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    • 6. 发明授权
    • Solid electrolyte obtained by the polymerization of diacrylate monomer
having a rigid alkane segment
    • 通过具有刚性烷烃链段的二丙烯酸酯单体的聚合获得的固体电解质
    • US5463179A
    • 1995-10-31
    • US162746
    • 1993-12-06
    • Benjamin Chaloner-GillM. Neal Golovin
    • Benjamin Chaloner-GillM. Neal Golovin
    • H01M4/02H01M4/62H01M4/66H01M6/18
    • H01M4/02H01M4/66H01M6/181H01M4/62H01M4/621H01M4/624H01M4/625
    • This invention is directed to single phase solid solvent-containing electrolyte having recurring units derived from a diacrylate monomer having relatively rigid alkane segments within the solid polymeric matrix of such solid electrolyte as described. A preferred diacrylate monomer is 1,6-hexanediol diacrylate. Also, in a preferred embodiment recurring oxyalkylene units of 2 to 3 carbon atoms which are relatively flexible in nature are absent in the polymer backbone of the resulting solid polymeric matrix. A novel electrolytic cell that incorporates the subject electrolyte also is provided. The specific molecular structure having recurring rigid alkane groups present therein as described is believed to include relatively stable three-dimensional openings between adjacent molecular chains which advantageously facilitate the positioning of an inorganic ion salt and solvent among adjacent polymeric molecules during service within the single phase solid electrolyte.
    • 本发明涉及具有如上所述的这种固体电解质的固体聚合物基质中具有相对刚性烷烃链段的二丙烯酸酯单体的重复单元的单相固体溶剂的电解质。 优选的二丙烯酸酯单体是1,6-己二醇二丙烯酸酯。 而且,在优选的实施方案中,在所得固体聚合物基质的聚合物骨架中不存在2-3个碳原子的相对柔性的氧化烯单元。 还提供了一种并入目标电解质的新型电解池。 据信在其中存在如上所述的具有重复的刚性烷烃基团的特定分子结构包括在相邻分子链之间的相对稳定的三维开口,其有利于在单相固体中使用期间相邻聚合物分子之间的无机离子盐和溶剂的定位 电解液