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1. 发明申请

WO2008092771A1 CATIONIC DYES 审中-公开
标题翻译：阳光染色
公开(公告)号：WO2008092771A1
公开(公告)日：2008-08-07
申请号：PCT/EP2008/050666
申请日：2008-01-22
申请人： CIBA HOLDING INC. , ELIU, Victor Paul , FRÖHLING, Beate , KAUFFMANN, Dominique
发明人： ELIU, Victor Paul , FRÖHLING, Beate , KAUFFMANN, Dominique
IPC分类号： A61K8/49 , A61Q5/10 , C09B69/00
CPC分类号： A61Q5/065 , A61K8/4986 , A61K2800/94 , C09B44/101 , C09B44/107 , C09B55/003
摘要： Disclosed are dyes of Formula (I) wherein D is the radical of anthraquinone, acridine, azo, azomethine, hydrazomethine, benzodifuranone, coumarine, diketopyrrolopyrrol, dioxaxine, diphenylmethane, formazane, indigoid, indophenol, naphtalimide, naphthaquinone, nitroaryl, merocyanine, methine, oxazine,perinone, perylene, pyrenequinone, phtalocyanine, phenazine, quinoneimine, quinacridone, quinophtalone, stilbene, styryl, triphenylmethane, xanthene, thiazine dye and thioxanthene dye; Q is C 1 -C 30 alkylene, -C 2 -C 12 alkenylene, C 5 -C 10 arylene-, C 5 -C 10 cycloalkylene-or -C 1 - C 10 alkylene(C 5 -C 10 arylene)-which may be interrupted and/or terminated at one or both ends by one or more than one -O-, -S-, -N=, -N(R 1 )-, SO 2, -(CH 2 CH 2-O) 1-5-, -(CH 2 CH 2 CH 2 -O) 1-5-, -C(O)-, -C(O)-C 1 -C 12 alkenylene, -C(O)O-, -OCO-, A N+ R 1 R 2, -CON(R 1 )-, -C(NR 1 R 2 ) 2 -, -(R 1 )NC(O)-, -CSR 1 -or an optionally substituted, saturated or unsaturated, fused or non-fused aromatic or nonaromatic (hetero)cyclic) bivalent radical optionally comprising at least one heteroatom; -O-; -S-; -N(R 1 )-; SO 2 ; -(CH 2 CH 2 -O) 1-5 -; -C(O)-; -C(O)-C 1 -C 12 alkenylene; -C(O)O-, -OCO-; B N+ R 1 R 2; -CON(R 1 )-; -C(NR 1 R 2 ) 2 -; -(R 1 )NC(O)-; CSR 1 ; saturated or unsaturated, fused or non-fused aromatic or nonaro- matic bivalent radical optionally comprising at least one heteroatom; which is optionally substituted by C 1 -C 30 alkyl, C 1 -C 30 alkoxy, -C 2 -C 12 alkenyl, C 5 -C 10 aryl, C 5 -C 10 cycloalkyl, C 1 - C 10 alkyl(C 5 -C 10 arylene), hydroxy or D+; R 1 and R 2 independently from each other are hydrogen; or unsubstituted or substituted, straight-chain or branched, monocyclic or polycyclic, interrupted or uninterrupted C 1 - C 14 alkyl; C 1 -C 14 hydroxyalkyl; C 1 -C 14 aminoalkyl; C 2 -C 14 alkenyl; C 6 -C 10 aryl; C 6 -C 10 aryl-C 1 - C 10 alkyl; or C 5 -C 10 alkyl(C 5 -C 10 aryl).
摘要翻译：公开了式（I）的染料，其中D是蒽醌，吖啶，偶氮，偶氮甲碱，肼基甲基，苯并二呋喃酮，香豆素，二酮吡咯并吡咯，二氧杂环己烷，二苯基甲烷，甲ane烷，靛类，靛酚，萘二甲酰亚胺，萘醌，硝基芳基，苝，苝醌，吩嗪，醌亚胺，喹吖啶酮，喹诺酮，二苯乙烯，苯乙烯基，三苯甲烷，呫吨，噻嗪染料和噻吨染料; Q是C 1 -C 30亚烷基，-C 2 -C 12亚烯基，C 5 C 1 -C 10亚芳基 - ，C 5 -C 10亚环烷基或-C 1 -C 10 - C 10亚烷基（C 5 -C 20 -C 10亚芳基） - 其可以在一个或两个末端被一个或多个中断和/或终止（CH 2） - ， - N（R 1） - ， - SO 2 - ， - CH 2 -O）1-5 - ， - （CH 2 CH 2 CH 2 CH 2 -O）1-5 - ， - C（（O） - ， - C（O）-C 1 -C 12亚烯基，-C（O）O-，-OCO-，AN + R 1 R 2， CON（R 1） - ， - （NR 1 R 2）2 - ， - （R' 任选地，任选取代的，饱和或不饱和的稠合或非稠合的芳族或非芳族（杂）环）二价基团，其中R 1，R 2，包含至少一个杂原子; -O-; -S-; -N（R _{1 ） - ; SO _{2 ; - （CH 2 CH 2 -O-O） - 1〜5 - ; -C（O） - ; -C（O）-C _{1 -C _{12 烯基; -C（O）O-，-OCO-; B N + R 1 R}}}}

