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1. 发明授权

US08057763B2 Process for recovering group VIB metals from a catalyst 有权
标题翻译：从催化剂中回收VIB族金属的方法
公开(公告)号：US08057763B2
公开(公告)日：2011-11-15
申请号：US11855894
申请日：2007-09-14
申请人： Bob Gerardus Oogjen , Harmannus Willem Homan Free , Johannes Cornelis Sitters
发明人： Bob Gerardus Oogjen , Harmannus Willem Homan Free , Johannes Cornelis Sitters
IPC分类号： C22B1/00
CPC分类号： C22B7/009 , B01J23/28 , B01J23/30 , B01J23/85 , B01J23/883 , B01J23/8885 , B01J37/031 , B01J38/68 , C10G49/04 , C10G2300/706 , C22B23/026 , C22B34/345 , C22B34/365 , Y02P10/214 , Y02P10/224 , Y02P10/23 , Y02P10/234
摘要： The invention relates to a process for recovering Group VIB metals from a catalyst, in particular a spent bulk catalyst, comprising one or more Group VIB metals and one or more Group VIII metals. Further, the invention relates to a solid Group VIB metal compound obtainable by the process according to the invention having the general formula H2XO4, wherein X=W1-yMoy, wherein y is between 0 and 1 and to its use in a process for the manufacture of a fresh catalyst. The process comprises the steps of: a) oxidizing the one or more Group VIB metals to one or more Group VIB metal oxides; b) separating the one or more Group VIB metal oxides from the one or more Group VIII metals; c) dissolving the one or more Group VIB metal oxides in water to produce an aqueous solution of one or more Group VIB metal oxides; d) precipitating the one or more Group VIB metal oxides from the aqueous solution by adding alkaline earth metal (Group IIa) ions to the aqueous solution; e) optionally filtering and washing the precipitate; and f) transforming the precipitate by adding an acid to form a solid metal compound comprising one or more Group VIB metals.
摘要翻译：本发明涉及从催化剂，特别是废体积催化剂中回收VIB族V族金属的方法，其中包括一种或多种VIB族金属和一种或多种第Ⅷ族金属。此外，本发明涉及通过根据本发明的方法获得的具有通式H 2 XO 4的固体VIB族金属化合物，其中X = W1-yMoy，其中y在0和1之间，并且其用于制造方法中的新鲜催化剂。该方法包括以下步骤：a）将一种或多种VIB族金属氧化成一种或多种VIB族金属氧化物; b）从一种或多种VIII族金属分离一种或多种VIB族金属氧化物; c）将一种或多种VIB族金属氧化物溶解在水中以产生一种或多种VIB族金属氧化物的水溶液; d）通过向该水溶液中加入碱土金属（IIa）族离子，使该VIB金属氧化物从该水溶液中沉淀出来; e）任选地过滤和洗涤沉淀物; 和f）通过加入酸形成包含一种或多种VIB族金属的固体金属化合物来转化沉淀物。

2. 发明申请

US20110319505A1 BULK SULFIDIC MIXED METAL CATALYST AND METHODS FOR ITS MANUFACTURE AND USE IN CONVERTING SYNGAS TO ALCOHOL 有权
标题翻译：大容量硫化金属催化剂及其制造方法及其在酒精转化中的应用
公开(公告)号：US20110319505A1
公开(公告)日：2011-12-29
申请号：US13203845
申请日：2010-03-05
申请人： Stephan Janbroers , Bob Gerardus Oogjen , Frans Lodewijk Plantenga , Harmannus Willem Homan Free , Sona Eijsbouts-Spickova , Edgar Evert Steenwinkel , Edwin Nuberg
发明人： Stephan Janbroers , Bob Gerardus Oogjen , Frans Lodewijk Plantenga , Harmannus Willem Homan Free , Sona Eijsbouts-Spickova , Edgar Evert Steenwinkel , Edwin Nuberg
IPC分类号： C07C27/00 , B01J27/051
CPC分类号： B01J27/0515 , B01J23/8872 , B01J37/0009 , B01J37/20 , C07C29/1518 , Y02P20/52 , C07C31/08 , C07C31/04
摘要： A process for sulfiding a cobalt-molybdenum bulk catalyst precursor to form a bulk sulfided alcohol synthesis catalyst. The process steps include contacting an oxidic bulk cobalt-molybdenum catalyst precursor with an amount of a sulfur-containing compound which is in the range of about 1 to about 10 moles of sulfur per mole of metals, at one or more temperatures at or in excess of about 300° C. in a medium which is substantially devoid of added hydrogen, so as to form a sulfided bulk cobalt-molybdenum catalyst product. Also described are processes for forming the catalyst precursor, processes for producing an alcohol using the catalyst product and the catalyst product itself.
摘要翻译：硫化钴 - 钼体积催化剂前体以形成本体硫化醇合成催化剂的方法。所述方法步骤包括使氧化体钴钴钼催化剂前体与一定量的含硫化合物接触，所述含硫化合物的量在约或约10摩尔硫/每摩尔金属的一个或多个温度下或过量在基本上不加入氢气的介质中约300℃，以便形成硫化体积的钴 - 钼催化剂产物。还描述了形成催化剂前体的方法，使用催化剂产物和催化剂产物本身生产醇的方法。

