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1. 发明授权

US06527816B2 Isosorbide derivatives that can be used in detergent compositions for gasoline-type fuels 失效
标题翻译：可用于汽油型燃料的洗涤剂组合物中的异山梨醇衍生物
公开(公告)号：US06527816B2
公开(公告)日：2003-03-04
申请号：US09730727
申请日：2000-12-07
申请人： Bruno Deflort , Stéphane Joly , Thierry Lacome , Patrick Gateau , Fabrice Paille
发明人： Bruno Deflort , Stéphane Joly , Thierry Lacome , Patrick Gateau , Fabrice Paille
IPC分类号： C10L118
CPC分类号： C07D493/04 , C10L1/1985 , C10L10/04 , C10L10/18
摘要： Compositions that comprise at least one compound that corresponds to the general formula in which R1, R2, R3 and R4 each represent a hydrogen atom or a hydrocarbon radical, for example alkyl, with 1 to 30 carbon atoms, whereby at least one of R1, R2, R3 and R4 is a hydrocarbon radical, m and m′ are each a number from 1 to 30, with m+m′ from 4 to 60, can be prepared by reaction of the isosorbide with one or more compounds that have an epoxide group. These compositions can be used as detergent additives for gasoline-type fuels.
摘要翻译：包含至少一种对应于通式的化合物的组合物，其中R 1，R 2，R 3和R 4各自表示具有1至30个碳原子的氢原子或烃基，例如烷基，其中R1，R2中的至少一个，R3和R4是烃基，m和m'各自为1至30的数，m + m'为4至60，可以通过使异山梨醇与一种或多种具有环氧基的化合物反应来制备。这些组合物可用作汽油型燃料的洗涤剂添加剂。

2. 发明授权

US06890364B2 Diesel fuel compounds containing glycerol acetals 失效
标题翻译：含有甘油缩醛的柴油燃料化合物
公开(公告)号：US06890364B2
公开(公告)日：2005-05-10
申请号：US10322760
申请日：2002-12-19
申请人： Bruno Delfort , Isabelle Durand , Anne Jaecker , Thierry Lacome , Xavier Montagne , Fabrice Paille
发明人： Bruno Delfort , Isabelle Durand , Anne Jaecker , Thierry Lacome , Xavier Montagne , Fabrice Paille
IPC分类号： C10L1/02 , C10L1/08 , C10L1/18 , C10L1/24 , C10L10/02
CPC分类号： C10L1/1855 , C10L1/026 , C10L10/02
摘要： A diesel fuel compound has a major proportion of at least one diesel fuel and a minor proportion of at least one glycerol acetal corresponding to one of general formulas: in which: R1 and R2 each represent a hydrogen atom, a hydrocarbon radical with 1 to 20 carbon atoms, aliphatic, cycloaliphatic or aromatic, or an alkyl-ether chain, R1 and R2 being able together to form an oxygenated heterocyclic radical; R3 represents a hydrogen atom or a radical of general formula: where R4 is a radical defined as R1 or R2, except for the hydrogen atom, or a radical of general formula: where R1 and R2 are defined as above, the sum of the number of carbon atoms of R1, R2 and R3 in formulas (1) and (2) being at least 2 and it has no metal compounds of group IIA.
摘要翻译：柴油燃料化合物具有主要比例的至少一种柴油燃料和少量至少一种对应于以下通式之一的甘油缩醛：其中：R 1和R 2各自表示氢原子，具有1至20个碳原子的烃基碳原子，脂族，脂环族或芳族，或烷基 - 醚链，R1和R2能够一起形成含氧杂环基; R3表示氢原子或通式的基团：其中R4是除了氢原子以外定义为R1或R2的基团，或下列通式的基团：其中R1和R2如上所定义，数字之和式（1）和（2）中R 1，R 2和R 3的碳原子数为2以上，并且不具有IIA族的金属化合物。