2. 发明申请

WO2005095522A2 2,5-DIAMINO SUBSTITUTED AZO DYES 审中-公开
标题翻译： 2,5-DIAMINO取代的AZO染料
公开(公告)号：WO2005095522A2
公开(公告)日：2005-10-13
申请号：PCT/EP2005/051323
申请日：2005-03-23
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , ELIU, Victor Paul , SAUDER, Thomas , KAUFFMANN, Dominique , FRÖHLING, Beate
发明人： ELIU, Victor Paul , SAUDER, Thomas , KAUFFMANN, Dominique , FRÖHLING, Beate
IPC分类号： C09B44/16
CPC分类号： C09B44/16
摘要： Disclosed are azo dyes of formula (1) , wherein R 1 is hydrogen; C 1 -C 14 alkyl; hydroxy- C 1 -C 14 alkyl; C 2 -C 14 alkenyl; a radical of formula (1a) -(CH 2 ) n1 -O-(CH 2 ) n2 -CH 3 ; a radical of formula (1b) C 10 aryl; or C 6 -C 10 aryl-C 1 -C 6 alkyl; R3 is hydrogen; C 1 -C 14 alkyl; C 2 -C 14 alkenyl; C 6 -C 10 aryl; C 6 -C 1 0aryl-C 1 -C 6 alkyl; or CO-R 6 ; R 4 is CO-R 6 ; R 5 is C 1 -C 14 alkyl; C 2 -C 14 alkenyl; C 6 -C 10 aryl; or C 6 -C 10 aryl-C 1 -C 6 alkyl; R 6 is hydrogen; C 1 -C 14 alkyl; C 2 -C 14 alkenyl; or C 6 -C 10 aryl; R 7 , R 8 , R 9 and R 10 , independently from each other are hydrogen; or C 1 -C 5 alkyl; m is 1; or 2; An - is an anion; If m = 1, R 2 is hydrogen; C 1 -C 14 alkyl; C 2 -C 14 alkenyl; a radical of formula (1a); a radical of formula (1b) ; C 6 -C 10 aryl; or C 6 -C 10 aryl-C 1 -C 6 alkyl; If m = 2, R 2 is the direct bond; or C 1 -C 14 alkylene, which is optionally substituted by one or more C 1 -C 4 alkyl, or which is optionally interrupted by C 5 -C 10 arylene, -O- or -NR 9 R 10 -; R 9 and R 10 , independently from each other are hydrogen; or C 1 -C 5 alkyl; and n1, n2, n3 and n4, independently from each other are a number from 0 to 5. The compounds are useful for the dyeing of organic material, preferably human hair.
摘要翻译：公开了式（1）的偶氮染料，其中R 1是氢; ç<子> 1 -C <子> 14 烷基; 羟基-C 1 -C 14 - 烷基; ç<子> 2 -C <子> 14 烯基; 式（1a） - （CH 2）n1 -O-（CH 2）n2 -n- CH <子> 3 ; 式（1b）C10芳基的基团; 或C 6 -C 10芳基-C 1 -C 6烷基;或C 6 -C 10芳基-C 1 -C 6烷基。 R3是氢; ç<子> 1 -C <子> 14 烷基; ç<子> 2 -C <子> 14 烯基; ç<子> 6 -C <子> 10 芳基; ç<子> 6 -C <子> 1 0aryl-C <子> 1 -C <子> 6 烷基; 或CO-R 6; R 4是CO-R 6; R 5是C 1 -C 14烷基; R 5是C 1 -C 14烷基。 ç<子> 2 -C <子> 14 烯基; ç<子> 6 -C <子> 10 芳基; 或C 6 -C 10芳基-C 1 -C 6烷基;或C 6 -C 10芳基-C 1 -C 6烷基。 R 6是氢; ç<子> 1 -C <子> 14 烷基; ç<子> 2 -C <子> 14 烯基; 或C≡C-C10芳基; R 7，R 8，R 9和R 10彼此独立地为氢; R 7，R 8，R 9和R 10彼此独立地为氢; 或C 1 -C 5烷基; m是1; 或2; An ^{- 是一个阴离子; 如果m = 1，则R 2是氢; ç<子> 1 -C <子> 14 烷基; ç<子> 2 -C <子> 14 烯基; 式（1a）的基团; 式（1b）的基团; ç<子> 6 -C <子> 10 芳基; 或C 6 -C 10芳基-C 1 -C 6烷基;或C 6 -C 10芳基-C 1 -C 6烷基。如果m = 2，则R 2是直接键; 或C 1 -C 14亚烷基，其任选被一个或多个C 1 -C 4烷基，或者任选地被C 5 -C 10亚芳基，-O-或-NR 9 R 10取代的亚苯基， > - ; R 9和R 10彼此独立地为氢; 或C 1 -C 5烷基; 并且n1，n2，n3和n4彼此独立地为0-5的数。所述化合物可用于染色有机材料，优选人发。}

