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1. 发明申请

WO2009027075A2 CATALYSTS 审中-公开
标题翻译：催化剂
公开(公告)号：WO2009027075A2
公开(公告)日：2009-03-05
申请号：PCT/EP2008/007007
申请日：2008-08-27
申请人： BOREALIS TECHNOLOGY OY , VOSKOBOYNIKOV, Alexander Zelmanovich , ASACHENKO, Andrei Fyodorovich , KONANOVICH, Dmitry , NIKULIN, Mikhail V. , TZAREV, Alexey , MAARANEN, Janne , VANNE, Tiina , KAUHANEN, Jyrki , MANSNER, Erik , KOKKO, Esa , SAARINEN, Laura
发明人： VOSKOBOYNIKOV, Alexander Zelmanovich , ASACHENKO, Andrei Fyodorovich , KONANOVICH, Dmitry , NIKULIN, Mikhail V. , TZAREV, Alexey , MAARANEN, Janne , VANNE, Tiina , KAUHANEN, Jyrki , MANSNER, Erik , KOKKO, Esa , SAARINEN, Laura
IPC分类号： C08F4/656 , C08F10/00 , C07F17/00 , C07C13/465
CPC分类号： C07F17/00 , C08F4/65912 , C08F4/65916 , C08F10/00 , C08F110/02 , C08F210/16 , C08F4/65927 , C08F2500/07 , C08F2500/12 , C08F2500/03 , C08F2500/18 , C08F210/14
摘要： A complex comprising a ligand of formula (I), wherein each R 1 , which may be the same or different, is hydrogen, an optionally substituted C 1-20 hydrocarbyl group, N(R 5 ) 2 , silyl, siloxy; an optionally substituted heteroaryl group, an optionally substituted heterocyclyl group or two R 1 groups on adjacent carbon atoms taken together may form an optionally substituted 5- to 8-membered fused ring; each R 2 , which may be the same or different is hydrogen, is hydrogen, an optionally substituted C 1-20 hydrocarbyl group, N(R 5 ) 2 , silyl, siloxy; an optionally substituted heteroaryl group, or an optionally substituted heterocyclyl group; R 3 , which binds to the 6-membered ring of the indenyl group, is -(Si(R 5 ) 2 ) p -, where p is 1 or 2, -(C(R 5 ) 2 )n- where n is an integer of 2 or more; each R 4 which may be the same or different, is hydrogen, an optionally substituted C 1-20 hydrocarbyl group, N(R 5 ) 2 , silyl, siloxy, an optionally substituted heteroaryl group, an optionally substituted heterocyclyl group or two R 4 groups on adjacent carbon atoms taken together can form an optionally substituted 5- to 8-membered fused carbon ring; each R 5 , which may be the same or different, is hydrogen, an optionally substituted C 1-20 hydrocarbyl group, or two R 5 groups taken together can form an optionally substituted 5- to 8-membered ring; a is 0 to 3; b is 0 to 3; c is 0 to 4; complexed to a metal ion, M.
摘要翻译：包含式（I）的配体的络合物，其中每个R 1可以相同或不同，为氢，任选取代的C 1-20烃基，N（R 5）2，甲硅烷基，甲硅烷氧基; 任选取代的杂芳基，任选取代的杂环基或相邻碳原子上的两个R 1基团可以一起形成任选取代的5-至8-元稠环; 每个R 2可以相同或不同，为氢，为氢，任选取代的C 1-20烃基，N（R 5）2，甲硅烷基，甲硅烷氧基; 任选取代的杂芳基，或任选取代的杂环基; 结合茚基的6元环的R 3为 - （Si（R 5）2）p - ，其中p为1或2， - （C（R 5）2）n - ，其中n为 2以上; 每个R 4可以相同或不同，为氢，任选取代的C 1-20烃基，N（R 5）2，甲硅烷基，甲硅烷氧基，任选取代的杂芳基，任选取代的杂环基或相邻碳上的两个R 4基团一起取代的原子可以形成任选取代的5至8元稠合碳环; 每个R 5可以相同或不同，为氢，任选取代的C 1-20烃基或两个R 5基团可以形成任选取代的5至8元环; a是0到3; b为0〜3; c为0〜4; 与金属离子络合

