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1. 发明授权

US06737497B2 Polyurethane/ureas useful for the production of spandex and a process for their production 失效
标题翻译：用于生产氨纶的聚氨酯/尿素及其生产工艺
公开(公告)号：US06737497B2
公开(公告)日：2004-05-18
申请号：US10158762
申请日：2002-05-30
申请人： Bruce D. Lawrey , Thomas A. J. Gross , Rolf-Volker Meyer
发明人： Bruce D. Lawrey , Thomas A. J. Gross , Rolf-Volker Meyer
IPC分类号： C08G1810
CPC分类号： D01F6/70 , C08G18/12 , C08G18/4808 , C08G18/4854 , C08G18/4866 , Y10S528/906 , C08G18/3234
摘要： Segmented polyurethane/ureas useful in the production of spandex are produced by chain extending an isocyanate-terminated prepolymer with a diamine chain extender that includes: (1) from about 7 to 25 equivalent percent of an asymmetric aliphatic and/or cycloaliphatic diamine and (2) a linear diamine such as ethylene diamine in the presence of a solvent. The isocyanate-terminated prepolymer is produced by reacting a stoichiometric excess of an isocyanate with an isocyanate-reactive component that includes: (1) from about 10 to about 70 equivalent percent of a polyoxypropylene diol having a molecular weight in excess of 1500 Da and an average unsaturation level no greater than about 0.03 meq/g and (2) from about 30 to about 90 equivalent percent of a polytetramethylene ether glycol having a molecular weight of at least 600 Da.
摘要翻译：用于生产氨纶的分段聚氨酯/尿素是通过用二胺增链剂将异氰酸酯封端的预聚物链延伸而制得的，其包括：（1）约7至25当量％的不对称脂族和/或脂环族二胺和（2 ）线性二胺如乙二胺在溶剂存在下进行。异氰酸酯封端的预聚物通过使化学计量过量的异氰酸酯与异氰酸酯反应性组分反应而制备，所述组分包括：（1）约10至约70当量的分子量超过1500Da的聚氧丙烯二醇和平均不饱和度不大于约0.03meq / g，（2）约30至约90当量分子量至少为600Da的聚四亚甲基醚二醇。

2. 发明授权

US06906163B2 Prepolymer catalysts suitable for preparing spandex fibers 失效
标题翻译：适用于制备氨纶纤维的预聚物催化剂
公开(公告)号：US06906163B2
公开(公告)日：2005-06-14
申请号：US10158988
申请日：2002-05-30
申请人： Bruce D. Lawrey , Thomas A. J. Gross , Rolf-Volker Meyer
发明人： Bruce D. Lawrey , Thomas A. J. Gross , Rolf-Volker Meyer
IPC分类号： C08G18/65 , C08G18/08 , C08G18/12 , C08G18/22 , C08G18/48 , D01F6/70 , C08G18/16
CPC分类号： D01F6/70 , C08G18/0852 , C08G18/12 , C08G18/222 , C08G18/4808 , C08G18/4866 , Y10S528/906 , C08G18/3225 , C08G18/2865
摘要： Segmented polyurethane/ureas useful for the production of spandex, particularly spandex fibers, are made from isocyanate-terminated prepolymers formed by reacting excess isocyanate with an isocyanate-reactive component satisfying specified compositional requirements in the presence of a catalyst which promotes linear polymerization but does not cause degradation of the polymer. Suitable catalysts include metal salts of organic fatty acids and/or of naphthenic acid. The isocyanate-reactive component includes at least 10 equivalent percent of a polyoxypropylene diol having a number average molecular weight of at least about 1500 Da and an average unsaturation level less than or equal to 0.03 meq/g and up to 90 equivalent percent of a polytetramethylene glycol having a number average molecular weight of at least 200 Da.
摘要翻译：用于生产氨纶，特别是氨纶纤维的分段聚氨酯/尿素由异氰酸酯封端的预聚物制成，所述异氰酸酯封端的预聚物通过使过量的异氰酸酯与异氰酸酯反应性组分反应，所述异氰酸酯反应性组分在催化剂存在下促进线性聚合而不满足特定组成要求导致聚合物降解。合适的催化剂包括有机脂肪酸和/或环烷酸的金属盐。异氰酸酯反应性组分包括至少10当量的数均分子量为至少约1500Da且平均不饱和度小于或等于0.03meq / g的聚氧丙烯二醇和至多90当量的聚四亚甲基数均分子量为200Da以上的二元醇。

