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1. 发明授权

US06906163B2 Prepolymer catalysts suitable for preparing spandex fibers 失效
标题翻译：适用于制备氨纶纤维的预聚物催化剂
公开(公告)号：US06906163B2
公开(公告)日：2005-06-14
申请号：US10158988
申请日：2002-05-30
申请人： Bruce D. Lawrey , Thomas A. J. Gross , Rolf-Volker Meyer
发明人： Bruce D. Lawrey , Thomas A. J. Gross , Rolf-Volker Meyer
IPC分类号： C08G18/65 , C08G18/08 , C08G18/12 , C08G18/22 , C08G18/48 , D01F6/70 , C08G18/16
CPC分类号： D01F6/70 , C08G18/0852 , C08G18/12 , C08G18/222 , C08G18/4808 , C08G18/4866 , Y10S528/906 , C08G18/3225 , C08G18/2865
摘要： Segmented polyurethane/ureas useful for the production of spandex, particularly spandex fibers, are made from isocyanate-terminated prepolymers formed by reacting excess isocyanate with an isocyanate-reactive component satisfying specified compositional requirements in the presence of a catalyst which promotes linear polymerization but does not cause degradation of the polymer. Suitable catalysts include metal salts of organic fatty acids and/or of naphthenic acid. The isocyanate-reactive component includes at least 10 equivalent percent of a polyoxypropylene diol having a number average molecular weight of at least about 1500 Da and an average unsaturation level less than or equal to 0.03 meq/g and up to 90 equivalent percent of a polytetramethylene glycol having a number average molecular weight of at least 200 Da.
摘要翻译：用于生产氨纶，特别是氨纶纤维的分段聚氨酯/尿素由异氰酸酯封端的预聚物制成，所述异氰酸酯封端的预聚物通过使过量的异氰酸酯与异氰酸酯反应性组分反应，所述异氰酸酯反应性组分在催化剂存在下促进线性聚合而不满足特定组成要求导致聚合物降解。合适的催化剂包括有机脂肪酸和/或环烷酸的金属盐。异氰酸酯反应性组分包括至少10当量的数均分子量为至少约1500Da且平均不饱和度小于或等于0.03meq / g的聚氧丙烯二醇和至多90当量的聚四亚甲基数均分子量为200Da以上的二元醇。

2. 发明授权

US06737497B2 Polyurethane/ureas useful for the production of spandex and a process for their production 失效
标题翻译：用于生产氨纶的聚氨酯/尿素及其生产工艺
公开(公告)号：US06737497B2
公开(公告)日：2004-05-18
申请号：US10158762
申请日：2002-05-30
申请人： Bruce D. Lawrey , Thomas A. J. Gross , Rolf-Volker Meyer
发明人： Bruce D. Lawrey , Thomas A. J. Gross , Rolf-Volker Meyer
IPC分类号： C08G1810
CPC分类号： D01F6/70 , C08G18/12 , C08G18/4808 , C08G18/4854 , C08G18/4866 , Y10S528/906 , C08G18/3234
摘要： Segmented polyurethane/ureas useful in the production of spandex are produced by chain extending an isocyanate-terminated prepolymer with a diamine chain extender that includes: (1) from about 7 to 25 equivalent percent of an asymmetric aliphatic and/or cycloaliphatic diamine and (2) a linear diamine such as ethylene diamine in the presence of a solvent. The isocyanate-terminated prepolymer is produced by reacting a stoichiometric excess of an isocyanate with an isocyanate-reactive component that includes: (1) from about 10 to about 70 equivalent percent of a polyoxypropylene diol having a molecular weight in excess of 1500 Da and an average unsaturation level no greater than about 0.03 meq/g and (2) from about 30 to about 90 equivalent percent of a polytetramethylene ether glycol having a molecular weight of at least 600 Da.
摘要翻译：用于生产氨纶的分段聚氨酯/尿素是通过用二胺增链剂将异氰酸酯封端的预聚物链延伸而制得的，其包括：（1）约7至25当量％的不对称脂族和/或脂环族二胺和（2 ）线性二胺如乙二胺在溶剂存在下进行。异氰酸酯封端的预聚物通过使化学计量过量的异氰酸酯与异氰酸酯反应性组分反应而制备，所述组分包括：（1）约10至约70当量的分子量超过1500Da的聚氧丙烯二醇和平均不饱和度不大于约0.03meq / g，（2）约30至约90当量分子量至少为600Da的聚四亚甲基醚二醇。

