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1. 发明授权

US5571881A Addition polymers derived from norbornene-functional monomers and process therefor 失效
公开(公告)号：US5571881A
公开(公告)日：1996-11-05
申请号：US476810
申请日：1995-06-07
申请人： Brian L. Goodall , George M. Benedikt , Lester H. McIntosh, III , Dennis A. Barnes , Larry F. Rhodes
发明人： Brian L. Goodall , George M. Benedikt , Lester H. McIntosh, III , Dennis A. Barnes , Larry F. Rhodes
IPC分类号： C08F4/70 , C08F4/30 , C08F4/42 , C08F4/80 , C08F32/00 , C08F32/08 , C08F36/04 , C08F36/20 , C08F210/14 , C08F232/08 , C08F236/20 , C08F4/76 , C08F4/78
CPC分类号： C08F232/08 , C08F32/08
摘要： Addition polymers derived from norbornene-functional monomers are terminated with an olefinic moiety derived from a chain transfer agent selected from a compound having a terminal olefinic double bond between adjacent carbon atoms, excluding styrenes, vinyl ethers, and conjugated dienes and at least one of said carbon atoms has two hydrogen atoms attached thereto. The addition polymers of this invention are prepared from a single or multicomponent catalyst system including a Group VIII metal ion source. The catalyst systems are unique in that they catalyze the insertion of the chain transfer agent exclusively at a terminal end of the polymer chain.

2. 发明授权

US5569730A Addition polymers derived from norbornene-functional monomers and process therefor 失效
标题翻译：衍生自降冰片烯官能单体的加成聚合物及其工艺
公开(公告)号：US5569730A
公开(公告)日：1996-10-29
申请号：US339863
申请日：1994-11-15
申请人： Brian L. Goodall , George M. Benedikt , Lester H. McIntosh, III , Dennis A. Barnes , Larry F. Rhodes
发明人： Brian L. Goodall , George M. Benedikt , Lester H. McIntosh, III , Dennis A. Barnes , Larry F. Rhodes
IPC分类号： C08F4/70 , C08F4/30 , C08F4/42 , C08F4/80 , C08F32/00 , C08F32/08 , C08F36/04 , C08F36/20 , C08F210/14 , C08F232/08 , C08F236/20 , C08F10/00 , C08F32/02 , C08F34/00
CPC分类号： C08F232/08 , C08F32/08
摘要： Addition polymers derived from norbornene-functional monomers are terminated with an olefinic moiety derived from a chain transfer agent selected from a compound having a terminal olefinic double bond between adjacent carbon atoms, excluding styrenes, vinyl ethers, and conjugated dienes and at least one of said carbon atoms has two hydrogen atoms attached thereto. The addition polymers of this invention are prepared from a single or multicomponent catalyst system including a Group VIII metal ion source. The catalyst systems are unique in that they catalyze the insertion of the chain transfer agent exclusively at a terminal end of the polymer chain.
摘要翻译：衍生自降冰片烯官能单体的加成聚合物由衍生自链转移剂的烯烃部分封端，所述链转移剂选自相邻碳原子之间具有末端烯属双键的化合物，不包括苯乙烯，乙烯基醚和共轭二烯，并且所述碳原子上连有两个氢原子。本发明的加成聚合物由包含VIII族金属离子源的单组分或多组分催化剂体系制备。催化剂体系是独特的，因为它们催化仅在聚合物链的末端插入链转移剂。

3. 发明授权

US06649707B1 Blends and alloys of polycyclic polymers 失效
标题翻译：多环聚合物的共混物和合金
公开(公告)号：US06649707B1
公开(公告)日：2003-11-18
申请号：US09679001
申请日：2000-10-04
申请人： Larry F. Rhodes , Brian L. Goodall , Rolf Mülhaupt , Robert A. Shick , George M. Benedikt , Sai Kumar Jayaraman , Lynn M. Soby , Lester H. McIntosh, III
发明人： Larry F. Rhodes , Brian L. Goodall , Rolf Mülhaupt , Robert A. Shick , George M. Benedikt , Sai Kumar Jayaraman , Lynn M. Soby , Lester H. McIntosh, III
IPC分类号： C08G7704
CPC分类号： C08G77/442 , C08F232/08 , C08F277/00 , C08L53/025 , C08L2666/04
摘要： Polycyclic addition polymers derived from norbornene-type monomers are mixed with a variety of other polymers to generate families of new blends, alloys, and block copolymers.
摘要翻译：衍生自降冰片烯型单体的多环加成聚合物与各种其它聚合物混合以产生新的共混物，合金和嵌段共聚物的族。

