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    • 5. 发明申请
    • MULTISTEP PROCESS FOR OBTAINING MODIFIED INORGANIC PARTICLES
    • 用于获得改性无机颗粒的多步骤方法
    • WO2013171237A1
    • 2013-11-21
    • PCT/EP2013/059975
    • 2013-05-15
    • BOREALIS AGROLINZ MELAMINE GMBH
    • DICKE, RenéROT, Katarina
    • C09C1/42C09C3/00C09C3/04C09C3/08C09C3/10C08K9/04
    • C09C1/42C01P2004/61C01P2006/22C09C3/006C09C3/043C09C3/08C09C3/10
    • The present invention relates to a multistep process for obtaining modified inorganic particles having a layered structure, characterized by the steps of a) Providing an aqueous solution or suspension comprising at least one first amino compound in a first vessel T1 and protonating the at least one first amino compound using at least one acid; b) Providing an aqueous homogenous suspension comprising at least one inorganic particle having a layered structure in a second vessel T2; c1) addition of the aqueous solution or suspension of the at least one first protonated amino compound from the first vessel T1 to the aqueous homogenous suspension comprising at least one inorganic particle having a layered structure in the second vessel T2; c2) Addition of at least one second non-protonated amino compound to the suspension obtained in step c1); d) Addition of at least one aldehyde to the homogenous suspension of the at least one inorganic particle being modified by the first protonated amino compound and second non-protonated amino compound in the second vessel T2; and e) removal and work up of the modified inorganic particles. The present invention relates also to modified inorganic particles obtained in this multistep process and their use.
    • 本发明涉及一种用于获得具有层状结构的改性无机颗粒的多步法,其特征在于以下步骤:a)在第一容器T1中提供包含至少一种第一氨基化合物的水溶液或悬浮液,并使所述至少一个第一 使用至少一种酸的氨基化合物; b)在第二容器T2中提供包含至少一种具有层状结构的无机颗粒的水均匀悬浮液; c1)将来自第一容器T1的至少一种第一质子化氨基化合物的水溶液或悬浮液添加到包含在第二容器T2中具有层状结构的至少一种无机颗粒的水性均匀悬浮液; c2)向步骤c1)中获得的悬浮液中加入至少一种第二非质子化氨基化合物; d)在第二容器T2中由第一质子化氨基化合物和第二非质子化氨基化合物修饰的至少一种无机颗粒的均匀悬浮液中加入至少一种醛; 和e)去除和后处理改性无机颗粒。 本发明还涉及在该多步法中获得的改性无机颗粒及其用途。
    • 6. 发明申请
    • METHOD FOR ALKYLATING AN AMINO COMPOUND
    • WO2018096011A1
    • 2018-05-31
    • PCT/EP2017/080149
    • 2017-11-23
    • BOREALIS AGROLINZ MELAMINE GMBH
    • GABRIEL, HerbertDICKE, René
    • C07D251/70C07C275/06
    • The invention relates to a method for alkylating an amino compound, characterized in that at least one triazine derivative of general formula (I) or at least one urea or urea derivative of the general formula (II), (II), wherein • R 4 and R 5 mean independently from each other Q 1 or a moiety of the formula R 6 -N-R 7 or R 8 -N-R 9 bound with its central nitrogen atom to the triazine ring of the structure of formula (I), whereat - Q 1 means a linear or branched C 1 -C 30 -alkyl or a cyclic substituent in form of a C 5- C 20 -cycloalkyl, a C 5 -C 20 -aryl, a C 1 -C 20 -alkylsubstituted C 5 -C 20 -aryl or an amide of a cyclic unsaturated carboxylic acid, whereat the C 1 -C 30 -alkyl or the cyclic substituent can be interrupted by one or multiple oxygen atoms, sulphur atoms, substituted nitrogen atoms and/or by one or multiple groups of the type –C(O)O-,-OC(O)-,-C(O)- and/or –OC(O)O-, • R 1 , R 2 , R 3 , R 6 , R 7 , R 8 and R 9 mean independently from each other H, linear or branched C 1 -C 20 -alkyl, C 5 -C 20 -cyclo alkyl, C 5 -C 20 -aryl, C 1 -C 20 -alkylsubstituted C 5 -C 20 -aryl, which in each case can be interrupted by one or multiple oxygen atoms, sulphur atoms and/or substituted nitrogen atoms and/or by one or multiple groups of the type –C(O)O-, - OC(O)-, -C(O)- and/or –OC(O) O- and/or can be functionalized by one or multiple hydroxyl groups and/or mercapto groups, and • X means O or S, is reacted with at least one alcohol of the general formula (III) R 10 -OH wherein R 10 means a linear or branched C 1 -C 20 -alkyl, C 5 -C 20 -cycloalkyl, or C 1 -C 20 - alkylsubstituted C 5 -C 20 -aryl, which can be in each case interrupted by one or multiple oxygen atoms, sulphur atoms, substituted nitrogen atoms and/or by one or multiple groups of the type –C(O)O-, -OC(O)-, -C(O)- and/or –OC(O)O- and/or can be functionalized by one or multiple hydroxyl groups and/or mercapto groups, wherein the reaction is carried out in the presence of at least one Ruthenate of the general formula (IV) M n (RuO 4 ) and/or at least one Perruthenate of the general formula (V) M(RuO4)n wherein the cation M is selected from a group comprising an alkali, earth alkali or substituted or non-substituted ammonium cation.
