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1. 发明授权

US5672716A Yellow diketopyrrolopyrrole pigments 失效
标题翻译：黄色二酮吡咯并吡咯颜料
公开(公告)号：US5672716A
公开(公告)日：1997-09-30
申请号：US551192
申请日：1995-10-31
申请人： Bernd Lamatsch , Olof Wallquist , Ingo Schloder
发明人： Bernd Lamatsch , Olof Wallquist , Ingo Schloder
IPC分类号： C07D487/04 , C08K5/00 , C08K5/3412 , C08K5/3417 , C09B57/00
CPC分类号： C07D487/04 , C08K5/0041 , C09B57/004
摘要： The invention relates to diketopyrrolo�3,4-c!pyrroles of formula ##STR1## wherein R.sub.1 and R.sub.2 are each independently of the other hydrogen, halogen, C.sub.1 -C.sub.6 alkyl, cyano or a --OR.sub.3, --COOR.sub.3, --CON(R.sub.3)(R.sub.4), --COR.sub.3 or --N(R.sub.3)(R.sub.4) group, and R.sub.3 and R.sub.4 are each independently of the other hydrogen, C.sub.1 -C.sub.6 alkyl, phenyl which is unsubstituted or substituted by halogen or C.sub.1 -C.sub.6 alkyl. Said diketopyrrolo�3,4-c!pyrroles are pigments colored in a strong yellow shade having good fastness properties.
摘要翻译：本发明涉及式（I）的二酮吡咯并[3,4-c]吡咯，其中R 1和R 2各自独立地为氢，卤素，C 1 -C 6烷基，氰基或-OR 3，-COOR 3，-CON （R3）（R4），-COR3或-N（R3）（R4）基团，R3和R4各自独立地为另一个氢，C1-C6烷基，未被取代或被卤素或C1-C6烷基取代的苯基。所述二酮吡咯并[3,4-c]吡咯是具有良好牢度特性的强黄色阴影中着色的颜料。

2. 发明授权

US6066202A Diketopyrrolopyrrole compositions 失效
标题翻译：二酮吡咯并吡咯组合物
公开(公告)号：US6066202A
公开(公告)日：2000-05-23
申请号：US072906
申请日：1998-05-05
申请人： Olof Wallquist , Ingo Schloder
发明人： Olof Wallquist , Ingo Schloder
IPC分类号： C07D487/04 , C09B57/00 , C09B67/20 , C09B67/22 , C08K5/34
CPC分类号： C09B67/0039
摘要： Substance compositions, which comprise at least one diketopyrrolopyrrole from each of formulae ##STR1## R.sub.1 is C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 alkoxy, C.sub.1 -C.sub.6 alkylthio, halogen or phenyl,R.sub.2 is a COX group, whereinX is NR.sub.4 R.sub.5 or a heterocyclic radical containing at least 2 N atoms, one of which N atoms forms an amide with the carbonyl group,R.sub.3 is hydrogen, halogen or C.sub.1 -C.sub.6 alkyl,Admixture of such a substance composition to diketopyrrolopyrrole pigments improves the rheological behaviour of the latter as well as the gloss of the colorations produced therewith to an unexpected degree.
摘要翻译：包含至少一个式R1的二酮吡咯并吡咯的物质组合物是C 1 -C 6烷基，C 1 -C 6烷氧基，C 1 -C 6烷硫基，卤素或苯基，R 2是COX基团，其中X是NR 4 R 5或含有至少2个N 原子，其中一个N原子与羰基形成酰胺，R3是氢，卤素或C1-C6烷基，这种物质组合物与二酮吡咯并吡咯颜料的混合改善了后者的流变行为以及产生的着色光泽度从而达到意想不到的程度。

