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1. 发明授权

US5679626A Ethylenic hydrocarbons sulphurized by elemental sulphur in the presence of alkali or alkaline-earth metal hydroxices and in the presence of glycols or polyglcols, or their alkyl ethers, and or water 失效
标题翻译：在碱金属或碱土金属羟基存在下，在二元醇或多元醇或其烷基醚和/或水的存在下，由元素硫硫化的乙烯烃
公开(公告)号：US5679626A
公开(公告)日：1997-10-21
申请号：US563794
申请日：1995-11-28
申请人： Maurice Born , Bruno Delport , Thierry Lacome
发明人： Maurice Born , Bruno Delport , Thierry Lacome
IPC分类号： B01J37/20 , C07C319/00 , C07C321/02 , C07C321/12 , C07G99/00 , C10M135/04
CPC分类号： C10M135/04 , B01J37/20 , C07C319/00 , C07C321/02 , C07C321/12 , C07G17/004 , C10M2219/022 , C10N2240/04 , C10N2240/042 , C10N2240/044 , C10N2240/046 , C10N2240/10 , C10N2240/101 , C10N2240/104 , C10N2240/106 , C10N2240/40
摘要： Sulphur-containing substances are derived from mono- or polyethylenic hydrocarbons by sulphurization using elemental sulphur in the presence of at least one alkali or alkaline-earth metal hydroxide and at least one glycol or polyglycol, or glycol or polyglycol monoether and/or water. Sulphur-containing substances, which may contain 20% to 70% by weight of sulphur, are generally soluble in lubricants to improve antiwear and extreme pressure properties. They can also be used as sulphurization agents, in particular for preparing catalysts for refining petroleum products.
摘要翻译：含硫物质通过使用元素硫在至少一种碱金属或碱土金属氢氧化物和至少一种二醇或聚二醇或二醇或聚乙二醇单醚和/或水存在下进行硫化而衍生自单 - 或多烯烃。可含有20％至70％重量的硫的含硫物质通常可溶于润滑剂，以改善耐磨和极压性能。它们也可以用作硫化剂，特别是用于制备炼制石油产品的催化剂。

2. 发明授权

US5854184A Colloidal products, their preparation and their uses 失效
标题翻译：胶体产品，其制备及其用途
公开(公告)号：US5854184A
公开(公告)日：1998-12-29
申请号：US842326
申请日：1997-04-24
申请人： Burno Delfort , Thierry Lacome , Maurice Born
发明人： Burno Delfort , Thierry Lacome , Maurice Born
IPC分类号： C07F9/165 , C10M159/20 , C10M159/24 , C10M135/10
CPC分类号： C10M159/24 , C07F9/1651 , C10M159/20
摘要： New overbased colloidal products that comprise a core of micellized alkali metal or alkaline-earth metal carbonate, surrounded by a ring of at least one surfactant compound that is selected from among the dihydrocarbyl-dithiophosphoryl-alkane-sulfonic acids, and their salts of alkali metals or alkaline-earth metals are described. They are derived from the carbonation of at least one oxide or hydroxide of an alkali metal or alkaline-earth metal that is carried out within an oily medium that contains hydrocarbon in the presence of at least one dihydrocarbyl-dithiophosphoryl-alkane-sulfonic acid that corresponds to general formula: ##STR1## in which R represents a monovalent aliphatic, cycloaliphatic or aromatic radical that contains 1 to 30 carbon atoms and x has a value of 3 to 6, or an alkali metal or alkaline-earth metal salt of such an acid. These colloidal products can be used as detergent additives notably providing anti-wear and extreme-pressure properties in lubricants. Because of the presence in their molecule of dihydrocarbyl-dithiophosphoric groups, they also exhibit anti-oxidizing properties.
摘要翻译：包含胶束化碱金属或碱土金属碳酸盐核心的新的高碱性胶体产物，被选自二烃基 - 二硫代磷酰基 - 烷烃磺酸中的至少一种表面活性剂化合物的环和其碱金属盐或碱土金属。它们衍生自碱金属或碱土金属的至少一种氧化物或氢氧化物的碳酸化，所述氧化物或氢氧化物在含有烃的油性介质中进行，所述油性介质在至少一种对应于二烃基 - 二硫代磷酰基 - 烷烃 - 磺酸的存在下通式为：其中R表示含有1至30个碳原子并且x具有3至6的值的一价脂族，脂环族或芳族基团，或这种酸的碱金属或碱土金属盐。这些胶体产品可用作洗涤剂添加剂，特别是在润滑剂中提供抗磨损和极压性能。由于它们在二烃基 - 二硫代磷酸基团的分子中的存在，它们也表现出抗氧化性质。