3. 发明授权

US07097674B2 Diesel fuel compositions that contain glycerol acetal carbonates 有权
标题翻译：含有甘油缩醛碳酸酯的柴油燃料组合物
公开(公告)号：US07097674B2
公开(公告)日：2006-08-29
申请号：US10322473
申请日：2002-12-19
申请人： Bruno Delfort , Isabelle Durand , Anne Jaecker , Thierry Lacome , Xavier Montagne , Fabrice Paille
发明人： Bruno Delfort , Isabelle Durand , Anne Jaecker , Thierry Lacome , Xavier Montagne , Fabrice Paille
IPC分类号： C10L1/18 , C10L1/24
CPC分类号： C10L1/19 , C10L1/026 , C10L10/02
摘要： A diese fuel composition containing a major proportion of at least one diesel fuel and a minor proportion of at least one glycerol acetal carbonate of the formulae: in which: R1 and R2 each represent a hydrogen atom, a hydrocarbon radical with 1 to 20 carbon atoms that is aliphatic, cycloaliphatic or aromatic, an alkyl-ether chain, whereby R1 and R2 together can form an oxygenated heterocyclic radical; R3 is a radical that is defined as R1 or R2, except for the hydrogen atom, or a radical of the formula: where R1 and R2 are defined as above.
摘要翻译：含有主要比例的至少一种柴油燃料和少部分至少一种下式的甘油缩醛碳酸酯的一种柴油燃料组合物：其中：R 1和R 2各自表示氢原子，具有1至20个碳原子的烃基即脂肪族，脂环族或芳族的烷基醚链，其中R1和R2一起可以形成含氧杂环基; R3是除了氢原子以外定义为R 1或R 2的基团，或下式的基团：其中R 1和R 2如上定义。

4. 发明授权

US06054418A Process for sulfurizing unsaturated fatty substances by elementary sulfur in the presence of amino compounds 失效
标题翻译：在氨基化合物存在下通过元素硫硫化不饱和脂肪物质的方法
公开(公告)号：US06054418A
公开(公告)日：2000-04-25
申请号：US819710
申请日：1997-03-18
申请人： Thierry Lacome , Bruno Delfort , Maurice Born
发明人： Thierry Lacome , Bruno Delfort , Maurice Born
IPC分类号： B01J31/02 , C07B61/00 , C07C319/14 , C07C323/51 , C10M135/06 , C10N30/06 , C10N30/10 , C10N40/04 , C10N40/20 , C10N50/10 , C11C3/00
CPC分类号： C10M135/06 , C10M2219/024 , Y02P20/582
摘要： A process for sulfurizing a composition of unsaturated fatty ester is described in which said composition is reacted with elemental sulfur in the presence of a promoter that consists of at least one compound with an amine group and in the presence of water. When the sulfur-containing product is separated from an aqueous phase that contains the compound with an amine group, the latter can be reused for several successive sulfurations without substantial loss of activity of the promoter. The compositions of unsaturated fatty esters can be used as additives for lubricating oils or fats.
摘要翻译：描述了一种硫化不饱和脂肪酸酯组合物的方法，其中所述组合物在由至少一种具有胺基的化合物和水的存在下组成的促进剂存在下与元素硫反应。当含硫产物与含有胺基的化合物的水相分离时，后者可以重复使用几次连续的硫化，而不会显着损失启动子的活性。不饱和脂肪酸酯的组成可用作润滑油或脂肪的添加剂。

5. 发明申请

US20050266139A1 Process for transesterification of vegetable or animal oils using heterogeneous catalysts based on titanium, zirconium or antimony and aluminium 失效
标题翻译：使用基于钛，锆或锑和铝的多相催化剂进行植物油或动物油酯交换的方法
公开(公告)号：US20050266139A1
公开(公告)日：2005-12-01
申请号：US10853725
申请日：2004-05-26
申请人： Thierry Lacome , Gerard Hillion , Bruno Delfort , Renaud Revel , Serge Leporq , Gustave Acakpo
发明人： Thierry Lacome , Gerard Hillion , Bruno Delfort , Renaud Revel , Serge Leporq , Gustave Acakpo
IPC分类号： B01J21/06 , B01J35/10 , B01J37/00 , B01J37/03 , C07C67/03 , C10L1/02 , C11C3/10 , A23D7/00
CPC分类号： C11C3/003 , B01J21/063 , B01J35/1014 , B01J35/1019 , B01J35/1042 , B01J35/108 , B01J37/0009 , B01J37/033 , C07C67/03 , C10L1/026 , C11C3/10 , Y02E50/13 , C07C69/52 , C07C69/24
摘要： A novel process is described for producing esters of linear monocarboxylic acids containing 6 to 26 carbon atoms, by reacting vegetable or animal oils, neutral or otherwise, with monoalcohols containing 1 to 18 carbon atoms in the presence of a catalyst selected from: mixtures of titanium oxide and alumina having formula: (TiOx)y(Al2O3)1-y where x has the value 1.5 to 2.2 and y, representing the weight ratio of the two oxides, has a value of 0.005 to 0.995; mixtures of zirconium oxide and alumina having formula: (ZrOx)y(Al2O3)1-y where x has the value 1.5 to 2.2 and y has a value of 0.005 to 0.995; and mixtures of antimony oxide and alumina having formula: (SbOx)y(Al2O3)1-y where x has the value 1.2 to 2.6 and y has a value of 0.005 to 0.995, in order to directly produce, in one or more steps, an ester for use as a fuel and a pure glycerin.
摘要翻译：描述了一种用于生产含有6至26个碳原子的直链单羧酸的酯的新方法，其通过在选自以下的催化剂的存在下，使中性或其它物质的植物油或动物油与含有1至18个碳原子的一元醇反应：钛氧化物和氧化铝，其具有下式：<？in-line-formula description =“In-line Formulas”end =“lead”？（TiO x x） α-in-line-formula description =“In-line Formulas”end =“tail”？>其中 x的值为1.5〜2.2，y表示两种氧化物的重量比，其值为0.005〜0.995; 氧化锆和氧化铝的混合物，具有下式：<？in-line-formula description =“In-line Formulas”end =“lead”？（ZrO x x） α-in-line-formula description =“In-line Formulas”end =“tail” 其中x的值为1.5至2.2，y的值为0.005至0.995; 和氧化锑和氧化铝的混合物，其具有下式：<？in-line-formula description =“In-line Formulas”end =“lead”？（SbO x x） α-in-line-formula description =“In-line Formulas”end =“tail “→”，其中x为1.2〜2.6，y为0.005〜0.995，为了直接以一个或多个步骤直接制备用作燃料和纯甘油的酯。