3. 发明授权

US06652738B2 Process for preparing a mixed metal catalyst composition 有权
标题翻译：制备混合金属催化剂组合物的方法
公开(公告)号：US06652738B2
公开(公告)日：2003-11-25
申请号：US10346018
申请日：2003-01-16
申请人： Sonja Eijsbouts , Bob Gerardus Oogjen , Harmannus Willem Homan Free , Marinus Bruce Cerfontain , Kenneth Lloyd Riley , Stuart Leon Soled , Sabato Miseo
发明人： Sonja Eijsbouts , Bob Gerardus Oogjen , Harmannus Willem Homan Free , Marinus Bruce Cerfontain , Kenneth Lloyd Riley , Stuart Leon Soled , Sabato Miseo
IPC分类号： C10G4504
CPC分类号： B01J35/002 , B01J23/85 , B01J23/8885 , B01J35/0053 , B01J35/008 , B01J35/1019 , B01J35/1038 , B01J35/1061 , B01J37/0009 , B01J37/0236 , B01J37/031 , B01J37/20 , C10G49/04
摘要： The invention pertains to a process for the hydroprocessing of a hydrocarbon feedstock wherein said feedstock is contacted at hydroprocessing conditions with a catalyst composition which comprises bulk catalyst particles which comprise at least one Group VIII non-noble metal and at least two Group VIB metals. The Group VIII and Group VIB metals comprise from about 50 wt. % to about 100 wt. %, calculated as oxides, of the total weight of the bulk catalyst particles. The metals are present in the catalyst composition in their oxidic and/or sulfidic state. The catalyst composition has an X-ray diffraction pattern in which the characteristic full width at half maximum does not exceed 2.5° when the Group VIB metals are molybdenum, tungsten, and, optionally, chromium, or does not exceed 4.0° when the Group VIB metals are molybdenum and chromium or tungsten and chromium.
摘要翻译：本发明涉及烃原料的加氢处理方法，其中所述原料在加氢处理条件下与催化剂组合物接触，所述催化剂组合物包含包含至少一种VIII族非贵金属和至少两种VIB族金属的本体催化剂颗粒。 VIII族和VIB族金属包含约50wt。％至约100重量％以体积催化剂颗粒的总重量计算的氧化物％。金属以其氧化和/或硫化态存在于催化剂组合物中。催化剂组合物具有X射线衍射图，其中当VIB族金属为钼，钨和任选的铬时，半峰的特征全宽度不超过2.5°，当VIB族VIB金属为不超过4.0°时金属是钼和铬或钨和铬。