4. 发明授权

US06294616B1 Blends and alloys of polycyclic polymers 失效
标题翻译：多环聚合物的共混物和合金
公开(公告)号：US06294616B1
公开(公告)日：2001-09-25
申请号：US08450648
申请日：1995-05-25
申请人： Larry F. Rhodes , Brian L. Goodall , Rolf Mülhaupt , Robert A. Shick , George M. Benedikt , Sai Kumar Jayaraman , Lynn M. Soby , Lester H. McIntosh, III
发明人： Larry F. Rhodes , Brian L. Goodall , Rolf Mülhaupt , Robert A. Shick , George M. Benedikt , Sai Kumar Jayaraman , Lynn M. Soby , Lester H. McIntosh, III
IPC分类号： C08F1014
CPC分类号： C08G77/442 , C08F232/08 , C08F277/00 , C08L53/025 , C08L2666/04
摘要： Polycyclic addition polymers derived from norbornene-type monomers are mixed with a variety of other polymers to generate families of new blends, alloys, and block copolymers.
摘要翻译：衍生自降冰片烯型单体的多环加成聚合物与各种其它聚合物混合以产生新的共混物，合金和嵌段共聚物的族。

5. 发明授权

US5468819A Process for making polymers containing a norbornene repeating unit by addition polymerization using an organo (nickel or palladium) complex 失效
标题翻译：使用有机（镍或钯）络合物通过加成聚合制备含有降冰片烯重复单元的聚合物的方法
公开(公告)号：US5468819A
公开(公告)日：1995-11-21
申请号：US153250
申请日：1993-11-16
申请人： Brian L. Goodall , George M. Benedikt , Lester H. McIntosh, III , Dennis A. Barnes
发明人： Brian L. Goodall , George M. Benedikt , Lester H. McIntosh, III , Dennis A. Barnes
IPC分类号： C08F4/70 , C08F4/30 , C08F4/42 , C08F4/80 , C08F32/00 , C08F32/08 , C08F36/04 , C08F36/20 , C08F210/14 , C08F232/08 , C08F236/20 , C08F4/76 , C08F4/78
CPC分类号： C08F232/08 , C08F32/08
摘要： A single component ionic catalyst consists essentially of an organonickel complex cation, and a weakly coordinating neutral counteranion. The cation is a neutral bidentate ligand removably attached to a Group VIII transition metal in an organometal complex. The ligand is easily displaced by a norbornene-type (NB-type) monomer in an insertion reaction which results in an unexpectedly facile addition polymerization. A NB-type monomer includes NB or substituted NB, or a multi-ringed cycloolefin having more than three rings in which one or more of the rings has a structure derived from NB, and a ring may have an alicyclic alkyl, alkylene or alkylidene substituent. The insertion reaction results in the formation of a unique propagating species more soluble in a polar than in a non-polar solvent and devoid of an available .beta.-hydrogen for termination. The ensuing propagation of a polymer chain proceeds without measurable unsaturation. The chain continues to grow until the insertion of a monoolefinic chain transfer reagent results in substantially all chains being terminated with the residue of the chain transfer reagent. This unique chain transfer reaction allows one to control the molecular weight in a relatively narrow range. The reaction mixture for controlling the mol wt of the polymer chains may contain any other catalyst which generates a propagating species by an insertion reaction in an essentially anhydrous solvent. Both, mol wt and glass transition temperature Tg are tailored to provide a weight average mol wt Mw>20,000 but preferably not greater than about 500,000, and a T.sub.g in the range from about 150.degree. C. to about 400.degree. C. or higher, if desired.
摘要翻译：单组分离子催化剂基本上由有机镍络合物阳离子和弱配位的中性抗衡阴离子组成。该阳离子是一种中和二齿配体，可以与有机金属络合物中的第VIII族过渡金属可去除地连接。配体在插入反应中容易被降冰片烯型（NB型）单体置换，导致出人意料的容易的加成聚合。 NB型单体包括NB或取代的NB，或具有多于三个环的多环环烯，其中一个或多个环具有源自NB的结构，并且环可以具有脂环族烷基，亚烷基或亚烷基取代基。插入反应导致形成比非极性溶剂更易溶于极性的独特的增殖物质，并且没有可用的β-氢终止。随后的聚合物链的扩散进行而没有可测量的不饱和度。链条继续生长，直到插入单烯烃链转移试剂导致基本上所有的链都被链转移试剂的残基终止。这种独特的链转移反应允许在相对较窄的范围内控制分子量。用于控制聚合物链的摩尔重量的反应混合物可以含有任何其它催化剂，其通过在基本上无水的溶剂中的插入反应产生传播物质。二氧化钼和玻璃化转变温度Tg均适用于提供重均分子量Mw> 20,000但优选不大于约500,000，Tg在约150℃至约400℃或更高的范围内，如果需要的话。

