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1. 发明申请

WO2004018529A3 MODIFIED ZIEGLER CATALYST, PROCESS FOR PREPARING IT AND PROCESS FOR PREPARING POLY-1-OLEFINS IN ITS PRESENCE 审中-公开
标题翻译：改性齐格勒催化剂，其制备方法及其制备聚-1-烯烃的方法
公开(公告)号：WO2004018529A3
公开(公告)日：2004-05-13
申请号：PCT/EP0308472
申请日：2003-07-31
申请人： BASELL POLYOLEFINE GMBH , ALT FRANK PETER , BOEHM LUDWIG , GUNDERT FRIEDHELM
发明人： ALT FRANK PETER , BOEHM LUDWIG , GUNDERT FRIEDHELM
IPC分类号： C08F4/652 , B01J31/00 , C08F4/44 , C08F4/64 , C08F4/69 , C08F10/02 , C08F110/02 , C08F10/00
CPC分类号： C08F10/02 , C08F110/02 , C08F4/6465 , C08F4/6567 , C08F2500/17 , C08F2500/24 , C08F2500/18 , C08F2500/04
摘要： The invention relates to a modified Ziegler catalyst for preparing a poly-1-olefin in suspension, in solution or in the gas phase, which catalyst comprises the reaction product of a magnesium alkoxide (component a) with a transition metal compound (component b) and an organometallic compound (component c) together with an additional component (d) comprising a compound of the chemical formula M - Rx where M is an element of main group IV of the Periodic Table, R is halogen or an organic radical such as alkyl having from 1 to 10 carbon atoms, oxyalkyl having from 1 to 10 carbon atoms, cycloalkyl having from 4 to 8 carbon atoms in the ring and, if desired, from 1 to 6 substituents R' on the ring, aryl having from 6 to 10 carbon atoms in the aromatic and, if desired, from 1 to 6 substituents R' on the aromatic, where R' is a halogen or an alkyl radical having from 1 to 4 carbon atoms or an OH group or an NO2 group or an oxyalkyl radical having from 1 to 4 carbon atoms, and x is an integer from 1 to 4. The invention also relates to a process for preparing the Ziegler catalyst and to the homopolymerization or copolymerization of 1-olefins in its presence.
摘要翻译：本发明涉及一种用于在悬浮液，溶液或气相中制备聚-1-烯烃的改性齐格勒催化剂，该催化剂包括烷氧基镁（组分a）与过渡金属化合物（组分b）的反应产物，和有机金属化合物（组分c）以及包含化学式M-Rx的化合物的另外的组分（d），其中M是元素周期表第IV族的元素，R是卤素或有机基团如烷基具有1至10个碳原子，具有1至10个碳原子的烷氧基烷基，环中具有4至8个碳原子的环烷基，如果需要，在环上具有1至6个取代基R'，具有6至10个如果需要，芳族中的1至6个取代基R'，其中R'是卤素或具有1至4个碳原子的烷基或OH基团或NO 2基团或氧烷基基团具有1至4个碳原子，x是整数本发明还涉及一种制备齐格勒催化剂的方法以及其存在下的1-烯烃的均聚或共聚。