3. 发明授权

US06637181B1 Elastane threads and method for the production thereof 失效
标题翻译：弹性丝线及其生产方法
公开(公告)号：US06637181B1
公开(公告)日：2003-10-28
申请号：US09701709
申请日：2000-12-01
申请人： Siegfried Korte , Rolf-Volker Meyer , Stefan Hütte
发明人： Siegfried Korte , Rolf-Volker Meyer , Stefan Hütte
IPC分类号： D02G302
CPC分类号： D01F6/70 , Y10T442/40
摘要： Described is a process for producing segmented polyurethanes having improved processing characteristics in the melt state and an efficient spinning process based thereon to form highly elastic, fine linear density elastane yarn and filament having improved mechanical and thermal properties by using hydroxyalkyl-terminated polysiloxanes in combination with specific crosslinking-capable polyisocyanates in the reaction of long-chain high molecular weight polyhydroxy compounds with organic diisocyanates and low molecular weight diols and also optionally further auxiliary and additive substances in the melt.
摘要翻译：描述了一种在熔融状态下具有改进的加工特性的分段聚氨酯的制造方法和基于其的有效的纺丝工艺，以形成高弹性，细密度的线性密度的弹性纤维丝和具有改善的机械和热性能的长丝，通过使用羟烷基封端的聚硅氧烷与在长链高分子量多羟基化合物与有机二异氰酸酯和低分子量二醇的反应中以及任选地在熔体中的另外的辅助和添加剂物质的反应中具有特异性交联的多异氰酸酯。

4. 发明授权

US06288158B1 Modified superabsorbent polymer based on polyacrylonitrile emulsions 失效
标题翻译：基于聚丙烯腈乳液的改性超吸收聚合物
公开(公告)号：US06288158B1
公开(公告)日：2001-09-11
申请号：US09247748
申请日：1999-02-09
申请人： Sergej Schapowalov , Günter Sackmann , Rolf-Volker Meyer , Siegfried Korte
发明人： Sergej Schapowalov , Günter Sackmann , Rolf-Volker Meyer , Siegfried Korte
IPC分类号： C08K334
CPC分类号： H01B3/447 , A61L15/24 , A61L15/60 , C08F8/00 , H01B3/428 , C08L33/20 , C08F20/44
摘要： A process for modifying superabsorbent polymers is disclosed. The surface of a polymer containing hydrolyzed polyacrylonitrile in the form of particulates, is modified by crosslinking in a water/alcohol reaction mixture and in the presence of silica. The resulting product features improved absorbency under load and lesser degree of gel blocking.
摘要翻译：公开了一种改性超吸收聚合物的方法。含有微粒形式的水解聚丙烯腈的聚合物的表面通过在水/醇反应混合物中和在二氧化硅存在下交联而被改性。所得产品具有改善的负载下的吸收性和较小程度的凝胶阻塞。

5. 发明授权

US6156848A Pre-formed super absorbers with high swelling capacity 失效
标题翻译：具有高溶胀能力的预成型超吸收体
公开(公告)号：US6156848A
公开(公告)日：2000-12-05
申请号：US964069
申请日：1997-11-04
申请人： Gunter Sackmann , Sergej Schapowalow , Siegfried Korte , Rolf-Volker Meyer
发明人： Gunter Sackmann , Sergej Schapowalow , Siegfried Korte , Rolf-Volker Meyer
IPC分类号： A61L15/00 , A61L15/60 , B01J20/26 , C08F6/14 , C08F8/12 , C08F20/04 , C08F20/44 , C08F20/56 , C09K17/16 , F16F1/36 , C08F120/44
CPC分类号： F16F1/3605 , A61L15/60 , C08F8/44 , C09K17/16 , C08F2800/20 , C08F2810/20
摘要： Super-absorbent polymer in the form of pre-formed spherical particles obtainable by alkaline hydrolysis of aqueous emulsions of crosslinked and/or un-crosslinked homopolymers and/or copolymers of acrylonitrile in water/alcohol mixtures and the use of the polymer in hygiene products, as a water-storing material in agriculture and for the sheathing of electrical cables.
摘要翻译：可通过碱水解丙烯腈在水/醇混合物中的交联和/或未交联的均聚物和/或共聚物的水性乳液获得的预形成的球形颗粒形式的超吸收性聚合物和聚合物在卫生产品中的用途，作为农业中的储水材料和电缆护套。