3. 发明申请

US20100222524A1 HIGH MODULUS TRANSPARENT THERMOPLASTIC POLYURETHANES CHARACTERIZED BY HIGH HEAT AND CHEMICAL RESISTANCE 审中-公开
标题翻译：高耐热耐化学性的高模量透明热塑性聚氨酯
公开(公告)号：US20100222524A1
公开(公告)日：2010-09-02
申请号：US12394444
申请日：2009-02-27
申请人： Bruce D. Lawrey , Leslie J. Vescio
发明人： Bruce D. Lawrey , Leslie J. Vescio
IPC分类号： C08L75/04
CPC分类号： C08G18/664 , C08G18/0895 , C08G18/758 , C08L75/04 , C08L2666/20
摘要： Transparent thermoplastic polyurethanes characterized by high impact resistance, high flexural modulus, high chemical resistance and a deflection temperature under load of at least 50° C. at 264 psi are produced by blending a polyurethane reaction product with from 3 to 20 parts by weight, per 100 parts by weight of total blend, of a thermoplastic polyurethane. The polyurethane reaction product is prepared from a diphenylmethane diisocyanate and at least one chain extender at an NCO/OH ratio of from 0.95:1 to 1.10:1 in the absence of any isocyanate-reactive material having a molecular weight greater than 400.
摘要翻译：通过将聚氨酯反应产物与3至20重量份的聚氨酯反应产物混合，其特征在于以264psi的高耐冲击性，高弯曲模量，高耐化学性和在负载下的挠曲温度至少为50℃的透明热塑性聚氨酯， 100重量份的总共混物，热塑性聚氨酯。在不存在分子量大于400的任何异氰酸酯反应性材料的情况下，聚氨酯反应产物由二苯基甲烷二异氰酸酯和至少一种NCO / OH比为0.95:1至1.10:1的扩链剂制备。

4. 发明授权

US07045650B2 Polyurethane elastomers having improved physical properties and a process for the production thereof 有权
公开(公告)号：US07045650B2
公开(公告)日：2006-05-16
申请号：US10932807
申请日：2004-09-02
申请人： Bruce D. Lawrey , Kurt C. Frisch , Nigel Barksby
发明人： Bruce D. Lawrey , Kurt C. Frisch , Nigel Barksby
IPC分类号： C07C271/28 , C07C271/06 , C07C271/08 , C08G18/48 , C08G18/40
CPC分类号： C08G18/4808
摘要： A polyol composition having a number average molecular weight of from about 1,000 to about 3,000 Daltons is made up of (1) at least 60% by weight of a low monol polyoxypropylene polyol having a number average molecular weight of from about 2,000 to 12,000 Da and a degree of unsaturation less than or equal to 0.02 meq/g and (2) no more than 40% by weight of a polyol having a number average molecular weight of from about 400 to about 1,000 Da and a polydispersity index greater than 1.1. This polyol composition is reacted with a diisocyanate, a polyisocyanate, an isocyanate-terminated prepolymer or an isocyanate-terminated quasi-prepolymer to produce polyurethane elastomers having good physical and mechanical properties. Any of the known processes for producing polyurethane elastomers, including one-shot processes, may be used to produce elastomers in accordance with the present invention.

5. 发明授权

US5648447A Elastomeric polyurethanes with improved properties based on crystallizable polyols in combination with low monol polyoxpropylene polyols 失效
标题翻译：基于可结晶多元醇与低单聚氧丙烯多元醇组合改进性能的弹性体聚氨酯
公开(公告)号：US5648447A
公开(公告)日：1997-07-15
申请号：US577959
申请日：1995-12-22
申请人： Stephen D. Seneker , Nigel Barksby , Bruce D. Lawrey
发明人： Stephen D. Seneker , Nigel Barksby , Bruce D. Lawrey
IPC分类号： C08G18/10 , C08G18/40 , C08G18/48
CPC分类号： C08G18/4866 , C08G18/10 , C08G18/4018 , C08G18/4808 , C08G2250/00
摘要： Polyurethane elastomers of improved elongation, tensile strength and other physical properties are prepared from a polyol component containing a crystallizable polyol and from 5 to 35 equivalent percent of a low monol polyoxypropylene polyol by one-shot, quasiprepolymer, and preferably, by prepolymer techniques involving chain extension with an aliphatic diol or aromatic amine.
摘要翻译：具有改善的伸长率，拉伸强度和其它物理性质的聚氨酯弹性体由含有可结晶多元醇的多元醇组分和5-35％当量的低一羟基聚氧丙烯多元醇通过单次，准双组分共聚物制备，优选通过涉及链的预聚物技术用脂族二醇或芳香胺延伸。

