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1. 发明申请

WO2004108639A1 A CATALYST COMPRISING A METALIC SUPPORT AND A PROCESS FOR THE PRODUCTION OF OLEFINS 审中-公开
标题翻译：包含金属支持的催化剂和生产烯烃的方法
公开(公告)号：WO2004108639A1
公开(公告)日：2004-12-16
申请号：PCT/GB2004/002140
申请日：2004-05-18
申请人： BP CHEMICALS LIMITED , LITTLE, Ian, Raymond , REID, Ian, Allan, Beattie , WILLIAMS, Vaughan, Clifford
发明人： LITTLE, Ian, Raymond , REID, Ian, Allan, Beattie , WILLIAMS, Vaughan, Clifford
IPC分类号： C07C11/02
CPC分类号： C07C5/48 , B01J23/56 , B01J23/8926 , B01J37/0205 , B01J37/0225 , C07C2521/02 , C07C2521/04 , C07C2523/10 , C07C2523/42 , C07C2523/72 , C07C2523/745 , C07C2523/75 , C07C2523/755 , C07C2523/86 , C07C2523/89 , Y02P20/52 , C07C11/02 , C07C11/04
摘要： A catalyst capable of supporting combustion beyond the fuel rich Iii-nit of flammability comprising a catalytic component and a metallic support wherein the support is a metallic structured packing comprising a multiplicity of open-ended channels and which has been loaded with a non metallic coating, and a process for the production of an olefin, said process comprising passing a mixture of a hydrocarbon and an oxygen-containing gas over said catalyst to produce an olefin.
摘要翻译：一种催化剂，其能够支持超过富含燃料的燃料的燃烧，其包含催化组分和金属载体，其中所述载体是包含多个开放式通道并且已经装载有非金属涂层的金属规整填料，以及一种生产烯烃的方法，所述方法包括使烃和含氧气体的混合物在所述催化剂上通过以产生烯烃。

2. 发明申请

WO2004054945A1 PROCESS FOR THE PRODUCTION OF OLEFINS 审中-公开
标题翻译：生产烯烃的方法
公开(公告)号：WO2004054945A1
公开(公告)日：2004-07-01
申请号：PCT/GB2003/004993
申请日：2003-11-18
申请人： BP CHEMICALS LIMITED , LITTLE, Ian, Raymond , REID, Ian, Allan, Beattie
发明人： LITTLE, Ian, Raymond , REID, Ian, Allan, Beattie
IPC分类号： C07C5/48
CPC分类号： C10G11/22 , C07C5/48 , C07C11/02
摘要： A process for the production of olefins from a hydrocarbon comprising the steps of: a) passing a first feed stream comprising gaseous reactants to a first reaction zone wherein said gaseous reactants react exothermically to provide a product stream b) producing a mixed feed stream comprising oxygen by passing the product stream produced in step (a) and a second feed stream comprising a hydrocarbon feedstock to a mixing zone, oxygen being passed to the mixing zone via (i) the product stream produced in step (a), (ii) the second feed stream comprising a hydrocarbon feedstock and/or (iii) a third stream comprising an oxygen-containing gas c) passing the mixed feed stream directly to an essentially adiabatic second reaction zone wherein in the absence of a supported platinum group metal catalyst at least a part of the oxygen is consumed and a stream comprising olefins is produced e) cooling the stream comprising olefins exiting the second reaction zone to less than 650°C within less than 150 milliseconds of formation and wherein the temperature of the mixed stream is at least 500°C, the mixing zone and the second reaction zone are maintained at a pressure of between 1.5-50 bar and the residence time within the mixing zone is less than the autoignition delay for the mixed stream.
摘要翻译：一种从烃生产烯烃的方法，包括以下步骤：a）将包含气态反应物的第一进料流送至第一反应区，其中所述气态反应物放热反应以提供产物流b）产生包含氧的混合进料流通过将步骤（a）中产生的产物流和包含烃原料的第二进料流传送到混合区，将氧气通过（i）步骤（a）中产生的产物流传递到混合区，（ii）包含烃原料的第二进料流和/或（iii）包含含氧气体的第三料流c）将混合进料流直接传递到基本绝热的第二反应区，其中在不存在负载的铂族金属催化剂的情况下至少氧气的一部分被消耗，并且产生包含烯烃的料流e）将包含离开第二反应区的烯烃的料流冷却至低于650℃的小于 150毫秒的形成，其中混合物流的温度为至少500℃，混合区和第二反应区保持在1.5-50巴之间的压力，混合区内的停留时间小于混合流的自动延迟。