3. 发明授权

US5492564A Diketopyrrolopyrrole pigment with high chroma 失效
标题翻译：具有高色度的二酮吡咯并吡咯颜料
公开(公告)号：US5492564A
公开(公告)日：1996-02-20
申请号：US216703
申请日：1994-03-23
申请人： Gary Wooden , Ingo Schloder , Olof Wallquist
发明人： Gary Wooden , Ingo Schloder , Olof Wallquist
IPC分类号： C07D487/04 , C08K5/3412 , C08K5/3415 , C09B57/00 , C09B67/10 , C09B67/20 , C09B67/48 , C09D7/12 , C07D471/02
CPC分类号： C07D487/04 , C09B57/004 , C09B67/0014
摘要： The pigment form of the diketopyrrolopyrrole pigment of formula ##STR1## having high saturation, characterised by a chroma C*.sub.ab of at least 45 in the CIELAB system when incorporated in a plasticised PVC pressed sheet. This pigment has superior opacity and an unexpectedly high chroma.
摘要翻译：具有高饱和度的式（I）的二酮吡咯并吡咯颜料的颜料形式，其特征在于当结合到增塑的PVC压片中时，CIELAB体系中的色度C * ab至少为45。该颜料具有优异的不透明度和意想不到的高色度。

4. 发明授权

US5738719A Pigment compositions of diketopyrrolopyrroles 失效
标题翻译：二酮吡咯并吡咯的颜料组成
公开(公告)号：US5738719A
公开(公告)日：1998-04-14
申请号：US799969
申请日：1997-02-14
申请人： Olof Wallquist , Ingo Schloder , Gary Wooden
发明人： Olof Wallquist , Ingo Schloder , Gary Wooden
IPC分类号： C07D487/04 , C08K5/3412 , C08K5/3415 , C08L23/00 , C08L101/00 , C09B57/00 , C09B67/20 , C09B67/22 , C08K5/00
CPC分类号： C09B67/0039
摘要： A pigment composition, comprising a) 80-99.8 mol % of a diketopyrrolopyrrole of formula ##STR1## wherein A and B are each independently of the other a ##STR2## wherein R.sub.1 and R.sub.2 are each independently of the other hydrogen, chloro, bromo, C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.8 alkoxy, C.sub.2 -C.sub.19 alkoxycarbonyl, C.sub.2 -C.sub.19 alkylcarbamoyl, C.sub.1 -C.sub.18 alkylmercapto, C.sub.1 -C.sub.18 alkylamino, C.sub.5 -C.sub.6 cycloalkyl, G is a direct bond or --O--, --S--, --SO--, --SO.sub.2 -- or --NR.sub.5 --, R.sub.3 and R.sub.4 are each independently of the other hydrogen, chloro, bromo, C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.18 alkoxy or C.sub.1 -C.sub.18 alkylamino, and R.sub.5 is hydrogen or C.sub.1 -C.sub.6 alkyl, and b) 20-0.2 mol % of a diketopyrrolopyrrole of formula ##STR3## wherein one of R.sub.6 or R.sub.7 is hydrogen and the other is --CN. Such pigment compositions are distinguished by excellent resistance to recrystallisation and heat.
摘要翻译：一种颜料组合物，其包含a）80-99.8mol％的式（I）的二酮吡咯并吡咯，其中A和B各自独立地为另一个，其中R 1和R 2各自独立于另一个氢，氯，溴，C 1 -C 6烷基，C 1 -C 8烷氧基，C 2 -C 19烷氧基羰基，C 2 -C 19烷基氨基甲酰基，C 1 -C 18烷基巯基，C 1 -C 18烷基氨基，C 5 -C 6环烷基，G是直接键或-O - ， - S - - ，-SO 2 - 或-NR 5 - ，R 3和R 4各自独立地为氢，氯，溴，C 1 -C 6烷基，C 1 -C 18烷氧基或C 1 -C 18烷基氨基，R 5为氢或C 1 -C 6烷基，b）20 -0.2摩尔％的式（II）的二酮吡咯并吡咯，其中R6或R7中的一个是氢，另一个是-CN。这种颜料组合物的特征在于优异的耐再结晶和耐热性。

