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1. 发明授权

US4792608A Pyrimidin-5-ylsulfonamides 失效
标题翻译：嘧啶-5-基磺酰胺
公开(公告)号：US4792608A
公开(公告)日：1988-12-20
申请号：US90262
申请日：1987-08-26
申请人： Beat B/o/ hner , Werner F/o/ ry , Rolf Schurter , Georg Pissiotas
发明人： Beat B/o/ hner , Werner F/o/ ry , Rolf Schurter , Georg Pissiotas
IPC分类号： A01N47/36 , C07D237/00 , C07D237/18 , C07D239/00 , C07D239/38 , C07D239/42 , C07D241/00 , C07D241/18 , C07D251/00 , C07D403/12 , C07D521/00 , C07D239/32
CPC分类号： C07D521/00 , A01N47/36 , C07D237/18 , C07D241/18
摘要： The invention relates to novel sulfonylureas of the formula I ##STR1## wherein R.sub.1 is hydrogen or C.sub.1 -C.sub.5 alkyl,R.sub.2 and R.sub.3, each independently of the other, are hydrogen, C.sub.1 -C.sub.5 alkyl, C.sub.1 -C.sub.5 alkoxy, C.sub.1 -C.sub.5 alkylthio, C.sub.1 -C.sub.5 haloalkyl, halogen, C.sub.1 -C.sub.5 haloalkylthio, C.sub.1 -C.sub.4 alkylamino, C.sub.1 -C.sub.4 dialkylamino, an alkoxyalkyl group or alkoxyalkoxy group, each containing not more than 6 carbon atoms,Z is oxygen or sulfur,E is --CH.dbd. or --N.dbd., andQ is an unsubstituted or substituted 6-membered heterocyclic radical containing 2 to 3 nitrogen atoms and bound through a carbon atom,and the salts thereof.A process for the preparation of the novel compounds and the use thereof are also described. The compounds of formula I can be used in the form of agriculturally useful compositions for controlling weeds and/or for selectively influencing plant growth.
摘要翻译：本发明涉及式I（I）的新型磺酰脲，其中R 1是氢或C 1 -C 5烷基，R 2和R 3各自独立地是氢，C 1 -C 5烷基，C 1 -C 5烷氧基，C 1 -C 5烷硫基，各自含有不超过6个碳原子，Z为氧或硫的C 1 -C 5卤代烷基，卤素，C 1 -C 5卤代烷硫基，C 1 -C 4烷基氨基，C 1 -C 4二烷基氨基，烷氧基烷基或烷氧基烷氧基，E为-CH =或-N = 并且Q是含有2至3个氮原子并通过碳原子结合的未取代或取代的6元杂环基及其盐。还描述了制备新化合物的方法及其用途。式I化合物可以用于控制杂草和/或选择性地影响植物生长的农业上有用的组合物的形式。