6. 发明授权

US07422836B2 Dissolution rate modifiers for photoresist compositions 有权
标题翻译：光刻胶组合物的溶解速率改性剂
公开(公告)号：US07422836B2
公开(公告)日：2008-09-09
申请号：US10783386
申请日：2004-02-20
申请人： Larry F. Rhodes , Lawrence Seger , Brian L. Goodall , Lester H. McIntosh, III , Robert J. Duff
发明人： Larry F. Rhodes , Lawrence Seger , Brian L. Goodall , Lester H. McIntosh, III , Robert J. Duff
IPC分类号： G03F7/00 , G03F7/004 , C08F136/00
CPC分类号： C08F232/08 , G03F7/0045 , G03F7/0046 , G03F7/038 , G03F7/0382 , G03F7/0392 , G03F7/0395 , G03F7/0397
摘要： Oligomers of polycyclic olefin monomers, and optionally allylic or olefinic monomers, and a method of making such oligomers that includes reacting polycyclic olefin monomers in the presence of a Ni or Pd containing catalyst, or in the case of allylic monomers in the presence of a free radical initiator. The oligomers can be included in photoresist compositions as dissolution rate modifiers. The photoresist compositions can further include a polymeric binder resin, a photoacid generator, and solvents.
摘要翻译：多环烯烃单体和任选的烯丙基或烯属单体的低聚物，以及制备这样的低聚物的方法，其包括在含有Ni或Pd的催化剂存在下使多环烯烃单体反应，或者在烯丙基单体的情况下，自由基引发剂。低聚物可以包含在光致抗蚀剂组合物中作为溶解速率改性剂。光致抗蚀剂组合物还可以包括聚合物粘合剂树脂，光致酸产生剂和溶剂。