5. 发明授权

US5476949A Finely divided highly transparent diketopyrrolopyrrole pigments 失效
标题翻译：细分高度透明的二酮吡咯并吡咯颜料
公开(公告)号：US5476949A
公开(公告)日：1995-12-19
申请号：US278594
申请日：1994-07-21
申请人： Olof Wallquist , Gary Wooden , Thomas Eichenberger , Ingo Schloder
发明人： Olof Wallquist , Gary Wooden , Thomas Eichenberger , Ingo Schloder
IPC分类号： C07D487/04 , C08K5/3412 , C08K5/3415 , C08K5/3417 , C09B57/00 , C09B67/02 , C09B67/22 , C08K5/34
CPC分类号： C07D487/04 , C08K5/3417 , C09B57/004
摘要： Finely divided 1,4-diketopyrrolo[3,4-c]pyrroles of the formula ##STR1## where A and B are each independently of the other a radical of the formula ##STR2## wherein at least 84% by weight of the particles have a Stokes equivalent diameter of .ltoreq.0.25 .mu.m, and mixtures thereof.The substituents R.sub.1 and R.sub.2 are defined in claim 1.These pigments are notable for a very pure hue and outstanding transparency.
摘要翻译：式（I）的细分1,4-二酮吡咯并[3,4-c]吡咯，其中A和B各自独立地为通式（II）的基团，其中至少84％的颗粒具有

6. 发明授权

US5817832A Blue diketopyrrolopyrrole pigments 失效
标题翻译：蓝色二酮吡咯并吡咯颜料
公开(公告)号：US5817832A
公开(公告)日：1998-10-06
申请号：US664271
申请日：1996-06-11
申请人： Olof Wallquist , Bernd Lamatsch , Thomas Ruch
发明人： Olof Wallquist , Bernd Lamatsch , Thomas Ruch
IPC分类号： C07D487/04 , C07F9/6561 , C08K5/3412 , C08K5/3415 , C09B57/00
CPC分类号： C07D487/04 , C07F9/6561 , C08K5/3415 , C09B57/004
摘要： Diketopyrrolo�3,4-c!pyrroles of the formula ##STR1## in which X and Y independently of one another are a divalent aromatic radical and R is a radical CN, COR.sub.5, CO.sub.2 R.sub.5, CON(R.sub.5).sub.2, NO.sub.2, SO.sub.2 R.sub.5, SOR.sub.5, SO.sub.2 N(R.sub.5).sub.2 or PO(OR.sub.6).sub.2. For the definition of the substituents R.sub.1, R.sub.2 and R.sub.5, refer to claim 1. These compounds are blue to violet, tinctorially strong pigments with good stability properties, in particular good light stability and weather stability.
摘要翻译：其中X和Y彼此独立的式（I）的二酮吡咯并[3,4-c]吡咯是二价芳族基团，R是基团CN，COR 5，CO 2 R 5，CON（R 5）2，NO 2 ，SO2R5，SOR5，SO2N（R5）2或PO（OR6）2。取代基R 1，R 2和R 5的定义如权利要求1所示。这些化合物是蓝色至紫色，具有良好稳定性的着色强颜料，特别是良好的光稳定性和气候稳定性。