2. 发明申请

WO2010052264A1 SOLID CATALYST COMPOSITION 审中-公开
标题翻译：固体催化剂组合物
公开(公告)号：WO2010052264A1
公开(公告)日：2010-05-14
申请号：PCT/EP2009/064670
申请日：2009-11-05
申请人： BOREALIS AG , MANSNER, Erik , KOKKO, Esa , KAUHANEN, Jyrki , SEVERN, John
发明人： MANSNER, Erik , KOKKO, Esa , KAUHANEN, Jyrki , SEVERN, John
IPC分类号： B01J31/16 , B01J31/22 , B01J31/12 , B01J31/14
CPC分类号： B01J31/2295 , B01J31/128 , B01J31/143 , B01J31/165 , B01J2231/122 , B01J2531/46 , B01J2531/48 , B01J2531/49 , C08F4/65925 , C08F10/00 , C08F110/06 , C08F4/65912
摘要： Solid catalyst composition comprising a polymer matrix (A) and distributed therein a solid catalyst system (B), wherein (a) the solid catalyst system (B) comprises • a transition metal compound of formula (I) L m R n MX q , (I) wherein "M" is a transition metal of anyone of the groups 3 to 10 of the periodic table (IUPAC), each "X" is independently a monovalent anionic σ-ligand, each "L" is independently an organic ligand which coordinates to the transition metal (M), "R" is a bridging group linking two organic ligands (L), said organic ligands (L) and said bridging groups (R) do not comprise polymerizable olefϊnic groups, "m" is 2 or 3, "n" is 0, 1 or 2, "q" is 1, 2 or 3, m+q is equal to the valency of the transition metal (M), and • a cocatalyst (Co) comprising a compound of Al, and (b) the polymer matrix (A) is not covalent bonded to anyone of the organic ligands (L) and/or to anyone of the bridging groups (R) of the transition metal compound.
摘要翻译：固体催化剂组合物，其包含聚合物基体（A）并分布在其中的固体催化剂体系（B），其中（a）所述固体催化剂体系（B）包含：式（I）的过渡金属化合物LmRnMXq，（I）其中“ M“是元素周期表（IUPAC）中的任何3至10族的过渡金属，每个”X“独立地是一价阴离子S-配体，”L“分别是与过渡金属配位的有机配体（M）中，“R”是连接两个有机配体（L），所述有机配体（L）和所述桥连基团（R）的桥连基团不包含可聚合的烯基，“m”为2或3， n“为0,1或2，”q“为1,2或3，m + q等于过渡金属（M）的化合价，和a为包含Al化合物的助催化剂（Co）和（ b）聚合物基质（A）不与任何有机配体（L）和/或任何过渡金属化合物的桥连基团（R）键合。