7. 发明授权

US06936672B2 Mold addition polymerization of norbornene-type monomers using group 10 metal complexes 有权
标题翻译：使用第10族金属络合物对降冰片烯型单体进行加模聚合
公开(公告)号：US06936672B2
公开(公告)日：2005-08-30
申请号：US09921051
申请日：2001-08-02
申请人： Andrew Bell , Larry F. Rhodes , Brian L. Goodall , John C. Fondran , Lester H. Mclntosh, III , Dennis A. Barnes
发明人： Andrew Bell , Larry F. Rhodes , Brian L. Goodall , John C. Fondran , Lester H. Mclntosh, III , Dennis A. Barnes
IPC分类号： B29C45/00 , B29K45/00 , C08F4/70 , C08F4/80 , C08F32/00 , C08F232/00 , C08F232/08 , C08F4/44 , C08F132/08
CPC分类号： C08F232/08 , C08F32/00 , C08F232/00
摘要： A catalyst system and a process for the bulk addition polymerization or of polycyclic olefins, such as norbornene, methylnorbornene, ethylnorbornene, butylnorbornene or hexylnorbornene, 1,2,3,4,4a,5,8,8a-octahydro-1,4:5,8-dimethanonapthalene, 5,5′-(1,2-ethanediyl)bisbicyclo[2.2.1]hept-2-ene, and 1,4,4a,4b,5,8,8a,8b-octahydro-1,4:5,8-dimethanobiphenylene are disclosed. The catalyst includes an organonickel or organopalladium transition metal procatalyst and an activator compound. Polymerization can be carried out in a reaction injection molding process to yield thermoplastic and thermoset molded polymeric articles possessing high glass transition temperatures.
摘要翻译：催化剂体系和本体加成聚合方法或降冰片烯，甲基降冰片烯，乙基降冰片烯，丁基降冰片烯或己基降冰片烯等多环烯烃，1,2,3,4,4a，5,8,8a-八氢-1,4： 5,8-二甲基萘，5,5' - （1,2-乙二基）双双环[2.2.1]庚-2-烯和1,4,4a，4b，5,8,8a，8b-八氢-1 ，4：5,8-二甲基亚二苯基。催化剂包括有机金属或有机钯过渡金属前催化剂和活化剂化合物。可以在反应注射成型工艺中进行聚合以产生具有高玻璃化转变温度的热塑性和热固性模塑聚合物制品。

8. 发明授权

US6031058A Addition polymers of polycycloolefins containing silyl functional groups 有权
标题翻译：含有甲硅烷基官能团的聚环烯烃的加成聚合物
公开(公告)号：US6031058A
公开(公告)日：2000-02-29
申请号：US263930
申请日：1999-03-08
申请人： Lester H. McIntosh, III , Brian L. Goodall , Robert A. Shick , Saikumar Jayaraman
发明人： Lester H. McIntosh, III , Brian L. Goodall , Robert A. Shick , Saikumar Jayaraman
IPC分类号： C08F4/605 , C08F4/606 , C08F32/08 , C08F4/80
CPC分类号： C08F32/08
摘要： Silyl substituted polymers of polycycloolefins are provided as well as catalyst systems for their preparation. The polymers of the invention include polycyclic repeat units that contain pendant silyl functional groups represented by the following formulae: ##STR1## wherein A is a divalent radical selected from the following structures: ##STR2## R.sup.9 independently represents hydrogen, methyl, or ethyl; R.sup.10, R.sup.11, and R.sup.12 independently represent halogen, linear or branched (C.sub.1 to C.sub.20) alkyl, linear or branched (C.sub.1 to C.sub.20) alkoxy, linear or branched (C.sub.1 to C.sub.20) alkyl carbonyloxy, (C.sub.1 to C.sub.20) alkyl peroxy, and substituted or unsubstituted (C.sub.6 to C.sub.20) aryloxy; R.sup.10, R.sup.11, and R.sup.12 together with the silicon atom to which they are attached form the group: ##STR3## n is a number from 0 to 5; and n' is 0 or 1; and n" is a number from 0 to 10.
摘要翻译：提供聚环烯烃的甲硅烷基取代聚合物以及用于其制备的催化剂体系。本发明的聚合物包括含有由下式表示的侧链甲硅烷基官能团的多环重复单元：其中A是选自以下结构的二价基团：R9独立地表示氢，甲基或乙基; R10，R11和R12独立地表示直链或支链（C1至C20）烷基，直链或支链（C1至C20）烷氧基，直链或支链（C1至C20）烷基羰基氧基，（C1至C20）烷基过氧基），和取代或未取代的（C6〜C20）芳氧基; R 10，R 11和R 12与它们所连接的硅原子一起形成基团：n为0至5的数; 并且n'为0或1; n“是从0到10的数字。