7. 发明授权

US5874588A Process for the preparation of diketopyrrolopyrrolecarboxylic acids and their esters and amides 失效
标题翻译：二酮吡咯并吡咯羧酸及其酯和酰胺的制备方法
公开(公告)号：US5874588A
公开(公告)日：1999-02-23
申请号：US933591
申请日：1997-09-19
申请人： Bernd Lamatsch , Olof Wallquist
发明人： Bernd Lamatsch , Olof Wallquist
IPC分类号： B01J27/10 , C07B61/00 , C07D233/58 , C07D233/60 , C07D487/04 , C09B57/00 , C07D487/02 , C07D209/02
CPC分类号： C07D487/04 , C09B57/004
摘要： Diketopyrrolopyrroles of formula I ##STR1## are prepared by reacting a diketopyrrolopyrrole of formula II ##STR2## with a) formic acid or b) a compound of formula IIIX'--H (III)or with an alkali metal formate or alkaline earth metal formate together with carbon monoxide in the presence of a catalyst, wherein, in formulae I, II and III, A is a direct bond or a group ##STR3## wherein phenylene is bound to the pyrrolopyrrole, R.sub.1, R.sub.2 and R.sub.3 are each independently of one another hydrogen, halogen, C.sub.1 -C.sub.6 alkyl, C.sub.5 -C.sub.6 cycloalkyl, C.sub.1 -C.sub.6 alkoxy, C.sub.1 -C.sub.6 alkylamino, C.sub.1 -C.sub.6 alkylmercapto, --CF.sub.3, --CN or --NO.sub.2, X is X' or OH, X' is --OR.sub.4 or --N(R.sub.5)(R.sub.6), wherein R.sub.4 is C.sub.1 -C.sub.18 alkyl, C.sub.5 -C.sub.6 cycloalkyl; phenyl or naphthyl which is unsubstituted or substituted by halogen, C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 alkoxy, C.sub.1 -C.sub.6 alkylamino, --CN or --NO.sub.2, R.sub.5 and R.sub.6 are each independently of the other hydrogen, C.sub.1 -C.sub.18 alkyl, C.sub.5 -C.sub.6 cycloalkyl; phenyl or naphthyl which is unsubstituted or substituted by halogen, C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 -alkoxy, C.sub.4 -C.sub.6 alkylamino, --CN or --NO.sub.2, or a group --(CH.sub.2).sub.n --SO.sub.3 R.sub.7, wherein R.sub.7 is hydrogen, potassium or sodium, and n is an integer from 2 to 6, or R.sub.5 and R.sub.6, together with the linking nitrogen atom, are an unsubstituted or C.sub.1 -C.sub.6 alkyl- or phenyl-substituted 5- or 6-membered heterocyclic radical selected from the group consisting of pyrrolidinyl, piperidyl, pyrrolyl, triazolyl, imidazolyl, pyrazolyl, piperazinyl, morpholinyl, thiomorpholinyl, phthalimidyl, carbazolyl, indolyl, indazolyl, benzimidazolyl and tetrahydroquinolinyl, Y is R.sub.3 or ##STR4## and Z is halogen.
摘要翻译：式I的二酮吡咯并吡咯（I）通过使式II的二酮吡咯并吡咯与（a）甲酸或b）式III的化合物X'-H（III）或与碱金属甲酸盐或碱土金属甲酸盐与一氧化碳在催化剂存在下一起，其中在式I，II和III中，A是直接键或基团，其中亚苯基与吡咯并吡咯结合，R1，R2和 R 3各自独立地为氢，卤素，C 1 -C 6烷基，C 5 -C 6环烷基，C 1 -C 6烷氧基，C 1 -C 6烷基氨基，C 1 -C 6烷基巯基，-CF 3，-CN或-NO 2，X为X'或OH，X' -OR4或-N（R5）（R6），其中R4是C1-C18烷基，C5-C6环烷基; 苯基或萘基，其未被取代或被卤素，C 1 -C 6烷基，C 1 -C 6烷氧基，C 1 -C 6烷基氨基，-CN或-NO 2，R 5和R 6各自独立地为氢，C 1 -C 18烷基，C 5 -C 6环烷基，苯基或萘基，其未被取代或被卤素，C 1 -C 6烷基，C 1 -C 6 - 烷氧基，C 4 -C 6烷基氨基，-CN或-NO 2或 - （CH 2）n -SO 3 R 7基团取代，其中R 7是氢，，和n为2至6的整数，或者R 5和R 6与连接氮原子一起是未取代的或C 1 -C 6烷基或苯基取代的5-或6-元杂环基，其选自吡咯烷基哌啶基，吡唑基，哌嗪基，吗啉基，硫代吗啉基，邻苯二甲酰亚氨基，咔唑基，吲哚基，吲唑基，苯并咪唑基和四氢喹啉基，Y为R3或Z。