2. 发明专利

ES2487900T3 Procedimiento para la preparación de (co)polímeros de etileno 未知
公开(公告)号：ES2487900T3
公开(公告)日：2014-08-25
申请号：ES06723041
申请日：2006-02-15
申请人： BASELL POLYOLEFINE GMBH
发明人： GUNDERT FRIEDHELM , SCHMITT MARIA , SCHNEIDER MARTIN
IPC分类号： C08F4/654 , C08F10/02
摘要： Un procedimiento par la preparación de un polímero de olefina, mediante la (co)polimerización de etileno o de etileno con un porcentaje de hasta un 10 %, en peso, en base a la cantidad total de monómeros, de una 1-olefina de la fórmula R-CH>=CH2, en donde, R, es un radical alquilo de cadena lineal o de cadena ramificada, el cual tiene de 1 a 12 átomos de carbono, en suspensión, en solución, o en fase de gas, a una temperatura comprendida dentro de unos márgenes que van desde los 20 °C hasta los 120 °C, y a una presión correspondiente a un valor comprendido dentro de unos márgenes que van desde los 0,2 MPa a los 6,0 MPa, en presencia de un catalizador, que comprende un componente (A) el cual comprende el producto de reacción de un alcóxido de magnesio, con un compuesto de transición tetravalente, y un componente (B), seleccionado de entre los compuestos de trialquilaluminio, que tienen de 1 a 6 átomos de carbono, en el radical alquilo, preparándose, el citado componente (A), mediante un procedimiento que comprende las siguientes etapas: (a) suspender o dispersar, como un gel, en un disolvente inerte, un alcóxido de magnesio de la fórmula I Mg(OR1)(OR2) (I), en donde, R1 y R2, son idénticas o diferentes, y son, cada una de ellas, radicales alquilo no ramificados o ramificados, los cuales tienen de 1 a 20 átomos de carbono, o un radical (CH2)nOR3; R3, es un radical alquilo, el cual tiene de 1 a 4 átomos de carbono; y n es un número entero de 2 a 6, (b) hacer reaccionar o suspensión o dispersión en concordancia con (a), con un compuesto de metal de transición, tetravalente, de la fórmula II M1Xm(OR4)4-m (II), en donde, M1, es titanio, R4, es un radical alquilo, el cual comprende de 1 a 9 átomos de carbono; X, es cloro; y m, es un número entero de cero a 4; a una temperatura comprendida dentro de unos márgenes que van desde los 20 °C hasta los 140 °C, en un factor de relación molar de Mg : M1 de 1 : 0,05 - 10; (c) proceder a someter a un post-tratamiento térmico, a la suspensión procedente de la etapa (b), a una temperatura correspondiente a un valor comprendido dentro de unos márgenes que van desde los 100 °C hasta los 140 °C, durante un transcurso de tiempo que va desde los 20 minutos hasta los 180 minutos. (d) lavar la suspensión procedente de la etapa (c), hasta que, el licor madre del sobrenadante, tenga unas concentraciones de Cl y de Ti, de menos de 10 mmol / l.

3. 发明专利

DE10236647A1 Ziegler catalyst for preparing olefin homopolymers and copolymers by polymerization of olefin, comprises reaction product of magnesium alkoxide with transition metal compound and organometallic compound together with additional component 未知
公开(公告)号：DE10236647A1
公开(公告)日：2004-02-19
申请号：DE10236647
申请日：2002-08-09
申请人： BASELL POLYOLEFINE GMBH
发明人： GUNDERT FRIEDHELM , ALT FRANK , BOEHM LUDWIG
IPC分类号： C08F10/02 , C08F110/02 , C08F4/646 , C08F10/00
摘要： A Ziegler catalyst for preparing 1-olefin homopolymers and copolymers by polymerization of a 1-olefin, in suspension, in solution or in the gas phase, comprises a reaction product of a magnesium alkoxide with a transition metal compound and an organometallic compound together with a main group IV component. A Ziegler catalyst for preparing 1-olefin homopolymers and copolymers by polymerization of a 1-olefin having a formula R4CH=CH2, in suspension, in solution or in the gas phase, comprises a reaction product of a magnesium alkoxide (a) with a transition metal compound (b) and an organometallic compound (c) together with an additional component (d) comprising a compound of formula M-Rx. R4 = hydrogen or 1-10C alkyl; M = an element of main group IV of the Periodic Table; R = halogen, or an organic radical, e.g. 1-10C alkyl; 1-10C oxyalkyl; 4-8C cycloalkyl optionally having from 1 to 6 substituents R' on the ring; 6-10C aryl optionally having 1-6 substituents R': R' = halogen or 1-4C alkyl, OH, NO2, or a 1-4C oxyalkyl; x = 1-4. Independent claims are also included for: (a) a process for preparing a Ziegler catalyst as above, comprising reacting the magnesium alkoxide with the organometallic compound at 20-100, preferably 60-90 degrees C, in the presence of an inert hydrocarbon while stirring, with a transition metal compound (0.05-5, preferably 0.1-3.5 mole/1 mole of magnesium alkoxide), where an additional component as above is added; and (b) a process for preparing 1-olefin homopolymers and copolymers by polymerization of a 1-olefin of the formula R4CH=CH2 as above, in the presence of a catalyst above combined with a cocatalyst in a stirred vessel at -30 to 150, preferably -10 to 120 degrees C, prior to the polymerization or directly in the polymerization vessel at 20-200 degrees C and the polymerization is carried out in solution, in suspension or in the gas phase, continuously or batchwise, in stage(s) at 20-200, preferably 50-150 degrees C, and a pressure of 0.5-50, preferably 1.5-30 bar.

