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1. 发明授权

US08492324B2 Use of metal hydrazide complex compounds as oxidation catalysts 有权
标题翻译：使用金属酰肼配合物作为氧化催化剂
公开(公告)号：US08492324B2
公开(公告)日：2013-07-23
申请号：US12936699
申请日：2009-03-30
申请人： Barbara Wagner , Hauke Rohwer , Marie-Josée Dubs , Menno Hazenkamp , Kai Eichin , Albert Schneider
发明人： Barbara Wagner , Hauke Rohwer , Marie-Josée Dubs , Menno Hazenkamp , Kai Eichin , Albert Schneider
IPC分类号： C11D3/26 , C11D3/28 , C11D3/39
CPC分类号： C11D3/28 , A01N47/34 , A61L2/18 , A61L12/128 , B01J27/20 , B01J27/24 , B01J31/1805 , B01J31/2208 , B01J2231/70 , B01J2531/0238 , B01J2531/72 , C11D3/168 , C11D3/32 , C11D3/323 , C11D3/3917 , C11D3/3927 , C11D3/3932 , C11D7/3209 , C11D7/3263 , C11D7/3281 , D06L4/12
摘要： The present invention relates to the use of selected metal complex compounds and ligands as oxidation catalysts as well as to a process for removing stains and soil on textiles and hard surfaces. The metal complex compounds have hydrazide ligands, preferably with electron withdrawing groups in the phenyl ring adjacent to the acyl group. Further aspects of the invention are formulations comprising such metal complex compounds, novel metal complex compounds and novel ligands.
摘要翻译：本发明涉及选择的金属络合物和配体作为氧化催化剂的用途以及去除织物和硬表面上的污渍和污垢的方法。金属络合物具有酰肼配体，优选在与酰基相邻的苯环中具有吸电子基团。本发明的其它方面是包含这种金属络合物，新型金属络合物和新型配体的制剂。

2. 发明申请

US20110071066A1 USE OF METAL HYDRAZIDE COMPLEX COMPOUNDS AS OXIDATION CATALYSTS 有权
标题翻译：使用金属氢化物复合化合物作为氧化催化剂
公开(公告)号：US20110071066A1
公开(公告)日：2011-03-24
申请号：US12936699
申请日：2009-03-30
申请人： Barbara Wagner , Hauke Rohwer , Marie-Josee Dubs , Menno Hazenkamp , Kai Eichin , Albert Schneider
发明人： Barbara Wagner , Hauke Rohwer , Marie-Josee Dubs , Menno Hazenkamp , Kai Eichin , Albert Schneider
IPC分类号： C11D3/395 , C07C243/18 , C07D295/155 , C07F13/00 , C11D3/60
CPC分类号： C11D3/28 , A01N47/34 , A61L2/18 , A61L12/128 , B01J27/20 , B01J27/24 , B01J31/1805 , B01J31/2208 , B01J2231/70 , B01J2531/0238 , B01J2531/72 , C11D3/168 , C11D3/32 , C11D3/323 , C11D3/3917 , C11D3/3927 , C11D3/3932 , C11D7/3209 , C11D7/3263 , C11D7/3281 , D06L4/12
摘要： The present invention relates to the use of selected metal complex compounds and ligands as oxidation catalysts as well as to a process for removing stains and soil on textiles and hard surfaces. The metal complex compounds have hydrazide ligands preferably with electron withdrawing groups in the phenyl ring adjacent to the acyl group. Further aspects of the invention are formulations comprising such metal complex compounds, novel metal complex compounds and novel ligands.
摘要翻译：本发明涉及选择的金属络合物和配体作为氧化催化剂的用途以及去除织物和硬表面上的污渍和污垢的方法。金属配位化合物优选在与酰基相邻的苯环中具有吸电子基团的酰肼配体。本发明的其它方面是包含这种金属络合物，新型金属络合物和新型配体的制剂。