3. 发明申请

WO2007039502A2 XANTHENE DYES 审中-公开
标题翻译：黄嘌呤染料
公开(公告)号：WO2007039502A2
公开(公告)日：2007-04-12
申请号：PCT/EP2006/066673
申请日：2006-09-25
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , ELIU, Victor Paul , FRÖHLING, Beate , KAUFFMANN, Dominique
发明人： ELIU, Victor Paul , FRÖHLING, Beate , KAUFFMANN, Dominique
CPC分类号： C09B49/126 , A61K8/49 , A61K8/498 , A61Q5/10 , C09B11/24 , C09B11/245
摘要： Disclosed are compounds of formula (1a), wherein R 1 is N + R 8 R 9 ; R 8 and/or R 9 independently from each other are hydrogen; C 1 -C 12 alkyl; or phenyl-C 1 -C 4 -alkyl; or R 8 and/or R 9 are a bivalent C 3 -C 6 alkylene radical which is linked to the carbon atoms C 1 or C 2 respectively and, together with the linking nitrogen atom form a 6 to 16-membered carbocyclic ring; R 2 is NR 10 R 11 ; or OR 10 ; R 10 and R 11 , independently from each other are hydrogen; C 1 -C 12 alkyl; or phenyl-C 1 -C 4 alkyl; or R 10 and/or R 11 are a bivalent C 3 -C 6 alkylene radical which is linked to the carbon atoms C 3 or C 4 respectively and, together with the linking nitrogen or oxygen atom form a 6 to 16- membered carbocyclic ring; or R 10 and R 11 together with the linking nitrogen atom form a 4 to 8 membered carbocyclic ring; R 3 , R 4 , R 5 , R 6 and R 7 independently form each other are hydrogen; C 1 -C 12 alkyl; halogen; NR 12 R 13 ; or a radical of formula (1a 1 ); R 12 and R 13 independently from each other are hydrogen; C 1 -C 12 alkyl; phenyl-C 1 -C 4 alkyl; or a radical of formula (1a 2 ); V is -O-; Or -NR 15 ; R 14 , R 15 R- 16 and R 17 independently from each other are hydrogen; or C 1 -C 5 alkyl; and Hal is a halogen atom; and wherein at least one of R 3 , R 4 , R 5 , R 6 and R 7 is hydrogen. The compounds are useful for dyeing of keratin-containing fibres with or without reducing agents.
摘要翻译：公开了式（1a）的化合物，其中R 1是N + 8 R 8 R 8， 9 ; R 8和/或R 9彼此独立地为氢; ç<子> 1 -C <子> 12 烷基; 或苯基-C 1 -C 4 - 烷基;或苯基-C 1 -C 4 - 烷基。或R 8和/或R 9是二价C 3 -C 6亚烷基，其连接到碳原子C 1或C 2分别与连接的氮原子一起形成6至16元碳环; R 2 = NR 10 R 11; 或OR _{10 ; R 10和R 11彼此独立地为氢; ç<子> 1 -C <子> 12 烷基; 或苯基-C 1 -C 4烷基;或苯基-C 1 -C 4烷基。或R 10和/或R 11是二价C 3 -C 6亚烷基，其连接到碳原子C 3或C 4分别与连接的氮或氧原子一起形成6至16元碳环; 或者R 10和R 11与连接的氮原子一起形成4至8元碳环; R 3，R 4，R 5，R 6和R 7各自独立地彼此形成氢; ç<子> 1 -C <子> 12 烷基; 卤素; NR <子> 12 ř<子> 13 ; 或式（1a1）的基团; R 12和R 13彼此独立地为氢; ç<子> 1 -C <子> 12 烷基; 苯基-C <子> 1 -C <子> 4 烷基; 或式（1a2）的基团; V是-O-; 或-NR 15 15; R 14，R 15，R 16和R 17彼此独立地为氢; R 14，R 15，R 16和R 17彼此独立地为氢; 或C 1 -C 5烷基; Hal是卤素原子; 并且其中R 3，R 4，R 5，R 6和R 6中的至少一个为氢， 7是氢。该化合物可用于含或不含还原剂的含角蛋白纤维的染色。}

4. 发明申请

WO2004100912A2 METHOD OF COLOURING POROUS MATERIAL 审中-公开
标题翻译：多孔材料着色方法
公开(公告)号：WO2004100912A2
公开(公告)日：2004-11-25
申请号：PCT/EP2004/050707
申请日：2004-05-05
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , ELIU, Victor Paul , FRÖHLING, Beate , KAUFFMANN, Dominique
发明人： ELIU, Victor Paul , FRÖHLING, Beate , KAUFFMANN, Dominique
IPC分类号： A61K7/13
CPC分类号： A61K8/466 , A61K8/40 , A61K8/49 , A61K8/494 , A61Q5/10
摘要： Process of colouring porous material, which comprises a) applying to the material being coloured at least one capped diazonium compound and b) then causing the capped diazonium compound present on the material to react with the hair. In addition, novel dyeing compounds and compositions thereof are claimed.
摘要翻译：着色多孔材料的方法，其包括：a）向被着色为至少一种封盖重氮化合物的材料施用，和b）然后使存在于材料上的被覆盖的重氮化合物与毛发反应。此外，要求保护新的染色化合物及其组合物。

