害。如果这些金属配合物与酶或酶的混合物组合使用，纤维和染色也不会有明显的损害。

2. 发明申请

WO2007090461A1 USE OF METAL COMPLEX COMPOUNDS AS OXIDATION CATALYSTS 审中-公开
标题翻译：使用金属复合化合物作为氧化催化剂
公开(公告)号：WO2007090461A1
公开(公告)日：2007-08-16
申请号：PCT/EP2006/050701
申请日：2006-02-06
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , SCHLINGLOFF, Gunther , NIVALKAR, Kishor, Ramachandra , WIEPRECHT, Torsten , DUBS, Marie-Josée , END, Nicole
发明人： SCHLINGLOFF, Gunther , NIVALKAR, Kishor, Ramachandra , WIEPRECHT, Torsten , DUBS, Marie-Josée , END, Nicole
IPC分类号： B01J31/18 , C07B33/00 , A61L2/18 , A61L2/23 , A61L12/12 , C11D3/39 , C11D17/00 , D06L3/02 , D06M11/32 , D06M11/50 , D21C9/16 , C02F1/72 , C02F1/74 , C07D213/22 , C07D401/14
CPC分类号： B01J31/1835 , A61L2/186 , A61L2/23 , A61L12/124 , A61L12/128 , A61L2202/17 , A61L2202/26 , B01J31/1815 , B01J31/182 , B01J31/183 , B01J31/184 , B01J2231/70 , B01J2531/0258 , B01J2531/16 , B01J2531/46 , B01J2531/72 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C02F1/683 , C02F1/722 , C02F1/725 , C02F2303/04 , C07D213/22 , C07D213/74 , C07D401/14 , C07D471/04 , C11D3/3932 , C11D17/0039 , C11D17/06 , D06M11/32 , D06M11/50 , D21C9/1036 , D21C9/163
摘要： The present invention relates to the use, as oxidation catalysts, of metal complex compounds having tetradentate ligands of formula (2) wherein all subsitutents have the meanings as defined in Claim 1. The present invention relates also to formulations comprising such metal complex compounds, to novel metal complex compounds and to novel ligands.
摘要翻译：本发明涉及作为氧化催化剂的具有式（2）的四齿配体的金属络合物的用途，其中所有的取代基具有如权利要求1中所定义的含义。本发明还涉及包含这种金属络合物的制剂，新型金属络合物和新配体。

3. 发明申请

WO2003014133A1 ISOXAZOLINE DERIVATIVES AS P, N LIGANDS 审中-公开
标题翻译： ISOXAZOLINE衍生物作为P，N配方
公开(公告)号：WO2003014133A1
公开(公告)日：2003-02-20
申请号：PCT/EP2002/008588
申请日：2002-08-01
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , END, Nicole , STOESSEL, Catherine , BERENS, Ulrich , COZZI, Pier, Giorgio
发明人： END, Nicole , STOESSEL, Catherine , BERENS, Ulrich , COZZI, Pier, Giorgio
IPC分类号： C07F9/6558
CPC分类号： C07F15/065 , C07C29/143 , C07C45/29 , C07F9/65583 , C07F9/65586 , C07F15/004 , C07F15/0053 , C07F15/0066 , C07F15/008 , C07F15/0093 , C07F15/045 , C07C33/22
摘要： The invention relates to novelligands of the phosphanylbenzothiophenyl-dihydroisoxazoline, phosphanyl-dihydrooxazolyl-indole and phosphanyl-dihydrooxazolyl-benzofuran type, especially compounds of formula (I) and mixtures of such compounds, wherein X is oxygen, sulfur, selenium or NO, wherein a is unsubstituted or substituted aryl, or alkyl or substituted alkyl and to processes for their preparation, to novel precursors and intermediates, to complexes with the said ligands, to their preparation and to their use as catalysts in organic synthesis (especially asymmetric organic synthesis).
摘要翻译：本发明涉及膦酰基苯并噻吩基 - 二氢异恶唑啉，膦基 - 二氢恶唑基 - 吲哚和膦基 - 二氢恶唑基 - 苯并呋喃型，特别是式（I）化合物和这些化合物的混合物，其中X是氧，硫，硒或NO，是未取代或取代的芳基，或烷基或取代的烷基，及其制备方法，新型前体和中间体，与所述配体的配合物，其制备及其作为有机合成（特别是不对称有机合成）中的催化剂的用途。