3. 发明授权

US06054418A Process for sulfurizing unsaturated fatty substances by elementary sulfur in the presence of amino compounds 失效
标题翻译：在氨基化合物存在下通过元素硫硫化不饱和脂肪物质的方法
公开(公告)号：US06054418A
公开(公告)日：2000-04-25
申请号：US819710
申请日：1997-03-18
申请人： Thierry Lacome , Bruno Delfort , Maurice Born
发明人： Thierry Lacome , Bruno Delfort , Maurice Born
IPC分类号： B01J31/02 , C07B61/00 , C07C319/14 , C07C323/51 , C10M135/06 , C10N30/06 , C10N30/10 , C10N40/04 , C10N40/20 , C10N50/10 , C11C3/00
CPC分类号： C10M135/06 , C10M2219/024 , Y02P20/582
摘要： A process for sulfurizing a composition of unsaturated fatty ester is described in which said composition is reacted with elemental sulfur in the presence of a promoter that consists of at least one compound with an amine group and in the presence of water. When the sulfur-containing product is separated from an aqueous phase that contains the compound with an amine group, the latter can be reused for several successive sulfurations without substantial loss of activity of the promoter. The compositions of unsaturated fatty esters can be used as additives for lubricating oils or fats.
摘要翻译：描述了一种硫化不饱和脂肪酸酯组合物的方法，其中所述组合物在由至少一种具有胺基的化合物和水的存在下组成的促进剂存在下与元素硫反应。当含硫产物与含有胺基的化合物的水相分离时，后者可以重复使用几次连续的硫化，而不会显着损失启动子的活性。不饱和脂肪酸酯的组成可用作润滑油或脂肪的添加剂。

4. 发明授权

US5698501A Ethylenic hydrocarbons sulphurized by elemental sulphur in the presence of an alkali metal carbonate or bicarbonate, their preparation and their use 失效
标题翻译：在碱金属碳酸盐或碳酸氢盐存在下，元素硫硫化的乙烯烃，其制备及其用途
公开(公告)号：US5698501A
公开(公告)日：1997-12-16
申请号：US584198
申请日：1996-01-11
申请人： Thierry Lacome , Bruno Delfort , Maurice Born
发明人： Thierry Lacome , Bruno Delfort , Maurice Born
IPC分类号： B01J27/232 , B01J37/20 , C07C319/00 , C07C321/02 , C07C321/12 , C10M135/04 , C10N30/06 , C10N40/04 , C10N40/20
CPC分类号： C10M135/04 , B01J27/232 , B01J37/20 , C07C319/00 , C07C321/02 , C07C321/12 , C10M2219/022 , C10N2240/04 , C10N2240/042 , C10N2240/044 , C10N2240/046 , C10N2240/06 , C10N2240/10 , C10N2240/101 , C10N2240/104 , C10N2240/106 , C10N2240/40
摘要： Sulphur-containing substances are derived from mono- or polyethylenic hydrocarbons by sulphurization using elemental sulphur in the presence of an alkali metal carbonate or bicarbonate and in the presence of water and/or at least one alkyleneglycol. The sulphur-containing substances, which may contain 20% to 70% by weight of sulphur, are generally soluble in lubricants to improve antiwear and extreme pressure properties. They can also be used as sulphurization agents, in particular for preparing catalysts for refining petroleum products.
摘要翻译：含硫物质通过在碱金属碳酸盐或碳酸氢盐存在下和在水和/或至少一种亚烷基二醇存在下使用元素硫进行硫化而衍生自单 - 或多烯烃。可含有20％至70％重量的硫的含硫物质通常可溶于润滑剂以改善耐磨和极压性能。它们也可以用作硫化剂，特别是用于制备炼制石油产品的催化剂。

