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    • 3. 发明授权
    • Injection molding material containing starch and plant protein
    • 含淀粉和植物蛋白的注塑材料
    • US08283006B2
    • 2012-10-09
    • US12337788
    • 2008-12-18
    • James H. WangGregory J. WidemanBo ShiSarah A. Funk
    • James H. WangGregory J. WidemanBo ShiSarah A. Funk
    • B27N5/02C08L3/00
    • C08L23/06B29C45/0001B29K2105/16B29K2711/00B29K2995/006C08L1/00C08L3/00C08L3/02C08L23/02C08L23/04C08L23/10C08L89/00C08L2205/02C08L2207/066Y10T428/1348Y10T428/1352C08L2666/06C08L2666/26
    • An injection molding material that includes a renewable resin containing a combination of renewable polymers (e.g., starch and plant protein) and a plasticizer is provided. Although such compounds are normally difficult to process into thermoplastics, the present inventors have discovered that injection molding materials may nevertheless be formed by melt blending the renewable resin with a synthetic resin (e.g., polyolefin) while selectively controlling the nature of the resins and their relative concentrations. In this manner, a morphology may be achieved in which the renewable resin is present as a discontinuous phase that is dispersed within a continuous phase of the synthetic resin (e.g., “island-in-the-sea” morphology). The discontinuous and continuous phases may each constitute from about 30 vol. % to about 70 vol. %, and in some embodiments, from about 40 vol. % to about 60 vol. %. With such a morphology, the continuity of the synthetic resin can minimize the aggregate properties of the renewable resin such that the molding material possesses melt properties similar to that of the synthetic resin. Further, this morphology may also minimize the need to use different molding tools as the shrinkage properties of the overall composition may be substantially similar to that of the synthetic resin.
    • 提供了一种注射成型材料,其包括含有可再生聚合物(例如淀粉和植物蛋白)和增塑剂的组合的可再生树脂。 虽然这些化合物通常难以加工成热塑性塑料,但是本发明人已经发现,注射成型材料可以通过将可再生树脂与合成树脂(例如聚烯烃)熔融共混而形成,同时选择性地控制树脂的性质及其相对 浓度 以这种方式,可以实现其中可再生树脂作为分散在合成树脂的连续相中的不连续相(例如海岛形态)存在的形态。 不连续和连续相可以各自构成约30体积% %至约70体积% %,在一些实施方案中为约40vol。 %至约60体积% %。 通过这种形态,合成树脂的连续性可以使可再生树脂的聚集性能最小化,使得成型材料具有与合成树脂类似的熔体性质。 此外,由于整个组合物的收缩性能可以基本上类似于合成树脂的收缩特性,所以这种形态还可以最小化使用不同的模制工具的需要。
    • 4. 发明申请
    • Injection Molding Material Containing Starch and Plant Protein
    • 含淀粉和植物蛋白的注射成型材料
    • US20100159170A1
    • 2010-06-24
    • US12337788
    • 2008-12-18
    • James H. WangGregory J. WidemanBo ShiSarah A. Funk
    • James H. WangGregory J. WidemanBo ShiSarah A. Funk
    • B32B1/00C08L89/00B29C45/00
    • C08L23/06B29C45/0001B29K2105/16B29K2711/00B29K2995/006C08L1/00C08L3/00C08L3/02C08L23/02C08L23/04C08L23/10C08L89/00C08L2205/02C08L2207/066Y10T428/1348Y10T428/1352C08L2666/06C08L2666/26
    • An injection molding material that includes a renewable resin containing a combination of renewable polymers (e.g., starch and plant protein) and a plasticizer is provided. Although such compounds are normally difficult to process into thermoplastics, the present inventors have discovered that injection molding materials may nevertheless be formed by melt blending the renewable resin with a synthetic resin (e.g., polyolefin) while selectively controlling the nature of the resins and their relative concentrations. In this manner, a morphology may be achieved in which the renewable resin is present as a discontinuous phase that is dispersed within a continuous phase of the synthetic resin (e.g., “island-in-the-sea” morphology). The discontinuous and continuous phases may each constitute from about 30 vol. % to about 70 vol. %, and in some embodiments, from about 40 vol. % to about 60 vol. %. With such a morphology, the continuity of the synthetic resin can minimize the aggregate properties of the renewable resin such that the molding material possesses melt properties similar to that of the synthetic resin. Further, this morphology may also minimize the need to use different molding tools as the shrinkage properties of the overall composition may be substantially similar to that of the synthetic resin.
    • 提供了一种注射成型材料,其包括含有可再生聚合物(例如淀粉和植物蛋白)和增塑剂的组合的可再生树脂。 虽然这些化合物通常难以加工成热塑性塑料,但是本发明人已经发现,注射成型材料可以通过将可再生树脂与合成树脂(例如聚烯烃)熔融共混而形成,同时选择性地控制树脂的性质及其相对 浓度 以这种方式,可以实现其中可再生树脂作为分散在合成树脂的连续相中的不连续相(例如“海岛”形态)存在的形态。 不连续和连续相可以各自构成约30体积% %至约70体积% %,在一些实施方案中为约40vol。 %至约60体积% %。 通过这种形态,合成树脂的连续性可以使可再生树脂的聚集性能最小化,使得成型材料具有与合成树脂类似的熔体性质。 此外,由于整个组合物的收缩性能可以基本上类似于合成树脂的收缩特性,所以这种形态还可以最小化使用不同的模制工具的需要。