4. 发明申请

WO2003004450A1 PROCESS FOR THE PREPARATION OF INTERMEDIATES USEFUL IN THE SYNTHESIS OF STATIN DERIVATIVES ESPECIALLY 7-AMINO 3,5-DIHYDROXY HEPTANOIC ACID DERIVATIVES, AND INTERMEDIATES THEREOF 审中-公开
标题翻译：制备适用于特异性衍生物的中间体的方法，特别是7-氨基3,5-二羟基丙酸衍生物及其中间体
公开(公告)号：WO2003004450A1
公开(公告)日：2003-01-16
申请号：PCT/EP2002/007307
申请日：2002-07-02
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , ÖHRLEIN, Reinhold , BAISCH, Gabriele , END, Nicole , BURKHARDT, Stephan , STUDER, Martin
发明人： ÖHRLEIN, Reinhold , BAISCH, Gabriele , END, Nicole , BURKHARDT, Stephan , STUDER, Martin
IPC分类号： C07C67/30
CPC分类号： C07C235/74 , C07C69/67 , C07C69/716 , C07C69/732 , C07C69/738 , C07C227/32 , C07C229/22 , C07C235/06 , C12P7/62 , Y02P20/55
摘要： The invention relates to synthesis methods for the preparation of statin derivatives, which methods proceed by way of a key intermediate of formula I wherein X is halogen, acyloxy, activated hydrocarbyloxy, activated hydrocarbylthio or N(CH 3 )OCH 3 , R a is a hydroxy-protecting group, and R b is a carboxy-protecting group, and, as well as to the compound of formula I, to further intermediates and methods for their preparation by Friedel-Crafts acylation.
摘要翻译：本发明涉及用于制备他汀类衍生物的合成方法，该方法通过式I的关键中间体进行，其中X为卤素，酰氧基，活化的烃氧基，活性烃硫基或N（CH 3）OCH 3，R a为羟基保护基并且Rb是羧基保护基团，以及式I化合物，用于通过Friedel-Crafts酰化制备其进一步的中间体及其制备方法。

5. 发明申请

WO2004080963A1 PROCESS FOR THE PREPARATION OF INDOLE DERIVATIVES BY ENZYMATIC ACYLATION 审中-公开
标题翻译：通过酶学方法制备吲哚衍生物的方法
公开(公告)号：WO2004080963A1
公开(公告)日：2004-09-23
申请号：PCT/EP2004/050244
申请日：2004-03-03
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , ÖHRLEIN, Reinhold , END, Nicole , BAISCH, Gabriele
发明人： ÖHRLEIN, Reinhold , END, Nicole , BAISCH, Gabriele
IPC分类号： C07D209/24
CPC分类号： C07D209/24
摘要： A process for the preparation of compounds of formula (1), by enzymatic acylation to form compounds of formulae (3a) and (3a') and then reacting the compound of formula (3a) with a compound introducing the radical of formula -CH 2 -COOR 8 , R 8 being an organic radical, and then reducing, and optionally hydrolysing, the resulting compound of formula (4).
摘要翻译：通过酶促酰化制备式（1）化合物以形成式（3a）和（3a'）化合物的方法，然后使式（3a）化合物与引入式-CH 2 - 的基团的化合物反应， COOR 8，R 8为有机基团，然后还原并任选地水解得到的式（4）化合物。