    • 8. 发明申请
    • NOVEL TRIAZINE-PRECONDENSATE-ALDEHYDE CONDENSATION PRODUCTS AND METHOD FOR OBTAINING THE SAME
    • 新的三嗪前体 - 醛 - 醛缩合产物及其获得方法
    • WO2018002106A1
    • 2018-01-04
    • PCT/EP2017/065940
    • 2017-06-28
    • BOREALIS AGROLINZ MELAMINE GMBH
    • GABRIEL, HerbertDICKE, RenéPUCHBERGER, Helmut
    • C07D251/00
    • The present invention relates to a triazine-precondensate-aldehyde condensation products is provided that is obtainable by reacting a) at least one triazine compound of the general formulae (I), b) at least one aldehyde, in particular formaldehyde, and c) at least one triazine precondensate of the general formula (II),, wherein R 1 means Q 1 or a moiety of the formula R 3 -N-R 4 connected with the nitrogen atom to the triazine ring of the structure of formula (I), wherein R9 means Q1 or a moiety of the formula R 7 -N-R 8 connected with the nitrogen atom to the triazine ring of the structure of formula (I), wherein R 2 , R 3 , R 4 and R 6 mean independently from each other H, Q 1 or formula, R 7 and R 8 mean independently from each other H, Q 1 , formula, R 10 and R 11 mean independently from each other R 7 or R 8 ; R 5 means linear or branched C 2 -C 20 -alkyl that can be interrupted by one or more oxygen atoms, sulphur atoms, substituted and non-substituted nitrogen atoms, R x , R y mean independently from each other H, OH, Q 1 , -[C 1 C 18 ]-OH or formula, wherein Q 1 means linear or branched C 1 -C- 20 -alkyl, linear or branched C 2 -C 20 -alkenyl, linear or branched C 2 -C 20 -alkinyl, C 3 -C 10 -cycloalkyl, C 5 -C 7 -cycloalkenyl, which in each case can be interrupted by one or more oxygen atoms, sulphur atoms, substituted or non-substituted nitrogen atoms and/or by one or more groups of the type -C(O)O-, -OC(O)-, -C(O)-, -NHC(0)0-, -OC(O) NH- and/or -OC(O)O-; and wherein n = 0-10, preferably 1 -8, most preferably 1 - 5, and m = 0-8, preferably 1 -7, most preferably 1 - 5 or mixtures thereof.
