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1. 发明授权

US5631323A Composition of styrene-acrylonitrile copolymer matrix with particles of graft copolymer and crosslinked copolymer 失效
标题翻译：苯乙烯 - 丙烯腈共聚物基体与接枝共聚物和交联共聚物颗粒的组成
公开(公告)号：US5631323A
公开(公告)日：1997-05-20
申请号：US567056
申请日：1995-12-04
申请人： Norbert Guntherberg , Ekkehard Jahns , Wolfgang Fischer , Graham E. McKee , Bernhard Rosenau
发明人： Norbert Guntherberg , Ekkehard Jahns , Wolfgang Fischer , Graham E. McKee , Bernhard Rosenau
IPC分类号： C08F2/18 , C08F2/20 , C08F212/06 , C08F212/10 , C08L25/12 , C08L51/00 , C08L51/04 , C08L55/02 , C08L35/04
CPC分类号： C08L25/12 , C08F212/10 , C08L55/02 , C08L51/04
摘要： Thermoplastic molding materials preparedA) from 35 to 99.5% by weight of a matrix copolymer (A) ofa.sub.1) from 50 to 95% by weight of styrene and/or .alpha.-methylstyrene,a.sub.2) from 5 to 50% by weight of acrylonitrile anda.sub.3) from 0 to 20% by weight of further comonomersB) from 0 to 50% by weight of a particulate graft copolymer (B) which is insoluble in (A), has a median particle diameter of from 0.03 to 1 .mu.m and preparedb.sub.1) from 30 to 80% by weight of a core comprising an elastomeric polymer having a glass transition temperature of less than -10.degree. C. andb.sub.2) from 20 to 70% by weight of a graft shell comprising a polymer which is compatible or partly compatible with (A)andC) from 0.5 to 30% by weight of a particulate crosslinked copolymer (C) which is insoluble in (A), has a median particle diameter of from 0.5 to 50 .mu.m and comprisesc.sub.1) from 50 to 89.95% by weight of styrene and/or .alpha.-methylstyrene,c.sub.2) from 10 to 50% by weight of acrylonitrile,c.sub.3) from 0.05 to 5% by weight of a polyfunctional, crosslinking monomer,c.sub.4) from 0 to 10% by weight of a monomer which contains acidic or basic groups andc.sub.5) from 0 to 20% by weight of further comonomers.
摘要翻译：制备的热塑性成型材料A）35至99.5重量％的a1）的基质共聚物（A），50-95重量％的苯乙烯和/或α-甲基苯乙烯，a2）5-50重量％的丙烯腈和a3）0至20重量％的另外的共聚单体B）0至50重量％的不溶于（A）的颗粒接枝共聚物（B），其中值粒径为0.03至1μm 并且制备b1）30至80重量％的芯，其包含玻璃化转变温度低于-10℃的弹性体聚合物，和b2）20至70重量％的包含聚合物的接枝壳，所述聚合物是与（A）和C）相容或部分相容的0.5至30重量％的不溶于（A）的颗粒状交联共聚物（C），其中值粒径为0.5至50μm，并包含c1）苯乙烯和/或α-甲基苯乙烯的50至89.95重量％，c2）10至50重量％的丙烯腈，c 3）0.05至5重量％ t的多官能交联单体，c4）0至10重量％的含酸性或碱性基团的单体，和c 5）0至20重量％的其它共聚单体。