3. 发明授权

US07928049B2 Use of metal complex compounds as oxidation catalysts 有权
标题翻译：使用金属络合物作为氧化催化剂
公开(公告)号：US07928049B2
公开(公告)日：2011-04-19
申请号：US12669797
申请日：2008-07-14
申请人： Barbara Wagner , Hauke Rohwer , Marie-Josée Dubs , Nicole End , Menno Hazenkamp , Sophie Marquais-Bienewald
发明人： Barbara Wagner , Hauke Rohwer , Marie-Josée Dubs , Nicole End , Menno Hazenkamp , Sophie Marquais-Bienewald
IPC分类号： C11D1/02 , C11D1/66 , C11D3/28 , C11D3/39 , C11D3/395
CPC分类号： B01J31/1815 , B01J31/1825 , B01J31/2217 , B01J2231/70 , B01J2531/0238 , B01J2531/0258 , B01J2531/16 , B01J2531/46 , B01J2531/72 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C07D213/81 , C07D213/88 , C07D215/38 , C07D401/12 , C11D3/0021 , C11D3/168 , C11D3/3932 , C11D3/3935 , C11D3/48
摘要： The present invention relates to the use of metal complex compounds having hydrazide ligands as oxidation catalysts. Further aspects of the invention are formulations comprising such metal complex compounds, novel metal complex compounds and novel ligands. The metal complex compounds are used especially for enhancing the action of peroxides, for example in the treatment of textile material, without at the same time causing any appreciable damage to fibers and dyeings. There is also no appreciable damage to fibers and dyeings if these metal complexes are used in combination with an enzyme or a mixture of enzymes.
摘要翻译：本发明涉及具有酰肼配位体的金属络合物作为氧化催化剂的用途。本发明的其它方面是包含这种金属络合物，新型金属络合物和新型配体的制剂。金属络合物特别用于增强过氧化物的作用，例如在纺织材料的处理中，而不会同时对纤维和染色造成明显的损害。如果这些金属配合物与酶或酶的混合物组合使用，纤维和染色也不会有明显的损害。

4. 发明申请

US20110021407A1 USE OF METAL COMPLEX COMPOUNDS AS OXIDATION CATALYSTS 有权
标题翻译：使用金属复合化合物作为氧化催化剂
公开(公告)号：US20110021407A1
公开(公告)日：2011-01-27
申请号：US12669797
申请日：2008-07-14
申请人： Barbara Wagner , Hauke Rohwer , Marie-Josee Dubs , Nicole End , Menno Hazenkamp , Sophie Marquais-Bienewald
发明人： Barbara Wagner , Hauke Rohwer , Marie-Josee Dubs , Nicole End , Menno Hazenkamp , Sophie Marquais-Bienewald
IPC分类号： C11D3/60 , C07D401/12 , C07F15/02 , C07F7/28 , C07F13/00 , C07F15/06 , C07F15/04 , C07F1/08 , C09K3/00
CPC分类号： B01J31/1815 , B01J31/1825 , B01J31/2217 , B01J2231/70 , B01J2531/0238 , B01J2531/0258 , B01J2531/16 , B01J2531/46 , B01J2531/72 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C07D213/81 , C07D213/88 , C07D215/38 , C07D401/12 , C11D3/0021 , C11D3/168 , C11D3/3932 , C11D3/3935 , C11D3/48
摘要： The present invention relates to the use of metal complex compounds having hydrazide ligands as oxidation catalysts. Further aspects of the invention are formulations comprising such metal complex compounds, novel metal complex compounds and novel ligands. The metal complex compounds are used especially for enhancing the action of peroxides, for example in the treatment of textile material, without at the same time causing any appreciable damage to fibres and dyeings. There is also no appreciable damage to fibres and dyeings if these metal complexes are used in combination with an enzyme or a mixture of enzymes.
摘要翻译：本发明涉及具有酰肼配位体的金属络合物作为氧化催化剂的用途。本发明的其它方面是包含这种金属络合物，新型金属络合物和新型配体的制剂。金属络合物特别用于增强过氧化物的作用，例如在纺织材料的处理中，而不会同时对纤维和染色造成明显的损害。如果这些金属配合物与酶或酶的混合物组合使用，纤维和染色也不会有明显的损害。