4. 发明授权

US08980782B2 Bulk sulfidic mixed metal catalyst and methods for its manufacture and use in converting syngas to alcohol 有权
标题翻译：散装硫化物混合金属催化剂及其合成气转化成酒精的方法
公开(公告)号：US08980782B2
公开(公告)日：2015-03-17
申请号：US13203845
申请日：2010-03-05
申请人： Stephan Janbroers , Bob Gerardus Oogjen , Frans Lodewijk Plantenga , Harmannus Willem Homan Free , Sona Eijsbouts-Spickova , Edgar Evert Steenwinkel , Edwin Nuberg
发明人： Stephan Janbroers , Bob Gerardus Oogjen , Frans Lodewijk Plantenga , Harmannus Willem Homan Free , Sona Eijsbouts-Spickova , Edgar Evert Steenwinkel , Edwin Nuberg
IPC分类号： B01J27/051 , B01J23/887 , B01J37/00 , B01J37/20 , C07C29/151
CPC分类号： B01J27/0515 , B01J23/8872 , B01J37/0009 , B01J37/20 , C07C29/1518 , Y02P20/52 , C07C31/08 , C07C31/04
摘要： A process for sulfiding a cobalt-molybdenum bulk catalyst precursor to form a bulk sulfided alcohol synthesis catalyst. The process steps include contacting an oxidic bulk cobalt-molybdenum catalyst precursor with an amount of a sulfur-containing compound which is in the range of about 1 to about 10 moles of sulfur per mole of metals, at one or more temperatures at or in excess of about 300° C. in a medium which is substantially devoid of added hydrogen, so as to form a sulfided bulk cobalt-molybdenum catalyst product. Also described are processes for forming the catalyst precursor, processes for producing an alcohol using the catalyst product and the catalyst product itself.
摘要翻译：硫化钴 - 钼体积催化剂前体以形成本体硫化醇合成催化剂的方法。所述方法步骤包括使氧化体钴钴钼催化剂前体与一定量的含硫化合物接触，所述含硫化合物的量在约或约10摩尔硫/每摩尔金属的一个或多个温度下或过量在基本上不加入氢气的介质中约300℃，以便形成硫化体积的钴 - 钼催化剂产物。还描述了形成催化剂前体的方法，使用催化剂产物和催化剂产物本身生产醇的方法。

5. 发明授权

US06534437B2 Process for preparing a mixed metal catalyst composition 有权
公开(公告)号：US06534437B2
公开(公告)日：2003-03-18
申请号：US09836101
申请日：2001-04-17
申请人： Sonja Eijsbouts , Bob Gerardus Oogjen , Harmannus Willem Homan Free , Marinus Bruce Cerfontain , Kenneth Lloyd Riley , Stuart Leon Soled , Sabato Miseo
发明人： Sonja Eijsbouts , Bob Gerardus Oogjen , Harmannus Willem Homan Free , Marinus Bruce Cerfontain , Kenneth Lloyd Riley , Stuart Leon Soled , Sabato Miseo
IPC分类号： B01J27043
CPC分类号： B01J35/002 , B01J23/85 , B01J23/8885 , B01J35/0053 , B01J35/008 , B01J35/1019 , B01J35/1038 , B01J35/1061 , B01J37/0009 , B01J37/0236 , B01J37/031 , B01J37/20 , C10G49/04
摘要： The invention pertains to a process for preparing a catalyst composition comprising bulk catalyst particles comprising at least one Group VIII non-noble metal and at least two Group VIB metals. The process comprises combining and reacting at least one Group VIII non-noble metal component with at least two Group VIB metal components in the presence of a protic liquid, with at least one of the metal components remaining at least partly in the solid state during the entire process. The Group VIII and Group VIB metals comprise from about 50 wt. % to about 100 wt. %, calculated as oxides, of the total weight of said bulk catalyst particles, with the solubility of those of the metal components which are at least partly in the solid state during the reaction being less than 0.05 mol/100 ml water at 18° C. The invention also covers a catalyst composition made by that process and a process for the hydroprocessing of a hydrocarbon feedstock by contacting the feedstock with that catalyst at hydroprocessing conditions.