5. 发明申请

WO2007025889A2 THIOL DYES 审中-公开
公开(公告)号：WO2007025889A2
公开(公告)日：2007-03-08
申请号：PCT/EP2006/065488
申请日：2006-08-21
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , ELIU, Victor Paul , FRÖHLING, Beate , KAUFFMANN, Dominique
发明人： ELIU, Victor Paul , FRÖHLING, Beate , KAUFFMANN, Dominique
IPC分类号： C09B69/00 , C09B44/16 , C09B26/04 , C09B23/14
CPC分类号： A61Q5/10 , A61K8/4926 , C09B23/145 , C09B26/04 , C09B44/107
摘要： Disclosed are thiol dyes of formula (I), wherein R 1 , R 2 , R 3 , R 4 and R 5 independently from each other are hydrogen; unsubstituted or substituted, straight-chain or branched, monocyclic or polycyclic, interrupted or uninterrupted C 1 -C 14 alkyl; C 2 -C 14 alkenyl; C 6 -C 10 aryl; C 6 -C 10 aryl-C 1 -C 10 alkyl; or C 5 -C 10 alkyl(C 5 -C 10 aryl); A is a residue of an organic dye; and Y 1 is the direct bond; C 1 C 10 alkylene; C 5 -C 10 cycloalkylene; C 5 -C 12 arylene; or C 5 -C 12 arylene- (C1-C 10 alkylene). The compounds are used to dye hair with or without reducing agents. Furthermore, the present invention relates to compositions comprising thiol dyes of formula (I) and to process for the preparation of theses compounds.
摘要翻译：公开了式（I）的硫醇染料，其中R 1，R 2，R 3，R 4，和R 5彼此独立地是氢; 未取代或取代的直链或支链的单环或多环，间断或不间断的C 1 -C 14烷基; ç_{2 -C _{14 烯基; ç_{6 -C _{10 芳基; ç_{6 -C _{10 芳基-C _{1 -C _{10 烷基; 或C 5 -C 10烷基（C 5 -C 10芳基）; A是有机染料的残留物; 和Y 1是直接键; ç_{1 C _{10 亚烷基; ç_{5 -C _{10 亚环烷基; ç_{5 -C _{12 亚芳基; 或C 5 -C 12亚芳基 - （C 1 -C 10亚烷基）。该化合物用于染发具有或不具有还原剂的头发。此外，本发明涉及包含式（I）的硫醇染料和用于制备这些化合物的方法的组合物。}}}}}}}}}}}}}}