5. 发明申请

US20130117941A1 METAL FREE BLEACHING COMPOSITION 有权
标题翻译：无金属漂白组合物
公开(公告)号：US20130117941A1
公开(公告)日：2013-05-16
申请号：US13703385
申请日：2011-06-21
申请人： Markus Frey , Hauke Rohwer , Frédérique Wendeborn , Menno Hazenkamp
发明人： Markus Frey , Hauke Rohwer , Frédérique Wendeborn , Menno Hazenkamp
IPC分类号： D06L3/02
CPC分类号： D06L4/15 , C07C225/06 , C07C225/22 , C07C317/32 , C07C323/32 , C07C381/12 , C07C2601/14 , C11D3/30 , C11D3/349 , C11D3/3902 , C11D3/3905 , C11D3/3915 , C11D3/3917 , C11D7/3236 , C11D7/3281 , C11D7/34 , D06L4/12
摘要： The present invention relates to the use of a composition comprising specific a-amino-ketones, H2O2, a H2O2 precursor or a peracid and optionally an activator as a bleaching mixture for textile materials or dishes either manually or in an automatic washing machine or dish washer. Further aspects of the invention are the composition comprising specific a-aminoketones and H2O2, a H2O2 precursor or a peracid and a process for bleaching of stains or of soiling on textile materials or dishes in the context of a washing process either manually or in an automatic washing machine or dish washer. Also aspects of the invention are detergent formulations comprising such a composition and novel compounds.
摘要翻译：本发明涉及包含特定的α-氨基酮，H 2 O 2，H 2 O 2前体或过酸和任选的活化剂的组合物作为纺织材料或盘子的漂白混合物的手段或者在自动洗衣机或洗碗机中的用途。本发明的其它方面是包含特定的α-氨基酮和H 2 O 2，H 2 O 2前体或过酸的组合物，以及在洗涤过程中手动或自动地漂洗污渍或污染纺织品材料或菜肴的方法洗衣机或洗碗机。本发明的另外方面是包含这种组合物和新化合物的洗涤剂制剂。

6. 发明授权

US09657435B2 Metal free bleaching composition 有权
公开(公告)号：US09657435B2
公开(公告)日：2017-05-23
申请号：US13703385
申请日：2011-06-21
申请人： Markus Frey , Hauke Rohwer , Frederique Wendeborn , Menno Hazenkamp
发明人： Markus Frey , Hauke Rohwer , Frederique Wendeborn , Menno Hazenkamp
IPC分类号： C11D3/39 , C11D3/395 , C11D7/54 , D06L3/02 , C07C225/06 , C07C225/22 , C07C317/32 , C07C323/32 , C07C381/12 , C11D3/30 , C11D3/34 , C11D7/32 , C11D7/34
CPC分类号： D06L4/15 , C07C225/06 , C07C225/22 , C07C317/32 , C07C323/32 , C07C381/12 , C07C2601/14 , C11D3/30 , C11D3/349 , C11D3/3902 , C11D3/3905 , C11D3/3915 , C11D3/3917 , C11D7/3236 , C11D7/3281 , C11D7/34 , D06L4/12
摘要： The present invention relates to the use of a composition comprising specific a-amino-ketones, H2O2, a H2O2 precursor or a peracid and optionally an activator as a bleaching mixture for textile materials or dishes either manually or in an automatic washing machine or dish washer. Further aspects of the invention are the composition comprising specific a-aminoketones and H2O2, a H2O2 precursor or a peracid and a process for bleaching of stains or of soiling on textile materials or dishes in the context of a washing process either manually or in an automatic washing machine or dish washer. Also aspects of the invention are detergent formulations comprising such a composition and novel compounds.