6. 发明授权

US5854184A Colloidal products, their preparation and their uses 失效
标题翻译：胶体产品，其制备及其用途
公开(公告)号：US5854184A
公开(公告)日：1998-12-29
申请号：US842326
申请日：1997-04-24
申请人： Burno Delfort , Thierry Lacome , Maurice Born
发明人： Burno Delfort , Thierry Lacome , Maurice Born
IPC分类号： C07F9/165 , C10M159/20 , C10M159/24 , C10M135/10
CPC分类号： C10M159/24 , C07F9/1651 , C10M159/20
摘要： New overbased colloidal products that comprise a core of micellized alkali metal or alkaline-earth metal carbonate, surrounded by a ring of at least one surfactant compound that is selected from among the dihydrocarbyl-dithiophosphoryl-alkane-sulfonic acids, and their salts of alkali metals or alkaline-earth metals are described. They are derived from the carbonation of at least one oxide or hydroxide of an alkali metal or alkaline-earth metal that is carried out within an oily medium that contains hydrocarbon in the presence of at least one dihydrocarbyl-dithiophosphoryl-alkane-sulfonic acid that corresponds to general formula: ##STR1## in which R represents a monovalent aliphatic, cycloaliphatic or aromatic radical that contains 1 to 30 carbon atoms and x has a value of 3 to 6, or an alkali metal or alkaline-earth metal salt of such an acid. These colloidal products can be used as detergent additives notably providing anti-wear and extreme-pressure properties in lubricants. Because of the presence in their molecule of dihydrocarbyl-dithiophosphoric groups, they also exhibit anti-oxidizing properties.
摘要翻译：包含胶束化碱金属或碱土金属碳酸盐核心的新的高碱性胶体产物，被选自二烃基 - 二硫代磷酰基 - 烷烃磺酸中的至少一种表面活性剂化合物的环和其碱金属盐或碱土金属。它们衍生自碱金属或碱土金属的至少一种氧化物或氢氧化物的碳酸化，所述氧化物或氢氧化物在含有烃的油性介质中进行，所述油性介质在至少一种对应于二烃基 - 二硫代磷酰基 - 烷烃 - 磺酸的存在下通式为：其中R表示含有1至30个碳原子并且x具有3至6的值的一价脂族，脂环族或芳族基团，或这种酸的碱金属或碱土金属盐。这些胶体产品可用作洗涤剂添加剂，特别是在润滑剂中提供抗磨损和极压性能。由于它们在二烃基 - 二硫代磷酸基团的分子中的存在，它们也表现出抗氧化性质。