2. 发明授权

US4487951A N-Phenylsulfonylcarbamates 失效
标题翻译： N-苯基磺酰基氨基甲酸酯
公开(公告)号：US4487951A
公开(公告)日：1984-12-11
申请号：US571976
申请日：1984-01-19
申请人： Werner F/o/ ry , Karl Gass , Willy Meyer , Rolf Schurter
发明人： Werner F/o/ ry , Karl Gass , Willy Meyer , Rolf Schurter
IPC分类号： A01N47/24 , A01N47/08 , A01N47/22 , A01N47/36 , C07C303/36 , C07C311/16 , C07C311/53 , C07C323/67 , C07D239/42 , C07D239/46 , C07D239/47 , C07D239/48 , C07D239/52 , C07D239/56 , C07D251/16 , C07D251/22 , C07D251/40 , C07D251/46 , C07D251/52 , C07D521/00 , C07C143/83
CPC分类号： C07C311/65 , A01N47/36 , C07D239/47 , C07D239/48 , C07D521/00
摘要： N-Phenylsulfonyl-N'-pyrimidinyl- and -triazinylureas of the general formula ##STR1## and the salts of these compounds with amines, with alkali or alkaline-earth metal bases or with quaternary ammonium bases, have good pre- and post-emergence selective, herbicidal and growth-regulating properties.The symbols in this formula are as follows:A is a C.sub.3 -C.sub.6 -alkynyl group,E is the methine group or nitrogen,X is oxygen, sulfur or a sulfinyl or sulfonyl bridge,Z is oxygen or sulfur,m is the number one or two,R.sub.1 is hydrogen, halogen, C.sub.1 -C.sub.5 -alkyl or C.sub.2 -C.sub.5 -alkenyl or a group --Y--R.sub.5,R.sub.2 is hydrogen, halogen, C.sub.1 -C.sub.5 -alkyl, C.sub.2 -C.sub.5 -alkenyl or C.sub.1 -C.sub.4 -haloalkyl, or a group --Y--R.sub.5, --COOR.sub.6, --NO.sub.2 or --CO--NR.sub.7 --R.sub.8,R.sub.3 and R.sub.4 independently of one another are each hydrogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 haloalkoxy, halogen or alkoxyalkyl having at most 4 carbon atoms,R.sub.5 and R.sub.6 are each C.sub.1 -C.sub.5 -alkyl, C.sub.2 -C.sub.5 -alkenyl or C.sub.2 -C.sub.6 -alkynyl,R.sub.7 and R.sub.8 independently of one another are each hydrogen, C.sub.1 -C.sub.5 -alkyl, C.sub.2 -C.sub.5 -alkenyl or C.sub.2 -C.sub.6 -alkynyl, andY is oxygen, sulfur or a sulfinyl or sulfonyl bridge.
摘要翻译：具有通式（I）的N-苯基磺酰基-N'-嘧啶基 - 和 - 三嗪基脲和这些化合物与胺与碱金属或碱土金属碱或季铵碱的盐具有良好的前和后芽后选择性，除草和生长调节性质。该式中的符号如下：A是C 3 -C 6炔基，E是次甲基或氮，X是氧，硫或亚磺酰基或磺酰基桥，Z是氧或硫，m是第一个或两个，R 1是氢，卤素，C 1 -C 5 - 烷基或C 2 -C 5 - 烯基或基团-Y-R 5，R 2是氢，卤素，C 1 -C 5 - 烷基，C 2 -C 5 - 烯基或C 1 -C 4 - 卤代烷基或基团-Y-R 5，-COOR 6，-NO 2或-CO-NR 7 -R 8，R 3和R 4彼此独立地为氢，C 1 -C 4 - 烷基，C 1 -C 4 - 烷氧基，C 1 -C 4 - 烷硫基，C 1 -C 4卤代烷基，C 1 -C 4卤代烷氧基，卤素或至多4个碳原子的烷氧基烷基，R 5和R 6各自为C 1 -C 5 - 烷基，C 2 -C 5 - 烯基或C 2 -C 6炔基，R 7和R 8独立地为各自为氢，C 1 -C 5 - 烷基，C 2 -C 5 - 烯基或C 2 -C 6 - 炔基，Y为氧，硫或亚磺酰基或磺酰基桥。

