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    • 1. 发明申请
    • METHOD FOR ALKYLATING AN AMINO COMPOUND
    • WO2018096011A1
    • 2018-05-31
    • PCT/EP2017/080149
    • 2017-11-23
    • BOREALIS AGROLINZ MELAMINE GMBH
    • GABRIEL, HerbertDICKE, René
    • C07D251/70C07C275/06
    • The invention relates to a method for alkylating an amino compound, characterized in that at least one triazine derivative of general formula (I) or at least one urea or urea derivative of the general formula (II), (II), wherein • R 4 and R 5 mean independently from each other Q 1 or a moiety of the formula R 6 -N-R 7 or R 8 -N-R 9 bound with its central nitrogen atom to the triazine ring of the structure of formula (I), whereat - Q 1 means a linear or branched C 1 -C 30 -alkyl or a cyclic substituent in form of a C 5- C 20 -cycloalkyl, a C 5 -C 20 -aryl, a C 1 -C 20 -alkylsubstituted C 5 -C 20 -aryl or an amide of a cyclic unsaturated carboxylic acid, whereat the C 1 -C 30 -alkyl or the cyclic substituent can be interrupted by one or multiple oxygen atoms, sulphur atoms, substituted nitrogen atoms and/or by one or multiple groups of the type –C(O)O-,-OC(O)-,-C(O)- and/or –OC(O)O-, • R 1 , R 2 , R 3 , R 6 , R 7 , R 8 and R 9 mean independently from each other H, linear or branched C 1 -C 20 -alkyl, C 5 -C 20 -cyclo alkyl, C 5 -C 20 -aryl, C 1 -C 20 -alkylsubstituted C 5 -C 20 -aryl, which in each case can be interrupted by one or multiple oxygen atoms, sulphur atoms and/or substituted nitrogen atoms and/or by one or multiple groups of the type –C(O)O-, - OC(O)-, -C(O)- and/or –OC(O) O- and/or can be functionalized by one or multiple hydroxyl groups and/or mercapto groups, and • X means O or S, is reacted with at least one alcohol of the general formula (III) R 10 -OH wherein R 10 means a linear or branched C 1 -C 20 -alkyl, C 5 -C 20 -cycloalkyl, or C 1 -C 20 - alkylsubstituted C 5 -C 20 -aryl, which can be in each case interrupted by one or multiple oxygen atoms, sulphur atoms, substituted nitrogen atoms and/or by one or multiple groups of the type –C(O)O-, -OC(O)-, -C(O)- and/or –OC(O)O- and/or can be functionalized by one or multiple hydroxyl groups and/or mercapto groups, wherein the reaction is carried out in the presence of at least one Ruthenate of the general formula (IV) M n (RuO 4 ) and/or at least one Perruthenate of the general formula (V) M(RuO4)n wherein the cation M is selected from a group comprising an alkali, earth alkali or substituted or non-substituted ammonium cation.
    • 2. 发明申请
    • NOVEL TRIAZINE-PRECONDENSATE-ALDEHYDE CONDENSATION PRODUCTS AND METHOD FOR OBTAINING THE SAME
    • 新的三嗪前体 - 醛 - 醛缩合产物及其获得方法
    • WO2018002106A1
    • 2018-01-04
    • PCT/EP2017/065940
    • 2017-06-28
    • BOREALIS AGROLINZ MELAMINE GMBH
    • GABRIEL, HerbertDICKE, RenéPUCHBERGER, Helmut
    • C07D251/00
    • The present invention relates to a triazine-precondensate-aldehyde condensation products is provided that is obtainable by reacting a) at least one triazine compound of the general formulae (I), b) at least one aldehyde, in particular formaldehyde, and c) at least one triazine precondensate of the general formula (II),, wherein R 1 means Q 1 or a moiety of the formula R 3 -N-R 4 connected with the nitrogen atom to the triazine ring of the structure of formula (I), wherein R9 means Q1 or a moiety of the formula R 7 -N-R 8 connected with the nitrogen atom to the triazine ring of the structure of formula (I), wherein R 2 , R 3 , R 4 and R 6 mean independently from each other H, Q 1 or formula, R 7 and R 8 mean independently from each other H, Q 1 , formula, R 10 and R 11 mean independently from each other R 7 or R 8 ; R 5 means linear or branched C 2 -C 20 -alkyl that can be interrupted by one or more oxygen atoms, sulphur atoms, substituted and non-substituted nitrogen atoms, R x , R y mean independently from each other H, OH, Q 1 , -[C 1 C 18 ]-OH or formula, wherein Q 1 means linear or branched C 1 -C- 20 -alkyl, linear or branched C 2 -C 20 -alkenyl, linear or branched C 2 -C 20 -alkinyl, C 3 -C 10 -cycloalkyl, C 5 -C 7 -cycloalkenyl, which in each case can be interrupted by one or more oxygen atoms, sulphur atoms, substituted or non-substituted nitrogen atoms and/or by one or more groups of the type -C(O)O-, -OC(O)-, -C(O)-, -NHC(0)0-, -OC(O) NH- and/or -OC(O)O-; and wherein n = 0-10, preferably 1 -8, most preferably 1 - 5, and m = 0-8, preferably 1 -7, most preferably 1 - 5 or mixtures thereof.