4. 发明专利

BR112012002406A2 componente catalisador para plimerização de olefinas. 未知
公开(公告)号：BR112012002406A2
公开(公告)日：2016-02-23
申请号：BR112012002406
申请日：2010-08-02
申请人： BASELL POLYOLEFINE GMBH
发明人： MARCZINKE BERND LOTHAR , GUNDERT FRIEDHELM , BERTHOLD JOACHIM , SCHNEIDER MARTIN
IPC分类号： C08F10/00 , C08F4/654 , C08F4/655

5. 发明专利

BRPI0606925A2 未知
公开(公告)号：BRPI0606925A2
公开(公告)日：2009-12-01
申请号：BRPI0606925
申请日：2006-02-15
申请人： BASELL POLYOLEFINE GMBH
发明人： GUNDERT FRIEDHELM , SCHMITT MARIA , SCHEIDER MARTIN
IPC分类号： C08F4/654 , C08F10/02
摘要： Preparation of olefin polymer comprises (co)polymerization of ethylene or of ethylene with up to 10 wt.%, based on the total amount of monomers, of l-olefin in suspension, in solution or in the gas phase, at 20-120[deg]C and 0.2-6 MPa in the presence of a catalyst comprising the reaction product of a magnesium alkoxide with a tetravalent transition metal compound, where a magnesium alkoxide suspended or dispersed as gel in an inert solvent, is reacted with tetravalent transition metal compound at 20-140[deg]C and the reaction product is then after-treated thermally at 90-200[deg]C for 10-180 minutes. Preparation of olefin polymer comprises (co)polymerization of ethylene or of ethylene with up to 10 wt.%, based on the total amount of monomers, of a l-olefin of formula R-CH=CH 2, in suspension, in solution or in the gas phase, at 20-120[deg]C and 0.2-6 MPa in the presence of a catalyst comprising the reaction product of a magnesium alkoxide with a tetravalent transition metal compound, where a magnesium alkoxide of formula Mg(OR 1>)(OR 2>), suspended or dispersed as gel in an inert solvent, is reacted with a tetravalent transition metal compound of formula MlX m(OR 4>) 4-m, at 20-140[deg]C and the reaction product is then after-treated thermally at 90-200[deg]C for 10-180 minutes. R : 1-12C alkyl; R 1>,R 2>1-20C alkyl radical or radical (CH 2) nOR 3>; R 3>1-4C alkyl radical; n : 2-6; M : Ti, Zr or Hf; R 4>1-9C alkyl radical; X : halo; m : 0-4. Independent claims are also included for: (1) an ethylene polymer prepared by the process; and (2) use of an ethylene polymer for producing films by film blowing process, for producing small and large hollow bodies by blow molding process and for producing pipes by extrusion process.