3. 发明授权

US4433998A Pyridyloxy-phenoxyalkanecarboxylic acid derivatives and their herbicidal use 失效
标题翻译：吡啶氧基 - 苯氧亚硬脂酸衍生物及其除草用途
公开(公告)号：US4433998A
公开(公告)日：1984-02-28
申请号：US355272
申请日：1982-03-05
申请人： Hermann Rempfler , Werner F/o/ ry
发明人： Hermann Rempfler , Werner F/o/ ry
IPC分类号： C07D413/12 , A01N43/40 , C07D213/63 , C07D213/65 , C07D213/79 , C07D213/82 , C07D213/83 , C07D213/85 , C07D405/12 , C07D213/64
CPC分类号： C07D213/83 , A01N43/40 , C07D213/63 , C07D213/85
摘要： Herbicidal and plant growth-regulating pyridyloxy-phenoxyalkanecarboxylic acid derivatives of the formula ##STR1## wherein A is cyano or carboxyl, an ester, thioester or amido radical or the salt of the carboxylic acid with a cation or a quaternary ammonium group,Z is hydrogen, halogen, cyano, nitro, C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 alkoxy,D is hydrogen, halogen, cyano, nitro or C.sub.1 -C.sub.4 alkoxy,E is halogen, trifluoromethyl or cyano.R.sub.1 is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.2 -C.sub.8 alkoxyalkyl or C.sub.1 -C.sub.5 alkoxy carbonyl andR.sub.2 is hydrogen or C.sub.1 -C.sub.4 alkyl.
摘要翻译：其中A为氰基或羧基，酯，硫酯或酰氨基或羧酸与阳离子或季铵基团的盐的除草剂和植物生长调节吡啶氧基 - 苯氧亚硬脂酸羧酸衍生物，其中A为氰基或羧基，Z为氢卤素，氰基，硝基，C 1 -C 4烷基或C 1 -C 4烷氧基，D是氢，卤素，氰基，硝基或C 1 -C 4烷氧基，E是卤素，三氟甲基或氰基。

4. 发明授权

US4479821A N-Phenylsulfonyl-N'-triazinylureas 失效
标题翻译： N-苯基磺酰基-N'-三嗪基脲
公开(公告)号：US4479821A
公开(公告)日：1984-10-30
申请号：US458695
申请日：1983-01-17
申请人： Willy Meyer , Werner F/o/ ry
发明人： Willy Meyer , Werner F/o/ ry
IPC分类号： C07D239/42 , A01N41/06 , A01N43/66 , A01N47/36 , A01P13/00 , C07C20060101 , C07C67/00 , C07C301/00 , C07C311/00 , C07C311/29 , C07C313/00 , C07C317/14 , C07C317/18 , C07C317/22 , C07C317/44 , C07C323/12 , C07C323/67 , C07D239/46 , C07D239/47 , C07D239/52 , C07D239/56 , C07D251/14 , C07D251/16 , C07D251/22 , C07D251/42 , C07D251/44 , C07D251/46 , C07D521/00
CPC分类号： C07D521/00 , A01N47/36
摘要： N-Phenylsulfonyl-N'-triazinylureas of the general formula ##STR1## and the salts thereof with amines, alkali metal or alkaline earth metal bases or with quaternary ammonium bases, have good pre- and postemergence selective herbicidal and growth regulating properties. In the above formulaA is a C.sub.1 -C.sub.6 alkyl radical which is substituted by C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkylthio, C.sub.1 -C.sub.4 alkylsulfinyl or C.sub.1 -C.sub.4 alkylsulfonyl,X is oxygen, sulfur, a sulfinyl or sulfonyl bridge,Z is oxygen or sulfur,m is 1 or 2,R.sub.2 is hydrogen, halogen, C.sub.1 -C.sub.5 alkyl, C.sub.2 -C.sub.5 alkenyl, C.sub.1 -C.sub.4 haloalkyl, or a radical --Y--R.sub.5, --COOR.sub.6, --NO.sub.2 or --CO--NR.sub.7 --R.sub.8,R.sub.3 and R.sub.4, each independently of the other, are hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkylthio, C.sub.1 -C.sub.4 haloalkyl, halogen or alkoxyalkyl or at most 4 carbon atoms,R.sub.5 and R.sub.6, each independently of the other, are C.sub.1 -C.sub.5 alkyl, C.sub.2 -C.sub.5 alkenyl or C.sub.2 -C.sub.6 alkynyl,R.sub.7 and R.sub.8, each independently of the other, are hydrogen, C.sub.1 -C.sub.5 alkyl, C.sub.2 -C.sub.5 alkenyl or C.sub.2 -C.sub.6 alkynyl, andY is oxygen, sulfur, a sulfinyl or sulfonyl bridge.
摘要翻译：具有通式“IMAGE”的N-苯基磺酰基-N'-三嗪基脲及其与胺，碱金属或碱土金属碱基或季铵碱的盐具有良好的芽前和芽后选择性除草和生长调节性质。在上式中，A是被C 1 -C 4烷氧基，C 1 -C 4烷硫基，C 1 -C 4烷基亚磺酰基或C 1 -C 4烷基磺酰基取代的C 1 -C 6烷基，X是氧，硫，亚磺酰基或磺酰基桥，Z是氧或硫，m 是1或2，R2是氢，卤素，C1-C5烷基，C2-C5链烯基，C1-C4卤代烷基或基团-Y-R5，-COOR6，-NO2或-CO-NR7-R8，R3和R4各自独立地的另一个是氢，C 1 -C 4烷基，C 1 -C 4烷氧基，C 1 -C 4烷硫基，C 1 -C 4卤代烷基，卤素或烷氧基烷基或至多4个碳原子，R 5和R 6各自独立地是C 1 -C 5烷基， C 5链烯基或C 2 -C 6炔基，R 7和R 8各自独立地为氢，C 1 -C 5烷基，C 2 -C 5烯基或C 2 -C 6炔基，Y为氧，硫，亚磺酰基或磺酰基桥。