5. 发明授权

US5693597A Colloidal alkaline or alkaline-earth carbonates containing a compound of calcium, phosphorus and sulphur in micellar form 失效
标题翻译：含有胶体形式的钙，磷和硫化合物的胶体碱性或碱土金属碳酸盐
公开(公告)号：US5693597A
公开(公告)日：1997-12-02
申请号：US634821
申请日：1996-04-19
申请人： Bruno Delfort , Bertrand Daoudal , Thierry Lacome , Fran.cedilla.oise Dixmier , Maurice Born
发明人： Bruno Delfort , Bertrand Daoudal , Thierry Lacome , Fran.cedilla.oise Dixmier , Maurice Born
IPC分类号： B01J13/00 , C01B25/00 , C01D7/00 , C01F11/18 , C10M159/12 , C10M159/24 , C10N10/02 , C10N10/04 , C10N30/06 , C01M159/12 , C01M135/10
CPC分类号： C10M159/24
摘要： Colloidal products are described which comprise micelles of alkaline metals or alkaline-earth metals, held in the colloidal state by at least one alkaline metal or alkaline-earth metal alkyl- or alkylarylsulphonate. The products further comprise micelles of a product containing calcium, phosphorus and sulphur resulting from the in situ reaction of calcium oxide or calcium hydroxide with a phosphorus sulphide, in particular tetraphosphorus decasulphide, and water. These colloidal products are used as antiwear and extreme pressure additives for lubricating greases and oils.
摘要翻译：描述了包含碱金属或碱土金属的胶束的胶体产物，其通过至少一种碱金属或碱土金属烷基或烷基芳基磺酸酯保持在胶体状态。产物还包含含有钙，磷和硫的产物的胶束，其由氧化钙或氢氧化钙与硫化磷，特别是四硫化四钯和水的原位反应产生。这些胶体产品用作润滑脂和油脂的抗磨和极压添加剂。

6. 发明授权

US5756432A Colloidal calcium hydroxide, its preparation and uses 失效
标题翻译：胶体氢氧化钙，其制备及用途
公开(公告)号：US5756432A
公开(公告)日：1998-05-26
申请号：US498769
申请日：1995-07-06
申请人： Maurice Born , Agnes Chive , Bruno Delfort
发明人： Maurice Born , Agnes Chive , Bruno Delfort
IPC分类号： B01J13/00 , C01F11/02 , C10M159/20 , C10M159/22 , C10M159/24 , C10M103/00 , C10M105/72
CPC分类号： C10M159/22 , C10M159/20 , C10M159/24 , Y10S516/924 , Y10S516/927
摘要： Novel colloidal products are described, containing calcium hydroxide in the center of micelles which are stabilised in an organic medium by a shell of a surfactant, in a reversed micelle. The products are obtained by reacting calcium oxide CaO, calcium hydride CaH.sub.2 or calcium metal with water in an organic medium in the present of a surfactant such as an alkine-earth or alkali metal alkylaryl sulphonate. They are used mainly as synthesis intermediates in reactions requiring lime to be introduced into an organic medium, or as detergent additives in lubricating oils.
摘要翻译：描述了新的胶体产物，其在反胶束中在胶束的中心含有通过表面活性剂的壳稳定在有机介质中的氢氧化钙。产物是通过在表面活性剂如碱土金属或碱金属烷基芳基磺酸盐存在下的有机介质中使氧化钙CaO，氢化钙CaH 2或钙金属与水反应得到的。它们主要用作需要将石灰引入有机介质或作为润滑油中的洗涤剂添加剂的反应中的合成中间体。