9. 发明授权

US5912313A Addition polymers of polycycloolefins containing silyl functional groups 失效
公开(公告)号：US5912313A
公开(公告)日：1999-06-15
申请号：US562345
申请日：1995-11-22
申请人： Lester H. McIntosh, III , Brian L. Goodall , Robert A. Shick , Saikumar Jayaraman
发明人： Lester H. McIntosh, III , Brian L. Goodall , Robert A. Shick , Saikumar Jayaraman
IPC分类号： C08F4/605 , C08F4/606 , C08F32/08 , C08F232/08 , C08F230/08
CPC分类号： C08F32/08
摘要： Silyl substituted polymers of polycycloolefins are provided as well as catalyst systems for their preparation. The polymers of the invention include polycyclic repeat units that contain pendant silyl functional groups represented by the following formulae: ##STR1## wherein A is a divalent radical selected from the following structures: ##STR2## R.sup.9 independently represents hydrogen, methyl, or ethyl; R.sup.10, R.sup.11, and R.sup.12 independently represent halogen, linear or branched (C.sub.1 to C.sub.20) alkyl, linear or branched (C.sub.1 to C.sub.20) alkoxy, linear or branched (C.sub.1 to C.sub.20) alkyl carbonyloxy, (C.sub.1 to C.sub.20) alkyl peroxy, and substituted or unsubstituted (C.sub.6 to C.sub.20) aryloxy; R.sup.10, R.sup.11, and R.sup.12 together with the silicon atom to which they are attached form the group: ##STR3## n is a number from 0 to 5; and n' is 0 or 1; and n" is a number from 0 to 10.

10. 发明授权

US07022790B2 Photosensitive compositions based on polycyclic polymers 有权
标题翻译：基于多环聚合物的光敏组合物
公开(公告)号：US07022790B2
公开(公告)日：2006-04-04
申请号：US10465511
申请日：2003-06-19
申请人： Edmund Elce , Takashi Hirano , Jeffrey C. Krotine, Jr. , Larry F. Rhodes , Brian L. Goodall , SaiKumar Jayaraman , W. Chris McDougall , Shenliang Sun
发明人： Edmund Elce , Takashi Hirano , Jeffrey C. Krotine, Jr. , Larry F. Rhodes , Brian L. Goodall , SaiKumar Jayaraman , W. Chris McDougall , Shenliang Sun
IPC分类号： C08F10/00
CPC分类号： G03F7/0382 , C08G59/3218 , C08G61/02 , C08G61/06
摘要： A copolymer composition including a copolymer having repeat units of structural formula I: where X is selected from —CH2—, —CH2—CH2— and O; m is an integer from 0 to 5; and each occurrence of R1–R4 are independently selected from H; C1 to C25 linear, branched, and cyclic alkyl, aryl, aralkyl, alkaryl, alkenyl and alkynyl that can include one or more hetero atoms selected from O, N, and Si; a group that contains an epoxy functionality; —(CH2)nC(O)OR5; —(CH2)nC(O)OR6; —(CH2)nOR6; —(CH2)nOC(O)R6; —(CH2)nC(O)R6; —(CH2)nOC(O)OR6; and any combination of two of R1, R2, R3, and R4 linked together by a linking group. A portion of the repeat units having structural formula I contain at least one epoxy functional pendant group. The copolymer composition can be included with a material that photonically forms a catalyst in a photodefinable dielectric composition, which can be used to form a photodefinable layer on a substrate.
摘要翻译：一种共聚物组合物，其包含具有结构式I的重复单元的共聚物：其中X选自-CH 2 - ， - CH 2 -CH 2 > - 和O; m是0至5的整数; 并且每次出现的R 1 -R 4独立地选自H; C 1至C 25直链，支链和环状的烷基，芳基，芳烷基，烷芳基，烯基和炔基，其可以包括一个或多个选自O，N，和Si; 含有环氧官能团的基团; - （CH 2）2 C（O）OR 5; - （CH 2）2 C（O）OR 6; - （CH 2 2）n - 或 - 6 - - （CH 2）n OC（O）R 6; - （CH 2 CH 2）n C（O）R 6; - （CH 2）n OC（O）OR 6; 并且R 1，R 2，R 3，R 4和R 4中的两个的任何组合通过连接组。具有结构式I的重复单元的一部分含有至少一个环氧官能侧基。该共聚物组合物可以包含在可光致定影的电介质组合物中光子形成催化剂的材料，该组合物可用于在基底上形成光可定义层。

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