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    • 4. 发明授权
    • Crosslinking agents for emulsion polymers
    • 乳液聚合物交联剂
    • US6103821A
    • 2000-08-15
    • US230743
    • 1998-02-01
    • Michael FischerGerhard LindenschmidtGraham Edmund Mc KeeBernhard RosenauHerbert Naarmann
    • Michael FischerGerhard LindenschmidtGraham Edmund Mc KeeBernhard RosenauHerbert Naarmann
    • C08F2/16C08F2/22C08F265/04
    • C08F265/04
    • Compounds of the general formula (I):H(--CH.sub.2 --CR.sup.1 R.sup.2).sub.m (--CH.sub.2 --CR.sup.1 R.sup.3).sub.n --H (I)whereR.sup.1 is H or methyl,R.sup.2 is --C(O)--Y--R.sup.4, where R.sup.4 is H, methyl, ethyl or allyl,R.sup.3 is --C(O)--Y--allyl andY is O or NH,orR.sup.1 is H or C.sub.1 -C.sub.20 -alkyl,R.sup.2 is H andR.sup.3 is (--CH.sub.2 --CR.sup.5 .dbd.CR.sup.6 --CH.sub.2).sub.p --H, where R.sup.5 and R.sup.6 independently are each H,methyl, ethyl or chlorine and p is 1-100,orR.sup.1 is H,R.sup.2 is OH or O-allyl andR.sup.3 is O-allyl,orR.sup.1 is H,R.sup.2 is OH or R.sup.3 andR.sup.3 is (meth)acrylate, --O--C(O)--CH.dbd.CH--COOH or --O--C(O)--CH.sub.2 --C(.dbd.CH.sub.2)--COOH,and m is an integer from 5 to 500,000 and n is an integer from 2 to 100,000, are used as crosslinking agents in particulate emulsion polymers having a glass transition temperature below 0.degree. C. and a mean particle size of from 50 to 1000 nm.
    • PCT No.PCT / EP97 / 04127 Sec。 371日期1999年2月1日 102(e)1999年2月1日PCT 1997年7月29日PCT公布。 出版物WO98 / 05695 日期:1998年2月12日通式(I)的化合物:其中R 1为H或甲基,R 2为-C(O)-Y-R 4的H(-CH 2 -CR 1 R 2)m(-CH 2 -CR 1 R 3)n H 其中R 4是H,甲基,乙基或烯丙基,R 3是-C(O)-Y-烯丙基,Y是O或NH,或R 1是H或C 1 -C 20烷基,R 2是H,且R 3是(-CH 2 -CR5 = CR6-CH2)pH,其中R5和R6各自独立地为H,甲基,乙基或氯,p为1-100,或R1为H,R2为OH或O-烯丙基,R3为O-烯丙基,或 R1为H,R2为OH或R3,R3为(甲基)丙烯酸酯,-OC(O)-CH = CH-COOH或-OC(O)-CH2-C(= CH2)-COOH,m为整数 5至500,000,n为2至100,000的整数,用作玻璃化转变温度低于0℃,平均粒度为50至1000nm的颗粒状乳液聚合物中的交联剂。
    • 7. 发明授权
    • Preparation of rubber-modified molding materials using peroxy-containing
compounds
    • 使用过氧化合物制备橡胶改性的成型材料
    • US5837777A
    • 1998-11-17
    • US836312
    • 1997-05-12
    • Graham Edmund McKeeRainer MoorsWalter HeckmannHarald LarbigBernhard Rosenau
    • Graham Edmund McKeeRainer MoorsWalter HeckmannHarald LarbigBernhard Rosenau
    • C08L15/00C08F2/18C08F220/12C08F265/04C08F285/00C08L51/00C08F8/00
    • C08F285/00
    • In the preparation of a rubber-modified molding material, in a first stage, a first mixture (A) contains at least one alkyl acrylate or methacrylate (a) of the formula (I) ##STR1## where R.sup.1 is hydrogen or methyl and R.sup.2 is alkyl of 1 to 32 carbon atoms, if required a first monomer (b) having two or more double bonds and, if required, also a second monomer (c) or a plurality thereof is polymerized, preferably with free radicals, to give a rubber (B), in a second stage, a third monomer (d) or a plurality thereof is added to the resulting rubber (B) to form a second mixture (C), whereby the rubber (B) is dissolved or swollen in the third monomer (d), with or with the addition of a solvent, and in a third stage, the second mixture (C) formed is polymerized with free radicals to give the rubber-modified molding material (D), and the mixture is reacted at >120.degree. C., during or after this polymerization, with a compound (e) which contains at least two peroxy groups.