3. 发明申请

WO2003086607A1 SUPPORT GRID 审中-公开
标题翻译：支持网
公开(公告)号：WO2003086607A1
公开(公告)日：2003-10-23
申请号：PCT/GB2003/001423
申请日：2003-04-01
申请人： BP CHEMICALS LIMITED , COLMAN, Derek, Alan , HESKETH, Trevor, John , REID, Ian, Allan, Beattie
发明人： COLMAN, Derek, Alan , HESKETH, Trevor, John , REID, Ian, Allan, Beattie
IPC分类号： B01J8/00
CPC分类号： B01J8/008 , B01J2208/00884
摘要： The present invention provides a support grid having the form of a web of vertically disposed plates said web of plates comprising (a) a network of strands of plate segments connected by junctions, the said strands terminating only at the periphery of the grid, and (b) one or more internal plate branches, each plate segment being joined at one end to a junction with at least two other plate segments and at the other end either being joined to a junction with at least two other plate segments or terminating at or near the periphery of the grid, said internal branch comprising a plate having a free end within the grid and being joined at one end thereof to a segment or to another branch, characterised in that in horizontal cross-section through the grid each segment has at least two angular and/or curved portions which alternate in direction.
摘要翻译：本发明提供了一种具有垂直设置板的腹板形式的支撑格栅，所述板的腹板包括（a）由连接点连接的板段的网状网，所述线仅在网格的外围终止，并且（ b）一个或多个内部板分支，每个板段在一端连接到与至少两个其它板段的连接处，并且在另一端连接到与至少两个其他板段的连接处或终止于或接近所述内部分支包括板，所述板在所述格栅内具有自由端并且在其一端处连接到一段或另一分支，其特征在于，在通过所述格栅的水平横截面中，每个段至少具有在方向上交替的两个角和/或弯曲部分。

4. 发明申请

WO2004074222A1 AUTO THERMAL CRACKING REACTOR 审中-公开
标题翻译：自动热裂解反应器
公开(公告)号：WO2004074222A1
公开(公告)日：2004-09-02
申请号：PCT/GB2004/000488
申请日：2004-02-06
申请人： BP CHEMICALS LIMITED , COLMAN, Derek, Alan , MATTHEWMAN, Michael, John, Alexander , REID, Ian, Allan, Beattie , WILLIAMS, Vaughan, Clifford , WOODFIN, William, Terence
发明人： COLMAN, Derek, Alan , MATTHEWMAN, Michael, John, Alexander , REID, Ian, Allan, Beattie , WILLIAMS, Vaughan, Clifford , WOODFIN, William, Terence
IPC分类号： C07C5/48
CPC分类号： B01J8/0453 , B01J8/0492 , B01J8/0496 , B01J2208/00522 , B01J2219/00094 , B01J2219/00265 , C07C5/48
摘要： The present invention provides a reactor design that enables an auto-thermal cracking process to be conducted at any suitable pressure wherein the gaseous reactants are preheated separately before mixing and then presented to the reaction zone in a uniformly distributed manner. In particular, the present - invention-relates to apparatus - for reacting a first and second gaseous reactant to form a gaseous product wherein the apparatus comprises at least one first supply means for the first gaseous reactant, at least one second supply means for the second gaseous reactant, a resistance zone and a reaction zone, preferably comprising a catalyst, wherein the first supply means comprises a plurality of first outlets for delivery of the first gaseous reactant, and the second supply means comprises a plurality of second outlets for delivery of the second gaseous reactant, the resistance zone is porous, the reaction zone is positioned downstream of the resistance zone with respect to the flow of the first and second gaseous reactants and wherein the first supply means and the second supply means are arranged such that the first gas and the second gas are contacted in an essentially parallel manner and mixed prior to contacting the resistance zone. The present invention also provides a process for the production of a mono-olefin utilizing said apparatus.
摘要翻译：本发明提供一种反应器设计，使得能够在任何合适的压力下进行自热裂解过程，其中气态反应物在混合之前分别预热，然后以均匀分布的方式呈现给反应区。特别地，本发明涉及用于使第一和第二气态反应物反应以形成气态产物的装置，其中所述装置包括用于第一气态反应物的至少一个第一供应装置，至少一个第二供应源用于第二气态反应物，电阻区和反应区的装置，优选包含催化剂，其中第一供应装置包括多个用于输送第一气态反应物的第一出口，第二供料装置包括多个第二出口为了输送第二气态反应物，电阻区是多孔的，反应区相对于第一和第二气态反应物的流动位于电阻区的下游，并且其中第一供给装置和第二供应装置被布置成第一气体和第二气体以基本平行的方式接触并在接触阻力区之前混合。本发明还提供了利用所述装置生产单烯烃的方法。

