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1. 发明专利

CZ298441B6 Katalyzátor pro výrobu vinylacetátu a zpusob výroby vinylacetátu 未知
公开(公告)号：CZ298441B6
公开(公告)日：2007-10-03
申请号：CZ20013947
申请日：2000-04-22
申请人： CELANESE CHEM EUROPE GMBH
发明人： HERZOG BERNHARD , SCHANFER AXEL , RENKEL KARL-HEINZ , WANG TAO
IPC分类号： B01J23/68 , B01J23/52 , C07B61/00 , C07C67/055 , C07C69/01 , C07C69/15
摘要： Katalyzátor na nosici obsahuje palladium a/nebo jeho slouceniny, zlato a/nebo jeho slouceniny, slouceniny alkalických kovu a dále vanad a/nebo jeho slouceniny a jeho použití pro výrobu vinylacetátu zkyseliny octové, ethylenu a kyslíku nebo plynu obsahujících kyslík.

2. 发明专利

ES2226061T3 CATALIZADOR, PROCEDIMIENTO PARA LA FABRICACION DEL CATALIZADOR Y PROCEDIMIENTO PARA LA FABRICACION DE VINILACETATO POR EL EMPLEO DEL CATALIZADOR. 未知
公开(公告)号：ES2226061T3
公开(公告)日：2005-03-16
申请号：ES98122923
申请日：1998-12-02
申请人： CELANESE CHEM EUROPE GMBH
发明人： HERZOG BERNHARD DR , STEIN ROSWITHA , RENKEL KARL-HEINZ
IPC分类号： B01J23/44 , B01J23/52 , B01J23/58 , B01J23/66 , B01J31/04 , B01J37/02 , B01J37/12 , B01J37/16 , C07B61/00 , C07C67/055 , C07C69/15
摘要： EL PRESENTE PROCEDIMIENTO HACE POSIBLE LA PREPARACION DEL CATALIZADOR PARA LA PRODUCCION DE ACETATO DE VINILO EN FASE GASEOSA A PARTIR DE ETILENO, ACIDO ACETICO Y OXIGENO O GASES QUE CONTIENEN OXIGENO, QUE CONTIENE PALADIO Y/O SUS COMPUESTOS, ORO Y/O SUS COMPUESTOS, ASI COMO COMPUESTOS DE METALES ALCALINOS SOBRE UN SOPORTE POROSO Y EN FORMA DE PARTICULAS, FORMANDOSE DE LA SIGUIENTE MANERA A) SE IMPREGNA EL SOPORTE CON COMPUESTOS SOLUBLES DE PALADIO Y ORO, B) LOS COMPUESTOS SOLUBLES DE PALADIO Y ORO SE TRANSFORMAN MEDIANTE LA ADICION DE UNA SOLUCION CON REACCION ALCALINA SOBRE EL SOPORTE EN COMPUESTOS INSOLUBLES DE PALADIO Y ORO, C) LOS COMPUESTOS INSOLUBLES DE PALADIO Y ORO SOBRE EL SOPORTE SE REDUCEN MEDIANTE UN AGENTE REDUCTOR EN FASE LIQUIDA O GASEOSA, D) SE IMPREGNA EL SOPORTE CON AL MENOS UN COMPUESTO SOLUBLE DE METAL ALCALINO Y E) FINALMENTE SE SECA EL SOPORTE COMO MUCHO A UNOS 150 °C, PONIENDOSE EL CATALIZADOR EN LA ETAPA B) EN CONTACTO CON AL MENOS UN COMPUESTO DE PEROXIDO.

3. 发明专利

DE59811750D1 未知
公开(公告)号：DE59811750D1
公开(公告)日：2004-09-09
申请号：DE59811750
申请日：1998-12-02
申请人： CELANESE CHEM EUROPE GMBH
发明人： HERZOG BERNHARD DR , STEIN ROSWITHA , RENKEL KARL-HEINZ
IPC分类号： B01J23/44 , B01J23/52 , B01J23/58 , B01J23/66 , B01J31/04 , B01J37/02 , B01J37/12 , B01J37/16 , C07B61/00 , C07C67/055 , C07C69/15
摘要： A catalyst for the production of vinyl acetate from ethylene, acetic acid and oxygen is obtained by impregnating a support with palladium and gold compounds and then treating the impregnated support with a peroxy compound before reducing the metal compounds, adding an alkali metal compound and drying. A method of producing a catalyst for the gas-phase production of vinyl acetate (Vac) from ethylene, acetic acid and oxygen or O2-containing gas is new. This catalyst contains palladium and/or Pd compounds, gold and/or Au compounds and alkali metal compounds on a porous, particulate support, and is obtained by (a) impregnating the support with soluble Pd and Au compounds, (b) converting these soluble compounds into insoluble Pd and Au compounds on the support by adding an alkaline solution, (c) reducing the metal compounds with a reducing agent in the liquid or gas phase, (d) impregnating the support with soluble alkali metal compound(s), and (e) drying at not above 150 degrees C. In step (b), the catalyst is brought into contact with at least one peroxy compound. Independent claims are also included for (1) a catalyst made by this process; and (2) a process for the production of Vac from ethylene, acetic acid and oxygen in presence of this catalyst.

