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1. 发明申请

WO2002096837A3 FISCHER-TROPSCH PROCESS 审中-公开
公开(公告)号：WO2002096837A3
公开(公告)日：2002-12-05
申请号：PCT/GB2002/002332
申请日：2002-05-17
申请人： BP EXPLORATION OPERATING COMPANY LIMITED , DAVY PROCESS TECHNOLOGY LIMITED , FONT FREIDE, Josephus, Johannes, Helena, Maria , HENSMAN, John, Richard , NEWTON, David , SHARP, Christopher , SMITH, Geoffrey, Benedict
发明人： FONT FREIDE, Josephus, Johannes, Helena, Maria , HENSMAN, John, Richard , NEWTON, David , SHARP, Christopher , SMITH, Geoffrey, Benedict
IPC分类号： C10G2/00
摘要： A process for the conversion of synthesis gas to hydrocarbons by contacting the synthesis gas at an elevated temperature and pressure with a suspension comprising a solid particulate catalyst suspended in a liquid medium, which contacting takes place in a system comprising at least one high shear mixing zone and a reactor vessel wherein the volume of suspension present in the high shear mixing zone(s) is substantially less than the volume of suspension present in the reactor vessel, suspension is mixed with synthesis gas in the high shear mixing zone(s), the resulting mixture of suspension and synthesis gas is discharged from the high shear mixing zone(s) into the reactor vessel and wherein kinetic energy is dissipated to the suspension present in the high shear mixing zone(s) at a rate of at least 0.5 kW/m 3 relative to the total volume of suspension present in the system.

2. 发明申请

WO2002096838A1 FISCHER-TROPSCH SYNTHESIS PROCESS CARRIED OUT ON A FLOATABLE STRUCTURE 审中-公开
标题翻译： FISCHER-TROPSCH合成工艺在可浮动结构上
公开(公告)号：WO2002096838A1
公开(公告)日：2002-12-05
申请号：PCT/GB2002/002266
申请日：2002-05-17
申请人： BP EXPLORATION OPERATING COMPANY LIMITED , DAVY PROCESS TECHNOLOGY LIMITED , FONT FREIDE, Josephus, Johannes, Helena, Maria , HENSMAN, John, Richard , NEWTON, David
发明人： FONT FREIDE, Josephus, Johannes, Helena, Maria , HENSMAN, John, Richard , NEWTON, David
IPC分类号： C07C1/06
CPC分类号： C10G2/342 , B01J8/22 , B01J19/26 , B01J2219/00006 , B63B35/44 , B63B2035/4473 , C10G2300/1025 , C10G2300/202 , C10G2300/4068 , C10G2300/4081 , C10G2300/44
摘要： A process for the conversion of natural gas to higher hydrocarbons in a system comprising (1) a synthesis gas production unit and (2) a Fischer-Tropsch synthesis unit comprising at least one high shear mixing zone and a reactor vessel wherein the units are located aboard a floatable structure, and the process comprises the steps of: (a) converting the natural gas to synthesis gas in the synthesis gas production unit; (b) converting the synthesis gas to higher hydrocarbons, at an elevated temperature and pressure, in the Fischer-Tropsch synthesis unit by (i) passing synthesis gas and a suspension comprising a particulate Fischer-Tropsch catalyst suspended in a liquid medium through the high shear mixing zone(s) wherein the synthesis gas is broken down into gas bubbles and/or irregularly shaped gas voids which are dispersed in the suspension, and (ii) discharging suspension containing the dispersed gas bubbles and/or irregularly shaped gas voids from the high shear mixing zone(s) into the reactor vessel.
摘要翻译：一种在系统中将天然气转化为高级烃的方法，包括（1）合成气生产单元和（2）包含至少一个高剪切混合区和反应器容器的费 - 托合成单元，其中所述单元位于该方法包括以下步骤：（a）将天然气转化为合成气生产单元中的合成气; （b）在费 - 托合成单元中，通过（i）将合成气和悬浮在液体介质中的微量费 - 托催化剂的悬浮液通过高温将合成气转化为高级烃，剪切混合区，其中合成气被分解成分散在悬浮液中的气泡和/或不规则形状的气体空隙，和（ii）将含有分散的气泡和/或不规则形状的气体空隙的悬浮液从高剪切混合区进入反应器容器。

3. 发明申请

WO2003040262A3 OLEFINS PRODUCTION PROCESS 审中-公开
公开(公告)号：WO2003040262A3
公开(公告)日：2003-05-15
申请号：PCT/GB2002/005005
申请日：2002-11-05
申请人： BP EXPLORATION OPERATING COMPANY LIMITED , FONT FREIDE, Josephus, Johannes, Helena, Maria
发明人： FONT FREIDE, Josephus, Johannes, Helena, Maria
IPC分类号： C10G9/00
摘要： The present invention provides a process for the production of olefins wherein a synthetic naphtha is passed to a steam cracker. The synthetic naphtha is derived from the fractionation of a Fischer-Tropsch product stream. The Fischer-Tropsch product stream may be separated into a lighter fraction and a heavy fraction and the heavy fraction may be hydrotreated prior to fractionation. Optionally the synthetic naphtha may be hydrogenated to produce a saturated synthetic naphtha which can then be subsequently passed to the steam cracker.

