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1. 发明专利

JP2011122167A Polyethylene molding material and high-strength pipe produced therewith 审中-公开
标题翻译：聚乙烯模塑材料和高强度管材生产
公开(公告)号：JP2011122167A
公开(公告)日：2011-06-23
申请号：JP2011022323
申请日：2011-02-04
申请人： Basell Polyolefine Gmbh , バーゼル、ポリオレフィン、ゲゼルシャフト、ミット、ベシュレンクテル、ハフツング
发明人： BOEHM LUDWIG , BERTHOLD JOACHIM , ENDERLE JOHANNES-FRIEDRICH , DAMM ELKE , SCHULTE ULRICH
IPC分类号： C08L23/06 , F16L9/12 , C08J5/00 , C08L23/04 , C08L23/08 , C09D123/04
CPC分类号： C09D123/04 , Y10T428/1352 , Y10T428/1397 , C08L2666/02 , C08L2666/04
摘要： PROBLEM TO BE SOLVED: To provide a high-strength pipe particularly suitable for transporting gases and water. SOLUTION: A polyethylene molding material with a bimodal molecular weight distribution has a total density of 0.948 g/cm 3 or more and a melt flow index MFI 190/5 of 0.2 dg/min or less. The material contains 35-65 wt.% of a low molecular weight ethylene homopolymer A having a viscosity number VZ A of 40-90 cm 3 /g, a melt flow index MFI 190/2.16A of 40-2,000 dg/min and a density d A of 0.965 g/cm 3 or more; and 35-65 wt.% of a high molecular weight ethylene copolymer B having a viscosity number VZ B of 500-2,000 cm 3 /g, a melt flow index MFI 190/5B of 0.02-0.2 dg/min and a density d B of 0.922-0.944 g/cm 3 . A fraction obtained in a preparative TREF analysis with p-xylene at a temperature of 78°C±3 K has a mean molar weight of 200,000 g/Mol or more. COPYRIGHT: (C)2011,JPO&INPIT
摘要翻译：要解决的问题：提供特别适用于输送气体和水的高强度管道。解决方案：具有双峰分子量分布的聚乙烯模塑材料的总密度为0.948g / cm 3 / SP> 3或更高，熔体流动指数MFI 190/5 为0.2dg / min以下。该材料含有35-65重量％的粘度为VZ A 为40-90cm 3 / SP / g的低分子量乙烯均聚物A，熔体流动指数 40-2,000dg / min的MFI 190 / 2.16A 和0.965g / cm 3> 3S / s以上的密度d A 和35-65重量％的具有500-2,000厘米3 / SP / 3的粘度值VZ B 的高分子量乙烯共聚物B，熔体流动指数MFI < SB> 190 / 5B 为0.02-0.2dg / min，密度d B 为0.922-0.944g / cm 3。在温度为78℃±3K的对二甲苯的制备型TREF分析中获得的馏分的平均摩尔重量为200,000g / mol以上。版权所有（C）2011，JPO＆INPIT

2. 发明申请

WO2005077992A8 PROCESS FOR PREPARING POLYOLEFINS IN SUSPENSION 审中-公开
标题翻译：制备悬浮液中的聚烯烃的方法
公开(公告)号：WO2005077992A8
公开(公告)日：2006-10-12
申请号：PCT/EP2005000708
申请日：2005-01-25
申请人： BASELL POLYOLEFINE GMBH , BERTHOLD JOACHIM , ALT FRANK PETER , EVERTZ KASPAR , KOELLE PETER
发明人： BERTHOLD JOACHIM , ALT FRANK PETER , EVERTZ KASPAR , KOELLE PETER
IPC分类号： C08F10/00 , C08F2/00 , C08F2/34 , C08F210/16 , C08L23/08 , C08L23/14
CPC分类号： C08F10/00 , C08F210/16 , C08F2/34 , C08F2/14 , C08F2/001 , C08F210/06
摘要： The invention relates to a continuous process for preparing polyolefins having a bimodal or multimodal molar mass distribution in suspension in at least two reactors R1, R2.x, R3.y which are connected in series and in which different reaction conditions are set. In this process, the offgases Al, A2.x, A3.y, A4 and A5 leaving all the reactors connected in series are firstly collected, the collected offgases are then compressed in a compression stage 10, the compressed offgases are subsequently cooled and the cooled material is separated into a gaseous fraction and a liquid fraction. The separated fractions are then recirculated to the polymerization process at different points. The process of the invention allows the total conversion of the polymerization, based on monomer and comonomer used, to be increased to a surprising extent.
摘要翻译：本发明涉及一种用于制备在至少两个串联连接并且设定不同反应条件的反应器R1，R2.x，R3.y中的悬浮液中具有双峰或多峰摩尔质量分布的聚烯烃的连续方法。在该过程中，首先收集离开所有串联连接的反应器的废气Al，A2.x，A3.y，A4和A5，然后将收集的废气在压缩级10中压缩，随后将压缩的废气冷却，冷却的材料被分离成气体馏分和液体馏分。然后将分离的级分在不同的点再循环到聚合过程中。本发明的方法允许基于使用的单体和共聚单体的聚合的总转化率增加到惊人的程度。