6. 发明专利

DE60306397D1 未知
公开(公告)号：DE60306397D1
公开(公告)日：2006-08-03
申请号：DE60306397
申请日：2003-07-31
申请人： BASELL POLYOLEFINE GMBH
发明人： ALT PETER , BOEHM LUDWIG , GUNDERT FRIEDHELM
IPC分类号： C08F4/652 , C08F10/00 , B01J31/00 , C08F4/44 , C08F4/64 , C08F4/69 , C08F10/02 , C08F110/02
摘要： The invention relates to a modified Ziegler catalyst for preparing a poly-1-olefin in suspension, in solution or in the gas phase, which catalyst comprises the reaction product of a magnesium alkoxide (component a) with a transition metal compound (component b) and an organometallic compound (component c) together with an additional component (d) comprising a compound of the chemical formula M-R x where M is an element of main group IV of the Periodic Table, R is halogen or an organic radical such as alkyl having from 1 to 10 carbon atoms, oxyalkyl having from 1 to 10 carbon atoms, cycloalkyl having from 4 to 8 carbon atoms in the ring and, if desired, from 1 to 6 substituents R' on the ring, aryl having from 6 to 10 carbon atoms in the aromatic and, if desired, from 1 to 6 substituents R' on the aromatic, where R' is a halogen or an alkyl radical having from 1 to 4 carbon atoms or an OH group or an NO 2 group or an oxyalkyl radical having from 1 to 4 carbon atoms, and x is an integer from 1 to 4. The invention also relates to a process for preparing the Ziegler catalyst and to the homopolymerization or copolymerization of 1-olefins in its presence.

7. 发明专利

AU2003258552A1 MODIFIED ZIEGLER CATALYST, PROCESS FOR PREPARING IT AND PROCESS FOR PREPARING POLY-1-OLEFINS IN ITS PRESENCE 未知
公开(公告)号：AU2003258552A1
公开(公告)日：2004-03-11
申请号：AU2003258552
申请日：2003-07-31
申请人： BASELL POLYOLEFINE GMBH
发明人： BOHM LUDWIG , GUNDERT FRIEDHELM , ALT FRANK PETER
IPC分类号： C08F4/652 , B01J31/00 , C08F4/44 , C08F4/64 , C08F4/69 , C08F10/02 , C08F110/02 , C08F10/00
摘要： The invention relates to a modified Ziegler catalyst for preparing a poly-1-olefin in suspension, in solution or in the gas phase, which catalyst comprises the reaction product of a magnesium alkoxide (component a) with a transition metal compound (component b) and an organometallic compound (component c) together with an additional component (d) comprising a compound of the chemical formula M-R x where M is an element of main group IV of the Periodic Table, R is halogen or an organic radical such as alkyl having from 1 to 10 carbon atoms, oxyalkyl having from 1 to 10 carbon atoms, cycloalkyl having from 4 to 8 carbon atoms in the ring and, if desired, from 1 to 6 substituents R' on the ring, aryl having from 6 to 10 carbon atoms in the aromatic and, if desired, from 1 to 6 substituents R' on the aromatic, where R' is a halogen or an alkyl radical having from 1 to 4 carbon atoms or an OH group or an NO 2 group or an oxyalkyl radical having from 1 to 4 carbon atoms, and x is an integer from 1 to 4. The invention also relates to a process for preparing the Ziegler catalyst and to the homopolymerization or copolymerization of 1-olefins in its presence.