    • PCT No.PCT / EP95 / 04476 Sec。 371日期:1997年5月12日 102(e)日期1997年5月12日PCT提交1995年11月14日PCT公布。 出版物WO96 / 15164 日期1996年5月23日在橡胶改性成型材料的制备中,在第一阶段中,第一混合物(A)含有至少一种式(I)的丙烯酸烷基酯或甲基丙烯酸烷基酯(a)(I)其中 R 1是氢或甲基,R 2是1至32个碳原子的烷基,如果需要,具有两个或更多个双键的第一单体(b),如果需要的话,也可以将第二单体(c)或多个单体聚合 与自由基反应得到橡胶(B),在第二阶段中,将第三单体(d)或多个添加到所得橡胶(B)中以形成第二混合物(C),由此橡胶(B )在第三单体(d)中溶解或溶胀,或者在添加溶剂的情况下,在第三阶段中,形成的第二混合物(C)与自由基聚合,得到橡胶改性的成型材料(D ),并且在该聚合期间或之后,混合物在> 120℃下与含有至少两个过氧基团的化合物(e)反应。
    • 8. 发明授权
    • Composition of styrene-acrylonitrile copolymer matrix with particles of
graft copolymer and crosslinked copolymer
    • 苯乙烯 - 丙烯腈共聚物基体与接枝共聚物和交联共聚物颗粒的组成
    • US5631323A
    • 1997-05-20
    • US567056
    • 1995-12-04
    • Norbert GuntherbergEkkehard JahnsWolfgang FischerGraham E. McKeeBernhard Rosenau
    • Norbert GuntherbergEkkehard JahnsWolfgang FischerGraham E. McKeeBernhard Rosenau
    • C08F2/18C08F2/20C08F212/06C08F212/10C08L25/12C08L51/00C08L51/04C08L55/02C08L35/04
    • C08L25/12C08F212/10C08L55/02C08L51/04
    • Thermoplastic molding materials preparedA) from 35 to 99.5% by weight of a matrix copolymer (A) ofa.sub.1) from 50 to 95% by weight of styrene and/or .alpha.-methylstyrene,a.sub.2) from 5 to 50% by weight of acrylonitrile anda.sub.3) from 0 to 20% by weight of further comonomersB) from 0 to 50% by weight of a particulate graft copolymer (B) which is insoluble in (A), has a median particle diameter of from 0.03 to 1 .mu.m and preparedb.sub.1) from 30 to 80% by weight of a core comprising an elastomeric polymer having a glass transition temperature of less than -10.degree. C. andb.sub.2) from 20 to 70% by weight of a graft shell comprising a polymer which is compatible or partly compatible with (A)andC) from 0.5 to 30% by weight of a particulate crosslinked copolymer (C) which is insoluble in (A), has a median particle diameter of from 0.5 to 50 .mu.m and comprisesc.sub.1) from 50 to 89.95% by weight of styrene and/or .alpha.-methylstyrene,c.sub.2) from 10 to 50% by weight of acrylonitrile,c.sub.3) from 0.05 to 5% by weight of a polyfunctional, crosslinking monomer,c.sub.4) from 0 to 10% by weight of a monomer which contains acidic or basic groups andc.sub.5) from 0 to 20% by weight of further comonomers.
    • 制备的热塑性成型材料A)35至99.5重量%的a1)的基质共聚物(A),50-95重量%的苯乙烯和/或α-甲基苯乙烯,a2)5-50重量%的丙烯腈 和a3)0至20重量%的另外的共聚单体B)0至50重量%的不溶于(A)的颗粒接枝共聚物(B),其中值粒径为0.03至1μm 并且制备b1)30至80重量%的芯,其包含玻璃化转变温度低于-10℃的弹性体聚合物,和b2)20至70重量%的包含聚合物的接枝壳,所述聚合物是 与(A)和C)相容或部分相容的0.5至30重量%的不溶于(A)的颗粒状交联共聚物(C),其中值粒径为0.5至50μm,并包含c1) 苯乙烯和/或α-甲基苯乙烯的50至89.95重量%,c2)10至50重量%的丙烯腈,c 3)0.05至5重量% t的多官能交联单体,c4)0至10重量%的含酸性或碱性基团的单体,和c 5)0至20重量%的其它共聚单体。