2. 发明授权

US5889111A Elastomeric graft polymeres 失效
标题翻译：弹性体接枝聚合物
公开(公告)号：US5889111A
公开(公告)日：1999-03-30
申请号：US849363
申请日：1997-06-05
申请人： Graham Edmund McKee , Ekkehard Jahns , Wolfgang Fischer , Norbert Guntherberg , Bernhard Rosenau
发明人： Graham Edmund McKee , Ekkehard Jahns , Wolfgang Fischer , Norbert Guntherberg , Bernhard Rosenau
IPC分类号： C08F257/02 , C08F265/04 , C08F267/08 , C08F279/02 , C08F285/00 , C08F291/00 , C08L51/00 , C08L51/04 , C08L55/02
CPC分类号： C08L55/02 , C08F257/02 , C08F265/04 , C08F267/08 , C08F279/02 , C08F285/00 , C08L51/003 , C08L51/04
摘要： Particulate elastomeric graft polymers which are suitable for improving the quality of macromolecular base materials B consist ofa) a grafting core comprising an elastomeric polymer P.sub.K, the particles having a mean particle diameter of from 1 to 150 .mu.m, andb) one or more shells, the outer shell S.sub.a consisting of a polymer P.sub.a which is compatible or partly compatible with the base material B.
摘要翻译： PCT No.PCT / EP95 / 04688第 371日期：1997年6月5日 102（e）日期1997年6月5日PCT提交1995年11月29日PCT公布。出版物WO96 / 17878 日期1996年6月13日适用于提高高分子基材B品质的弹性体接枝聚合物由以下组成：a）包含弹性体聚合物PK的接枝芯，平均粒径为1-150μm的颗粒，以及 b）一个或多个外壳，外壳Sa由与基材B相容或部分相容的聚合物Pa组成。

3. 发明授权

US5710197A Crosslinked polymer particles containing a fluorescent dye 失效
标题翻译：含有荧光染料的交联聚合物颗粒
公开(公告)号：US5710197A
公开(公告)日：1998-01-20
申请号：US501927
申请日：1995-07-13
申请人： Wolfgang Fischer , Andreas Deckers , Norbert Guntherberg , Ekkehard Jahns , Sylke Haremza , Werner Ostertag , Helmut Schmidt
发明人： Wolfgang Fischer , Andreas Deckers , Norbert Guntherberg , Ekkehard Jahns , Sylke Haremza , Werner Ostertag , Helmut Schmidt
IPC分类号： C09K11/06 , C08K5/00 , C09B3/14 , C09B57/02 , C09B67/20 , C09D11/50 , C09K11/02 , C08K5/45
CPC分类号： C09K11/02 , C08K5/0041 , C09B67/0061 , C09D11/50
摘要： Fluorescent pigments contain essentially a polymer matrix based on polymethyl methacrylate and a nonpolar fluorescent dye from the coumarin or perylene series, the polymer matrix being a crosslinked polymethacrylate or polyacrylate prepared by suspension polymerization.
摘要翻译：荧光颜料基本上包含基于聚甲基丙烯酸甲酯和来自香豆素或苝系列的非极性荧光染料的聚合物基质，聚合物基质是通过悬浮聚合制备的交联的聚甲基丙烯酸酯或聚丙烯酸酯。

4. 发明授权

US5837772A Dulled thermoplastic molding materials 失效
标题翻译：钝化热塑性成型材料
公开(公告)号：US5837772A
公开(公告)日：1998-11-17
申请号：US851613
申请日：1997-05-06
申请人： Graham Edmund Mc Kee , Jurgen Koch , Wolfgang Fischer , Axel Gottschalk , Norbert Guntherberg , Bernhard Rosenau
发明人： Graham Edmund Mc Kee , Jurgen Koch , Wolfgang Fischer , Axel Gottschalk , Norbert Guntherberg , Bernhard Rosenau
IPC分类号： C08L51/06 , C08F265/04 , C08F291/02 , C08L33/02 , C08L35/06 , C08L51/04 , C08L55/00 , C08L55/02 , C08L71/00 , C08L71/02 , C08L71/12 , C08L77/00 , C08L101/00
CPC分类号： C08L77/00 , C08F265/04 , C08F291/02 , C08L101/00 , C08L51/04 , C08L71/00 , C08L71/02 , C08L71/123 , C08L33/02 , C08L35/06
摘要： Thermoplastic molding materials contain A) from 50 to 99% by weight, based on the total weight of the molding material, of a toughened polymer, B) from 1 to 20% by weight, based on the total weight of the molding material, of a blend of B.sub.1) a copolymer comprising polymerized units which are derived from a polymerizable carboxylic acid or derivatives thereof and B.sub.2) a polyamide, C) from 0 to 40% by weight of a fibrous or particulate filler or of a mixture thereof and D) from 0 to 20% by weight of conventional additives and processing assistants.
摘要翻译：热塑性成型材料包含A）50至99重量％，基于成型材料的总重量，增韧聚合物B）1至20重量％，基于成型材料的总重量， B1）共聚物，其包含衍生自可聚合羧酸或其衍生物的聚合单元和B2）聚酰胺，C）0至40重量％的纤维或颗粒填料或其混合物，D） 0至20重量％的常规添加剂和加工助剂。