8. 发明授权

US5476886A Polyamides mass coloured with diketopyrrolopyrrole pigments 失效
标题翻译：用二酮吡咯并吡咯颜料着色的聚酰胺
公开(公告)号：US5476886A
公开(公告)日：1995-12-19
申请号：US276278
申请日：1994-07-18
申请人： Olof Wallquist , Bernd Lamatsch
发明人： Olof Wallquist , Bernd Lamatsch
IPC分类号： C08K5/00 , C08K5/3415 , C08K5/3417
CPC分类号： C08K5/0041 , C08K5/3415
摘要： Mass-coloured synthetic polyamide containing, as pigment, at least one diketopyrrolopyrrole pigment of formula ##STR1## wherein A and B are each independently of the other a radical of formula ##STR2## wherein Q is a --CONH.sub.2 group,m is 1 or 2,R.sub.1 and R.sub.2 are each independently of the other hydrogen, Cl, Br, CH.sub.3 or C.sub.2 H.sub.5,R.sub.3 is hydrogen, CH.sub.3, C.sub.2 H.sub.5 or phenyl,X is a direct bond, --O--, --S--, --SO.sub.2 --, --CH.dbd.CH--, --CH.sub.2 -- or --C(CH.sub.3).sub.2 --, andY is --O-- or --S--.Polyamides mass-coloured with the pigments useful in the practice of this invention have exceptional heat stability and excellent lightfastness.
摘要翻译：含有颜料的至少一种式（I）的至少一种二酮吡咯并吡咯颜料的大量合成聚酰胺，其中A和B各自独立地为醛基的基团Q为-CONH 2基团，m为1或2， R 1和R 2各自独立地为氢，Cl，Br，CH 3或C 2 H 5，R 3是氢，CH 3，C 2 H 5或苯基，X是直接键，-O - ， - S - ， - SO 2 - CH-，-CH 2 - 或-C（CH 3）2 - ，Y是-O-或-S-。用可用于本发明实践的颜料大量着色的聚酰胺具有优异的热稳定性和优异的耐光性。

9. 发明授权

US08221508B2 Polymeric hair dyes 有权
标题翻译：聚合染发剂
公开(公告)号：US08221508B2
公开(公告)日：2012-07-17
申请号：US13133234
申请日：2009-12-04
申请人： Sophie Marquais-Bienewald , Christian Cremer , Olof Wallquist , Xian-Zhi Zhou , Barbara Wagner
发明人： Sophie Marquais-Bienewald , Christian Cremer , Olof Wallquist , Xian-Zhi Zhou , Barbara Wagner
IPC分类号： A61Q5/10 , C07D213/22
CPC分类号： A61K8/64 , A61K8/645 , A61K8/65 , A61K2800/4322 , A61Q5/065 , C09B69/10 , C09B69/101 , C09B69/106
摘要： Polymeric dye comprising oligo and polypeptides selected from natural or synthetic aminoacids bearing at least one covalently bounded cationic dye. Very good dyeing results on human hair are obtained with these dyes.
摘要翻译：包含寡核苷酸和多肽的聚合染料选自具有至少一种共价结合阳离子染料的天然或合成氨基酸。用这些染料获得人毛发上的非常好的染色结果。

10. 发明授权

US08118882B2 Polymeric hair dyes 有权
标题翻译：聚合染发剂
公开(公告)号：US08118882B2
公开(公告)日：2012-02-21
申请号：US12812782
申请日：2009-01-07
申请人： Christian Cremer , Sophie Marquais-Bienewald , Olof Wallquist
发明人： Christian Cremer , Sophie Marquais-Bienewald , Olof Wallquist
IPC分类号： A61Q5/10 , C07D213/09
CPC分类号： C09B69/101 , C09B1/32 , C09B1/34 , C09B69/106
摘要： Disclosed are cationic oligomeric dye, comprising a low molecular weight polyamine comprising the repeating units (1a) or (1b), wherein at least 90% of the polyamine molecules are selected from tetramines, pentamines and hexamines; and R is the residue of a cationic dye, which is covalently bonded, optionally via a linker, to the nitrogen atoms of the polyamine; or hydrogen; wherein the polyamine repeating units (1a) and (1b) comprise at least one carionic dye residue; and n is a number from 3-12. The dyes are distinguished by their depth of shade and their good fastness properties to washing, such as, for example, fastness to light, shampooing and rubbing.
摘要翻译：公开了阳离子低聚染料，其包含包含重复单元（1a）或（1b）的低分子量多胺，其中至少90％的多胺分子选自四胺，五胺和六胺; 并且R是阳离子染料的残基，其任选地经由接头共价键合到多胺的氮原子上; 或氢; 其中所述多胺重复单元（1a）和（1b）包含至少一个卡莲染料残基; n是3-12的数字。这些染料的特征在于它们的色调深度和它们对洗涤性能的良好牢度，例如耐光牢度，洗发剂和摩擦性。

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