5. 发明申请

WO2004108279A1 CATALYST AND PROCESS FOR THE PRODUCTION OF OLEFINS 审中-公开
标题翻译：催化剂和生产烯烃的方法
公开(公告)号：WO2004108279A1
公开(公告)日：2004-12-16
申请号：PCT/GB2004/002132
申请日：2004-05-18
申请人： BP CHEMICALS LIMITED , REID, Ian, Allan, Beattie , WILLIAMS, Vaughan, Clifford
发明人： REID, Ian, Allan, Beattie , WILLIAMS, Vaughan, Clifford
IPC分类号： B01J23/56
CPC分类号： B01J35/04 , B01J23/56 , B01J23/92 , C07C5/48 , C10G2400/20 , Y02P20/584 , C07C11/02
摘要： A catalyst system capable of supporting combustion beyond the fuel rich limit of flammability comprising a catalytic component, a first support and a second support and wherein the catalytic component is present on both the first and the second support, and a process for the production of an olefin, said process comprising passing a mixture of a hydrocarbon and an oxygen-containing gas over said catalyst system to produce said olefin. The first support and the second support must differ in at least one of the following aspects: support material, support type and/or structural dimension.
摘要翻译：一种催化剂体系，其能够支持超过燃料富含燃烧极限的燃烧，其包括催化组分，第一载体和第二载体，并且其中所述催化组分存在于所述第一和第二载体上，以及用于生产所述方法包括使烃和含氧气体的混合物在所述催化剂体系上通过以产生所述烯烃。以下至少一个方面，第一个支撑和第二个支撑必须不同：支撑材料，支撑类型和/或结构尺寸。

6. 发明申请

WO2006117509A1 PROCESS FOR THE PRODUCTION OF OLEFINS BY AUTOTHERMAL CRACKING 审中-公开
标题翻译：通过自动破碎生产烯烃的方法
公开(公告)号：WO2006117509A1
公开(公告)日：2006-11-09
申请号：PCT/GB2006/001449
申请日：2006-04-20
申请人： INEOS EUROPE LIMITED , MESSENGER, Brian, Edward , REID, Ian, Allan, Beattie
发明人： MESSENGER, Brian, Edward , REID, Ian, Allan, Beattie
IPC分类号： C07C5/48 , C07C11/04 , C10G47/14
CPC分类号： C07C4/025 , C07C5/48 , C07C2521/04 , C07C2523/42 , C07C2523/44 , C10G2400/20 , C07C11/04
摘要： The present invention relates to a process for the production of an olefin, said process comprising passing a feedstream which comprises a paraffinic hydrocarbon, hydrogen and an oxygen-containing gas through a catalyst zone which is capable of supporting combustion beyond the fuel rich limit of flammability to produce said olefin, said catalyst zone comprising at least a first catalyst bed which comprises platinum and palladium and wherein the feedstream comprises at least 0.5% by volume of the total feedstream of carbon monoxide.
摘要翻译：本发明涉及一种生产烯烃的方法，所述方法包括将包含链烷烃，氢和含氧气体的进料流通过催化剂区域，所述催化剂区域能够支持超出燃料浓度极限的燃烧性所述催化剂区包含至少一个包含铂和钯的第一催化剂床，并且其中所述原料流包含至少0.5体积％的一氧化碳的总进料流量。