6. 发明申请

WO2006120133A2 COLORING KERATIN FIBERS WITH METAL COMPLEXES 审中-公开
标题翻译：具有金属复合物的着色金属纤维
公开(公告)号：WO2006120133A2
公开(公告)日：2006-11-16
申请号：PCT/EP2006/061990
申请日：2006-05-03
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , END, Nicole , SCHÖNING, Kai-Uwe , FRÖHLING, Beate
发明人： END, Nicole , SCHÖNING, Kai-Uwe , FRÖHLING, Beate
IPC分类号： A61K8/49 , A61Q5/10 , C07D213/74 , C07D249/08 , C07D249/10 , C07D251/12 , C07D285/08 , C07D271/06 , A61Q5/12 , C07D471/04 , C07F15/02 , C07F13/00
CPC分类号： C07D271/06 , A61K8/19 , A61K8/40 , A61K8/49 , A61K8/4926 , A61K8/496 , A61K8/4966 , A61K2800/58 , A61Q5/065 , C07D213/74 , C07D249/08 , C07D285/08 , C07D471/04 , C09B55/006 , C09B57/00 , C09B57/10
摘要： The present invention concerns coloring keratin fibers, especially human hair, with colored metal complexes.
摘要翻译：本发明涉及用着色金属络合物着色角蛋白纤维，特别是人类头发。

7. 发明申请

WO2004103977A2 PROCESS FOR THE PREPARATION OF PYRIMIDINE DERIVATIVES 审中-公开
标题翻译：制备吡嗪衍生物的方法
公开(公告)号：WO2004103977A2
公开(公告)日：2004-12-02
申请号：PCT/EP2004/050762
申请日：2004-05-12
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , END, Nicole , RICHTER, Yvonne
发明人： END, Nicole , RICHTER, Yvonne
IPC分类号： C07D239/42
CPC分类号： C07D239/22 , C07D239/38 , C07D239/42 , C07D405/06 , C07F9/65122 , Y02P20/55
摘要： There is described a process for the preparation of compounds of formula (1) starting from the reaction of the compounds of formulae (24), (25) and (26) to form the compound of formula (23), wherein in each case R 1 , R 2 and R 3 are each independently of the others an unsubstituted or substituted organic radical; R 4 is hydrogen, unsubstituted or substituted C 1 -C 8 alkyl, C 1 -C 8 alkoxy, phenoxy or benzyloxy, or halogen; Y 1 and Y 2 are each independently of the other hydrogen or a protecting group, or Y 1 and Y 2 together are a protecting bridge; and X 1 is hydrogen, an organic radical or a cation; and also novel intermediates.
摘要翻译：描述了从式（24），（25）和（26）的化合物的反应开始制备式（1）化合物以形成式（23）的化合物的方法，其中在每种情况下R1 R2和R3各自独立地为未取代或取代的有机基团; R4是氢，未取代或取代的C1-C8烷基，C1-C8烷氧基，苯氧基或苄氧基或卤素; Y1和Y2各自独立于另一个氢或保护基，或Y1和Y2一起是保护桥; X1为氢，有机基或阳离子; 还有新的中间体。

