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    • 3. 发明授权
    • In-situ generation of oxygen-releasing metal peroxides
    • 释放氧气的金属过氧化物的原位生成
    • US07160471B2
    • 2007-01-09
    • US10976089
    • 2004-10-27
    • Brian B. LooneyMiles E. Denham
    • Brian B. LooneyMiles E. Denham
    • B09C1/08C02F1/72
    • B09C1/08B09C1/002B09C1/02B09C1/10
    • A method for remediation of contaminants in soil and groundwater is disclosed. The method generates oxygen releasing solids in groundwater or soil by injecting an aqueous energetic oxidant solution containing free radicals, oxidative conditions can be created within or ahead of a contaminant plume. Some contaminants may be remediated directly by reaction with the free radicals. Additionally and more importantly, the free radicals create an oxidative condition whereby native or injected materials, especially metals, are converted to peroxides. These peroxides provide a long-term oxygen reservoir, releasing oxygen relatively slowly over time. The oxygen can enhance microbial metabolism to remediate contaminants, can react with contaminant metals either to form immobile precipitants or to mobilize other metals to permit remediation through leaching techniques. Various injection strategies for injecting the energetic oxidant solution are also disclosed.
    • 公开了一种补救土壤和地下水中污染物的方法。 该方法通过注入含有自由基的含水能量氧化剂溶液在地下水或土壤中产生释放氧的固体,可以在污染物羽流内或之前产生氧化条件。 一些污染物可以通过与自由基的反应直接补救。 另外且更重要的是,自由基产生氧化条件,其中将天然或注入的材料,特别是金属转化为过氧化物。 这些过氧化物提供长期的氧气储存器,随着时间的推移释放氧气相对较慢。 氧气可以增强微生物代谢以修复污染物,可以与污染金属反应形成固定的沉淀剂或调动其他金属,以允许通过浸出技术进行修复。 还公开了用于注入高能氧化剂溶液的各种注入策略。
    • 5. 发明授权
    • Method and device for removing a non-aqueous phase liquid from a groundwater system
    • 从地下水系统去除非水相液体的方法和装置
    • US06367563B1
    • 2002-04-09
    • US09585539
    • 2000-06-02
    • Brian B. LooneyJoseph RossabiBrian D. Riha
    • Brian B. LooneyJoseph RossabiBrian D. Riha
    • E21B4908
    • B09C1/002B09C1/00
    • A device for removing a non-aqueous phase liquid from a groundwater system includes a generally cylindrical push-rod defining an internal recess therein. The push-rod includes first and second end portions and an external liquid collection surface. A liquid collection member is detachably connected to the push-rod at one of the first and second end portions thereof. The method of the present invention for removing a non-aqueous phase liquid from a contaminated groundwater system includes providing a lance including an external hydrophobic liquid collection surface, an internal recess, and a collection chamber at the bottom end thereof. The lance is extended into the groundwater system such that the top end thereof remains above the ground surface. The liquid is then allowed to collect on the liquid collection surface, and flow downwardly by gravity into the collection chamber to be pumped upwardly through the internal recess in the lance.