5. 发明授权

US5912305A Dulled thermoplastic molding material 失效
标题翻译：无光塑料成型材料
公开(公告)号：US5912305A
公开(公告)日：1999-06-15
申请号：US998941
申请日：1997-12-29
申请人： Graham Edmund Mc Kee , Jurgen Koch , Wolfgang Fischer , Axel Gottschalk , Norbert Guntherberg , Bernhard Rosenau
发明人： Graham Edmund Mc Kee , Jurgen Koch , Wolfgang Fischer , Axel Gottschalk , Norbert Guntherberg , Bernhard Rosenau
IPC分类号： C08L51/06 , C08F265/04 , C08F291/02 , C08L33/02 , C08L35/06 , C08L51/04 , C08L55/00 , C08L55/02 , C08L71/00 , C08L71/02 , C08L71/12 , C08L77/00 , C08L101/00 , C08G69/48
CPC分类号： C08L77/00 , C08F265/04 , C08F291/02 , C08L101/00 , C08L51/04 , C08L71/00 , C08L71/02 , C08L71/123 , C08L33/02 , C08L35/06
摘要： Thermoplastic molding materials containA) from 50 to 99% by weight, based on the total weight of the molding material, of a toughened polymer,B) from 1 to 20% by weight, based on the total weight of the molding material, of a blend ofB.sub.1) a copolymer comprising polymerized units which are derived from a polymerizable carboxylic acid or derivatives thereof andB.sub.2) a polyamide,C) from 0 to 40% by weight of a fibrous or particulate filler or of a mixture thereof andD) from 0 to 20% by weight of conventional additives and processing assistants.
摘要翻译：热塑性成型材料包含A）50至99重量％，基于成型材料的总重量，增韧聚合物B）1至20重量％，基于成型材料的总重量， B1）共聚物，其包含衍生自可聚合羧酸或其衍生物的聚合单元和B2）聚酰胺，C）0至40重量％的纤维或颗粒填料或其混合物，D） 0至20重量％的常规添加剂和加工助剂。

6. 发明授权

US5834550A Dull thermoplastic molding material 失效
标题翻译：无光塑料成型材料
公开(公告)号：US5834550A
公开(公告)日：1998-11-10
申请号：US763304
申请日：1996-12-10
申请人： Wolfgang Fischer , Norbert Guntherberg
发明人： Wolfgang Fischer , Norbert Guntherberg
IPC分类号： C08K5/098 , C08L51/00 , C08L51/04 , C08L55/02 , C08K3/26 , C08K3/10
CPC分类号： C08L51/003 , C08K5/098 , C08L51/04 , C08L55/02
摘要： Thermoplastic molding materials which contain from 0.1 to 10% by weight of a compound of a polyvalent metal are suitable for the production of dull moldings having high impact strength.
摘要翻译：含有0.1〜10重量％的多价金属化合物的热塑性成型材料适用于生产具有高冲击强度的钝模制品。