7. 发明授权

US07592470B2 Process for transesterification of vegetable or animal oils using heterogeneous catalysts based on titanium, zirconium or antimony and aluminium 失效
标题翻译：使用基于钛，锆或锑和铝的多相催化剂进行植物油或动物油酯交换的方法
公开(公告)号：US07592470B2
公开(公告)日：2009-09-22
申请号：US10853725
申请日：2004-05-26
申请人： Thierry Lacome , Gerard Hillion , Bruno Delfort , Renaud Revel , Serge Leporq , Gustave Acakpo
发明人： Thierry Lacome , Gerard Hillion , Bruno Delfort , Renaud Revel , Serge Leporq , Gustave Acakpo
IPC分类号： C11C3/10 , C09F7/00 , C07C67/02
CPC分类号： C11C3/003 , B01J21/063 , B01J35/1014 , B01J35/1019 , B01J35/1042 , B01J35/108 , B01J37/0009 , B01J37/033 , C07C67/03 , C10L1/026 , C11C3/10 , Y02E50/13 , C07C69/52 , C07C69/24
摘要： A novel process is described for producing esters of linear monocarboxylic acids containing 6 to 26 carbon atoms, by reacting vegetable or animal oils, neutral or otherwise, with monoalcohols containing 1 to 18 carbon atoms in the presence of a catalyst selected from: mixtures of titanium oxide and alumina having formula: (TiOx)y(Al2O3)1-y where x has the value 1.5 to 2.2 and y, representing the weight ratio of the two oxides, has a value of 0.005 to 0.995; mixtures of zirconium oxide and alumina having formula: (ZrOx)y(Al2O3)1-y where x has the value 1.5 to 2.2 and y has a value of 0.005 to 0.995; and mixtures of antimony oxide and alumina having formula: (SbOx)y(Al2O3)1-y where x has the value 1.2 to 2.6 and y has a value of 0.005 to 0.995, in order to directly produce, in one or more steps, an ester for use as a fuel and a pure glycerin.
摘要翻译：描述了一种用于生产含有6至26个碳原子的直链单羧酸的酯的新方法，其通过在选自以下的催化剂的存在下，使中性或其它物质的植物油或动物油与含有1至18个碳原子的一元醇反应：钛氧化物和氧化铝，其具有式：<？in-line-formula description =“In-line Formulas”end =“lead”？>（TiOx）y（Al2O3）1-y <？in-line-formula description = 线公式“end =”tail“？>其中x的值为1.5至2.2，y表示两种氧化物的重量比，其值为0.005至0.995; 氧化锆和氧化铝的混合物，具有下式：<？in-line-formula description =“In-line Formulas”end =“lead”？>（ZrOx）y（Al2O3）1-y <？in-line-formula description = “直线公式”end =“tail”？>其中x的值为1.5至2.2，y的值为0.005至0.995; 和氧化锑和氧化铝的混合物，其具有下式：<？in-line-formula description =“In-line Formulas”end =“lead”→（SbOx）y（Al2O3）1-y < =“直线公式”end =“tail”？>其中x的值为1.2至2.6，y的值为0.005至0.995，以便在一个或多个步骤中直接生产用作燃料和纯甘油。

8. 发明授权

US5698501A Ethylenic hydrocarbons sulphurized by elemental sulphur in the presence of an alkali metal carbonate or bicarbonate, their preparation and their use 失效
标题翻译：在碱金属碳酸盐或碳酸氢盐存在下，元素硫硫化的乙烯烃，其制备及其用途
公开(公告)号：US5698501A
公开(公告)日：1997-12-16
申请号：US584198
申请日：1996-01-11
申请人： Thierry Lacome , Bruno Delfort , Maurice Born
发明人： Thierry Lacome , Bruno Delfort , Maurice Born
IPC分类号： B01J27/232 , B01J37/20 , C07C319/00 , C07C321/02 , C07C321/12 , C10M135/04 , C10N30/06 , C10N40/04 , C10N40/20
CPC分类号： C10M135/04 , B01J27/232 , B01J37/20 , C07C319/00 , C07C321/02 , C07C321/12 , C10M2219/022 , C10N2240/04 , C10N2240/042 , C10N2240/044 , C10N2240/046 , C10N2240/06 , C10N2240/10 , C10N2240/101 , C10N2240/104 , C10N2240/106 , C10N2240/40
摘要： Sulphur-containing substances are derived from mono- or polyethylenic hydrocarbons by sulphurization using elemental sulphur in the presence of an alkali metal carbonate or bicarbonate and in the presence of water and/or at least one alkyleneglycol. The sulphur-containing substances, which may contain 20% to 70% by weight of sulphur, are generally soluble in lubricants to improve antiwear and extreme pressure properties. They can also be used as sulphurization agents, in particular for preparing catalysts for refining petroleum products.
摘要翻译：含硫物质通过在碱金属碳酸盐或碳酸氢盐存在下和在水和/或至少一种亚烷基二醇存在下使用元素硫进行硫化而衍生自单 - 或多烯烃。可含有20％至70％重量的硫的含硫物质通常可溶于润滑剂以改善耐磨和极压性能。它们也可以用作硫化剂，特别是用于制备炼制石油产品的催化剂。