6. 发明授权

US07964528B2 Process for the preparation of a shaped bulk catalyst 有权
标题翻译：用于制备成型体积催化剂的方法
公开(公告)号：US07964528B2
公开(公告)日：2011-06-21
申请号：US12091362
申请日：2006-10-25
申请人： Sona Eijsbouts-Spickova , Robertus Gerardus Leliveld , Johannes Cornelis Sitters , Marinus Bruce Cerfontain , Bob Gerardus Oogjen
发明人： Sona Eijsbouts-Spickova , Robertus Gerardus Leliveld , Johannes Cornelis Sitters , Marinus Bruce Cerfontain , Bob Gerardus Oogjen
IPC分类号： C10G45/00
CPC分类号： B01J23/85 , B01J23/002 , B01J23/881 , B01J23/888 , B01J23/8885 , B01J35/0006 , B01J37/0009 , B01J37/0027 , B01J37/04 , B01J37/20 , B01J2523/00 , C10G45/04 , C10G45/08 , C10G45/50 , C10G45/60 , C10G47/02 , C10G47/04 , C10G2300/202 , B01J2523/68 , B01J2523/69 , B01J2523/847
摘要： The invention relates to a process for the preparation of a shaped bulk catalyst comprising metal oxide particles comprising one or more Group VIII metals and two or more Group VIB metals which process comprises the steps of providing first metal oxidic particles comprising one or more first Group VIII metals and one or more first Group VIB metals, providing separately prepared second metal oxidic particles comprising one or more second Group VIII metals and one or more second Group VIB metals, wherein the composition of Group VIB and Group VIII metals in the first and second metal oxidic particles are different, combining the first and second metal oxidic particles before and/or during shaping and shaping the combined first and second metal oxide particles to form a shaped bulk catalyst. The invention further relates to the shaped bulk catalyst obtainable with the process In sulphided or unsulphided form and the use thereof in hydroprocessing.
摘要翻译：本发明涉及一种制备成形体积催化剂的方法，其包括包含一种或多种第VIII族金属和两种或更多种VIB族金属的金属氧化物颗粒，其包括以下步骤：提供第一金属氧化物颗粒，其包含一个或多个第一VIII族金属和一种或多种第一族VIB金属，提供单独制备的包含一种或多种第二族VIII族金属和一种或多种第二族VIB金属的第二金属氧化物颗粒，其中第一和第二金属中的VIB族和第VIII族金属的组成氧化颗粒是不同的，在第一和第二金属氧化物颗粒的成形和成形之前和/或之间组合第一和第二金属氧化物颗粒以形成成型的本体催化剂。本发明还涉及通过硫化或未硫化形式的方法获得的成型体催化剂及其在加氢处理中的用途。

7. 发明申请

US20080308462A1 Bulk Catalyst Composition And A Process Preparing The Bulk Catalyst Composition 有权
标题翻译：大量催化剂组合物和制备大量催化剂组合物的方法
公开(公告)号：US20080308462A1
公开(公告)日：2008-12-18
申请号：US12091679
申请日：2006-10-25
申请人： Sona Eijsbouts-Spickova , Robertus Gerardos Leliveld , Bob Gerardus Oogjen , Marinus Bruce Cerfontain , Johannes Cornelis Sitters
发明人： Sona Eijsbouts-Spickova , Robertus Gerardos Leliveld , Bob Gerardus Oogjen , Marinus Bruce Cerfontain , Johannes Cornelis Sitters
IPC分类号： C10G45/04 , B01J23/24 , B01J23/652 , B01J23/85
CPC分类号： B01J23/85 , B01J23/002 , B01J23/881 , B01J23/888 , B01J23/8885 , B01J35/0006 , B01J37/0009 , B01J37/0027 , B01J37/04 , B01J37/20 , B01J2523/00 , C10G45/04 , C10G45/08 , C10G45/50 , C10G45/60 , C10G47/02 , C10G47/04 , C10G2300/202 , B01J2523/68 , B01J2523/69 , B01J2523/847
摘要： The invention relates to a bulk catalyst composition comprising metal oxidic particles comprising one or more Group VIII metals and two or more Group VIB metals, which bulk catalyst composition comprises first metal oxidic particles comprising one or more first Group VIII metals and one or more first Group VIB metals and separately prepared second metal oxidic particles comprising one or more second Group VIII metals and one or more second Group VIB metals, wherein the composition of Group VIB and Group VIII metals in the first and second metal oxidic particles are different, wherein the first and second oxidic bulk particles-are separately shaped to separate first and second shaped bulk catalyst particles, which are combined, preferably into a homogeneous blend, to form the bulk catalyst composition. The invention further relates to a process for the preparation of the bulk catalyst composition and to hydroprocessing a hydrocarbon feed using the bulk catalyst composition.
摘要翻译：本发明涉及包含包含一种或多种VIII族金属和两种或更多种VIB族金属的金属氧化物颗粒的本体催化剂组合物，该主体催化剂组合物包含包含一种或多种第一VIII族金属的第一金属氧化物颗粒和一种或多种第一族 VIB金属和单独制备的包含一种或多种第二族VIII族金属和一种或多种第二族VIB金属的第二金属氧化物颗粒，其中第一和第二金属氧化物颗粒中的VIB族和第VIII族金属的组成不同，其中第一和第二氧化体积颗粒 - 被分开成形以分离第一和第二成型体积催化剂颗粒，其优选组合成均匀的共混物以形成本体催化剂组合物。本发明还涉及一种制备本体催化剂组合物的方法，并且使用本体催化剂组合物对烃进料进行加氢处理。