6. 发明授权

US5837796A Polyisocyanates containing isocyanurate groups and prepared by trimerizing alkyl-substituted cycloaliphatic diisocyanates 失效
标题翻译：含有异氰脲酸酯基并通过三烷基取代的环脂族二异氰酸酯制备的多异氰酸酯
公开(公告)号：US5837796A
公开(公告)日：1998-11-17
申请号：US883477
申请日：1997-06-25
申请人： Hans-Joachim Scholl , Bernhard Jansen , Rolf-Volker Meyer
发明人： Hans-Joachim Scholl , Bernhard Jansen , Rolf-Volker Meyer
IPC分类号： C07D251/34 , C08G18/02 , C08G18/18 , C08G18/70 , C08G18/79 , C08G18/82
CPC分类号： C07D251/34 , C08G18/706 , C08G18/792
摘要： The present invention relates to a process for preparing polyisocyanates containing isocyanurate groups by trimerizing a portion of the isocyanate groups of an organic polyisocyanate component containing a) one or more diisocyanates corresponding to formula (1) ##STR1## wherein R represents a saturated, straight-chain, aliphatic hydrocarbon group having 8 to 15 carbon atoms and optionally b) up to 95 NCO equivalent-%, based on the total equivalents a) and b), of one or more organic polyisocyanates other than a), in the presence of trimerization catalysts and terminating the trimerization reaction at any desired degree of trimerization. The invention also relates to the polyisocyanates containing isocyanurate groups obtained by this process and to their use, optionally in excess starting polyisocyanates and optionally blocked with blocking agents for isocyanate groups, as an isocyanate component for preparing polyisocyanate addition products.
摘要翻译：本发明涉及通过将有机多异氰酸酯组分的一部分异氰酸酯基团三聚而制备含有异氰脲酸酯基的多异氰酸酯的方法，该有机多异氰酸酯组分含有a）一种或多种对应于式（1）的二异氰酸酯，其中R表示饱和，具有8至15个碳原子的直链脂族烃基和任选的b）基于a）和b）的总当量a）和b）至多95NCO当量，一种或多种除a）之外的有机多异氰酸酯，在存在三聚催化剂并以任何所需的三聚程度终止三聚反应。本发明还涉及通过该方法获得的含有异氰脲酸酯基团的多异氰酸酯基团，以及它们的用途，任选地过量起始多异氰酸酯，并任选地用异氰酸酯基团的封端剂封端，作为用于制备多异氰酸酯加成产物的异氰酸酯组分。

7. 发明授权

US5109108A Hexahydrotriazinetrione-containing polyarylene sulphide 失效
标题翻译：含十四烷基四氢呋喃的聚亚锡酯
公开(公告)号：US5109108A
公开(公告)日：1992-04-28
申请号：US565128
申请日：1990-08-10
申请人： Burkhard Kohler , Rolf-Volker Meyer
发明人： Burkhard Kohler , Rolf-Volker Meyer
IPC分类号： C08G75/0222 , C08G75/0231 , C08G75/06
CPC分类号： C08G75/0222 , C08G75/0231
摘要： The invention relates to new hexahydrotriazinetrione-containing high molecular weight polyarylene sulphides (PAS), preferably polyphenylene sulphides (PPS), and a process for their preparation.
摘要翻译：本发明涉及新的含六氢三嗪三酮的高分子量聚亚芳基硫醚（PAS），优选聚亚苯基硫醚（PPS）及其制备方法。