6. 发明申请

US20160347900A1 SOFTENING THERMOPLASTIC POLYURETHANES USING IONOMER TECHNOLOGY 审中-公开
标题翻译：使用IONOMER技术的热塑性聚氨酯
公开(公告)号：US20160347900A1
公开(公告)日：2016-12-01
申请号：US15166948
申请日：2016-05-27
申请人： Matthew BECKER , Robert A. Weiss , Zachary Kurtiss Zander , Don S. Wardius , Karl W. Haider , Bruce D. Lawrey
发明人： Matthew BECKER , Robert A. Weiss , Zachary Kurtiss Zander , Don S. Wardius , Karl W. Haider , Bruce D. Lawrey
IPC分类号： C08G18/08 , C08G18/10 , C08G18/38 , C08G18/48 , C08G18/65 , C08G18/76 , C08G18/32
CPC分类号： C08G18/10 , C08G18/0814 , C08G18/0828 , C08G18/42 , C08G18/44 , C08G18/48 , C08G18/603 , C08G18/7671 , C08G18/3206 , C08G18/3857 , C08G18/3855
摘要： In one or more embodiments, the present invention provides a novel approach to the addition of plasticizers for softening TPUs, i.e., lowering the durometer and the melt viscosity. This approach involves incorporating bonded sulfonate groups with quaternary ammonium counterions into the TPU. In one or more embodiments of the present invention, the softening of TPU is achieved by incorporating an ionic diol, such as N,N-bis (2-hydoxyethyl)-2-aminoethane-sulfonic acid (BES), coupled with various bulky alkyl ammonium cations, during the chain extension step of the TPU synthesis. It is believed that that steric hindrance of the bulky quaternary ammonium groups weakens the dipole-dipole interactions of the sulfonate groups and/or lowers the crystallinity of the hard block, thereby creating additional free volume that softens the polymer and lowers the melt viscosity.
摘要翻译：在一个或多个实施方案中，本发明提供了添加用于软化TPU的增塑剂的新方法，即降低硬度和熔融粘度。这种方法包括将键合的磺酸盐基团与季铵抗衡离子结合到TPU中。在本发明的一个或多个实施方案中，TPU的软化通过加入离子二醇，例如N，N-双（2-羟乙基）-2-氨基乙磺酸（BES），与各种大体积烷基在TPU合成的扩链步骤期间，铵阳离子。据信大体积季铵基团的空间位阻削弱了磺酸盐基团的偶极 - 偶极相互作用和/或降低了硬块的结晶度，从而产生了使聚合物软化并降低了熔体粘度的额外的自由体积。

7. 发明授权

US07511111B2 Polyurethane elastomers having improved physical properties and a process for the production thereof 有权
标题翻译：具有改善的物理性质的聚氨酯弹性体及其制备方法
公开(公告)号：US07511111B2
公开(公告)日：2009-03-31
申请号：US11374789
申请日：2006-03-14
申请人： Bruce D. Lawrey , Kurt C. Frisch , Nigel Barksby
发明人： Bruce D. Lawrey , Kurt C. Frisch , Nigel Barksby
IPC分类号： C08G18/12 , C08G18/10 , C08G18/48 , C08G18/32 , C08G18/40
CPC分类号： C08G18/4866 , C08G18/10 , C08G18/3206
摘要： A polyol composition having a number average molecular weight of from about 1,000 to about3,000 Daltons is made up of (1) at least 55% by weight of a low monol polyoxypropylene polyol having a number average molecular weight of from about 1,000 to 12,000 Da and a degree of unsaturation less than or equal to 0.02 meq/g and (2) no more than 45% by weight of a polyol having a number average molecular weight of from about 400 to about 1,000 Da and a polydispersity index greater than1.1. This polyol composition is reacted with a diisocyanate, a polyisocyanate, an isocyanate-terminated prepolymer or an isocyanate-terminated quasi-prepolymer to produce polyurethanes, particularly, polyurethane elastomers having good physical and mechanical properties. Any of the known processes for producing polyurethanes, particularly, elastomers, including one-shot processes, may be used to produce polyurethanes in accordance with the present invention.
摘要翻译：数均分子量为约1,000至约3,000道尔顿的多元醇组合物由以下组成：（1）至少55重量％的数均分子量为约1,000至12,000Da的低一羟基聚氧丙烯多元醇和不足于0.02meq / g的不饱和度和（2）不超过45重量％的数均分子量为约400至约1,000Da的多元醇和多分散指数大于1.1 。该多元醇组合物与二异氰酸酯，多异氰酸酯，异氰酸酯封端的预聚物或异氰酸酯封端的预预聚物反应以制备聚氨酯，特别是具有良好物理和机械性能的聚氨酯弹性体。用于生产聚氨酯的任何已知方法，特别是弹性体，包括一步法，可用于制备根据本发明的聚氨酯。