3. 发明申请

WO2009103516A3 ADHESIVE POLYMER COMPOSITION 审中-公开
标题翻译：粘合聚合物组合物
公开(公告)号：WO2009103516A3
公开(公告)日：2009-11-05
申请号：PCT/EP2009001164
申请日：2009-02-18
申请人： BASELL POLYOLEFINE GMBH , VOGT HEINZ , MIHAN SHAHRAM , MANNEBACH GERD , MEIER GERHARDUS , BERTHOLD JOACHIM , HECKER MANFRED
发明人： VOGT HEINZ , MIHAN SHAHRAM , MANNEBACH GERD , MEIER GERHARDUS , BERTHOLD JOACHIM , HECKER MANFRED
IPC分类号： C09J151/06 , C08F10/02 , H01B3/44
CPC分类号： C08F255/02 , B29C41/003 , B29C41/04 , B29K2023/06 , B29K2995/0088 , B32B1/08 , B32B7/10 , B32B7/12 , B32B15/02 , B32B15/08 , B32B15/18 , B32B27/08 , B32B27/18 , B32B27/308 , B32B27/32 , B32B27/38 , B32B2270/00 , B32B2307/30 , B32B2307/50 , B32B2307/554 , B32B2307/7246 , B32B2597/00 , C08F4/65912 , C08F4/65916 , C08F4/65925 , C08F10/00 , C08F210/02 , C08F210/16 , C08J5/18 , C08J2323/08 , C08L23/04 , C08L23/0869 , C08L51/06 , C08L2666/02 , C08L2666/04 , C08L2666/24 , C09J123/0869 , C09J151/06 , H01B3/441 , Y10T428/2933 , C08F4/61904 , C08F220/06 , C08F220/10 , C08F210/14 , C08F2500/04 , C08F2500/19 , C08F2500/12 , C08F4/7042 , C08F210/06 , C08F210/10
摘要： A novel adhesive composition suitable for composing multilayered coatings onto large, industrial equipement such as pipeline tubes is devised. The composition is a blend based on a polyethylene which determines the blend' s favorable properties, which polyethylene itself can be used further in coating cables and for producing mouldings, especially rotomoulded articles.
摘要翻译：设计出适用于在诸如管道管的大型工业设备上构成多层涂层的新型粘合剂组合物。组合物是基于聚乙烯的共混物，其确定共混物的有利性质，聚乙烯本身可以进一步用于涂覆电缆和用于生产模制品，特别是滚塑制品。

4. 发明申请

WO2007022908A3 MULTIMODAL POLYETHYLENE MOLDING COMPOSITION FOR PRODUCING PIPES HAVING IMPROVED MECHANICAL PROPERTIES 审中-公开
标题翻译：用于生产具有改进的机械性能的管道的多模聚乙烯模塑组合物
公开(公告)号：WO2007022908A3
公开(公告)日：2007-05-18
申请号：PCT/EP2006008101
申请日：2006-08-17
申请人： BASELL POLYOLEFINE GMBH , BERTHOLD JOACHIM , VOGT HEINZ , NITZ HANS-JOERG , ROTHHOEFT WERNER
发明人： BERTHOLD JOACHIM , VOGT HEINZ , NITZ HANS-JOERG , ROTHHOEFT WERNER
IPC分类号： F16L9/12 , C08L23/06
CPC分类号： C08L23/06 , C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16 , C08L23/08 , C08L23/0807 , C08L2205/03 , Y02P20/52 , C08F2/001 , C08F2/18 , C08L2666/06 , C08F2500/01 , C08F2500/07 , C08F2500/17 , C08F2500/12 , C08F210/08 , C08F2500/05
摘要： A polyethylene molding composition having a multimodal molecular mass distribution and comprising from 45 to 55 % by weight of a low molecular weight ethylene homopolymer A, from 20 to 40 % by weight of a high molecular weight copolymer B comprising ethylene and another olefin having from 4 to 8 carbon atoms and from 15 to 30 % by weight of an ultrahigh molecular weight ethylene copolymer C can be prepared in the presence of a Ziegler catalyst in a three-stage process and is highly suitable for producing pipes having excellent mechanical properties.
摘要翻译：具有多峰分子量分布的聚乙烯模塑组合物，包含45至55重量％的低分子量乙烯均聚物A，20至40重量％的包含乙烯和另一种烯烃的高分子量共聚物B 至8个碳原子和15至30重量％的超高分子量乙烯共聚物C可以在齐格勒催化剂的存在下在三步法中制备，并且非常适合于生产具有优异机械性能的管。