4. 发明专利

AT249879T 未知
公开(公告)号：AT249879T
公开(公告)日：2003-10-15
申请号：AT00929409
申请日：2000-04-22
申请人： CELANESE CHEM EUROPE GMBH
发明人： HERZOG BERNHARD , SCHAEFER AXEL , RENKEL KARL-HEINZ , WANG TAO
IPC分类号： B01J23/52 , B01J23/68 , C07B61/00 , C07C67/055 , C07C69/01 , C07C69/15
摘要： A process for preparing vinyl acetate in the gas phase from ethylene, acetic acid and oxygen or oxygen-containing gases over a catalyst, consisting essentially of palladium and/or its compounds, gold and/or its compounds and alkali metal compounds on a support, wherein the catalyst further comprises vanadium and/or its compounds and catalyst therefrom.

5. 发明专利

CZ20013947A3 Catalyst for producing vinyl acetate and process for producing vinyl acetate 未知
公开(公告)号：CZ20013947A3
公开(公告)日：2002-03-13
申请号：CZ20013947
申请日：2000-04-22
申请人： CELANESE CHEM EUROPE GMBH
发明人： HERZOG BERNHARD , SCHAFER AXEL , RENKEL KARL-HEINZ , WANG TAO
IPC分类号： B01J23/52 , B01J23/68 , C07B61/00 , C07C67/055 , C07C69/01 , C07C69/15
摘要： A process for preparing vinyl acetate in the gas phase from ethylene, acetic acid and oxygen or oxygen-containing gases over a catalyst, consisting essentially of palladium and/or its compounds, gold and/or its compounds and alkali metal compounds on a support, wherein the catalyst further comprises vanadium and/or its compounds and catalyst therefrom.

6. 发明专利

ID30434A 未知
公开(公告)号：ID30434A
公开(公告)日：2001-12-06
申请号：ID20012315
申请日：2000-04-22
申请人： CELANESE CHEM EUROPE GMBH
发明人： HERZOG B , SCHAFER A , RENKEL KARL-HEINZ , WANG TAO
IPC分类号： B01J23/52 , B01J23/68 , C07B61/00 , C07C67/055 , C07C69/01 , C07C69/15
摘要： A process for preparing vinyl acetate in the gas phase from ethylene, acetic acid and oxygen or oxygen-containing gases over a catalyst, consisting essentially of palladium and/or its compounds, gold and/or its compounds and alkali metal compounds on a support, wherein the catalyst further comprises vanadium and/or its compounds and catalyst therefrom.

7. 发明专利

DE19920390A1 未知
公开(公告)号：DE19920390A1
公开(公告)日：2000-11-16
申请号：DE19920390
申请日：1999-05-04
申请人： CELANESE CHEM EUROPE GMBH
发明人： HERZOG BERNHARD , SCHAEFER AXEL , RENKEL KARL-HEINZ , WANG TAO
IPC分类号： B01J23/52 , B01J23/68 , C07B61/00 , C07C67/055 , C07C69/01 , C07C69/15 , B01J31/04
摘要： The invention relates to a supported catalyst which contains palladium and/or compounds thereof, gold and/or compounds thereof, alkali metal compounds and also vanadium and/or compounds thereof. The invention also relates to the use of said supported catalyst for producing vinyl acetate from acetic acid, ethylene and oxygen, or gases containing oxygen.

8. 发明专利

CA2373048A1 CATALYST AND PROCESS FOR PREPARING VINYL ACETATE 未知
公开(公告)号：CA2373048A1
公开(公告)日：2000-11-09
申请号：CA2373048
申请日：2000-04-22
申请人： CELANESE CHEM EUROPE GMBH
发明人： WANG TAO , HERZOG BERNHARD , RENKEL KARL-HEINZ , SCHAFER AXEL
IPC分类号： B01J23/52 , B01J23/68 , C07B61/00 , C07C67/055 , C07C69/01 , C07C69/15
摘要： The invention relates to a supported catalyst which contains palladium and/or compounds thereof, gold and/or compounds thereof, alkali metal compounds and also vanadium and/or compounds thereof. The invention also relates to the us e of said supported catalyst for producing vinyl acetate from acetic acid, ethylene and oxygen, or gases containing oxygen.

9. 发明专利

ES2206235T3 未知
公开(公告)号：ES2206235T3
公开(公告)日：2004-05-16
申请号：ES00929409
申请日：2000-04-22
申请人： CELANESE CHEM EUROPE GMBH
发明人： HERZOG BERNHARD , SCHIFER AXEL , RENKEL KARL-HEINZ , WANG TAO
IPC分类号： B01J23/52 , B01J23/68 , C07B61/00 , C07C67/055 , C07C69/01 , C07C69/15
摘要： A process for preparing vinyl acetate in the gas phase from ethylene, acetic acid and oxygen or oxygen-containing gases over a catalyst, consisting essentially of palladium and/or its compounds, gold and/or its compounds and alkali metal compounds on a support, wherein the catalyst further comprises vanadium and/or its compounds and catalyst therefrom.

10. 发明专利

DE50003746D1 未知
公开(公告)号：DE50003746D1
公开(公告)日：2003-10-23
申请号：DE50003746
申请日：2000-04-22
申请人： CELANESE CHEM EUROPE GMBH
发明人： HERZOG BERNHARD , SCHAEFER AXEL , RENKEL KARL-HEINZ , WANG TAO
IPC分类号： B01J23/52 , B01J23/68 , C07B61/00 , C07C67/055 , C07C69/01 , C07C69/15
摘要： A process for preparing vinyl acetate in the gas phase from ethylene, acetic acid and oxygen or oxygen-containing gases over a catalyst, consisting essentially of palladium and/or its compounds, gold and/or its compounds and alkali metal compounds on a support, wherein the catalyst further comprises vanadium and/or its compounds and catalyst therefrom.

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