7. 发明授权

US09051285B2 Bleach catalysts 有权
标题翻译：漂白催化剂
公开(公告)号：US09051285B2
公开(公告)日：2015-06-09
申请号：US13992888
申请日：2011-12-08
申请人： Hauke Rohwer , Barbara Wagner , Frederique Wendeborn , Katherina Misteli
发明人： Hauke Rohwer , Barbara Wagner , Frederique Wendeborn , Katherina Misteli
IPC分类号： C11D3/26 , C11D3/395 , C11D7/32 , C11D7/54 , C07D295/15 , C11D3/39 , B01J31/02 , B01J31/18 , C11D3/28 , C11D3/32 , C11D7/34 , C11D11/02 , D06L3/02 , C11D3/34
CPC分类号： B01J31/0271 , B01J31/0202 , B01J31/0204 , B01J31/0218 , B01J31/0245 , B01J31/0247 , B01J31/18 , B01J2231/70 , B08B3/08 , C07B33/00 , C07D295/15 , C11D3/28 , C11D3/30 , C11D3/32 , C11D3/3481 , C11D3/349 , C11D3/3902 , C11D3/391 , C11D3/3917 , C11D3/392 , C11D3/3927 , C11D3/3942 , C11D3/3945 , C11D3/3947 , C11D7/3263 , C11D7/3281 , C11D7/34 , C11D11/02 , D06L4/10 , D06L4/12
摘要： The present invention relates to specific acylhydrazone compounds, their use as oxidation catalysts and to a process for removing stains and soil on textiles and hard surfaces. The compounds are substituted with a specific cyclic ammonium group adjacent to the acyl group. Further aspects of the invention are compositions or formulations comprising such compounds.
摘要翻译：本发明涉及具体的酰腙化合物，它们作为氧化催化剂的用途以及去除织物和硬表面上的污渍和污垢的方法。化合物被与酰基相邻的特定的环状铵基取代。本发明的其它方面是包含这些化合物的组合物或制剂。

8. 发明申请

US20130261041A1 BLEACH CATALYSTS 有权
标题翻译：漂白催化剂
公开(公告)号：US20130261041A1
公开(公告)日：2013-10-03
申请号：US13992888
申请日：2011-12-08
申请人： Hauke Rohwer , Barbara Wagner , Frederique Wendeborn , Katherina Misteli
发明人： Hauke Rohwer , Barbara Wagner , Frederique Wendeborn , Katherina Misteli
IPC分类号： C07D295/15 , C11D3/32
CPC分类号： B01J31/0271 , B01J31/0202 , B01J31/0204 , B01J31/0218 , B01J31/0245 , B01J31/0247 , B01J31/18 , B01J2231/70 , B08B3/08 , C07B33/00 , C07D295/15 , C11D3/28 , C11D3/30 , C11D3/32 , C11D3/3481 , C11D3/349 , C11D3/3902 , C11D3/391 , C11D3/3917 , C11D3/392 , C11D3/3927 , C11D3/3942 , C11D3/3945 , C11D3/3947 , C11D7/3263 , C11D7/3281 , C11D7/34 , C11D11/02 , D06L4/10 , D06L4/12
摘要： The present invention relates to specific acylhydrazone compounds, their use as oxidation catalysts and to a process for removing stains and soil on textiles and hard surfaces. The compounds are substituted with a specific cyclic ammonium group adjacent to the acyl group. Further aspects of the invention are compositions or formulations comprising such compounds.
摘要翻译：本发明涉及具体的酰腙化合物，它们作为氧化催化剂的用途以及去除织物和硬表面上的污渍和污垢的方法。化合物被与酰基相邻的特定的环状铵基取代。本发明的其它方面是包含这些化合物的组合物或制剂。