5. 发明专利

ES2498768T3 Procedimiento para la preparación de un componente de catalizador, para la polimerización de olefinas 未知
公开(公告)号：ES2498768T3
公开(公告)日：2014-09-25
申请号：ES10739918
申请日：2010-08-02
申请人： BASELL POLYOLEFINE GMBH
发明人： GUNDERT FRIEDHELM , SCHNEIDER MARTIN , BERTHOLD JOACHIM , MARCZINKE BERND LOTHAR
IPC分类号： C08F10/00 , C08F4/654 , C08F4/655
摘要： Un procedimiento para la preparación de un componente de catalizador sólido, el cual comprende (a) el proceder a hacer reaccionar un compuesto de alcoholato de magnesio de la fórmula Mg(OR1)(OR2), en el cual, R1 y R2, son idénticas o diferentes, y son, cada uno de ellas, un radical alquilo que tiene de 1 a 10 átomos de carbono, con un tetracloruro de titanio, el cual se lleva cabo en un hidrocarburo, a una temperatura comprendida dentro de unos márgenes de 50 °C - 100 °C, y un factor de relación molar de Ti / Mg, correspondiente a un rango comprendido dentro de unos márgenes que van desde 1,5 a 4, (b) someter la mezcla de reacción obtenida en (a), a un tratamiento térmico, a una temperatura correspondiente a un valor comprendido dentro de unos márgenes que van desde 100 °C hasta los 140 °C, durante un transcurso de tiempo comprendido dentro de unos márgenes que van desde las 5 horas hasta las 25 horas, (c) aislando y lavando con un hidrocarburo, el sólido obtenido en (b), teniendo, el citado catalizador sólido, un factor de relación molar Cl / Ti, mayor de 2,5, y un factor de relación molar de Mg : Ti : Cl, igual a 1 : 0,8 - 1,5 : 3,2 - 4,2.

6. 发明专利

AT499562T 未知
公开(公告)号：AT499562T
公开(公告)日：2011-03-15
申请号：AT06776906
申请日：2006-08-17
申请人： BASELL POLYOLEFINE GMBH
发明人： BERTHOLD JOACHIM , VOGT HEINZ , NITZ HANS-JOERG , ROTHHOEFT WERNER
IPC分类号： F16L9/12 , C08L23/06
摘要： Polyethylene moulding material (I) with a multi-modal mol. wt. distribution for the production of tubing, comprising (A) 45-55 wt% low-mol. wt. ethylene homopolymer, (B) 20-40 wt% high-mol. wt. copolymer of ethylene and a 4-8C olefin and (C) 15-30 wt% ultrahigh-mol. wt. ethylene copolymer. Independent claims are included for (1) a method for the production of (I) by polymerisation in suspension at 70-100 (preferably 75-90) [deg]C and 2-10 bar in presence of a highly-active Ziegler catalyst comprising a transition metal compound and an organoaluminum compound, carrying out the reaction in 3 stages in 3 reactors in series and adjusting the mol. wt. of the polyethylene produced in each stage with the aid of hydrogen (2) tubes made from (I), with a stress cracking resistance (FNCT) of more than 1500 (preferably more than 2500) hours and a notched impact strength of more than 12.5 kJ/m2> at -30 [deg]C .

7. 发明专利

AT492596T 未知
公开(公告)号：AT492596T
公开(公告)日：2011-01-15
申请号：AT06708479
申请日：2006-02-23
申请人： BASELL POLYOLEFINE GMBH
发明人： BERTHOLD JOACHIM , HEINICKE LUTZ-GERD , MEIER GERHARDUS
IPC分类号： C08L23/04 , C08F297/08
摘要： The invention relates to a polyethylene molding composition having a multimodal molar mass distribution particularly suitable for blow molding films having a thickness in the range from 8 to 200 μm. The molding composition has a density at a temperature of 23° C. in the range from 0.948 to 0.953 g/cm3 and an MFR190/5 of the final product after extrusion in the range from 0.10 to 0.50 dg/min. The composition comprises from 30 to 60% by weight of a first ethylene polymer fraction made of a homopolymer A having a first molecular weight, from 22 to 40% by weight of a second ethylene polymer fraction made of a further homopolymer or first copolymer B of ethylene and at least one first comonomer from the group of olefins having from 4 to 8 carbon atoms, the first copolymer B having a second molecular weight higher than the first molecular weight, and from 10 to 30% by weight of a third ethylene polymer fraction made of a second copolymer C having a third molecular weight higher than the second molecular weight. The molding composition of the invention allows to produce films having a good balance between processability and mechanical properties.