4. 发明申请

WO2002097011A2 FISCHER-TROPSCH PROCESS 审中-公开
标题翻译： FISCHER-TROPSCH过程
公开(公告)号：WO2002097011A2
公开(公告)日：2002-12-05
申请号：PCT/GB2002/002328
申请日：2002-05-17
申请人： BP EXPLORATION OPERATING COMPANY LIMITED , DAVY PROCESS TECHNOLOGY LIMITED , FONT FREIDE, Josephus, Johannes, Helena, Maria , NAY, Barry , SHARP, Christopher
发明人： FONT FREIDE, Josephus, Johannes, Helena, Maria , NAY, Barry , SHARP, Christopher
IPC分类号： C10G2/00
CPC分类号： C10G2/332 , C10G2/342
摘要： A process which comprises contacting a gaseous reactant stream comprising synthesis gas at elevated temperature and pressure with a suspension of a particulate Fischer-Tropsch catalyst comprising cobalt in a liquid medium in a reactor system comprising at least one high shear mixing zone and a reactor vessel wherein the process comprises the steps of: a) contacting the particulate Fischer-Tropsch catalyst with a reducing gas at elevated temperature and pressure outside of the high shear mixing zone(s) and the reactor vessel and subsequently suspending the particulate Fischer-Tropsch catalyst in the liquid medium; b) passing the suspension from step a) through the high shear mixing zone(s) where the gaseous reactant stream comprising synthesis gas is mixed with the suspension; c) discharging a mixture comprising the synthesis gas and the suspension from the high shear mixing zone(s) into the reactor vessel; and d) converting the synthesis gas to liquid hydrocarbons in the reactor vessel to form a product suspension comprising the particulate Fischer-Tropsch catalyst suspended in the liquid medium and liquid hydrocarbons.
摘要翻译：一种方法，其包括使包含合成气体的气态反应物流在升高的温度和压力下与包含钴的微粒费 - 托催化剂的悬浮液在包含至少一个高剪切混合区和反应器容器的反应器系统中的液体介质中接触，该方法包括以下步骤：a）在高剪切混合区和反应器容器外的升高的温度和压力下使微量费 - 托催化剂与还原气体接触，随后将颗粒状费 - 托催化剂悬浮在液体介质; b）将来自步骤a）的悬浮液通过高剪切混合区，其中包含合成气的气态反应物流与悬浮液混合; c）将包含合成气和悬浮液的混合物从高剪切混合区排出到反应器容器中; 和d）将合成气转化为反应器容器中的液体烃，以形成悬浮在液体介质中的包含微量费 - 托催化剂和液体烃的产物悬浮液。

5. 发明申请

WO2002096834A2 FISCHER-TROPSCH PROCESS 审中-公开
标题翻译： FISCHER-TROPSCH过程
公开(公告)号：WO2002096834A2
公开(公告)日：2002-12-05
申请号：PCT/GB2002/002267
申请日：2002-05-17
申请人： BP EXPLORATION OPERATING COMPANY LIMITED , DAVY PROCESS TECHNOLOGY LIMITED , FONT FREIDE, Josephus, Johannes, Helena, Maria
发明人： FONT FREIDE, Josephus, Johannes, Helena, Maria
IPC分类号： C07C1/00
CPC分类号： C10G2/34 , B01J8/228 , B01J2208/00274 , B01J2208/003 , B01J2208/00637
摘要： A method of starting up a Fischer-Tropsch reaction in a system comprising at least one high shear mixing zone and a reactor vessel which method comprises a) passing a suspension of a particulate Fischer-Tropsch catalyst in a liquid medium through the high shear mixing zone(s) into the reactor vessel and recycling at least a portion of the suspension to the high shear mixing zone(s) in the substantial absence of a gaseous reactant feed stream comprising synthesis gas; b) increasing the temperature and/or pressure within the reactor vessel until a threshold temperature and/or pressure is reached and subsequently introducing a gaseous reactant stream comprising synthesis gas into the high shear mixing zone(s) where the gaseous reactant stream is mixed with the suspension; c) discharging a mixture comprising synthesis gas and the suspension from the high shear mixing zone(s) into the reactor vessel; d) converting the synthesis gas to liquid hydrocarbons in the reactor vessel to form a product suspension comprising the particulate Fischer-Tropsh catalyst suspended in the liquid medium and liquid hydrocarbons; and e) recycling at least a portion of the product suspension to the high shear mixing zone(s).
摘要翻译：一种在包括至少一个高剪切混合区和反应器容器的系统中启动费 - 托反应的方法，该方法包括：a）使液体介质中的微量费 - 托催化剂的悬浮液通过高剪切混合区并将基本上不含有合成气的气态反应物进料流的至少一部分悬浮液再循环到高剪切混合区; b）增加反应器容器内的温度和/或压力，直到达到阈值温度和/或压力，随后将包含合成气体的气态反应物流引入高剪切混合区，其中气态反应物流与暂停; c）将包含合成气的混合物和悬浮液从高剪切混合区排出到反应器容器中; d）将合成气转化成反应器容器中的液体烃，以形成悬浮在液体介质中的悬浮在液体介质中的颗粒状费 - 托普催化剂和液体烃的产物悬浮液; 和e）将至少一部分产物悬浮液再循环到高剪切混合区。