5. 发明授权

US4668800A Certain sulfonyl carbamate on thiocarbamate intermediates 失效
标题翻译：某些磺酰氨基甲酸酯在硫代氨基甲酸酯中间体
公开(公告)号：US4668800A
公开(公告)日：1987-05-26
申请号：US708204
申请日：1985-03-04
申请人： Willy Meyer , Werner F/o/ ry , Werner T/o/ pfl
发明人： Willy Meyer , Werner F/o/ ry , Werner T/o/ pfl
IPC分类号： C07D251/16 , A01N47/36 , C07C67/00 , C07C301/00 , C07C303/36 , C07C311/53 , C07C325/00 , C07C333/12 , C07D239/42 , C07D239/47 , C07D333/38 , C07D521/00 , C07D333/32 , C07C147/13 , C07C155/02 , C07D333/34
CPC分类号： C07D521/00 , C07D333/38
摘要： There is described a process for producing sulfonylureas of the formula ##STR1## wherein G is an unsubstituted or substituted furanyl, thienyl, pyrrolyl, pyridinyl or phenyl radical,X is alkyl, haloalkyl, alkoxy, alkylthio, halogen, haloalkoxy, alkylamino or dialkylamino,Y is alkyl, alkoxy or haloalkoxy,Z is a nitrogen atom or the methyne group --CH.dbd..This novel process comprises reacting a sulfonamide of the formulaG--SO.sub.2 --NH.sub.2,in the presence of a base, with a chloroformic acid ester of the formulaCl--CO--Q--T,or a sulfonyl chloride of the formulaG--SO.sub.2 Cl,in the presence of a base, with a urethane of the formulaH.sub.2 N--CO--Q--T;and converting the formed carbamate of the formulaG--SO.sub.2 --NH--CO--Q--Tby reaction with an amine of the formula ##STR2## into the sulfonylurea of the above formula. There are also described novel sulfonylcarbamates of the above formula as intermediates.
摘要翻译：描述了一种制备式IMA的磺酰脲的方法，其中G是未取代或取代的呋喃基，噻吩基，吡咯基，吡啶基或苯基，X是烷基，卤代烷基，烷氧基，烷硫基，卤素，卤代烷氧基，烷基氨基或二烷基氨基， Y是烷基，烷氧基或卤代烷氧基，Z是氮原子或甲炔基-CH =。该新方法包括使式G-SO 2 -NH 2的磺酰胺在碱的存在下与式Cl-CO-QT的氯甲酸酯或式G-SO 2 Cl的磺酰氯反应，碱的存在与式H2N-CO-QT的氨基甲酸酯反应; 并且通过与下式的磺酰脲反应将式G-SO 2 -NH-CO-Q-T的所形成的氨基甲酸酯转化为式（I）所示的磺酰脲。还描述了上述式的新型磺酰基氨基甲酸酯作为中间体。

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