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    • 7. 发明授权
    • Method and apparatus for separating C.sub.4 hydrocarbons from a gaseous
mixture
    • 从气体混合物中分离C4烃的方法和设备
    • US5329774A
    • 1994-07-19
    • US958170
    • 1992-10-08
    • Dennis C. TanguayGerard E. DupuisBao Ha
    • Dennis C. TanguayGerard E. DupuisBao Ha
    • C07C7/09F25J3/06
    • F25J3/0655C07C7/09F25J3/062F25J3/065F25J2210/12F25J2270/12F25J2270/18F25J2270/66
    • A method of and apparatus for separating C.sub.4 hydrocarbons from a feed comprising a gaseous mixture. The feed is cooled and partially condensed in a plurality of successive stages of condensation and phase separation. A gaseous overhead from each separation stage is further cooled and supplied to the next separation stage and the liquid separated from each stage is used to cool the gas. Further refrigeration is supplied to the gas to effect the condensations by indirect heat exchange with a closed cycle refrigerant subjected to a compression/expansion cycle. The feed undergoes no compression and no abrupt expansion during the separation, so that the feed undergoes a pressure decrease due only to friction of the passage of the feed through the apparatus. The pressure loss is no more than about 20 psi. The temperature of the feed is maintained below 150.degree. F. at all times, to prevent polymerization of 1,3-butadiene. A mixed refrigerant passes through the closed refrigeration cycle and contains, in decreasing order of plentitude, propane, ethylene, isopentane and nitrogen. The mixed refrigerant is subjected to a single compression followed by cooling and phase separation. The phases of the mixed refrigerant thus separated are separately cooled and expanded and the material thus produced by expansion is used to cool the feed.
    • 从包含气体混合物的进料中分离C4烃的方法和装置。 进料冷却并在多个连续阶段的冷凝和相分离中部分冷凝。 来自每个分离阶段的气体塔顶馏出物被进一步冷却并供应到下一个分离阶段,并且使用从每个阶段分离的液体来冷却气体。 通过与经受压缩/膨胀循环的封闭循环制冷剂进行间接热交换,向气体供给进一步的制冷以实现冷凝。 进料在分离期间不经受压缩而没有突然膨胀,使得进料仅由于进料通过装置的通道的摩擦而经历压力降低。 压力损失不超过约20 psi。 进料的温度始终保持在150°F以下,以防止1,3-丁二烯的聚合。 混合的制冷剂通过封闭的制冷循环,并以含量的顺序含有丙烷,乙烯,异戊烷和氮气。 混合的制冷剂经受单次压缩,然后进行冷却和相分离。 这样分离的混合制冷剂的相分别冷却和膨胀,并且通过膨胀产生的材料用于冷却进料。
    • 9. 发明授权
    • Process and installation for producing high-pressure nitrogen
    • 生产高压氮气的工艺和安装
    • US08991209B2
    • 2015-03-31
    • US12965958
    • 2010-12-13
    • Shinji TomitaKouhei NakamuraKenji HiroseJerome BeauvisageBao Ha
    • Shinji TomitaKouhei NakamuraKenji HiroseJerome BeauvisageBao Ha
    • F25J3/00F25J3/04
    • F25J3/04412F25J3/04048F25J3/0406F25J3/04212F25J3/04309F25J3/04315F25J3/04321F25J3/04333F25J3/04393F25J3/0486F25J2200/40F25J2200/54F25J2230/08F25J2235/42F25J2245/02F25J2245/42
    • A method and apparatus for producing high pressure nitrogen is provided. This system includes a first compressor for compressing air and cooling air to substantially the dew-point, a high pressure column, a medium pressure column, a conduit for introducing at least a portion of the compressed air at a base of the high pressure column; a conduit for removing a oxygen enriched liquid from the base of the high pressure column; a first valve for reducing the pressure of the oxygen enriched liquid to a medium pressure, where the medium pressure is between the high pressure and atmospheric pressure, a conduit for introducing the oxygen enriched liquid at an intermediate place of the medium pressure column; a second expander for reducing the pressure of at least a part of the liquid removed from the base of the medium pressure distillation column, to a low pressure to cool a top condenser of the medium pressure column and to form a waste vapor stream; a cold compressor for compressing a vapor stream removed form the medium pressure column, cooling the compressed vapor stream, and introducing it into the base of the high pressure column; a heat exchanger for heating the waste vapor stream, a first expander for expanding the heated stream to produce power; a conduit for withdrawing liquid from the top of the medium pressure column, pump for pumping the withdrawn liquid to high pressure and injecting it at the top of the high pressure column; and conduit for withdrawing product nitrogen from the top of the high pressure column.
    • 提供了一种生产高压氮的方法和装置。 该系统包括用于将空气和冷却空气压缩至基本露点的第一压缩机,高压塔,中压塔,用于在压力塔的底部引入至少一部分压缩空气的导管; 用于从高压塔的底部除去富氧液体的管道; 第一阀,用于将富氧液体的压力降低到介质压力介于高压和大气压之间的介质压力,用于将富氧液体引入中压塔的中间位置的导管; 第二膨胀机,用于将从中压蒸馏塔底部排出的至少一部分液体的压力降低到低压以冷却中压塔的顶部冷凝器并形成废蒸气流; 用于压缩从中压塔除去的蒸气流的冷压缩机,冷却压缩的蒸气流,并将其引入高压塔的底部; 用于加热废蒸汽流的热交换器,用于膨胀加热的流以产生动力的第一膨胀器; 用于从中压塔的顶部抽出液体的管道,用于将排出的液体泵送到高压并将其注入高压塔顶部的泵; 以及用于从高压塔的顶部排出产品氮的管道。