7. 发明授权

US5717033A Dull, transparent thermoplastic resins 失效
标题翻译：透明的热塑性树脂
公开(公告)号：US5717033A
公开(公告)日：1998-02-10
申请号：US714490
申请日：1996-09-18
申请人： Wolfgang Fischer , Norbert Guntherberg , Graham Edmund McKee
发明人： Wolfgang Fischer , Norbert Guntherberg , Graham Edmund McKee
IPC分类号： C08L25/00 , C08F2/22 , C08F212/00 , C08F212/04 , C08F212/06 , C08F220/12 , C08L25/12 , C08L25/14 , C08L35/06
CPC分类号： C08F220/12 , C08F212/04 , C08L25/12 , C08L2205/02 , C08L2205/18 , C08L25/14
摘要： A particulate polymer A having a mean particle size of less than 1000 nm consists of a1: up to 99.8% by weight of at least one vinylaromatic monomer a1, a2: up to 99.8% by weight of at least one alkyl methacrylate a2 where the alkyl radical is of 1 to 8 carbon atoms, a3: up to 50% by weight of at least one polar, copolymerizable, ethylenically unsaturated monomer a3, a4: from 0.1 to 10% by weight of at least one polyfunctional, crosslinking monomer a4 and a5: from 0.1 to 15, preferably from 0.5 to 10, % by weight of at least one monomer a5 containing one or more acidic, basic or epoxy groups, the sum of the components a1, a2 and a3 being from 75 to 99.8% by weight, based on A, and the sum of a1, a2, a3, a4 and a5 being 100% by weight, based on A.
摘要翻译：平均粒径小于1000nm的颗粒聚合物A由a1：至多99.8重量％的至少一种乙烯基芳族单体a1，a2：至多99.8重量％的至少一种甲基丙烯酸烷基酯a2组成，其中烷基自由基具有1-8个碳原子，a3：至多50重量％的至少一种极性，可共聚的烯属不饱和单体a3，a4：0.1-10重量％的至少一种多官能交联单体a4和a5 至少一种含有一个或多个酸性，碱性或环氧基团的单体a5的0.1至15，优选0.5至10重量％，组分a1，a2和a3的总和为75至99.8重量％，基于A，a1，a2，a3，a4和a5的总和为100重量％，基于A.

8. 发明授权

US6022915A Thermoplastic molding compounds and a method of reducing the formation of residual monomers in these molding compounds 失效
标题翻译：热塑性成型化合物和减少这些模塑料中残留单体形成的方法
公开(公告)号：US6022915A
公开(公告)日：2000-02-08
申请号：US981688
申请日：1998-05-12
申请人： Anton Ticktin , Graham Edmund Mc Kee , Wolfgang Fischer , Binnur Gunesin , Norbert Guntherberg
发明人： Anton Ticktin , Graham Edmund Mc Kee , Wolfgang Fischer , Binnur Gunesin , Norbert Guntherberg
IPC分类号： C08J3/20 , C08F2/44 , C08F6/00 , C08K5/1545 , C08L25/16 , C08L33/12 , C08L33/20 , C08L55/02 , C08K5/15
CPC分类号： C08K5/1545
摘要： The invention relates to thermoplastic molding compositions consisting ofA) 98-99.995% by weight, based on A+B, of at least one acrylonitrile-containing polymer, andB) 0.005-2% by weight, based on A+B, of .alpha.-tocopherol.The invention also relates to a method for reducing the formation of residual monomers on thermal stress and shearing of the thermoplastic molding compositions by adding .alpha.-tocopherol.
摘要翻译： PCT No.PCT / EP96 / 02896 Sec。 371日期：1998年5月12日 102（e）日期1998年5月12日PCT 1996年7月2日PCT公布。出版物WO97 / 02314 日本1997年1月23日本发明涉及由A）98-99.995重量％（基于A + B）至少一种含丙烯腈的聚合物组成的热塑性模塑组合物，以及B）0.005-2重量％ A + B，α-生育酚。本发明还涉及通过加入α-生育酚来减少残余单体在热应力上的形成和热塑性模塑组合物的剪切的方法。

9. 发明授权

US5747568A Thermoplastic molding material 失效
标题翻译：热塑性成型材料
公开(公告)号：US5747568A
公开(公告)日：1998-05-05
申请号：US638593
申请日：1996-04-29
申请人： Wolfgang Fischer , Norbert Guntherberg
发明人： Wolfgang Fischer , Norbert Guntherberg
IPC分类号： C08K5/36 , C08K5/1545 , C08K5/372 , C08L25/12 , C08L51/00 , C08L51/04 , C08L51/06 , C08K5/15
CPC分类号： C08K5/1545 , C08K5/372 , C08L51/04
摘要： A thermoplastic molding material consists of A) 30-80% by weight, based on A+B, of an elastomeric grafting base A defined in more detail and B) 20-70% by weight, based on A+B, of a shell grafted onto the grafting base A and defined in more detail and C) 0.001-1 part by weight, based on 100 parts by weight of A+B, of .alpha.-tocopherol and D) from a half to ten times the amount, based on C, of a thiodipropionic ester selected from dilauryl and distearyl thiodipropionate.
摘要翻译：热塑性成型材料由A）30-80％（重量），基于A + B，更详细地定义的弹性体接枝基体A和B）基于A + B的20-70％重量的壳接枝到接枝基材A上并且更详细地定义为C）0.001-1重量份，基于100重量份的A + B，α-生育酚和D），其量为该组合物的一半至十倍，基于 C，选自二月桂基和硫代二丙酸二硬脂酯的硫代二丙酸酯。