8. 发明授权

US5102935A Free-flowing polyamide molding compounds and blends 失效
标题翻译：自由流动的聚酰胺模塑化合物和共混物
公开(公告)号：US5102935A
公开(公告)日：1992-04-07
申请号：US403133
申请日：1989-09-05
申请人： Hans-Detlef Heinz , Harald Pielartzik , Aziz El-Sayed , Rolf-Volker Meyer , Martin Wandel , Peter-Roger Nyssen
发明人： Hans-Detlef Heinz , Harald Pielartzik , Aziz El-Sayed , Rolf-Volker Meyer , Martin Wandel , Peter-Roger Nyssen
IPC分类号： C08G63/60 , C08K5/105 , C08K5/12 , C08K5/20 , C08L77/00
CPC分类号： C08K5/20 , C08G63/60 , C08K5/105 , C08K5/12 , C08L77/00
摘要： The invention relates to new, free-flowing polyamide molding compounds and blends, characterized in that they are prepared by mixing of polyamides known per se in the melt with low molecular weight, liquid-crystalline esters and/or ester amides corresponding to formula (I) and/or liquid-crystalline, oligomeric esters and/or ester amides corresponding to formula (II) and, optionally, other additives, at least one polymeric blending component being used as a further additive in the case of polyamide blends, and to the use of these liquid-crystalline (LC) additives I and/or II as flow promoters in polyamide molding compounds and blends and to a process for the production of the new polyamide molding compounds and blends. The invention also relates to the new oligomeric esters and/or ester amides corresponding to formula (II).
摘要翻译：本发明涉及新的自由流动的聚酰胺模塑料和共混物，其特征在于它们通过将熔体中本身已知的聚酰胺与对应于式（I）的低分子量，液晶酯和/或酯酰胺）和/或对应于式（II）的液晶，低聚酯和/或酯酰胺和任选的其它添加剂，在聚酰胺共混物的情况下使用至少一种聚合共混组分作为另外的添加剂，并且使用这些液晶（LC）添加剂I和/或II作为聚酰胺模塑料和共混物中的流动促进剂，以及生产新的聚酰胺模塑料和共混物的方法。本发明还涉及对应于式（II）的新的低聚酯和/或酯酰胺。

9. 发明授权

US4960855A Polyarylene ether containing benzoxazole groups and a process for their preparation 失效
标题翻译：含聚苯醚的苯并恶唑基及其制备方法
公开(公告)号：US4960855A
公开(公告)日：1990-10-02
申请号：US354810
申请日：1989-05-22
申请人： Burkhard Kohler , Rolf-Volker Meyer
发明人： Burkhard Kohler , Rolf-Volker Meyer
IPC分类号： C08G65/26 , C08G65/40 , C08G75/23
CPC分类号： C08G65/4006 , C08G75/23
摘要： This invention relates to polyarylene ethers containing benzoxazole groups and to a process for their preparation.
摘要翻译：本发明涉及含有苯并恶唑基团的聚亚芳基醚及其制备方法。

10. 发明授权

US4946927A Preparation of aromatic polycarbonates, aromatic polyester carbonates and aromatic polyesters with organic phase comprising mixture of hydrocarbons 失效
标题翻译：芳族聚碳酸酯，芳族聚酯碳酸酯和芳族聚酯与有机相的制备，包括烃的混合物
公开(公告)号：US4946927A
公开(公告)日：1990-08-07
申请号：US331313
申请日：1989-03-30
申请人： Wolfgang Ebert , Rolf-Volker Meyer , Rolf Dhein , Udo Oels
发明人： Wolfgang Ebert , Rolf-Volker Meyer , Rolf Dhein , Udo Oels
IPC分类号： C08G63/19 , C08G63/64 , C08G63/79 , C08G64/22 , C08G64/24
CPC分类号： C08G63/64 , C08G63/79 , C08G64/24
摘要： The present invention relates to a process for the preparation of aromatic polycarbonates, aromatic polyester carbonates and aromatic polyesters by the known two phase interface process, which is characterized in that the organic phase used is a mixture of aromatic hydrocarbons with alkanes and/or cycloalkanes.
摘要翻译：本发明涉及通过已知的两相界面方法制备芳族聚碳酸酯，芳族聚酯碳酸酯和芳族聚酯的方法，其特征在于所用的有机相是芳族烃与烷烃和/或环烷烃的混合物。

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