8. 发明专利

DE602006013427D1 未知
公开(公告)号：DE602006013427D1
公开(公告)日：2010-05-20
申请号：DE602006013427
申请日：2006-02-23
申请人： BASELL POLYOLEFINE GMBH
发明人： BERTHOLD JOACHIM , HEINICKE LUTZ-GERD , MEIER GERHARDUS
IPC分类号： C08J5/18 , C08L23/04
摘要： The invention relates to a polyethylene molding composition having a multimodal molar mass distribution particularly suitable for blow molding films having a thickness in the range from 8 to 200 μm. The molding composition has a density at a temperature of 23° C. in the range from 0.953 to 0.960 g/cm3 and an MFR190/5 of the final product after extrusion in the range from 0.10 to 0.50 dg/min. The composition comprises from 30 to 60% by weight of a first ethylene polymer fraction made of a homopolymer A having a first molecular weight, from 22 to 40% by weight of a second ethylene polymer fraction made of a further homopolymer or first copolymer B of ethylene and at least one first comonomer from the group of olefins having from 4 to 8 carbon atoms, the first copolymer B having a second molecular weight higher than the first molecular weight, and from 10 to 30% by weight of a third ethylene polymer fraction made of a second copolymer C having a third molecular weight higher than the second molecular weight. The molding composition of the invention allows to produce thin films having improved processability without impairing the mechanical properties.

9. 发明专利

AT463530T 未知
公开(公告)号：AT463530T
公开(公告)日：2010-04-15
申请号：AT06743201
申请日：2006-02-23
申请人： BASELL POLYOLEFINE GMBH
发明人： BERTHOLD JOACHIM , HEINICKE LUTZ-GERD , MEIER GERHARDUS
IPC分类号： C08J5/18 , C08L23/04
摘要： The invention relates to a polyethylene molding composition having a multimodal molar mass distribution particularly suitable for blow molding films having a thickness in the range from 8 to 200 μm. The molding composition has a density at a temperature of 23° C. in the range from 0.953 to 0.960 g/cm3 and an MFR190/5 of the final product after extrusion in the range from 0.10 to 0.50 dg/min. The composition comprises from 30 to 60% by weight of a first ethylene polymer fraction made of a homopolymer A having a first molecular weight, from 22 to 40% by weight of a second ethylene polymer fraction made of a further homopolymer or first copolymer B of ethylene and at least one first comonomer from the group of olefins having from 4 to 8 carbon atoms, the first copolymer B having a second molecular weight higher than the first molecular weight, and from 10 to 30% by weight of a third ethylene polymer fraction made of a second copolymer C having a third molecular weight higher than the second molecular weight. The molding composition of the invention allows to produce thin films having improved processability without impairing the mechanical properties.

10. 发明专利

MX2009014079A COMPOSICION PARA MOLDEO DE PE, PARA MOLDEO POR INSUFLACION DE AIRE DE PEQUEÑAS PIEZAS DE BAJA DENSIDAD. 未知
公开(公告)号：MX2009014079A
公开(公告)日：2010-03-01
申请号：MX2009014079
申请日：2008-06-26
申请人： BASELL POLYOLEFINE GMBH
发明人： BERTHOLD JOACHIM , BOOS DIANA , MEIER GERHARDUS
IPC分类号： C08L23/06 , C08L23/08
摘要： La invención concierne a una composición para moldeo de polietileno con distribución poli-modal de masa molar, la cual es particularmente adecuada para el moldeo por insuflación de aire de pequeñas piezas moldeadas por insuflación de aire, cuya capacidad está en el intervalo desde 250 a 5000 ml. La densidad de la composición para moldeo a una temperatura de 23 °C está en el intervalo desde 0.949 g/cm3 a 0.954 g/cm3, y su MFI190/5 está en el intervalo desde 1.3 a 2,0 g/10 min. Comprende desde 37 a 43 % en peso de un homopolímero A de etileno de bajo peso molecular, desde 37 a 43 % en peso de un co-polímero B de alto peso molecular compuesto de etileno y de otra olefina que tenga de 4 a 8 átomos de carbono, y desde 18 a 23 % en peso de un co-polímero C de etileno de ultra alto peso molecular.

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