8. 发明专利

ES2610142T3 Componentes catalíticos para la polimerización de olefinas y catalizadores obtenidos 未知
公开(公告)号：ES2610142T3
公开(公告)日：2017-04-26
申请号：ES11723086
申请日：2011-06-06
申请人： BASELL POLYOLEFINE GMBH
发明人： GUNDERT FRIEDHELM , SCHNEIDER MARTIN
IPC分类号： C08F10/00
摘要： Un procedimiento para la preparación de un componente catalizador para la polimerización de olefinas, que comprende: (a) hacer reaccionar en un medio de suspensión de hidrocarburo inerte un compuesto de Mg (OR1) (OR2), donde R1 y R2 son iguales o diferentes y cada uno es un radical alquilo que tiene de 1 a 10 átomos de carbono, con un compuesto de metal de transición tetravalente que tiene al menos un enlace metal-halógeno, utilizado en cantidades tales que la relación molar metal/Mg es de 0,1 a 1, y se obtiene así un producto de reacción sólido disperso en una suspensión de hidrocarburos, (b) lavar el producto de reacción sólido disperso en una suspensión de hidrocarburo con un hidrocarburo líquido; (c) poner en contacto el producto de reacción sólido lavado obtenido en (b) con un compuesto de titanio tetravalente en una relación molar de Ti/Mg de 0,01 a 0,1; y (d) poner en contacto el producto obtenido en (c) con un compuesto organometálico de un metal del grupo 1, 2 o 13 de la Tabla Periódica en relación molar de 0,1 a 2 con respecto al alcóxido de magnesio donde dicho compuesto organometálico se elige entre los compuestos organoaluminio.

9. 发明专利

ES2266899T3 CATALIZADOR ZIEGLER MODIFICADO, PROCESO PARA PREPARARLO Y PROCESO PARA PREPARAR POLI-1-OLEFINAS EN SU PRESENCIA. 未知
公开(公告)号：ES2266899T3
公开(公告)日：2007-03-01
申请号：ES03792238
申请日：2003-07-31
申请人： BASELL POLYOLEFINE GMBH
发明人： ALT FRANK PETER , BOHM LUDWIG , GUNDERT FRIEDHELM
IPC分类号： C08F4/652 , B01J31/00 , C08F10/00 , C08F4/44 , C08F4/64 , C08F4/69 , C08F10/02 , C08F110/02
摘要： Un catalizador Ziegler para preparar homopolímeros y copolímeros de 1-olefina mediante polimerización de una 1-olefina de la fórmula R 4 CH=CH2, donde R 4 es hidrógeno ó un radical alquilo que tiene de 1 a 10 átomos de carbono, en suspensión, en solución ó en la fase gaseosa, cuyo catalizador incluye el producto de reacción de un alcóxido de magnesio (componente a) con un compuesto de titanio (componente b) y un compuesto organometálico (componente c) junto con un componente adicional (d) que incluye un compuesto químico de la fórmula M - Rx Donde M es un elemento del grupo principal IV de la Tabla Periódica y R es halógeno.

10. 发明专利

BR112012032361A2 componentes catalisadores para a polimerização de olefinas e catalisadores obtidos das mesmas 未知
公开(公告)号：BR112012032361A2
公开(公告)日：2016-11-08
申请号：BR112012032361
申请日：2011-06-06
申请人： BASELL POLYOLEFINE GMBH
发明人： GUNDERT FRIEDHELM , SCHNEIDER MARTIN
IPC分类号： C08F10/00
摘要： componentes catalisadores para a polimerização de olefinas e catalisadores obtidos das mesmas. a presnete invenção refere-se a um componente catalisador para a polimerização de olefinas obtido taravés de: (a) reação em um meio de suspensão hidrocarboneto inerte de um composto mg(or1)(or2), no qual r1 e r2 são idênticos ou diferentes e são, cada, um radical alquila tendo 1 a 10 átomos de carbono, com um composto metal de transição tetravalente tendo pelo menos uma ligação metal - halogênio, usado em quantidades de modo que a razão molar de metal / mg seja de 0,05 a 10, com isso obtendo um produto d ereação sólido disperso em uma pasta de hidrocarboneto, (b) lavagem de produto de reação sólido em uma pata de hidrocarboneto com um hidrocarboneto líquido, (c) contato de produto de reação sólido lavado obtido em (b) com um composto de titânio tetravalente e (d) contatode produto obtido em (c) com um composto organometálico d eum metal do grupo 1,2 ou 13 da tabela periódica.

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