    • 本发明涉及三嗪 - 预缩合物 - 醛缩合产物,其可通过使a)至少一种通式(I)的三嗪化合物,b)至少一种醛, 特别是甲醛,和c)至少一种通式(II)的三嗪预缩合物,其中R 1表示Q 1或式R 1部分 (I)结构的三嗪环与氮原子连接,其中R 9是指Q1或下式的部分R 7: (I)结构的三嗪环与氮原子连接,其中R 2,R 3,R 3, R 4和R 6彼此独立地表示H,Q 1或式R 7和 R 8彼此独立地表示H,Q 1,式,R 10和R 11 意思是相互独立的R 7或R 8; R5 5是指可以被一个或多个氧原子,硫原子,取代的和被一个或多个氧原子间隔的直链或支链C 2 -C 20烷基 未取代的氮原子,R x,R y相互独立地表示H,OH,Q 1, - [C≡N] 1 C18] - OH或式,其中Q 1表示直链或支链的C 1 -C 20 - 直链或支链的C 2 -C 20 - 烯基,直链或支链的C 2 -C 20 低级烷基,C 3 -C 10 - 环烷基,C 5 -C 7 - 环烯基 其在每种情况下可以被一个或多个氧原子,硫原子,取代或未取代的氮原子和/或一个或多个-C(O)O - , - OC(O) - ,-C(O) - , - NHC(O)O - , - OC(O)NH-和/或-OC(O)O-。 并且其中n = 0-10,优选1-8,最优选1-5和m = 0-8,优选1-7,最优选1-5或其混合物。
    • 3. 发明申请
    • NOVEL TRIAZINE PRECONDENSATE AND METHOD FOR OBTAINING THE SAME
    • 新的三嗪前体及其获得方法
    • WO2018001825A1
    • 2018-01-04
    • PCT/EP2017/065242
    • 2017-06-21
    • BOREALIS AGROLINZ MELAMINE GMBH
    • GABRIEL, HerbertDICKE, RenéPUCHINGER, Helmut
    • C07D251/70
    • The present invention relates to a triazine precondensate according to the general formula (I) wherein R 1 means Q 1 or a moiety of the formula R 3 –N–R 4 connected with the nitrogen atom to the triazine ring of the structure of formula (I), wherein R 9 means Q 1 or a moiety of the formula R 7 –N–R 8 connected with the nitrogen atom to the triazine ring of the structure of formula (I), wherein R 2 , R 3 , R 4 and R 6 mean independently from each other H, Q 1 or (i), R 7 and R 8 mean independently from each other H, Q 1 , (ii) or (iii) or (i), R 10 and R 11 mean independently from each other R 7 or R 8 ; R 5 means linear or branched C 2 -C 20 -alkyl that can be interrupted by one or more oxygen atoms, sulphur atoms, substituted or non-substituted nitrogen atoms, R x , R y mean independently from each other H, OH, Q 1 , -[C 1 -C 18 ]-OH or (iv) wherein Q 1 means linear or branched C 1 -C 20 -alkyl, linear or branched C 2 -C 20 -alkenyl, linear or branched C 2 -C 20 -alkinyl, C 3 -C 10 -cycloalkyl, C 5 -C 7 -cycloalkenyl, C 6 -C 12 aryl which in each case can be interrupted by one or more oxygen atoms, sulphur atoms, and/or by one or more groups of the type -C(O)O-, -OC(O)-, -C(O)-, -NHC(O)O-, -OC(O)NH- and/or -OC(O)O-; and wherein n = 0-10, preferably 1-8, most preferably 1-5, and m = 0-8, preferably 1-7, most preferably 1-5 or mixtures thereof.