7. 发明申请

WO2006077370A1 PROCESS FOR THE PRODUCTION OF OLEFINS BY AUTOTHERMAL CRACKING 审中-公开
标题翻译：通过自动破碎生产烯烃的方法
公开(公告)号：WO2006077370A1
公开(公告)日：2006-07-27
申请号：PCT/GB2005/005048
申请日：2005-12-22
申请人： INNOVENE EUROPE LIMITED , BURNS, Andrew, Lindsay , REID, Ian, Allan, Beattie
发明人： BURNS, Andrew, Lindsay , REID, Ian, Allan, Beattie
IPC分类号： C10G11/20 , C07C5/48
CPC分类号： C10G27/04 , B01J23/40 , B01J23/56 , B01J23/62 , B01J23/74 , B01J23/76 , B01J23/89 , B01J35/04 , C07C4/06 , C07C2523/42 , C10G11/20 , C10G2400/20 , C07C11/02
摘要： The present invention provides a process for the production of olefins by autothermal cracking of a liquid paraffinic hydrocarbon-containing feedstock in the presence of a molecular oxygen-containing gas, wherein said process comprises (a) providing a liquid paraffinic hydrocarbon-containing feedstock, (b) mixing said liquid paraffinic hydrocarbon-containing feedstock with a diluent comprising steam, said diluent being pre-heated to a temperature of at least 300°C, to produce a vaporised diluted liquid paraffinic hydrocarbon-containing feedstream comprising at least 20% by volume of steam, (c) subsequently mixing said vaporised diluted liquid paraffinic hydrocarbon-containing feedstream with a molecular oxygen-containing gas to produce a diluted mixed feedstream, (d) subsequently contacting said diluted mixed feedstream with a catalyst capable of supporting combustion beyond the normal fuel rich limit of flammability, to provide a hydrocarbon product stream comprising olefins.
摘要翻译：本发明提供了一种在含分子氧的气体存在下通过含液态含链烃烃原料的自热裂解生产烯烃的方法，其中所述方法包括（a）提供含液体链烷烃的原料（ b）将含有液体链烷烃的原料与包含蒸汽的稀释剂混合，将所述稀释剂预加热到至少300℃的温度，以产生包含至少20体积％的蒸发的稀释液体含链烷烃的进料流的蒸汽，（c）随后将所述蒸发的稀释液体含链烷烃的进料流与含分子氧的气体混合以产生稀释的混合进料流，（d）随后使所述稀释的混合进料流与能够支持燃烧超过常规的催化剂接触燃料丰富的可燃性极限，以提供包含烯烃的烃产物流。

8. 发明申请

WO2008009876A2 APPARATUS AND PROCESS FOR THE PRODUCTION OF OLEFINS 审中-公开
标题翻译：装置和生产烯烃的方法
公开(公告)号：WO2008009876A2
公开(公告)日：2008-01-24
申请号：PCT/GB2007/002191
申请日：2007-06-12
申请人： INEOS EUROPE LIMITED , COLMAN, Derek, Alan , HESKETH, Trevor, John , REID, Ian, Allan, Beattie , WILSON, David, Charles
发明人： COLMAN, Derek, Alan , HESKETH, Trevor, John , REID, Ian, Allan, Beattie , WILSON, David, Charles
IPC分类号： B01J8/02 , C10G11/22 , F28F27/02
CPC分类号： F28F9/0265 , B01J8/0285 , B01J2208/0053 , B01J2219/00006 , B01J2219/00081 , C10G11/22 , F28D7/163 , F28D2021/0075
摘要： The present invention relates to an apparatus for reacting a first gaseous reactant stream with a second gaseous reactant stream to form a gaseous product stream, wherein the apparatus comprises at least one first supply means for the first gaseous reactant stream, at least one second supply means for the second gaseous reactant stream, a catalyst zone, a product quench zone and a waste heat boiler, wherein the product quench zone is positioned downstream of the catalyst zone and comprises a plurality of quench tubes, and wherein the waste heat boiler is positioned downstream of the exits of the quench tubes and comprises a plurality of boiler tubes, the waste heat boiler having a surface on which gas exiting the exits of the quench tubes impinges.
摘要翻译：本发明涉及一种用于使第一气态反应物流与第二气态反应物流反应以形成气态产物流的设备，其中该设备包括至少一个用于第一气态反应物的第一供给装置至少一个用于第二气体反应物流的第二供给装置，催化剂区，产物骤冷区和废热锅炉，其中产物骤冷区位于催化剂区的下游并且包括多个骤冷管，以及其中所述废热锅炉位于所述骤冷管的出口的下游并且包括多个锅炉管，所述废热锅炉具有表面，在所述表面上离开所述骤冷管的出口的气体撞击到所述表面上。