3. 发明申请

WO2010052263A1 SOLID CATALYST COMPOSITION 审中-公开
标题翻译：固体催化剂组合物
公开(公告)号：WO2010052263A1
公开(公告)日：2010-05-14
申请号：PCT/EP2009/064669
申请日：2009-11-05
申请人： BOREALIS AG , HAKALA, Kimmo , MANSNER, Erik , DENIFL, Peter , LEHTINIEMI, Ismo , KAUHANEN, Jyrki , HUHTANEN, Lauri
发明人： HAKALA, Kimmo , MANSNER, Erik , DENIFL, Peter , LEHTINIEMI, Ismo , KAUHANEN, Jyrki , HUHTANEN, Lauri
IPC分类号： B01J31/12 , B01J31/16 , B01J31/22 , B01J31/14 , C08F4/00
CPC分类号： B01J31/128 , B01J31/143 , B01J31/165 , B01J31/2295 , B01J2231/122 , B01J2531/46 , B01J2531/48 , B01J2531/49 , C08F4/65925 , C08F4/65927 , C08F10/00 , C08F110/02 , C08F110/06 , C08F210/16 , C08F4/65912 , C08F210/14 , C08F2500/12 , C08F2500/18 , C08F2500/24
摘要： Solid catalyst composition comprising a polymer matrix (A) and distributed therein a solid catalyst system (B), wherein • the solid catalyst system (B) • has a porosity measured according to ASTM 4641 of less than 1.40 ml/g, • comprises a transition metal compound of formula (I) L m R n MX q , (I) wherein "M" is a transition metal of anyone of the groups 3 to 10 of the periodic table (IUPAC), each "X" is independently a monovalent anionic σ-ligand, each "L" is independently an organic ligand which coordinates to the transition metal (M), "R" is a bridging group linking two organic ligands (L), "m" is 2 or 3, "n" is 0, 1 or 2, "q" is 1, 2 or 3, m+q is equal to the valency of the transition metal (M), and a cocatalyst (Co) comprising a compound of A1, and • the weight ratio of the polymer matrix (A) and the catalyst system (B) [weight polymer matrix (A)/weight catalyst system (B)] in the solid catalyst composition is below 25.0.
摘要翻译：包含聚合物基体（A）并分布在其中的固体催化剂体系（B）的固体催化剂组合物，其中固体催化剂体系（B）°具有根据ASTM 4641测量的孔隙率小于1.40ml / g的固体催化剂组合物包含式（I）的过渡金属化合物LmRnMXq，（I）其中“M”是周期表（IUPAC）中3至10族中的任何一个的过渡金属，每个“X”独立地是一价阴离子S-配体，每个“L”独立地是与过渡金属（M）配位的有机配体，“R”是连接两个有机配体（L）的桥连基团，“m”是2或3，“n”是0,1或 2中，“q”为1,2或3，m + q等于过渡金属（M）的化合价，以及包含A1化合物的助催化剂（Co），以及聚合物基质的重量比 A）和固体催化剂组合物中的催化剂体系（B）[重量聚合物基质（A）/重量催化剂体系（B）]低于25.0。

4. 发明申请

WO2010052260A1 SOLID CATALYST COMPOSITION 审中-公开
标题翻译：固体催化剂组合物
公开(公告)号：WO2010052260A1
公开(公告)日：2010-05-14
申请号：PCT/EP2009/064666
申请日：2009-11-05
申请人： BOREALIS AG , HAKALA, Kimmo , MANSNER, Erik , HÄTÖNEN, Jari , HUHTANEN, Lauri , TUOMINEN, Olli , AUMO, Jeanette , LEHTINIEMI, Ismo
发明人： HAKALA, Kimmo , MANSNER, Erik , HÄTÖNEN, Jari , HUHTANEN, Lauri , TUOMINEN, Olli , AUMO, Jeanette , LEHTINIEMI, Ismo
IPC分类号： C08F4/00 , B01J31/16 , B01J31/22 , B01J31/12 , B01J31/14
CPC分类号： B01J31/2295 , B01J31/128 , B01J31/143 , B01J31/165 , B01J2531/46 , B01J2531/48 , B01J2531/49 , C08F4/65912 , C08F4/65925 , C08F4/65927 , C08F10/00 , C08F110/06 , C08F210/06 , C08F210/16 , C08F210/14
摘要： Solid catalyst composition comprising a polymer matrix (A) and distributed therein a solid catalyst system (B), wherein - the solid catalyst system (B) has a porosity measured according to ASTM 4641 of less than 1.40 ml/g, comprises a transition metal compound of formula (I), L m R n MX q (I) wherein "M" is a transition metal of anyone of the groups 3 to 10 of the periodic table (IUPAC), each "X" is independently a monovalent anionic σ-ligand, each "L" is independently an organic ligand which coordinates to the transition metal (M), "R" is a bridging group linking two organic ligands (L), said organic ligands (L) and said bridging groups (R) do not comprise polymerizable olefinic groups, "m" is 2 or 3, "n" is 0, 1 or 2, "q" is 1, 2 or 3, m+q is equal to the valency of the transition metal (M), and a cocatalyst (Co) comprising a compound of Al, and - the mol ratio of Al of the cocatalyst (Co) and the transition metal "M" of the transition metal compound [Al/M] is from 100 to 800 mol/mol.
摘要翻译：固体催化剂组合物，其包含聚合物基质（A）并在其中分布有固体催化剂体系（B），其中固体催化剂体系（B）具有根据ASTM 4641测量的小于1.40ml / g的孔隙，包含过渡金属式（I）的化合物，其中“M”是周期表（IUPAC）的3至10族中的任何一个的过渡金属的LmRnMXq（I），每个“X”独立地是一价阴离子S-配体， L“独立地是与过渡金属（M）配位的有机配体，”R“是连接两个有机配体（L）的桥连基团，所述有机配体（L）和所述桥连基团（R）不包含可聚合烯烃基团“m”为2或3，“n”为0,1或2，“q”为1,2或3，m + q等于过渡金属（M）的化合价和助催化剂 Co）和 - 助催化剂（Co）的Al与过渡金属化合物[Al / M]的过渡金属“M”的摩尔比为100〜800摩尔/摩尔的化合物。