6. 发明申请

WO2006134043A2 STYRYL SULFIDE DYES 审中-公开
公开(公告)号：WO2006134043A2
公开(公告)日：2006-12-21
申请号：PCT/EP2006/062946
申请日：2006-06-07
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , ELIU, Victor Paul , FRÖHLING, Beate , KAUFFMANN, Dominique
发明人： ELIU, Victor Paul , FRÖHLING, Beate , KAUFFMANN, Dominique
CPC分类号： C09B23/14 , A61K8/4926 , A61Q5/10 , C09B23/145 , C09B49/00
摘要： Disclosed are styryl sulfide dyes of formula (1), wherein R 1 , R' 1 , R 2 , R' 2 , R 3 and R' 3 , independently from each other are hydrogen; C 1 -C 20 alkyl or C 1 - C 20 alkoxy, which may be substituted by one or more C 1 -C 5 alkoxy, halogen, -NH 2 , mono-C 1 -C 5 alkylamino, di-C 1 -C 5 alkylamino, -NO 2 or hydroxy; C 3 -C 6 cycloalkyl; -C(O)H; -C(O)-C 1 -C 5 alkyl; halogen; NO 2 ; OH; phenyl, which may be substituted by one or more C 1 -C 5 alkyl, C 1 -C 5 alkoxy, halogen, -NH 2 , mono-C 1 -C 5 alkylamino, di-C 1 -C 5 alkylamino, -NO 2 or hydroxy; or a radical of formula -NR 4 R 5 , wherein R 4 and R 5 independently from each other are hydrogen; C 1 -C 12 alkyl, which may be substituted by one or more C 1 -C 5 alkyl, C 1 -C 5 -alkoxy, hydroxy or -(CO)-H; -(CO)-C 1 -C 5 alkyl; phenyl or phenyl-C 1 -C 4 alkyl, wherein the phenyl moiety may be substituted by one or more C 1 -C 5 alkyl, C 1 -C 5 alkoxy, halogen, -NH 2 , mono-C 1 -C 5 alkylamino, di-C 1 -C 5 alkylamino, -NO 2 , carboxy or hydroxy; W 1 , W' 1 , W 2 , W' 2 , W 3 , W' 3 , W 4 or W' 4 , independently from each other are -CH- or -N + -; wherein only one of W 1 /W' 1 , W 2 /W' 2 , W 3 /W' 3 , W 4 /W 4 ' is -N + ; and the bivalent radical -Q-Z-Y-S-S-Y'-Z'-Q'- is bonded to W 1 or W 2 and W' 1 or W' 2 respectively; Y 1 and Y 2 independently from each other are C 1 -C 10 alkylene; C 5 -C 10 cycloalkylene; C 