    • 本发明涉及三嗪 - 预缩合物 - 醛缩合产物,其可通过使a)至少一种通式(I)的三嗪化合物,b)至少一种醛, 特别是甲醛,和c)至少一种通式(II)的三嗪预缩合物,其中R 1表示Q 1或式R 1部分 (I)结构的三嗪环与氮原子连接,其中R 9是指Q1或下式的部分R 7: (I)结构的三嗪环与氮原子连接,其中R 2,R 3,R 3, R 4和R 6彼此独立地表示H,Q 1或式R 7和 R 8彼此独立地表示H,Q 1,式,R 10和R 11 意思是相互独立的R 7或R 8; R5 5是指可以被一个或多个氧原子,硫原子,取代的和被一个或多个氧原子间隔的直链或支链C 2 -C 20烷基 未取代的氮原子,R x,R y相互独立地表示H,OH,Q 1, - [C≡N] 1 C18] - OH或式,其中Q 1表示直链或支链的C 1 -C 20 - 直链或支链的C 2 -C 20 - 烯基,直链或支链的C 2 -C 20 低级烷基,C 3 -C 10 - 环烷基,C 5 -C 7 - 环烯基 其在每种情况下可以被一个或多个氧原子,硫原子,取代或未取代的氮原子和/或一个或多个-C(O)O - , - OC(O) - ,-C(O) - , - NHC(O)O - , - OC(O)NH-和/或-OC(O)O-。 并且其中n = 0-10,优选1-8,最优选1-5和m = 0-8,优选1-7,最优选1-5或其混合物。
    • 9. 发明申请
    • NOVEL TRIAZINE PRECONDENSATE AND METHOD FOR OBTAINING THE SAME
    • 新的三嗪前体及其获得方法
    • WO2018001825A1
    • 2018-01-04
    • PCT/EP2017/065242
    • 2017-06-21
    • BOREALIS AGROLINZ MELAMINE GMBH
    • GABRIEL, HerbertDICKE, RenéPUCHINGER, Helmut
    • C07D251/70
    • The present invention relates to a triazine precondensate according to the general formula (I) wherein R 1 means Q 1 or a moiety of the formula R 3 –N–R 4 connected with the nitrogen atom to the triazine ring of the structure of formula (I), wherein R 9 means Q 1 or a moiety of the formula R 7 –N–R 8 connected with the nitrogen atom to the triazine ring of the structure of formula (I), wherein R 2 , R 3 , R 4 and R 6 mean independently from each other H, Q 1 or (i), R 7 and R 8 mean independently from each other H, Q 1 , (ii) or (iii) or (i), R 10 and R 11 mean independently from each other R 7 or R 8 ; R 5 means linear or branched C 2 -C 20 -alkyl that can be interrupted by one or more oxygen atoms, sulphur atoms, substituted or non-substituted nitrogen atoms, R x , R y mean independently from each other H, OH, Q 1 , -[C 1 -C 18 ]-OH or (iv) wherein Q 1 means linear or branched C 1 -C 20 -alkyl, linear or branched C 2 -C 20 -alkenyl, linear or branched C 2 -C 20 -alkinyl, C 3 -C 10 -cycloalkyl, C 5 -C 7 -cycloalkenyl, C 6 -C 12 aryl which in each case can be interrupted by one or more oxygen atoms, sulphur atoms, and/or by one or more groups of the type -C(O)O-, -OC(O)-, -C(O)-, -NHC(O)O-, -OC(O)NH- and/or -OC(O)O-; and wherein n = 0-10, preferably 1-8, most preferably 1-5, and m = 0-8, preferably 1-7, most preferably 1-5 or mixtures thereof.
    • 本发明涉及根据通式(I)的三嗪预缩合物,其中R 1表示Q 1或式 其中R 9表示与氮原子连接的式(I)结构的三嗪环,其中R 9表示 Q 1或式R 7 -N-R 8的部分与氮原子连接到式(I)结构的三嗪环上, (I)的化合物,其中R 2,R 3,R 4和R 6彼此独立地表示H ,Q 1或(i)中,R 7和R 8彼此独立地表示H,Q 1, ,(ii)或(iii)或(i)中,R 10和R 11彼此独立地表示彼此独立的R 7或R 9 > 8 ; R 5表示可以被一个或多个氧原子,硫原子,取代的或被一个或多个氧原子间隔的直链或支链C 2 -C 20 - 烷基 未取代的氮原子,R x,R y相互独立地表示H,OH,Q 1, - [C≡N] (iv)其中Q 1表示直链或支链的C 1 -C 12烷基, 直链或支链C 2 -C 20 - 烯基,直链或支链C 2 -C 20 - 20-炔基,C 3 -C 10 - 环烷基,C 5 -C 7 - 烷基,C 5 -C 10环烷基, 环烯基,C≡C-C12芳基,其在每种情况下可以被一个或多个氧原子,硫原子和/或一个或多个类型的基团 (O)O-,-OC(O) - , - C(O) - ,-NHC(O)O-,-OC(O)NH-和/或-OC(O)O-。 并且其中n = 0-10,优选1-8,最优选1-5,并且m = 0-8,优选1-7,最优选1-5或其混合物。