7. 发明授权

US5468399A Colloidal products containing sulfur and/or phosphorus and/or boron, their preparation and their utilization as additives for lubricants 失效
标题翻译：含硫和/或磷和/或硼的胶体产品，其制备及其作为润滑剂添加剂的利用
公开(公告)号：US5468399A
公开(公告)日：1995-11-21
申请号：US153926
申请日：1993-11-18
申请人： Bruno Delfort , Bertrand Daoudal , Jacques Lallement , Maurice Born , Jean-Claude Hipeaux , Pierre Marchand
发明人： Bruno Delfort , Bertrand Daoudal , Jacques Lallement , Maurice Born , Jean-Claude Hipeaux , Pierre Marchand
IPC分类号： B01J13/00 , C10M159/12 , C10M159/24 , C10N40/04 , C10N40/08 , C10N40/20 , C10N40/25 , C10M135/10
CPC分类号： C10M159/24
摘要： Colloidal products are described which contain an element selected from sulphur, phosphorus and possibly boron, as well as an element chosen from metal alkalis, alkaline earth metals and zinc, micellized in at least one detergent agent. They can be obtained in micelle form by reaction of at least one mineral acid or organic acid, containing sulphur and/or phosphorus and possibly an acid containing boron, these acids being directly introduced or formed in situ with at least one basic derivative containing a alkali metal and/or an alkaline earth metal and/or zinc, in the presence of at least one surface active agent. The colloidal products can be used as wear resistance and extreme pressure additives for lubricants.
摘要翻译：描述了含有选自硫，磷和可能的硼的元素的胶体产物，以及选自金属碱，碱土金属和锌的元素，其在至少一种洗涤剂中胶束化。它们可以通过至少一种含硫和/或磷的无机酸或有机酸与可能含有硼的酸反应获得，这些酸直接引入或原位与至少一种含有碱的碱性衍生物形成金属和/或碱土金属和/或锌，在至少一种表面活性剂的存在下。胶体产品可用作润滑剂的耐磨性和极压添加剂。

8. 发明授权

US5284592A (Poly) sulfurized carboxylic compounds, their preparation and their use as petroleum additives for lubricating oils 失效
标题翻译：（聚）硫化羧酸化合物，它们的制备及其作为润滑油的石油添加剂的用途
公开(公告)号：US5284592A
公开(公告)日：1994-02-08
申请号：US872196
申请日：1992-04-22
申请人： Ourida Aberkane , Maurice Born , Jean-Luc Mieloszynski , Daniel Paquer , Guy Parc
发明人： Ourida Aberkane , Maurice Born , Jean-Luc Mieloszynski , Daniel Paquer , Guy Parc
IPC分类号： C10M135/26 , C07C319/20 , C07C323/12 , C10M135/24 , C10N30/06
CPC分类号： C10M135/24 , C07C323/12 , C10M2219/084
摘要： Novel (poly)sulfurized carboxylic compounds, their preparation, and their use as additives to lubricating oils are disclosed. Such novel carboxylic compounds are more particularly esters of the general formula:[R.sup.3 --OC(O)--].sub.q R.sup.2 {--C(O)O--(CH.sub.2).sub.m --CH.sub.3-z [--(CH.sub.2).sub.n --S.sub.x --R.sup.1 ].sub.z }.sub.p (1)wherein R.sup.1 is a saturated or unsaturated monovalent aliphatic radical with 1 to 30 carbon atoms; the number x is equal to or greater than 1; z equals 1 or 2; when z equals 1, n is an integer from 0 to 5 and m an integer from 0 to 0.5, with m+n an integer from 1 to 10; when z equals 2, n is an integer from 1 to 5 and m an integer from 0 to 5, with m+n an integer from 1 to 10; R.sup.2 is a hydrocarbon radical with 1 to 31 carbon atoms and a valency of p+q; R.sup.3 is a hydrogen atom or an aliphatic radical with 1 to 30 carbon atoms; p is an integer from 1 to 4; and q is an integer from 0 to 3, with p+q being an integer from 1 to 4. They are obtained by esterifying carboxylic acid R.sup.2 (--COOH).sub.p+q with a (poly)sulfurized monoalcohol:[R.sup.1 --S.sub.x --(CH.sub.2).sub.n --].sub.z CH.sub.3-z --(CH.sub.2).sub.m --OHand possibly an alcohol R.sup.3 OH. They are used as anti-wear and extreme pressure additives in lubricating oils.
摘要翻译：公开了新型（多）硫化羧酸化合物，它们的制备及其作为润滑油添加剂的用途。这样的新型羧酸化合物更特别是以下通式的酯：（R3-OC（O） - ）qR2（-C（O）O-（CH2）m-CH3-z（ - （CH2）n-Sx-R1） z）p（1）其中R1是具有1至30个碳原子的饱和或不饱和的一价脂族基; 数x等于或大于1; z等于1或2; 当z为1时，n为0〜5的整数，m为0〜0.5的整数，m + n为1〜10的整数。当z为2时，n为1〜5的整数，m为0〜5的整数，m + n为1〜10的整数。 R2是具有1至31个碳原子并且p + q的化合价的烃基; R3是氢原子或具有1至30个碳原子的脂族基团; p是1至4的整数; 并且q为0〜3的整数，p + q为1〜4的整数。它们是通过用（多）硫化一元醇将羧酸R2（-COOH）p + q酯化得到的：（R1-Sx- （CH 2）n - ）z CH 3 -Z-（CH 2）m -OH以及可能的醇R 3 OH。它们用作润滑油中的抗磨和极压添加剂。