6. 发明申请

WO2006087522A2 MODIFIED CATALYST AND USE OF THIS CATALYST FOR THE CONVERSION OF SYNTHESIS GAS TO HYDROCARBONS 审中-公开
标题翻译：改性催化剂和该催化剂用于将合成气转化为烃类的用途
公开(公告)号：WO2006087522A2
公开(公告)日：2006-08-24
申请号：PCT/GB2006/000453
申请日：2006-02-09
申请人： BP EXPLORATION OPERATING COMPANY LIMITED , DAVY PROCESS TECHNOLOGY LIMITED , FONT FREIDE, Josephus, Johannes, Helena, Maria , HARDY, Lawrence, Trevor
发明人： FONT FREIDE, Josephus, Johannes, Helena, Maria , HARDY, Lawrence, Trevor
CPC分类号： B01J31/0275 , B01J23/462 , B01J23/74 , B01J23/75 , B01J23/8913 , B01J31/0231 , B01J31/0247 , B01J31/0274 , B01J33/00 , B01J35/023 , B01J37/0203 , B01J37/0205 , B01J2231/648 , C10G2/33 , C10G2/332 , C10G2/333
摘要： The present invention relates to a process for the conversion of synthesis gas to hydrocarbons in the presence of a modified supported Fischer-Tropsch catalyst composition.
摘要翻译：本发明涉及在改性的载体费 - 托催化剂组合物存在下将合成气转化为烃的方法。

7. 发明申请

WO2003040262A2 OLEFINS PRODUCTION PROCESS 审中-公开
标题翻译： OLEFINS生产过程
公开(公告)号：WO2003040262A2
公开(公告)日：2003-05-15
申请号：PCT/GB2002/005005
申请日：2002-11-05
申请人： BP EXPLORATION OPERATING COMPANY LIMITED , FONT FREIDE, Josephus, Johannes, Helena, Maria
发明人： FONT FREIDE, Josephus, Johannes, Helena, Maria
IPC分类号： C10G
CPC分类号： C10G2/32 , C10G2400/20 , Y10S208/95
摘要： The present invention provides a process for the production of olefins wherein a synthetic naphtha is passed to a steam cracker. The synthetic naphtha is derived from the fractionation of a Fischer-Tropsch product stream. The Fischer-Tropsch product stream may be separated into a lighter fraction and a heavy fraction and the heavy fraction may be hydrotreated prior to fractionation. Optionally the synthetic naphtha may be hydrogenated to produce a saturated synthetic naphtha which can then be subsequently passed to the steam cracker.
摘要翻译：本发明提供一种生产烯烃的方法，其中将合成石脑油通入蒸汽裂化器。合成石脑油衍生自费 - 托产物流的分馏。费 - 托产物流可以分离成轻馏分和重馏分，重馏分可以在分馏之前进行加氢处理。任选地，合成石脑油可以被氢化以产生饱和的合成石脑油，然后可以随后将其加入到蒸汽裂化器中。

8. 发明申请

WO2002097009A2 FISCHER-TROPSCH PROCESS 审中-公开
标题翻译： FISCHER-TROPSCH过程
公开(公告)号：WO2002097009A2
公开(公告)日：2002-12-05
申请号：PCT/GB2002/002314
申请日：2002-05-17
申请人： BP EXPLORATION OPERATING COMPANY LIMITED , DAVY PROCESS TECHNOLOGY LIMITED , FONT FREIDE, Josephus, Johannes, Helena, Maria , LENG, Stephen, Anthony , GRIFFITHS, David, Charles
发明人： FONT FREIDE, Josephus, Johannes, Helena, Maria , LENG, Stephen, Anthony , GRIFFITHS, David, Charles
IPC分类号： C10G2/00
CPC分类号： C10G2/332 , B01J8/222 , C10G2/342
摘要： A process for the conversion of synthesis gas to a product comprising liquid hydrocarbons and oxygenates wherein said process comprises contacting synthesis gas at an elevated temperature and pressure with a mixed particulate catalyst comprising a mixture of a particulate Fischer-Tropsch catalyst and a particulate oxygenate synthesis catalyst.
摘要翻译：一种用于将合成气转化为包含液体烃和含氧化合物的产物的方法，其中所述方法包括在升高的温度和压力下将合成气与混合颗粒催化剂接触，所述混合颗粒催化剂包含微量的费 - 托催化剂和颗粒氧化合物催化剂的混合物。