8. 发明授权

US08476184B2 Bulk catalyst composition and a process preparing the bulk catalyst composition 有权
标题翻译：大量催化剂组合物和制备本体催化剂组合物的方法
公开(公告)号：US08476184B2
公开(公告)日：2013-07-02
申请号：US12091679
申请日：2006-10-25
申请人： Sona Eijsbouts-Spickova , Robertus Gerardus Leliveld , Bob Gerardus Oogjen , Marinus Bruce Cerfontain , Johannes Cornelis Sitters
发明人： Sona Eijsbouts-Spickova , Robertus Gerardus Leliveld , Bob Gerardus Oogjen , Marinus Bruce Cerfontain , Johannes Cornelis Sitters
IPC分类号： C10G45/04
CPC分类号： B01J23/85 , B01J23/002 , B01J23/881 , B01J23/888 , B01J23/8885 , B01J35/0006 , B01J37/0009 , B01J37/0027 , B01J37/04 , B01J37/20 , B01J2523/00 , C10G45/04 , C10G45/08 , C10G45/50 , C10G45/60 , C10G47/02 , C10G47/04 , C10G2300/202 , B01J2523/68 , B01J2523/69 , B01J2523/847
摘要： The invention relates to a bulk catalyst composition comprising metal oxidic particles comprising one or more Group VIII metals and two or more Group VIB metals, which bulk catalyst composition comprises first metal oxidic particles comprising one or more first Group VIII metals and one or more first Group VIB metals and separately prepared second metal oxidic particles comprising one or more second Group VIII metals and one or more second Group VIB metals, wherein the composition of Group VIB and Group VIII metals in the first and second metal oxidic particles are different, wherein the first and second oxidic bulk particles-are separately shaped to separate first and second shaped bulk catalyst particles, which are combined, preferably into a homogeneous blend, to form the bulk catalyst composition. The invention further relates to a process for the preparation of the bulk catalyst composition and to hydroprocessing a hydrocarbon feed using the bulk catalyst composition.
摘要翻译：本发明涉及包含包含一种或多种VIII族金属和两种或更多种VIB族金属的金属氧化物颗粒的本体催化剂组合物，该主体催化剂组合物包含包含一种或多种第一VIII族金属的第一金属氧化物颗粒和一种或多种第一族 VIB金属和单独制备的包含一种或多种第二族VIII族金属和一种或多种第二族VIB金属的第二金属氧化物颗粒，其中第一和第二金属氧化物颗粒中的VIB族和第VIII族金属的组成不同，其中第一和第二氧化体积颗粒 - 被分开成形以分离第一和第二成型体积催化剂颗粒，其优选组合成均匀的共混物以形成本体催化剂组合物。本发明还涉及一种制备本体催化剂组合物的方法，并且使用本体催化剂组合物对烃进料进行加氢处理。