5 -C 12 arylene; or C 5 -C 12 arylene-(C 1 -C 10 alkylene); Q and Q' independently from each other are the direct bond; or -C(O)-; -C(O)O-; -OCO-; -N(R 6 )-; formula (AA); -C(O)N(R 6 )-; -(R 6 )NC(O)-; -O-; -S-; -S(O)-; or -S(O) 2 -; and R 6 and R 7 independently from each other are hydrogen; C 1 -C 14 alkyl; C 2 -C 14 alkenyl; C 6 - C 12 aryl; C 6 -C 12 aryl-C 1 -C 10 alkyl; or C 1 -C 10 alkyl(C 5 -C 12 aryl). Further, the present invention relates to novel styryl sulfide compounds, compositions thereof, especially comprising other dyes, and to processes for their preparation.
摘要翻译：公开了式（1）的苯乙烯基硫化物染料，其中R 1，R'1，R 2，R'2， R 3，R 3和R 3'彼此独立地是氢; C 1 -C 20烷基或C 1 -C 20烷氧基，其可以被一个或多个 C 1 -C 5 -C 5烷氧基，卤素，-NH 2，单-C 1 -C 3烷基， 5个烷基氨基，二-C 1 -C 5烷基氨基，-NO 2 2或羟基; ç_{3 -C _{6 环烷基; -C（O）H; -C（O）-C _{1 -C _{5 烷基; 卤素; NO _{2 ; 哦; 苯基，其可以被一个或多个C 1 -C 5烷基取代，C 1 -C 5 -C 5烷基，烷氧基，卤素，-NH 2，单-C 1 -C 5烷基氨基，二-C 1 - C 5烷基氨基，-NO 2或羟基; 或式-NR 4 R 5的基团，其中R 4和R 5彼此独立地为氢; C 1 -C 12烷基，其可以被一个或多个C 1 -C 5烷基取代， C 1 -C 5 - 烷氧基，羟基或 - （CO）-H; - （CO）-C _{1 -C _{5 烷基; 苯基或苯基-C 1 -C 4烷基，其中苯基部分可以被一个或多个C 1 -C 4烷基取代， C 1 -C 5烷基，C 1 -C 5烷氧基，卤素，-NH 2，C 1 -C 12烷基， C 1 -C 5烷基氨基，二-C 1 -C 5烷基氨基，-NO 2 2，羧基或羟基; W 1，W 2，W 2，W'2，W 3，/ SO 2 >，W'3，W 4或W'4，彼此独立地是-CH-或-N + / SUP> - ; 其中W 1 / W'1，W 2 / W'2，W 2中的仅一个， 3 / W 3，W 4或W 4是-N + O 3。并且二价基团-QZYSS-Y'-Z'-Q'-键合到W 1或W 2和W'1或分别为W'2 Y 1和Y 2彼此独立地是C 1 -C 10亚烷基; ç_{5 -C _{10 亚环烷基; ç_{5 -C _{12 亚芳基; 或C 5 -C 12亚芳基 - （C 1 -C 10亚烷基）; Q和Q'彼此独立是直接键; 或-C（O） - ; -C（O）O-; -OCO-; -N（R _{6 ） - ; 式（AA）; -C（O）N（R _{6 ） - ; - （R _{6 ）NC（O） - ; -O-; -S-; -所以）-; 或-S（O）2 - ; R 6和R 7和R 7彼此独立地是氢; ç_{1 -C _{14 烷基; ç_{2 -C _{14 烯基; C 6 -C 12芳基; ç_{6 -C _{12 芳基-C _{1 -C _{10 烷基; 或C 1 -C 10烷基（C 5 -C 12 - 芳基）。此外，本发明涉及新颖的苯乙烯基硫化物，其组合物，特别是其它染料，以及其制备方法。}}}}}}}}}}}}}}}}}}}}}}