    • 本发明涉及根据通式(I)的三嗪预缩合物,其中R 1表示Q 1或式 其中R 9表示与氮原子连接的式(I)结构的三嗪环,其中R 9表示 Q 1或式R 7 -N-R 8的部分与氮原子连接到式(I)结构的三嗪环上, (I)的化合物,其中R 2,R 3,R 4和R 6彼此独立地表示H ,Q 1或(i)中,R 7和R 8彼此独立地表示H,Q 1, ,(ii)或(iii)或(i)中,R 10和R 11彼此独立地表示彼此独立的R 7或R 9 > 8 ; R 5表示可以被一个或多个氧原子,硫原子,取代的或被一个或多个氧原子间隔的直链或支链C 2 -C 20 - 烷基 未取代的氮原子,R x,R y相互独立地表示H,OH,Q 1, - [C≡N] (iv)其中Q 1表示直链或支链的C 1 -C 12烷基, 直链或支链C 2 -C 20 - 烯基,直链或支链C 2 -C 20 - 20-炔基,C 3 -C 10 - 环烷基,C 5 -C 7 - 烷基,C 5 -C 10环烷基, 环烯基,C≡C-C12芳基,其在每种情况下可以被一个或多个氧原子,硫原子和/或一个或多个类型的基团 (O)O-,-OC(O) - , - C(O) - ,-NHC(O)O-,-OC(O)NH-和/或-OC(O)O-。 并且其中n = 0-10,优选1-8,最优选1-5,并且m = 0-8,优选1-7,最优选1-5或其混合物。
    • 5. 发明公开
    • METHOD FOR ALKYLATING AN AMINO COMPOUND
    • EP3544963A1
    • 2019-10-02
    • EP17816488.5
    • 2017-11-23
    • Borealis Agrolinz Melamine GmbH
    • GABRIEL, HerbertDICKE, René
    • C07D251/70C07C275/06
    • The invention relates to a method for alkylating an amino compound, characterized in that at least one triazine derivative of general formula (I) or at least one urea or urea derivative of the general formula (II) wherein €¢ R 4 and R 5 mean independently from each other Q 1 or a moiety of the formula R 6 -N-R 7 or R 8 -N-R 9 bound with its central nitrogen atom to the triazine ring of the structure of formula (I), whereat - Q 1 means a linear or branched C 1 -C 30 -alkyl or a cyclic substituent in form of a C 5 -C 20 -cycloalkyl, a C 5 -C 20 -aryl, a C 1 -C 20 -alkylsubstituted C 5 -C 20 -aryl or an amide of a cyclic unsaturated carboxylic acid, whereat the C 1 -C 30 -alkyl or the cyclic substituent can be interrupted by one or multiple oxygen atoms, sulphur atoms, substituted nitrogen atoms and/or by one or multiple groups of the type -C(O)O-, -OC(O)-, -C(O)- and/or -OC(O)O-, €¢ R 1 , R 2 , R 3 , R 6 , R 7 , R 8 and R 9 mean independently from each other H, linear or branched C 1 -C 20 -alkyl, C 5 -C 20 -cyclo alkyl, C 5 -C 20 -aryl, C 1 -C 20 -alkylsubstituted C 5 -C 20 -aryl, which in each case can be interrupted by one or multiple oxygen atoms, sulphur atoms and/or substituted nitrogen atoms and/or by one or multiple groups of the type -C(O)O-, - OC(O)-, -C(O)- and/or -OC(O)O- and/or can be functionalized by one or multiple hydroxyl groups and/or mercapto groups, and €¢ X means O or S, is reacted with at least one alcohol of the general formula (III) €ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ R 10 -OH wherein R 10 means a linear or branched C 1 -C 20 -alkyl, C 5 -C 20 -cycloalkyl, or C 1 -C 20 -alkylsubstituted C 5 -C 20 -aryl, which can be in each case interrupted by one or multiple oxygen atoms, sulphur atoms, substituted nitrogen atoms and/or by one or multiple groups of the type -C(O)O-, -OC(O)-, -C(O)- and/or -OC(O)O- and/or can be functionalized by one or multiple hydroxyl groups and/or mercapto groups, wherein the reaction is carried out in the presence of at least one Ruthenate of the general formula (IV) M n (RuO 4 ) and/or at least one Perruthenate of the general formula (V) M(RuO 4 )n wherein the cation M is selected from a group comprising an alkali, earth alkali or substituted or non-substituted ammonium cation.