8. 发明授权

US06624281B1 Polyurethane/ureas useful for the production of spandex and a process for their production 失效
标题翻译：用于生产氨纶的聚氨酯/尿素及其生产工艺
公开(公告)号：US06624281B1
公开(公告)日：2003-09-23
申请号：US10158616
申请日：2002-05-30
申请人： Bruce D. Lawrey
发明人： Bruce D. Lawrey
IPC分类号： C08G1810
CPC分类号： D01F6/70 , C08G18/12 , C08G18/222 , C08G18/4808 , C08G18/4854 , C08G18/4866 , Y10S528/906 , C08G18/3234
摘要： Segmented polyurethane/ureas useful for the production of spandex are produced by chain extending, in the presence of a solvent, an isocyanate-terminated prepolymer prepared by reacting a stoichiometric excess of an isocyanate with an isocyanate-reactive component which includes: (1) from about 5 to about 30 equivalent percent of a polyoxy-propylene diol having a molecular weight of at least 1500 Da and an unsaturation level less than or equal to 0.03 meq/g; (2) from about 20 to about 60 equivalent percent of a polytetramethylene ether glycol having a molecular weight less than 1000 Da; and (3) from about 25 to about 65 equivalent percent of a polytetramethylene ether glycol having a molecular weight greater than or equal to 1000 Da.
摘要翻译：可用于生产氨纶的分段聚氨酯/尿素通过在溶剂存在下通过使化学计量过量的异氰酸酯与异氰酸酯反应性组分反应制备的异氰酸酯封端的预聚物链延伸生产，所述异氰酸酯封端的预聚物包括：（1）约5至约30当量的分子量至少为1500Da且不饱和度小于或等于0.03meq / g的聚氧丙烯二醇; （2）约20至约60当量％的分子量小于1000Da的聚四亚甲基醚二醇; 和（3）约25至约65当量％的分子量大于或等于1000Da的聚四亚甲基醚二醇。

9. 发明授权

US06420445B1 Polyurethane and polyurethane/urea heat-cured and moisture-cured elastomers with improved physical properties 失效
标题翻译：具有改善物理性能的聚氨酯和聚氨酯/尿素热固化和湿固化弹性体
公开(公告)号：US06420445B1
公开(公告)日：2002-07-16
申请号：US09487087
申请日：2000-01-19
申请人： Nigel Barksby , Bruce D. Lawrey , Susan M. Clift
发明人： Nigel Barksby , Bruce D. Lawrey , Susan M. Clift
IPC分类号： C08J904
CPC分类号： C08G18/6674 , C08G18/12 , C08G18/4866 , C08G18/307
摘要： Elastomers with improved physical properties, particularly hardness, resilience, tear strength, and compression set, may be prepared by the chain extension or moisture cure of isocyanate-terminated prepolymers prepared from a polyol component comprising a high molecular weight, low unsaturation polyoxypropylene diol and a low molecular weight diol. The elastomers are useful for applications such as rollers and other applications for which these physical properties are important.
摘要翻译：具有改进的物理性能，特别是硬度，弹性，撕裂强度和压缩永久变形的弹性体可以通过由包含高分子量，低不饱和聚氧丙烯二醇和多元醇的多元醇组分制备的异氰酸酯封端的预聚物的链延长或水分固化来制备低分子量二醇。弹性体可用于诸如辊和其它这些物理性质重要的应用。

10. 发明授权

US5691441A Spandex elastomers 失效
标题翻译：氨纶弹性体
公开(公告)号：US5691441A
公开(公告)日：1997-11-25
申请号：US728922
申请日：1996-10-11
申请人： Stephen D. Seneker , Bruce D. Lawrey
发明人： Stephen D. Seneker , Bruce D. Lawrey
IPC分类号： C08G18/48 , C08G18/12 , C07C269/02
CPC分类号： C08G18/4866 , C08G18/4808 , Y10S528/906
摘要： Substitution of from 5 to 50 equivalent percent of an ultra-low unsaturation polyoxypropylene diol for PTMEG in isocyanate-terminated prepolymers used in spandex production is found to lower considerably both prepolymer viscosity and hysteresis while substantially retaining other desirable physical properties. Such products may offer higher fiber production rates than are possible while employing an all PTMEG-derived polymer.
摘要翻译：发现用于氨纶生产中用于异氰酸酯封端的预聚物中的用于PTMEG的超低不饱和聚氧丙烯二醇的5至50当量的替代物显着降低了预聚物粘度和滞后，同时基本上保持了其它所需的物理性质。当使用所有的PTMEG衍生的聚合物时，这样的产品可能提供比可能的更高的纤维生产速率。

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