9. 发明授权

US07425222B2 Process for improving the sun protection factor of cellulosic fibre material 失效
标题翻译：改善纤维素纤维材料防晒系数的方法
公开(公告)号：US07425222B2
公开(公告)日：2008-09-16
申请号：US10504945
申请日：2002-02-11
申请人： Georges Metzger , Jean-Jacques Donzé , Hans Kramer , Serge Hauger , Volker Papendick , Michael Milde , Ted Deisenroth , Rainer Hans Traber , Ullrich Menge , Hauke Rohwer
发明人： Georges Metzger , Jean-Jacques Donzé , Hans Kramer , Serge Hauger , Volker Papendick , Michael Milde , Ted Deisenroth , Rainer Hans Traber , Ullrich Menge , Hauke Rohwer
IPC分类号： D06L3/12
CPC分类号： D06M13/358 , C07D251/68 , D06M2200/25
摘要： A process for improving the sun protection factor (SPF) of cellulosic fibre materials and blends thereof, which comprises contacting said materials with at least one compound of the formula (1) in which M is hydrogen, an alkali metal atom, ammonium or a cation formed from an amine; R1 and R1′ independently of each other are hydrogen, hydroxy, optionally substituted alkyl, 4-morpholinyl, —NH—R3, —N(R3)2 or —O—R3, wherein R3is optionally substituted alkyl or optionally substituted aryl, R2 is a group of formula (2) wherein X is —O— or —NH— and R4 is C1-C4-alkyl which carries at least one hydrophilic substituent and R2′ has the meaning of R1 or R2.
摘要翻译：一种用于改善纤维素纤维材料及其共混物的防晒因子（SPF）的方法，其包括使所述材料与至少一种其中M为氢的式（1）化合物，碱金属原子，铵或阳离子由胺形成; R 1和R 2彼此独立地是氢，羟基，任选取代的烷基，4-吗啉基，-NH-R 3， -N（R 3 3）2或-OR 3，其中R 3是任选取代的烷基或任选取代的芳基，R 2是式（2）的基团，其中X是-O-或-NH-，R 4是C 1 - 携带至少一个亲水取代基的C 4 - 烷基和R 2'具有R 1或R 2的含义， SUB>。

10. 发明授权

US07105479B2 Fabric rinse composition containing a benztriazole UV absorber 失效
标题翻译：含有苯并三唑UV吸收剂的织物漂洗组合物
公开(公告)号：US07105479B2
公开(公告)日：2006-09-12
申请号：US10472791
申请日：2002-03-19
申请人： Thomas Ehlis , Robert Hochberg , Hauke Rohwer
发明人： Thomas Ehlis , Robert Hochberg , Hauke Rohwer
IPC分类号： C11D3/28
CPC分类号： C11D3/42 , C11D3/0015
摘要： Disclosed is a fabric rinse composition comprising a) 0.1 to 10% by weight of a UV absorber of formula (1), wherein A is a radical of formula (1a); B is a radical of formula (1c); (1d); (1e); (1f), (1g); (1b); (1i); (1k); (1l); or (1m); R1, R2, R3, R4, R5 and R6 are each independently of the others hydrogen, C1–C18alkyl; C5–C7-cycloalkyl; halogen; R9 is hydrogen C1–C12hydroxyalkyl; or C5–C7cycloalkyl; R7, R8 and R10 are each independently of the others hydrogen, C1–C18alkyl, C5–C7cycloalkyl, C1–C12hydroxyalkyl; X is halogen; a radical of formula (1s); or (1u); sulfate, phosphate, lactate, citrate, tartrate; R11 is C1–C12alkyl; C5–C7cycloalkyl or phenyl: x is from 0 to 10; and y is from 1 to 20; b) 5 to 25% by weight, based on the total weight of the composition of a fabric softener agent; and c) the remainder being substantially water
摘要翻译：公开了一种织物漂洗组合物，其包含a）0.1至10重量％的式（1）的UV吸收剂，其中A为式（1a）的基团; B是式（1c）的基团; （1d）; （1e）; （1f），（1g）; （1b）; （1i）; （1k）; （1l）; 或（1m）; R 1，R 2，R 3，R 4，R 5和R 5， R 6各自独立地为氢，C 1 -C 18烷基; C 5 -C 7 - 环烷基; 卤素; R 9是氢C 1 -C 12羟烷基; 或C 5 -C 7环烷基; R 7，R 8和R 10各自独立地为氢，C 1 -C 3 C 18 -C 18烷基，C 5 -C 7环烷基，C 1 -C 12羟烷基，C 1 -C 12烷基， X是卤素; 式（1s）的基团; 或（1u）; 硫酸盐，磷酸盐，乳酸盐，柠檬酸盐，酒石酸盐; R 11是C 1 -C 12烷基; C 5 -C 7环烷基或苯基：x为0至10; y为1〜20; b）5至25重量％，基于织物柔软剂的组合物的总重量; 和c）其余部分基本上是水

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