7. 发明申请

WO2005058840A2 METHOD OF COLORING WITH CAPPED DIAZOTIZED COMPOUND AND COUPLING COMPONENT 审中-公开
标题翻译：着色重氮化合物和偶联成分的着色方法
公开(公告)号：WO2005058840A2
公开(公告)日：2005-06-30
申请号：PCT/EP2004/053335
申请日：2004-12-08
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , ELIU, Victor Paul , FRÖHLING, Beate , KAUFFMANN, Dominique
发明人： ELIU, Victor Paul , FRÖHLING, Beate , KAUFFMANN, Dominique
IPC分类号： C07D233/00
CPC分类号： C07D213/77 , A61K8/49 , A61K8/4926 , A61K8/4946 , A61K8/496 , A61Q5/065 , A61Q5/10 , B27K3/34 , B27K3/343 , B27K3/38 , B27K5/02 , C07D233/88 , C07D249/14 , C07D277/50 , C09B56/20
摘要： The present invention relates to a method of coloring porous material, which comprises contacting the material being colored, with a) a capped diazonium compound of formula (1) wherein A + is a cationic radical of an organic compound, B is a radical of an unsubstituted or substituted, aliphatic or aromatic amine, An is an anion,and b) optionally a coupling component. Further, the present invention relates to novel compounds and compositions thereof.
摘要翻译：本发明涉及着色多孔材料的方法，该方法包括使着色材料与a）式（1）的封端的重氮化合物接触，其中A + 是有机化合物的阳离子基团，B是未取代或取代的脂肪族或芳香族胺的基团，An是阴离子，和b）任选的偶联组分。此外，本发明涉及新型化合物及其组合物。

8. 发明申请

WO2003060015A1 YELLOW CATIONIC DYES FOR DYING OF ORGANIC MATERIAL 审中-公开
标题翻译：用于染色有机物的黄色阳离子染料
公开(公告)号：WO2003060015A1
公开(公告)日：2003-07-24
申请号：PCT/EP2003/000068
申请日：2003-01-07
申请人： CIBA SPECIALITY CHEMICALS HOLDING INC. , ELIU, Victor Paul , FRÖHLING, Beate , HAUSER, Julia
发明人： ELIU, Victor Paul , FRÖHLING, Beate , HAUSER, Julia
IPC分类号： C09B26/04
CPC分类号： C09B26/04
摘要： The present invention relates to novel cationic yellow dyes of formula (1) wherein R 1 and R 2 are each independently of the other a C 1 -C 8 alkyl radical or an unsubstituted or substituted benzyl radical, R 3 is hydrogen, C 1 -C 8 alkyl, C 1 -C 8 alkoxy, cyanide or halide, preferably hydrogen and X is an anion, with the proviso that at least one of the substitutents R 1 is a benzyl radical and R 2 is a methyl radical, R 2 is not hydrogen, also to compositions therof, especially comprising other dyes, to processes for the preparation therof and to the use therof in the dyeing of organic material, such as keratin, wool, leather, silk, cellulose or polyamides, especially keratin-containging fibres, cotton or nylon, and preferably human hair.
摘要翻译：本发明涉及式（1）的新型阳离子黄色染料，其中R1和R2各自独立地为C1-C8烷基或未取代或取代的苄基，R3为氢，C1-C8烷基，C1-C8烷氧基，氰化物或卤化物，优选氢，X是阴离子，条件是至少一个取代基R 1是苄基，R 2是甲基，R 2不是氢，也包括其它染料的组合物，特别是其它染料用于制备和用于染色有机材料如角蛋白，羊毛，皮革，丝绸，纤维素或聚酰胺，特别是含角蛋白的纤维，棉或尼龙，优选人发的用途。