10. 发明申请

US20070167573A1 Thermoplastic moulding compounds exhibiting improved chemical resistance 失效
标题翻译：具有改善耐化学性的热塑性模塑料
公开(公告)号：US20070167573A1
公开(公告)日：2007-07-19
申请号：US10596344
申请日：2004-12-14
申请人： Martin Stork , Martin Weber , Axel Gottschalk , Sven Riechers , Norbert Guntherberg , Wolfgang Fischer , Ludger Leber , Peter Ittemann , Stephan Jungling
发明人： Martin Stork , Martin Weber , Axel Gottschalk , Sven Riechers , Norbert Guntherberg , Wolfgang Fischer , Ludger Leber , Peter Ittemann , Stephan Jungling
IPC分类号： C08F8/00
CPC分类号： C08L51/04 , C08F257/02 , C08F279/02 , C08F285/00 , C08L25/12 , C08L33/12 , C08L35/06 , C08L51/00 , C08L51/003 , C08L55/02 , C08L2205/03 , C08L2666/02 , C08L2666/04
摘要： The present invention relates to thermoplastic molding compositions comprising a mixture of (A) from 30 to 69% by weight, based on the sum of components (A), (B) and (C), of a methyl methacrylate polymer, (B) from 30 to 69% by weight, based on the sum of components (A), (B) and (C), of a copolymer obtainable by polymerizing a styrenic monomer and a vinyl cyanide, and (C) from 1 to 40% by weight, based on the sum of components (A), (B) and (C), of a graft copolymer obtainable from (C1) from 60 to 90% by weight, based on (C), of a core obtainable by polymerizing a 1,3-diene and a styrenic monomer, (C2) from 5 to 20% by weight, based on (C), of a first graft shell, and (C3) from 5 to 20% by weight, based on (C), of a second graft shell composed of an alkyl (meth)acrylate polymer, with the proviso that the ratio of (C2) to (C3) is in the range from 2:1 to 1:2, the essence of the invention being that the first graft shell (C2) is obtainable by polymerizing a monomer mixture consisting of (C21) from 30 to 39% by weight, based on (C2), of a styrenic monomer, (C22) from 61 to 70% by weight, based on (C2), of a C1-C8-alkyl ester of methacrylic acid and (C23) from 0 to 3% by weight, based on (C2), of a crosslinking monomer, and also to processes for producing these molding compositions, to their use and to the moldings obtainable therefrom.
摘要翻译：本发明涉及热塑性模塑组合物，其包含（A）基于甲基丙烯酸甲酯聚合物的组分（A），（B）和（C）的总和为30至69重量％的混合物，（B）基于通过聚合苯乙烯类单体和乙烯基氰获得的共聚物的组分（A），（B）和（C）的总和的30至69重量％，和（C）1至40重量％以（C）为基准，从（C）得到的（C）成分（A），（B）和（C））的总和为基于（C）为60〜90重量％ 1,3-二烯和苯乙烯单体，（C）基于（C）的5-20重量％（C），第一接枝壳和（C）5-20重量％的（C3），由（甲基）丙烯酸烷基酯聚合物组成的第二接枝壳，条件是（C2）与（C3）的比例在2:1至1:2的范围内，本发明的本质是第一接枝壳（C2）可以通过聚合由（C） 21），基于（C2），基于（C2）的苯乙烯类单体（C22）为30〜39重量％，基于（C2）为61〜70重量％的C 1〜甲基丙烯酸的C 8 - 烷基酯和（C 23）0-3重量％，基于（C2）的交联单体，以及制备这些模塑组合物的方法，使用和可从其获得的模制品。

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