9. 发明申请

WO2002096839A1 FISCHER-TROPSCH PROCESS 审中-公开
标题翻译： FISCHER-TROPSCH过程
公开(公告)号：WO2002096839A1
公开(公告)日：2002-12-05
申请号：PCT/GB2002/002310
申请日：2002-05-17
申请人： BP EXPLORATION OPERAING COMPANY LIMITED , DAVY PROCESS TECHNOLOGY LIMITED , FONT FREIDE, Josephus, Johannes, Helena, Maria , LENG, Stephen, Anthony , SHARP, Christopher
发明人： FONT FREIDE, Josephus, Johannes, Helena, Maria , LENG, Stephen, Anthony , SHARP, Christopher
IPC分类号： C07C1/06
CPC分类号： C07C1/06 , B01J8/228 , B01J19/26 , B01J23/80 , B01J2208/00256 , B01J2208/00274 , B01J2208/00283 , B01J2208/003 , B01J2208/00398 , B01J2208/00415 , B01J2219/00006 , B01J2219/185 , B01J2219/1943 , C07C2523/80 , C10G2/32 , C10G2300/1022 , C10G2300/4081 , C07C9/02
摘要： The present invention provides a process for the conversion of synthesis gas to hydrocarbons comprising the steps of: a) contacting synthesis gas at an elevated temperature and pressure with a particulate Fischer-Tropsch catalyst in a Fischer-Tropsch reactor system to generate hydrocarbons comprising gaseous and liquid hydrocarbons; b) in a gas separation zone, separating a gaseous phase comprising saturated gaseous hydrocarbons from a liquid phase comprising liquid hydrocarbons and from the particulate Fischer-Tropsch catalyst; c) passing at least a portion of the separated gaseous phase to a dehydrogenation reactor where at least a portion of the saturated gaseous hydrocarbons are converted to unsaturated hydrocarbons; and d) recycling at least a portion of said unsaturated hydrocarbons back to the Fischer-Tropsch reactor system.
摘要翻译：本发明提供了一种将合成气转化为烃的方法，包括以下步骤：a）在费 - 托反应器系统中将高温和高压的合成气与微量费 - 托催化剂接触以产生包含气态和液态烃; b）在气体分离区中，从包含液体烃的液相和来自微量费 - 托催化剂的液相中分离包含饱和气态烃的气相; c）将至少一部分分离的气相通入脱氢反应器，其中至少一部分饱和气态烃转化为不饱和烃; 和d）将至少一部分所述不饱和烃再循环回费 - 托反应器系统。

10. 发明授权

EP1392622B1 FISCHER-TROPSCH PROCESS 有权
标题翻译： FISCHER TROPSCHVERFAHREN
公开(公告)号：EP1392622B1
公开(公告)日：2005-01-12
申请号：EP02730434.4
申请日：2002-05-17
申请人： BP EXPLORATION OPERATING COMPANY LIMITED , Davy Process Technology Limited
发明人： FONT FREIDE, Josephus, Johannes, Helena, Maria , HENSMAN, John, Richard , NEWTON, David , SHARP, Christopher , SMITH, Geoffrey, Benedict
IPC分类号： C07C1/00
CPC分类号： C10G2/342 , B01J8/228 , B01J2208/00132 , B01J2208/00256 , B01J2208/003 , C07C1/0485
摘要： A process for the conversion of synthesis gas to hydrocarbons by contacting the synthesis gas at an elevated temperature and pressure with a suspension comprising a solid particulate catalyst suspended in a liquid medium, which contacting takes place in a system comprising at least one high shear mixing zone and a reactor vessel wherein the volume of suspension present in the high shear mixing zone(s) is substantially less than the volume of suspension present in the reactor vessel, suspension is mixed with synthesis gas in the high shear mixing zone(s), the resulting mixture of suspension and synthesis gas is discharged from the high shear mixing zone(s) into the reactor vessel and wherein kinetic energy is dissipated to the suspension present in the high shear mixing zone(s) at a rate of at least 0.5 kW/m3 relative to the total volume of suspension present in the system.

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