9. 发明申请

WO2004076564A1 CATIONIC DYES, THEIR PRODUCTION AND USE 审中-公开
标题翻译：阳光染色体，其生产和使用
公开(公告)号：WO2004076564A1
公开(公告)日：2004-09-10
申请号：PCT/EP2004/050132
申请日：2004-02-16
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , ELIU, Victor Paul , FRÖHLING, Beate
发明人： ELIU, Victor Paul , FRÖHLING, Beate
IPC分类号： C09B69/06
CPC分类号： C09B69/065 , A61K8/4946 , A61Q5/065 , C09B44/103
摘要： The present invention relates to novel cationic dye of formula (1) wherein R 1 and R 7 are each independently of the other hydrogen, hydroxyl; unsubstituted or substituted C 1 -C 6 alkyl, aryl radical or C 1 I-C 6 alkoxy; or -NR 3 R 4 , wherein R 3 and R 4 are each independently of the other hydrogen, unsubstituted or substituted aryl radical or C 1 -C 6 alkyl, and R 2 is hydrogen, hydroxyl, unsubstituted or substituted C 1 C 6 alkyl, aryl radical or C 1 -C 6 alkoxy, - NR3R4 , or an organic radical of formula (2) wherein R 5 is hydrogen, unsubstituted or substituted aryl radical or C 1 -C 6 alkyl, and X is an anion. Further, the present invention relates to compositions thereof, especially comprising other dyes, to processes for the preparation thereof and to the use thereof in the dyeing of organic material, such as keratin, wool, leather, silk, cellulose or polyamides, and preferably human hair.
摘要翻译：本发明涉及式（1）的新型阳离子染料，其中R 1和R 7各自独立地为氢，羟基; 未取代或取代的C 1 -C 6烷基，芳基或C 1 -C 6烷氧基; 或-NR 3 R 4，其中R 3和R 4各自独立地为氢，未取代或取代的芳基或C 1 -C 6烷基，且R 2为氢，羟基，未取代或取代的C 1 -C 6烷基，芳基或C 1 -C 6烷氧基，-NR 3 R 4或式（2）的有机基团，其中R 5是氢，未取代或取代的芳基或C 1 -C 6烷基，X是阴离子。此外，本发明涉及其组合物，特别是其它染料，其制备方法及其在染色有机材料如角蛋白，羊毛，皮革，丝，纤维素或聚酰胺，优选人头发。

10. 发明申请

WO2007039527A3 THIOL DYES 审中-公开
公开(公告)号：WO2007039527A3
公开(公告)日：2007-04-12
申请号：PCT/EP2006/066773
申请日：2006-09-27
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , ELIU, Victor Paul , FRÖHLING, Beate , BÜHRER, Achim
发明人： ELIU, Victor Paul , FRÖHLING, Beate , BÜHRER, Achim
IPC分类号： C09B23/14 , A61K8/49
摘要： Disclosed are thiol dyes of formula (1), wherein R 1 is hydrogen; C 1 -C 12 alkyl; or phenyl-C 1 -C 4 alkyl; X is C 1 -C 12 alkylene; C 2 -C 12 alkenylene; C 5 -C 10 cycloalkylene; C 5 -C 10 arylene; or C 5 -C 10 arylene- C 1 -C 10 alkylene; Y is the residue of an organic dye which corresponds to the formula (1a), wherein R 2 is hydrogen; or C 1 -C 5 alkyl; R 3 is a radical of formula (1a 1 ) : (1a 2 ); or (1a 3 ) ; or R 2 and R 3 together with the linking carbon atom 1 C form a 6 to 10 membered carbocyclic ring which may optionally be a condensated aromatic system and may contain one or more than one hetero atom; and R 4 , R 5 and R 6 independently form each other are hydrogen, or C 1 -C 5 alkyl; Z is H; or a thio ester group of formula (1b), wherein A is O; S; or N-R9; B is -OR7; -NR7R8, or -SR7; and A is O; S; or N-R 9 ; B is -OR 7 ; -NR 7 R 8 , or -SR 7 ; and R 7 , R 8 and R 9 , independently from each other are hydrogen; C 1 -C 12 alkyl C 6 -C 12 aryl; or C 6 -C 12 aryl- C 1 -C 12 alkyl. The compounds are useful for the dyeing of organic materials, such as keratin fibers, preferably human hair.

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