5. 发明公开

EP2215129A2 CATALYSTS 审中-公开
标题翻译：催化剂
公开(公告)号：EP2215129A2
公开(公告)日：2010-08-11
申请号：EP08785709.0
申请日：2008-08-27
申请人： Borealis Technology OY
发明人： VOSKOBOYNIKOV, Alexander Zelmanovich , ASACHENKO, Andrei Fyodorovich , KONANOVICH, Dmitry , NIKULIN, Mikhail V. , TZAREV, Alexey , MAARANEN, Janne , VANNE, Tiina , KAUHANEN, Jyrki , MANSNER, Erik , KOKKO, Esa , SAARINEN, Laura
IPC分类号： C08F4/656 , C08F10/00 , C07F17/00 , C07C13/465
CPC分类号： C07F17/00 , C08F4/65912 , C08F4/65916 , C08F10/00 , C08F110/02 , C08F210/16 , C08F4/65927 , C08F2500/07 , C08F2500/12 , C08F2500/03 , C08F2500/18 , C08F210/14
摘要： A complex comprising a ligand of formula (I), wherein each R1, which may be the same or different, is hydrogen, an optionally substituted C1-20 hydrocarbyl group, N(R5)2, silyl, siloxy; an optionally substituted heteroaryl group, an optionally substituted heterocyclyl group or two R1 groups on adjacent carbon atoms taken together may form an optionally substituted 5- to 8-membered fused ring; each R2, which may be the same or different is hydrogen, is hydrogen, an optionally substituted C1-20 hydrocarbyl group, N(R5)2, silyl, siloxy; an optionally substituted heteroaryl group, or an optionally substituted heterocyclyl group; R3, which binds to the 6-membered ring of the indenyl group, is -(Si(R5)2)p-, where p is 1 or 2, -(C(R5)2 )n- where n is an integer of 2 or more; each R4 which may be the same or different, is hydrogen, an optionally substituted C1-20 hydrocarbyl group, N(R5)2, silyl, siloxy, an optionally substituted heteroaryl group, an optionally substituted heterocyclyl group or two R4 groups on adjacent carbon atoms taken together can form an optionally substituted 5- to 8-membered fused carbon ring; each R5, which may be the same or different, is hydrogen, an optionally substituted C1-20 hydrocarbyl group, or two R5 groups taken together can form an optionally substituted 5- to 8-membered ring; a is 0 to 3; b is 0 to 3; c is 0 to 4; complexed to a metal ion, M.
摘要翻译：包含式（I）配体的配合物，其中每个R 1可以相同或不同，为氢，任选取代的C 1-20烃基，N（R 5）2，甲硅烷基，甲硅烷氧基; 任选取代的杂芳基，任选取代的杂环基或相邻碳原子上的两个R 1基团一起形成任选取代的5-至8-元稠合环; 每个可以相同或不同的R 2是氢，是氢，任选取代的C 1-20烃基，N（R 5）2，甲硅烷基，甲硅烷氧基; 任选取代的杂芳基或任选取代的杂环基; 与茚基的6元环结合的R3是 - （Si（R5）2）p-，其中p是1或2， - （C（R5）2）n-，其中n是 2或更多; 每个可以相同或不同的R 4是氢，任选取代的C 1-20烃基，N（R 5）2，甲硅烷基，甲硅烷氧基，任选取代的杂芳基，任选取代的杂环基或邻近碳上的两个R 4基团原子结合在一起可形成任选取代的5-至8-元稠合碳环; 每个可以相同或不同的R5为氢，任选取代的C1-20烃基或两个R5基团一起形成任选取代的5-至8-元环; a是0到3; b是0至3; c是0至4; 与金属离子复合，M.

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