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1. 发明申请

WO2004108639A1 A CATALYST COMPRISING A METALIC SUPPORT AND A PROCESS FOR THE PRODUCTION OF OLEFINS 审中-公开
标题翻译：包含金属支持的催化剂和生产烯烃的方法
公开(公告)号：WO2004108639A1
公开(公告)日：2004-12-16
申请号：PCT/GB2004/002140
申请日：2004-05-18
申请人： BP CHEMICALS LIMITED , LITTLE, Ian, Raymond , REID, Ian, Allan, Beattie , WILLIAMS, Vaughan, Clifford
发明人： LITTLE, Ian, Raymond , REID, Ian, Allan, Beattie , WILLIAMS, Vaughan, Clifford
IPC分类号： C07C11/02
CPC分类号： C07C5/48 , B01J23/56 , B01J23/8926 , B01J37/0205 , B01J37/0225 , C07C2521/02 , C07C2521/04 , C07C2523/10 , C07C2523/42 , C07C2523/72 , C07C2523/745 , C07C2523/75 , C07C2523/755 , C07C2523/86 , C07C2523/89 , Y02P20/52 , C07C11/02 , C07C11/04
摘要： A catalyst capable of supporting combustion beyond the fuel rich Iii-nit of flammability comprising a catalytic component and a metallic support wherein the support is a metallic structured packing comprising a multiplicity of open-ended channels and which has been loaded with a non metallic coating, and a process for the production of an olefin, said process comprising passing a mixture of a hydrocarbon and an oxygen-containing gas over said catalyst to produce an olefin.
摘要翻译：一种催化剂，其能够支持超过富含燃料的燃料的燃烧，其包含催化组分和金属载体，其中所述载体是包含多个开放式通道并且已经装载有非金属涂层的金属规整填料，以及一种生产烯烃的方法，所述方法包括使烃和含氧气体的混合物在所述催化剂上通过以产生烯烃。

2. 发明申请

WO2004074222A1 AUTO THERMAL CRACKING REACTOR 审中-公开
标题翻译：自动热裂解反应器
公开(公告)号：WO2004074222A1
公开(公告)日：2004-09-02
申请号：PCT/GB2004/000488
申请日：2004-02-06
申请人： BP CHEMICALS LIMITED , COLMAN, Derek, Alan , MATTHEWMAN, Michael, John, Alexander , REID, Ian, Allan, Beattie , WILLIAMS, Vaughan, Clifford , WOODFIN, William, Terence
发明人： COLMAN, Derek, Alan , MATTHEWMAN, Michael, John, Alexander , REID, Ian, Allan, Beattie , WILLIAMS, Vaughan, Clifford , WOODFIN, William, Terence
IPC分类号： C07C5/48
CPC分类号： B01J8/0453 , B01J8/0492 , B01J8/0496 , B01J2208/00522 , B01J2219/00094 , B01J2219/00265 , C07C5/48
摘要： The present invention provides a reactor design that enables an auto-thermal cracking process to be conducted at any suitable pressure wherein the gaseous reactants are preheated separately before mixing and then presented to the reaction zone in a uniformly distributed manner. In particular, the present - invention-relates to apparatus - for reacting a first and second gaseous reactant to form a gaseous product wherein the apparatus comprises at least one first supply means for the first gaseous reactant, at least one second supply means for the second gaseous reactant, a resistance zone and a reaction zone, preferably comprising a catalyst, wherein the first supply means comprises a plurality of first outlets for delivery of the first gaseous reactant, and the second supply means comprises a plurality of second outlets for delivery of the second gaseous reactant, the resistance zone is porous, the reaction zone is positioned downstream of the resistance zone with respect to the flow of the first and second gaseous reactants and wherein the first supply means and the second supply means are arranged such that the first gas and the second gas are contacted in an essentially parallel manner and mixed prior to contacting the resistance zone. The present invention also provides a process for the production of a mono-olefin utilizing said apparatus.
摘要翻译：本发明提供一种反应器设计，使得能够在任何合适的压力下进行自热裂解过程，其中气态反应物在混合之前分别预热，然后以均匀分布的方式呈现给反应区。特别地，本发明涉及用于使第一和第二气态反应物反应以形成气态产物的装置，其中所述装置包括用于第一气态反应物的至少一个第一供应装置，至少一个第二供应源用于第二气态反应物，电阻区和反应区的装置，优选包含催化剂，其中第一供应装置包括多个用于输送第一气态反应物的第一出口，第二供料装置包括多个第二出口为了输送第二气态反应物，电阻区是多孔的，反应区相对于第一和第二气态反应物的流动位于电阻区的下游，并且其中第一供给装置和第二供应装置被布置成第一气体和第二气体以基本平行的方式接触并在接触阻力区之前混合。本发明还提供了利用所述装置生产单烯烃的方法。