9. 发明授权

US5693597A Colloidal alkaline or alkaline-earth carbonates containing a compound of calcium, phosphorus and sulphur in micellar form 失效
标题翻译：含有胶体形式的钙，磷和硫化合物的胶体碱性或碱土金属碳酸盐
公开(公告)号：US5693597A
公开(公告)日：1997-12-02
申请号：US634821
申请日：1996-04-19
申请人： Bruno Delfort , Bertrand Daoudal , Thierry Lacome , Fran.cedilla.oise Dixmier , Maurice Born
发明人： Bruno Delfort , Bertrand Daoudal , Thierry Lacome , Fran.cedilla.oise Dixmier , Maurice Born
IPC分类号： B01J13/00 , C01B25/00 , C01D7/00 , C01F11/18 , C10M159/12 , C10M159/24 , C10N10/02 , C10N10/04 , C10N30/06 , C01M159/12 , C01M135/10
CPC分类号： C10M159/24
摘要： Colloidal products are described which comprise micelles of alkaline metals or alkaline-earth metals, held in the colloidal state by at least one alkaline metal or alkaline-earth metal alkyl- or alkylarylsulphonate. The products further comprise micelles of a product containing calcium, phosphorus and sulphur resulting from the in situ reaction of calcium oxide or calcium hydroxide with a phosphorus sulphide, in particular tetraphosphorus decasulphide, and water. These colloidal products are used as antiwear and extreme pressure additives for lubricating greases and oils.
摘要翻译：描述了包含碱金属或碱土金属的胶束的胶体产物，其通过至少一种碱金属或碱土金属烷基或烷基芳基磺酸酯保持在胶体状态。产物还包含含有钙，磷和硫的产物的胶束，其由氧化钙或氢氧化钙与硫化磷，特别是四硫化四钯和水的原位反应产生。这些胶体产品用作润滑脂和油脂的抗磨和极压添加剂。

10. 发明授权

US5679626A Ethylenic hydrocarbons sulphurized by elemental sulphur in the presence of alkali or alkaline-earth metal hydroxices and in the presence of glycols or polyglcols, or their alkyl ethers, and or water 失效
标题翻译：在碱金属或碱土金属羟基存在下，在二元醇或多元醇或其烷基醚和/或水的存在下，由元素硫硫化的乙烯烃
公开(公告)号：US5679626A
公开(公告)日：1997-10-21
申请号：US563794
申请日：1995-11-28
申请人： Maurice Born , Bruno Delport , Thierry Lacome
发明人： Maurice Born , Bruno Delport , Thierry Lacome
IPC分类号： B01J37/20 , C07C319/00 , C07C321/02 , C07C321/12 , C07G99/00 , C10M135/04
CPC分类号： C10M135/04 , B01J37/20 , C07C319/00 , C07C321/02 , C07C321/12 , C07G17/004 , C10M2219/022 , C10N2240/04 , C10N2240/042 , C10N2240/044 , C10N2240/046 , C10N2240/10 , C10N2240/101 , C10N2240/104 , C10N2240/106 , C10N2240/40
摘要： Sulphur-containing substances are derived from mono- or polyethylenic hydrocarbons by sulphurization using elemental sulphur in the presence of at least one alkali or alkaline-earth metal hydroxide and at least one glycol or polyglycol, or glycol or polyglycol monoether and/or water. Sulphur-containing substances, which may contain 20% to 70% by weight of sulphur, are generally soluble in lubricants to improve antiwear and extreme pressure properties. They can also be used as sulphurization agents, in particular for preparing catalysts for refining petroleum products.
摘要翻译：含硫物质通过使用元素硫在至少一种碱金属或碱土金属氢氧化物和至少一种二醇或聚二醇或二醇或聚乙二醇单醚和/或水存在下进行硫化而衍生自单 - 或多烯烃。可含有20％至70％重量的硫的含硫物质通常可溶于润滑剂，以改善耐磨和极压性能。它们也可以用作硫化剂，特别是用于制备炼制石油产品的催化剂。

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