9. 发明申请

WO2007071925A1 CATALYST HOLDER, APPARATUS CONTAINING IT AND PROCESS FOR THE REACTION OF AN HYDROCARBON WITH OXYGEN 审中-公开
标题翻译：催化剂容器，含有与氧气反应的方法的装置
公开(公告)号：WO2007071925A1
公开(公告)日：2007-06-28
申请号：PCT/GB2006/004642
申请日：2006-12-12
申请人： INEOS EUROPE LIMITED , COLMAN, Derek, Alan , HESKETH, Trevor, John , REID, Ian, Allan, Beattie , WILSON, David, Charles
发明人： COLMAN, Derek, Alan , HESKETH, Trevor, John , REID, Ian, Allan, Beattie , WILSON, David, Charles
IPC分类号： B01J8/02
CPC分类号： B01J8/008 , B01J8/0242 , B01J8/0285 , B01J23/622 , B01J23/8926 , B01J23/8966 , B01J2208/00194 , B01J2208/00212 , B01J2208/00522 , B01J2208/00814 , B01J2208/00884
摘要： The present invention relates to a catalyst holder, and in particular to a catalyst holder for a catalyst for the reaction of a hydrocarbon with oxygen, wherein the catalyst holder comprises: (i) a first part which is adapted to provide a sealing engagement between the catalyst holder and a source of reactants, (ii) a second part, downstream of the first part as defined with respect to a flow of reactants, and (iii) a third part, downstream of the first and second parts as defined with respect to a flow of reactants and which is adapted to house the catalyst bed, the catalyst holder having a wall which defines the internal cross-sections of the first, second and third parts and extends from the first part to the third part, and wherein the wall of the second part has an average thickness narrower than the average wall thickness of the third part.
摘要翻译：本发明涉及一种催化剂保持器，特别涉及一种用于使烃与氧气反应的催化剂的催化剂保持器，其中催化剂保持器包括：（i）第一部分，其适于提供密封接合催化剂保持器和反应物源，（ii）相对于反应物流定义的第一部分的下游的第二部分，以及（iii）第一部分和第二部分的下游第三部分，如关于反应物流并且适于容纳催化剂床，催化剂保持器具有限定第一，第二和第三部分的内部横截面并从第一部分延伸到第三部分的壁，并且其中壁的第二部分的平均厚度比第三部分的平均壁厚窄。

10. 发明申请

WO2006077368A1 PROCESS FOR THE PRODUCTION OF OLEFINS BY AUTOTHERMAL CRACKING 审中-公开
标题翻译：通过自动破碎生产烯烃的方法
公开(公告)号：WO2006077368A1
公开(公告)日：2006-07-27
申请号：PCT/GB2005/005005
申请日：2005-12-22
申请人： INNOVENE EUROPE LIMITED , GRACEY, Benjamin, Patrick , REID, Ian, Allan, Beattie
发明人： GRACEY, Benjamin, Patrick , REID, Ian, Allan, Beattie
IPC分类号： C10G11/20 , C07C5/48 , B01J23/40 , B01J35/04 , C10G27/04
CPC分类号： C07C4/06 , B01J23/40 , B01J23/56 , B01J23/62 , B01J23/74 , B01J23/76 , B01J23/89 , B01J35/04 , C07C2523/42 , C10G11/20 , C10G27/04 , C10G2400/20 , C10G2400/22 , C07C11/02
摘要： The present invention provides a process for the production of olefins by autothermal cracking of a paraffinic hydrocarbon-containing feedstock in the presence of a molecular oxygen-containing gas, wherein said process comprises (a) providing a pre-heated, mixed feedstream comprising said paraffinic hydrocarboncontaining feedstock and said molecular oxygen-containing gas, (b) subsequently mixing said pre-heated, mixed feedstream with a diluent, said diluent being pre-heated to a temperature of at least 400°C, to produce a diluted mixed feedstream comprising at least 10% by volume of diluent, and (c) contacting said diluted mixed feedstream with a catalyst capable of supporting combustion beyond the normal fuel rich limit of flammability, to provide a hydrocarbon product stream comprising olefins.
摘要翻译：本发明提供了一种在含分子氧的气体存在下通过含有含链烷烃的原料的自热裂解生产烯烃的方法，其中所述方法包括（a）提供预热的混合进料流，其包含所述链烷烃（b）随后将所述预热的混合进料流与稀释剂混合，将所述稀释剂预加热至至少400℃的温度，以产生稀释的混合进料流，所述混合进料流包含至少10体积％的稀释剂，和（c）使所述稀释的混合进料流与能够支持燃烧的催化剂接触超过正常燃料浓度的可燃性极限，以提供包含烯烃的烃产物流。

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