    • 用于从地下水系统去除非水相液体的装置包括在其中限定内部凹部的大致圆柱形的推杆。 推杆包括第一和第二端部和外部液体收集表面。 液体收集构件在其第一和第二端部中的一个处可拆卸地连接到推杆。 从污染的地下水系统中除去非水相液体的本发明的方法包括在其底端提供包括外部疏水性液体收集表面,内部凹陷和收集室的喷枪。 喷枪延伸到地下水系统中,使得其顶端保持在地面上方。 然后允许液体收集在液体收集表面上,并通过重力向下流入收集室,以向上泵送通过喷枪内部凹槽。
    • 7. 发明授权
    • Method for phosphate-accelerated bioremediation
    • 磷酸盐加速生物修复方法
    • US5480549A
    • 1996-01-02
    • US186065
    • 1994-01-25
    • Brian B. LooneyKenneth H. LombardTerry C. HazenSusan M. PfiffnerTommy J. PhelpsJames W. Borthen
    • Brian B. LooneyKenneth H. LombardTerry C. HazenSusan M. PfiffnerTommy J. PhelpsJames W. Borthen
    • B09C1/10C02F3/34
    • B09C1/10B09C2101/00Y02E50/343
    • An apparatus and method for supplying a vapor-phase nutrient to contaminated soil for in situ bioremediation. The apparatus includes a housing adapted for containing a quantity of the liquid nutrient, a conduit in fluid communication with the interior of the housing, means for causing a gas to flow through the conduit, and means for contacting the gas with the liquid so that a portion thereof evaporates and mixes with the gas. The mixture of gas and nutrient vapor is delivered to the contaminated site via a system of injection and extraction wells configured to the site. The mixture has a partial pressure of vaporized nutrient that is no greater than the vapor pressure of the liquid. If desired, the nutrient and/or the gas may be heated to increase the vapor pressure and the nutrient concentration of the mixture. Preferably, the nutrient is a volatile, substantially nontoxic and nonflammable organic phosphate that is a liquid at environmental temperatures, such as triethyl phosphate or tributyl phosphate.
    • 一种用于向污染土壤供应气相营养物质用于原位生物修复的装置和方法。 该装置包括适于容纳一定数量的液体营养物质的壳体,与壳体内部流体连通的导管,用于使气体流过导管的装置,以及用于使气体与液体接触的装置, 其部分蒸发并与气体混合。 气体和营养蒸气的混合物通过配置到现场的注射和提取井的系统输送到污染部位。 该混合物具有不大于液体的蒸气压的汽化营养物的分压。 如果需要,可以加热营养物和/或气体以增加混合物的蒸气压和营养物浓度。 优选地,营养物是在环境温度下为液体的挥发性,基本上无毒的和不可燃的有机磷酸盐,例如磷酸三乙酯或磷酸三丁酯。
    • 8. 发明授权
    • Modular, multi-level groundwater sampler
    • 模块化,多级地下水采样器
    • US5293931A
    • 1994-03-15
    • US966267
    • 1992-10-26
    • Ralph L. NicholsMark A. WiddowsonHarry MullinexWilliam H. OrneBrian B. Looney
    • Ralph L. NicholsMark A. WiddowsonHarry MullinexWilliam H. OrneBrian B. Looney
    • E21B43/00E21B43/12E21B47/06E21B49/08
    • E21B49/08E21B43/00E21B43/121E21B47/06
    • Apparatus for taking a multiple of samples of groundwater or pressure measurements from a well simultaneously. The apparatus comprises a series of chambers arranged in an axial array, each of which is dimensioned to fit into a perforated well casing and leave a small gap between the well casing and the exterior of the chamber. Seals at each end of the container define the limits to the axial portion of the well to be sampled. A submersible pump in each chamber pumps the groundwater that passes through the well casing perforations into the gap from the gap to the surface for analysis. The power lines and hoses for the chambers farther down the array pass through each chamber above them in the array. The seals are solid, water-proof, non-reactive, resilient disks supported to engage the inside surface of the well casing. Because of the modular design, the apparatus provides flexibility for use in a variety of well configurations.
    • 用于从井中同时获取多个地下水样本或压力测量的装置。 该装置包括以轴向排列的一系列腔室,每个腔室的尺寸适于装配到穿孔井套管中,并且在井壳体和腔室的外部之间留下小的间隙。 在容器的每个端部处的密封件限定要被采样的井的轴向部分。 每个室中的潜水泵将通过井套管穿孔的地下水泵送到从间隙到表面的间隙中进行分析。 用于更远离阵列的腔室的电源线和软管通过阵列中的每个腔室。 密封件是固体的,防水的,非反应性的弹性盘,其被支撑以接合井套管的内表面。 由于采用模块化设计,该设备提供了灵活性,可用于各种井筒配置。