8. 发明申请

WO2003018555A1 PROCESS FOR THE PREPARATION OF INDOLE DERIVATIVES 审中-公开
标题翻译：制备吲哚衍生物的方法
公开(公告)号：WO2003018555A1
公开(公告)日：2003-03-06
申请号：PCT/EP2002/009046
申请日：2002-08-13
申请人： CIBA SPECIALITY CHEMICALS HOLDING INC. , WOLLEB, Heinz , WOLLEB, Annemarie , VAN DER SCHAAF, Paul, Adriaan , KOLLY, Roman , END, Nicole
发明人： WOLLEB, Heinz , WOLLEB, Annemarie , VAN DER SCHAAF, Paul, Adriaan , KOLLY, Roman , END, Nicole
IPC分类号： C07D209/24
CPC分类号： C07D405/06 , C07D209/24 , C07D319/06 , C07F5/025 , Y02P20/55
摘要： A process for the preparation of compounds of formula (I) wherein R 1 is unsubstituted or substituted C 1 -C 8 alkyl, R 2 , R 3 , R 4 and R 5 are each independently of the others hydrogen, unsubstituted or substituted C 1 -C 8 alkyl, C 1 -C 8 alkoxy, phenoxy or benzyloxy, or halogen, Y 1 and Y 2 are each independently of the other hydrogen or a protecting group, or Y 1 and Y 2 together form a protecting bridge, and X 1 is hydrogen, an organic radical or a cation, in which process a compound of formula (II) wherein R 1 R 2 R 3 , R 4 and R 5 are as defined above and Z 1 is a leaving group, is reacted, in the presence of a catalytically effective amount of a palladium catalyst, with a compound of formula (III) wherein R 6 is hydrogen, bromine, chlorine, iodine, -OSO 2 CF 3 , -COCI, -B(OH) 2 or a mono- or di-ester derived from -B(OH) 2 , Y 3 and Y 4 are each a protecting group, or Y 3 and Y 4 together form a protecting bridge, and X 1 is as defined above, to form a compound of formula (IV) and if desired the radicals Y 3 and Y 4 are converted into the radicals Y 1 and Y 2 where Y 1 and Y 2 are hydrogen.
摘要翻译：制备其中R 1为未取代或取代的C 1 -C 8烷基，R 2，R 3，R 4和R 5的式（I）化合物的方法各自独立地为氢，未取代或取代的C 1 -C 8烷基，C 1 -C 8烷氧基，苯氧基或苄氧基或卤素，Y1和Y2各自独立地为另一个氢或保护基，或Y1和Y2一起形成保护桥，并且X 1是氢，有机基团或阳离子，其中式（II）其中R1 R2 R3，R4和R5如上定义，Z1是离去基团，在催化有效量的钯催化剂存在下与式（III）化合物反应，其中R 6是氢，溴，氯，碘，-OSO 2 CF 3，-COCI，-B（OH）2或衍生自-B（OH）2，Y 3和Y 4的单酯或二酯各自为保护基，或Y 3和Y 4一起形成保护桥，X1如上所定义，形成式（IV）的化合物，如果需要，基团Y 3和Y 4为转化为Y1和Y2基团，其中Y1和Y2是氢。

9. 发明公开

EP1981635A1 USE OF METAL COMPLEX COMPOUNDS AS OXIDATION CATALYSTS 审中-公开
标题翻译：金属络合物作为氧化催化剂使用
公开(公告)号：EP1981635A1
公开(公告)日：2008-10-22
申请号：EP06708048.1
申请日：2006-02-06
申请人： Ciba Holding Inc.
发明人： SCHLINGLOFF, Gunther , NIVALKAR, Kishor, Ramachandra , WIEPRECHT, Torsten , DUBS, Marie-Josée , END, Nicole
IPC分类号： B01J31/18 , C07B33/00 , A61L2/18 , A61L2/23 , A61L12/12 , C11D3/39 , C11D17/00 , D06L3/02 , D06M11/32 , D06M11/50 , D21C9/16 , C02F1/72 , C02F1/74 , C07D213/22 , C07D401/14
CPC分类号： B01J31/1835 , A61L2/186 , A61L2/23 , A61L12/124 , A61L12/128 , A61L2202/17 , A61L2202/26 , B01J31/1815 , B01J31/182 , B01J31/183 , B01J31/184 , B01J2231/70 , B01J2531/0258 , B01J2531/16 , B01J2531/46 , B01J2531/72 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C02F1/683 , C02F1/722 , C02F1/725 , C02F2303/04 , C07D213/22 , C07D213/74 , C07D401/14 , C07D471/04 , C11D3/3932 , C11D17/0039 , C11D17/06 , D06M11/32 , D06M11/50 , D21C9/1036 , D21C9/163
摘要： The present invention relates to the use, as oxidation catalysts, of metal complex compounds having tetradentate ligands of formula (2) wherein all subsitutents have the meanings as defined in Claim 1. The present invention relates also to formulations comprising such metal complex compounds, to novel metal complex compounds and to novel ligands.

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