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    • 1. 发明申请
    • PHOTOGRAPHIC ELEMENT CONTAINING A SPEED-ENHANCING COMPOUND
    • 含增速化合物的摄影元件
    • US20080248433A1
    • 2008-10-09
    • US10574669
    • 2004-10-01
    • Bernard A. ClarkPhilip A. AllwayTania ZuberiStephen P. SingerCharles E. HecklerLouis E. Friedrich
    • Bernard A. ClarkPhilip A. AllwayTania ZuberiStephen P. SingerCharles E. HecklerLouis E. Friedrich
    • G03C7/26
    • G03C7/39252G03C7/3022G03C7/3029G03C7/3924G03C2001/03511G03C2007/3034
    • The invention provides a colour photographic element comprising at least one light-sensitive silver halide emulsion layer or a non silver-containing light-insensitive layer, in which at least one of these layers contains a colourless imidazole compound of formula (I) that undergoes less than 10% chemical or redox reaction directly with oxidized developer and which has a partition coefficient to enable the photographic speed of the element to be increased by at least 0.03 stop without increasing granularity, compared to the same element without the compound, wherein the compound of formula: (I) has the structure: wherein X is H or a substituent; Z represents the atoms necessary to complete an unsubstituted or substituted imidazole ring, which may form part of a fused unsubstituted or substituted ring system containing no further ring heteroatoms; wherein there is present at least one —NH group either in the imidazole ring or directly attached to the imidazole ring as part of X; provided that (a) when Z represents the atoms necessary to complete an unsubstituted or substituted benzimidazole ring, an —NH group is directly attached to the imidazole ring as part of X, and X is located between the imidazole nitrogen atoms; (b) when the —N—H group is located in the ring adjacent to the carbon atom bearing X, and X is located between the imidazole nitrogen atoms, the imidazole ring is not fused to a phenanthrene ring. The compounds of formula (I) increase speed without a concomitant increase in size of the light-sensitive silver halide grains.
    • 本发明提供了一种彩色照相元件,其包括至少一种感光卤化银乳剂层或不含银的光不敏感层,其中这些层中的至少一层含有经历较少的式(I)的无色咪唑化合物 与氧化显影剂直接进行10%以上的化学或氧化还原反应,并且具有分配系数,使得与没有化合物的相同元素相比,元素的照相速度可以提高至少0.03秒而不增加粒度,其中化合物 式(I)具有以下结构:其中X为H或取代基; Z表示完成未取代或取代的咪唑环所必需的原子,其可以形成不含其它环杂原子的稠合未取代或取代的环系的一部分; 其中在咪唑环中存在至少一个-NH基团或作为X的一部分直接连接到咪唑环上; 条件是(a)当Z表示完成未取代或取代的苯并咪唑环所需的原子时,-NH基团作为X的一部分直接连接到咪唑环上,X位于咪唑氮原子之间; (b)当-N-H基团位于与带有X的碳原子相邻的环中,X位于咪唑氮原子之间时,咪唑环不与菲环稠合。 式(I)的化合物增加速度,而不会伴随着感光卤化银颗粒的尺寸增加。
    • 3. 发明授权
    • Photographic element containing a speed-enhancing compound
    • 含有增速化合物的摄影元件
    • US07455959B2
    • 2008-11-25
    • US10574669
    • 2004-10-01
    • Bernard A. ClarkPhilip A. AllwayTania ZuberiStephen P. SingerCharles E. HecklerLouis E. Friedrich
    • Bernard A. ClarkPhilip A. AllwayTania ZuberiStephen P. SingerCharles E. HecklerLouis E. Friedrich
    • G03C1/46G03C1/06G03C1/36G03C1/08G03C5/18
    • G03C7/39252G03C7/3022G03C7/3029G03C7/3924G03C2001/03511G03C2007/3034
    • The invention provides a color photographic element comprising at least one light-sensitive silver halide emulsion layer or a non silver-containing light-insensitive layer, in which at least one of these layers contains a colorless imidazole compound of formula (I) that undergoes less than 10% chemical or redox reaction with oxidized developer and which enables the photographic speed of the element to be increased by at least 0.05 stop without increasing granularity, compared to the same element without the compound, wherein the compound of formula (I) has the structure: wherein X is H or a substituent; Z represents the atoms necessary to complete an unsubstituted or substituted imidazole ring, which may form part of a fused unsubstituted or substituted ring system containing no further ring heteroatoms; wherein there is present at least one —NH group either in the imidazole ring or directly attached to the imidazole ring as part of X; provided that (a) when Z represents the atoms necessary to complete an unsubstituted or substituted benzimidazole ring, an —NH group is directly attached to the imidazole ring as part of X, and X is located between the imidazole nitrogen atoms; (b) when the —NH group is located in the ring adjacent to the carbon atom bearing X, and X is located between the imidazole nitrogen atoms, the imidazole ring is not fused to a phenanthrene ring. The compounds of formula (I) increase speed without a concomitant increase in size of the light-sensitive silver halide grains.
    • 本发明提供了一种彩色照相元件,其包括至少一种感光卤化银乳剂层或不含银的光不敏感层,其中这些层中的至少一层含有经历较少的式(I)的无色咪唑化合物 与氧化显影剂进行10%以上的化学或氧化还原反应,并且与没有化合物的相同元素相比,使得元件的照相速度可以提高至少0.05个停止而不增加粒度,其中式(I)化合物具有 结构:其中X是H或取代基; Z表示完成未取代或取代的咪唑环所必需的原子,其可以形成不含其它环杂原子的稠合未取代或取代的环系的一部分; 其中在咪唑环中存在至少一个-NH基团或作为X的一部分直接连接到咪唑环上; 条件是(a)当Z表示完成未取代或取代的苯并咪唑环所需的原子时,-NH基团作为X的一部分直接连接到咪唑环上,X位于咪唑氮原子之间; (b)当-NH基团位于与带有X的碳原子相邻的环中,X位于咪唑氮原子之间时,咪唑环不与菲环稠合。 式(I)的化合物增加速度,而不会伴随着感光卤化银颗粒的尺寸增加。