3. 发明申请

WO2004108279A1 CATALYST AND PROCESS FOR THE PRODUCTION OF OLEFINS 审中-公开
标题翻译：催化剂和生产烯烃的方法
公开(公告)号：WO2004108279A1
公开(公告)日：2004-12-16
申请号：PCT/GB2004/002132
申请日：2004-05-18
申请人： BP CHEMICALS LIMITED , REID, Ian, Allan, Beattie , WILLIAMS, Vaughan, Clifford
发明人： REID, Ian, Allan, Beattie , WILLIAMS, Vaughan, Clifford
IPC分类号： B01J23/56
CPC分类号： B01J35/04 , B01J23/56 , B01J23/92 , C07C5/48 , C10G2400/20 , Y02P20/584 , C07C11/02
摘要： A catalyst system capable of supporting combustion beyond the fuel rich limit of flammability comprising a catalytic component, a first support and a second support and wherein the catalytic component is present on both the first and the second support, and a process for the production of an olefin, said process comprising passing a mixture of a hydrocarbon and an oxygen-containing gas over said catalyst system to produce said olefin. The first support and the second support must differ in at least one of the following aspects: support material, support type and/or structural dimension.
摘要翻译：一种催化剂体系，其能够支持超过燃料富含燃烧极限的燃烧，其包括催化组分，第一载体和第二载体，并且其中所述催化组分存在于所述第一和第二载体上，以及用于生产所述方法包括使烃和含氧气体的混合物在所述催化剂体系上通过以产生所述烯烃。以下至少一个方面，第一个支撑和第二个支撑必须不同：支撑材料，支撑类型和/或结构尺寸。

4. 发明申请

WO2004106463A1 PROCESS FOR THE PRODUCTION OF OLEFINS 审中-公开
标题翻译：生产烯烃的方法
公开(公告)号：WO2004106463A1
公开(公告)日：2004-12-09
申请号：PCT/GB2004/002035
申请日：2004-05-12
申请人： BP CHEMICALS LIMITED , LITTLE, Ian, Raymond , WILLIAMS, Vaughan, Clifford
发明人： LITTLE, Ian, Raymond , WILLIAMS, Vaughan, Clifford
IPC分类号： C10G11/22
CPC分类号： C10G11/22 , C07C4/025 , C07C2523/42 , C07C2523/83 , Y02P20/52 , C07C11/04
摘要： The present invention relates to a process for the production of an olefin, said process comprising passing a mixture of a hydrocarbon and an oxygen-containing gas through a catalyst zone which is capable of supporting combustion beyond the fuel rich limit of flammability to produce said olefin, said catalyst zone comprising at least a first catalyst bed and a second catalyst bed, and wherein the second catalyst bed is located downstream of the first catalyst bed, is of a different composition to the first catalyst bed and has the general formula of: M 1 a M 2 b M 3 c O z wherein M 1 is selected from groups IIA, JIB, IIIB, IVB, VB, VIB, VIIB, lanthanides and actinides, M 2 is selected from groups IIA, IB, JIB, IIIB, IVB, VB, VIB, and M 3 is selected from groups IIA, IB, IIB, IIIB, IVB, VB, VIB and VIIIB.
摘要翻译：本发明涉及一种生产烯烃的方法，所述方法包括使烃和含氧气体的混合物通过催化剂区域，该催化剂区域能够支持燃料超过燃料富含的可燃性极限以产生所述烯烃所述催化剂区域包括至少第一催化剂床和第二催化剂床，并且其中所述第二催化剂床位于所述第一催化剂床的下游，具有与所述第一催化剂床不同的组成，并具有以下通式：M 其中M 1选自IIA，JIB，IIIB，IVB，VB，VIB，VIIB，镧系元素和锕系元素，M 2选自IIA，IB ，JIB，IIIB，IVB，VB，VIB和M 3选自IIA，IB，IIB，IIIB，IVB，VB，VIB和VIIIB组。

5. 发明申请

WO2008003922A1 METHOD FOR STARTING OFAN AUTOTHERMAL CRACKING REACTION 审中-公开
标题翻译：自动破碎反应开始的方法
公开(公告)号：WO2008003922A1
公开(公告)日：2008-01-10
申请号：PCT/GB2007/002106
申请日：2007-06-07
申请人： INEOS EUROPE LIMITED , PARKER, Graeme, Alexander , REID, Ian, Allan, Beattie , WATSON, John, Alexander , WILLIAMS, Vaughan, Clifford , WILSON, David, Charles
发明人： PARKER, Graeme, Alexander , REID, Ian, Allan, Beattie , WATSON, John, Alexander , WILLIAMS, Vaughan, Clifford , WILSON, David, Charles
IPC分类号： C07C4/02
CPC分类号： C07C4/025 , C07C11/02
摘要： The present invention provides a method for starting an autothermal cracking reaction for the production of one or more olefins, said autothermal cracking reaction comprising contacting a paraffinic hydrocarbon and oxygen with a catalyst at an elevated pressure, P1, which start-up method comprises: a) establishing a flow of a purge gas immediately downstream of the catalyst, b) contacting a pre-heated feed mixture comprising hydrogen, oxygen and a diluent with the catalyst at an elevated pressure, P2, which is less than P1, wherein the hydrogen to oxygen molar ratio is at least 0.5:1 and wherein the total feed mixture comprises less than 25wt% oxygen and at least 50wt% diluent, c) increasing the oxygen concentration in the feed mixture until a catalyst exit temperature of at least 7000C is reached, and d) increasing the pressure to the desired reaction pressure P1.
摘要翻译：本发明提供了一种用于开始用于生产一种或多种烯烃的自热裂化反应的方法，所述自热裂化反应包括在升高的压力下使链烷烃和氧与催化剂接触，P1，该启动方法包括：）在催化剂的下游建立净化气体的流动，b）在升高的压力下将包含氢气，氧气和稀释剂的预热进料混合物与催化剂接触，P2小于P1，其中氢气氧摩尔比为至少0.5:1，并且其中总进料混合物包含小于25wt％的氧和至少50wt％的稀释剂，c）增加进料混合物中的氧浓度，直到达到至少700℃的催化剂出口温度，和d）将压力增加到所需的反应压力P1。