9. 发明申请

US20090014356A1 Process For The Preparation Of A Shaped Bulk Catalyst 有权
标题翻译：一种形成块状催化剂的制备方法
公开(公告)号：US20090014356A1
公开(公告)日：2009-01-15
申请号：US12091362
申请日：2006-10-25
申请人： Sona Eijsbouts-Spickova , Robertus Gerardus Leliveld , Johannes Cornelis Sitters , Marinus Bruce Cerfontain , Bob Gerardus Oogjen
发明人： Sona Eijsbouts-Spickova , Robertus Gerardus Leliveld , Johannes Cornelis Sitters , Marinus Bruce Cerfontain , Bob Gerardus Oogjen
IPC分类号： C10G45/00
CPC分类号： B01J23/85 , B01J23/002 , B01J23/881 , B01J23/888 , B01J23/8885 , B01J35/0006 , B01J37/0009 , B01J37/0027 , B01J37/04 , B01J37/20 , B01J2523/00 , C10G45/04 , C10G45/08 , C10G45/50 , C10G45/60 , C10G47/02 , C10G47/04 , C10G2300/202 , B01J2523/68 , B01J2523/69 , B01J2523/847
摘要： The invention relates to a process for the preparation of a shaped bulk catalyst comprising metal oxide particles comprising one or more Group VIII metals and two or more Group VIB metals which process comprises the steps of providing first metal oxidic particles comprising one or more first Group VIII metals and one or more first Group VIB metals, providing separately prepared second metal oxidic particles comprising one or more second Group VIII metals and one or more second Group VIB metals, wherein the composition of Group VIB and Group VIII metals in the first and second metal oxidic particles are different, combining the first and second metal oxidic particles before and/or during shaping and shaping the combined first and second metal oxide particles to form a shaped bulk catalyst. The invention further relates to the shaped bulk catalyst obtainable with the process In sulphided or unsulphided form and the use thereof in hydroprocessing.
摘要翻译：本发明涉及一种制备成形体积催化剂的方法，其包括包含一种或多种第VIII族金属和两种或更多种VIB族金属的金属氧化物颗粒，其包括以下步骤：提供第一金属氧化物颗粒，其包含一个或多个第一VIII族金属和一种或多种第一族VIB金属，提供单独制备的包含一种或多种第二族VIII族金属和一种或多种第二族VIB金属的第二金属氧化物颗粒，其中第一和第二金属中的VIB族和第VIII族金属的组成氧化颗粒是不同的，在第一和第二金属氧化物颗粒的成形和成形之前和/或之间组合第一和第二金属氧化物颗粒以形成成型的本体催化剂。本发明还涉及通过硫化或未硫化形式的方法获得的成型体催化剂及其在加氢处理中的用途。

10. 发明申请

US20100248945A1 BULK CATALYST COMPOSITION COMPRISING BULK METAL OXIDE PARTICLES 审中-公开
标题翻译：包含大块金属氧化物颗粒的大块催化剂组合物
公开(公告)号：US20100248945A1
公开(公告)日：2010-09-30
申请号：US12743153
申请日：2008-12-04
申请人： Sona Eijsbouts-Spickova , Robertus Gerardus Leliveld , Paul Joseph Maria Lebens , Frans Lodewijk Plantenga , Bob Gerardus Oogjen , Henk Jan Tromp , Stuart Leon Soled , Sabato Miseo
发明人： Sona Eijsbouts-Spickova , Robertus Gerardus Leliveld , Paul Joseph Maria Lebens , Frans Lodewijk Plantenga , Bob Gerardus Oogjen , Henk Jan Tromp , Stuart Leon Soled , Sabato Miseo
IPC分类号： B01J23/883 , B01J23/24 , B01J21/16 , B01J23/20 , B01J27/236 , B01J27/049 , B01J23/755 , B01J27/051
CPC分类号： B01J23/8885 , B01J21/16 , B01J23/85 , B01J23/888 , B01J35/002 , B01J37/0009 , B01J37/03 , B01J37/20 , C10G49/04
摘要： The invention relates to a process for preparing bulk metal oxide particles comprising the steps of combining in a reaction mixture (i) dispersible nanoparticles having a dimension of less than about 1 μm upon being dispersed in a liquid, (ii) at least one Group VIII non-noble metal compound, (iii) at least one Group VIB metal compound, and (iv) a protic liquid; and reacting the at least one Group VIII non-noble metal compound and the at least one Group VIB metal in the presence of the nanoparticles. It also relates to bulk metal hydroprocessing catalysts obtainable by such method.
摘要翻译：本发明涉及一种制备本体金属氧化物颗粒的方法，包括以下步骤：在反应混合物中混合（i）分散在液体中的尺寸小于约1μm的可分散纳米颗粒，（ii）至少一种VIII族非贵金属化合物，（iii）至少一种VIB族金属化合物，和（iv）质子液体; 并在所述纳米颗粒存在下使所述至少一种第VIII族非贵金属化合物和所述至少一种第ⅥB族金属反应。它还涉及通过这种方法获得的散装金属加氢处理催化剂。

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