9. 发明授权

US5045221A Polysulphurized olefin compositions, their preparation and their use as additives for lubricants 失效
标题翻译：多硫化烯烃组合物，它们的制备及其作为润滑剂添加剂的用途
公开(公告)号：US5045221A
公开(公告)日：1991-09-03
申请号：US403968
申请日：1989-09-07
申请人： Maurice Born , Lucienne Briquet , Jacques Lallement , Guy Parc
发明人： Maurice Born , Lucienne Briquet , Jacques Lallement , Guy Parc
IPC分类号： C07C319/14 , C07C321/00 , C10M135/04 , C10N30/06 , C10N40/04 , C10N40/22
CPC分类号： C10M135/04
摘要： Polysulphurized olefin compositions used as additives for gear oils, cutting oils, and as sulphurizing agents in organic media are obtained by a process comprising:a stage (1) in which at least one compound chosen from among sulphur dichloride and monochloride is reacted with at least one aliphatic monpolefin with 2 to 12 carbon atoms, thus forming an adduct;a stage (2) in which sulphurized hydrogen and at least one mercaptan is reacted with ammonium or alkali metal hydroxide dissolved in at least one aliphatic monoalcohol with 1 to 4 carbon atoms, which is substantially anhydrous, so as to give an alcoholic solution;a stage (3) in which contacting takes place between the adduct obtained in stage (1) and the alcoholic solution obtained in stage (2);a stage (4), in which the resulting mixture is heated and then the aliphatic monoalcohol is eliminated by distillation, while adding water in a quantity adequate for maintaining in solution the reagents and the mineral products formed during the reaction; anda stage (5) in which elimination takes place of the aqueous phase and recovery takes place of the organic phase mainly constituted by the polysulphurized olefin composition.
摘要翻译：用于齿轮油，切削油和作为有机介质中的硫化剂的添加剂的多硫化烯烃组合物通过以下方法获得，该方法包括：其中至少一种选自二氯化硫和一氯化物的化合物至少与一种具有2至12个碳原子的脂族单烯烃，从而形成加合物; 使硫化氢和至少一种硫醇与溶解在至少一种具有1-4个碳原子的脂族一元醇中的铵或碱金属氢氧化物反应的阶段（2），其基本上是无水的，以得到醇溶液; 在阶段（1）中获得的加合物和阶段（2）中获得的醇溶液之间发生接触的阶段（3）; 加热得到的混合物，然后通过蒸馏除去脂肪族一元醇的阶段（4），同时加入足以维持溶液中的水，反应物中形成的试剂和矿物产物; 以及主要由多硫化烯烃组合物构成的有机相进行水相脱除发生阶段（5）。

10. 发明授权

US4352729A Process for hydrotreating heavy hydrocarbons in the presence of a molybdenum containing catalyst 失效
标题翻译：在含钼催化剂存在下加氢处理重质烃的方法
公开(公告)号：US4352729A
公开(公告)日：1982-10-05
申请号：US222228
申请日：1981-01-05
申请人： Yves Jacquin , Dai-Nghia Huynh , Maurice Born
发明人： Yves Jacquin , Dai-Nghia Huynh , Maurice Born
IPC分类号： B01J23/28 , B01J23/88 , C10G45/04 , C10G45/08
CPC分类号： B01J23/88 , B01J23/28 , C10G2300/107
摘要： Process for hydrogenating a heavy hydrocarbon charge containing asphaltenes, in the liquid phase, in the presence, as catalyst, of a molybdenum blue solution in a polar organic solvent soluble in the charge, so as to remove impurities therefrom before subjecting it to further refining.
摘要翻译：在可溶于电荷的极性有机溶剂中的钼蓝溶液作为催化剂在液相中氢化含有沥青质的重质烃装料的方法，以便在进一步精炼之前除去杂质。

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