6. 发明申请

WO2007119042A2 PROCESS FOR THE TREATMENT OF A PRODUCT STREAM 审中-公开
标题翻译：处理产品流程的过程
公开(公告)号：WO2007119042A2
公开(公告)日：2007-10-25
申请号：PCT/GB2007/001077
申请日：2007-03-26
申请人： INEOS EUROPE LIMITED , WILLIAMS, Vaughan, Clifford
发明人： WILLIAMS, Vaughan, Clifford
CPC分类号： B01D53/1456 , B01D53/1493 , C10G11/22 , C10G27/04 , C10G70/04 , C10G2400/20 , Y02C10/06 , Y02C10/08 , Y02P20/128 , Y02P30/40 , Y02P30/446 , Y02P30/464
摘要： The present invention relates to a process for the treatment of a product stream, more specifically of a product stream from an autothermal cracking process, said product stream comprising one or more olefins, hydrogen, carbon monoxide, carbon dioxide and one or more oxygenates, said process comprising contacting the product stream with at least one compound selected from those represented by formulas: (1) H 2 N-OR 1 , and (2) H 2 N-NR 2 R 3 , where: R 1 , R 2 and R 3 may each be independently selected from H and carbon containing substituents.
摘要翻译：本发明涉及一种用于处理产物流的方法，更具体地说是来自自热裂解方法的产物流，所述产物流包含一种或多种烯烃，氢气，一氧化碳，二氧化碳和一种或多种含氧化合物，所述方法包括使产物流与至少一种选自下式的化合物接触：（1）H 2 N-OR 1，和（2）H 2 N-NR 2 R 3，其中：R 1，R 2和R 2，各自独立地选自H和含碳取代基。

7. 发明申请

WO2007083077A1 PROCESS FOR CONTACTING A HYDROCARBON AND AN OXYGEN- CONTAINING GAS WITH A CATALYST BED 审中-公开
标题翻译：用催化床接触含烃和含氧气体的方法
公开(公告)号：WO2007083077A1
公开(公告)日：2007-07-26
申请号：PCT/GB2006/004825
申请日：2006-12-20
申请人： INEOS EUROPE LIMITED , WILLIAMS, Vaughan, Clifford
发明人： WILLIAMS, Vaughan, Clifford
IPC分类号： B01J19/24 , B01J35/04
CPC分类号： B01J19/2485 , B01J8/0085 , B01J8/009 , B01J19/24 , B01J19/30 , B01J23/825 , B01J23/835 , B01J23/8926 , B01J35/04 , B01J2208/00362 , B01J2208/00557 , B01J2208/00814 , B01J2208/00849 , B01J2208/00884 , B01J2208/021 , B01J2208/025 , B01J2219/00123 , B01J2219/00166 , B01J2219/192 , B01J2219/1928 , B01J2219/3023 , B01J2219/30234 , B01J2219/30246 , B01J2219/30249 , B01J2219/30416 , B01J2219/30475 , B01J2219/3085
摘要： The present invention relates to a process for contacting a hydrocarbon and an oxygen-containing gas with a catalyst bed in a reactor at a space velocity of at least 10,000 h -1 , said process being characterised in that a) the reactor has a polygonal internal cross-section at least in the section where the catalyst bed is held, b) the catalyst bed is made up of 2 or more layers of catalyst in the form of tiles of polygonal shape, said tiles having at least 4 sides, c) each layer of catalyst comprises at least 4 tiles which tessellate together to form said layer, and d) the edges where 2 tiles meet in one layer do not align with the edges where 2 tiles meet in an adjacent layer.
摘要翻译：本发明涉及使烃和含氧气体与催化剂床在反应器中以至少10,000h -1 -1的空间速度接触的方法，所述方法的特征在于：）反应器至少在保持催化剂床的部分具有多边形内部横截面，b）催化剂床由多层形状的瓷砖形式的2层或更多层催化剂组成，所述砖具有至少4边，c）每层催化剂包括至少4块镶嵌在一起以形成所述层的瓦片，以及d）2瓦片在一层中相遇的边缘不与2瓦片在相邻层中相遇的边缘对准。

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