    • 6. 发明公开
    • NOVEL TRIAZINE-PRECONDENSATE-ALDEHYDE CONDENSATION PRODUCTS AND METHOD FOR OBTAINING THE SAME
    • EP3478667A1
    • 2019-05-08
    • EP17740303.7
    • 2017-06-28
    • Borealis Agrolinz Melamine GmbH
    • GABRIEL, HerbertDICKE, RenéPUCHBERGER, Helmut
    • C07D251/00
    • The present invention relates to a triazine-precondensate-aldehyde condensation products is provided that is obtainable by reacting a) at least one triazine compound of the general formulae (I) b) at least one aldehyde, in particular formaldehyde, and c) at least one triazine precondensate of the general formula (II) as additive, wherein R 1 means Q 1 or a moiety of the formula R 3 -N-R 4 connected with the nitrogen atom to the triazine ring of the structure of formula (I), wherein Rg means Q 1 or a moiety of the formula R 7 -N-R 8 connected with the nitrogen atom to the triazine ring of the structure of formula (I), wherein R 2 , R 3 , R 4 and R 6 mean independently from each other H, Q 1 or R 7 and R 8 mean independently from each other H, Q 1 , or R 10 and R 11 mean independently from each other R 7 or R 8 ; R 5 means linear or branched C 2 -C 20 -alkyl that can be interrupted by one or more oxygen atoms, sulphur atoms, substituted and non-substituted nitrogen atoms, R x , R y mean independently from each other H, OH, Q 1 , -[C 1 -C 18 ]-OH or wherein Q 1 means linear or branched C 1 -C 20 -alkyl, linear or branched C 2 -C 20 -alkenyl, linear or branched C 2 -C 20 -alkinyl, C 3 -C 10 -cycloalkyl, C 5 -C 7 -cycloalkenyl, which in each case can be interrupted by one or more oxygen atoms, sulphur atoms, substituted or non-substituted nitrogen atoms and/or by one or more groups of the type -C(O)O-, -OC(O)-, -C(O)-, -NHC(O)O-, -OC(O)NH- and/or -OC(O)O-; and wherein n = 0-10, preferably 1-8, most preferably 1 - 5, and m = 0-8, preferably 1-7, most preferably 1 - 5 or mixtures thereof.
    • 7. 发明公开
    • NOVEL TRIAZINE-PRECONDENSATE-ALDEHYDE CONDENSATION PRODUCTS AND METHOD FOR OBTAINING THE SAME
    • 新的三嗪前体 - 醛 - 醛缩合产物及其获得方法
    • EP3263560A1
    • 2018-01-03
    • EP16176870.0
    • 2016-06-29
    • Borealis Agrolinz Melamine GmbH
    • GABRIEL, HerbertDICKE, RenéPUCHINGER, Helmut
    • C07D251/00
    • C07D251/64C07D487/22C08G12/32C09D161/28C09J161/28
    • The present invention relates to a triazine-precondensate-aldehyde condensation products is provided that is obtainable by reacting
      a) at least one triazine compound of the general formulae (I)

      b) at least one aldehyde, in particular formaldehyde, and c) at least one triazine precondensate of the general formula (II)

      as additive, wherein R 1 means Q 1 or a moiety of the formula R 3 -N-R 4 connected with the nitrogen atom to the triazine ring of the structure of formula (I), wherein Rg means Q 1 or a moiety of the formula R 7 -N-R 8 connected with the nitrogen atom to the triazine ring of the structure of formula (I), wherein R 2 , R 3 , R 4 and R 6 mean independently from each other H, Q 1 or

      R 7 and R 8 mean independently from each other H, Q 1 ,

      or

      R 10 and R 11 mean independently from each other R 7 or R 8 ; R 5 means linear or branched C 2 -C 20 -alkyl that can be interrupted by one or more oxygen atoms, sulphur atoms, substituted and non-substituted nitrogen atoms, R x , R y mean independently from each other H, OH, Q 1 , -[C 1 -C 18 ]-OH or

      wherein Q 1 means linear or branched C 1 -C 20 -alkyl, linear or branched C 2 -C 20 -alkenyl, linear or branched C 2 -C 20 -alkinyl, C 3 -C 10 -cycloalkyl, C 5 -C 7 -cycloalkenyl, which in each case can be interrupted by one or more oxygen atoms, sulphur atoms, substituted or non-substituted nitrogen atoms and/or by one or more groups of the type -C(O)O-, -OC(O)-, -C(O)-, -NHC(O)O-, -OC(O)NH- and/or -OC(O)O-; and wherein n = 0-10, preferably 1-8, most preferably 1 - 5, and m = 0-8, preferably 1-7, most preferably 1 - 5 or mixtures thereof.
    • 本发明涉及三嗪 - 预缩合物 - 醛缩合产物,其可通过以下方式获得:a)至少一种通式(I)的三嗪化合物,b)至少一种醛,特别是甲醛,和c)至少一种 一种通式(II)的三嗪预缩合物作为添加剂,其中R1是指Q1或式R3-N-R4与氮原子连接在式(I)结构的三嗪环上的部分,其中Rg是指Q1 或与氮原子连接的具有式(I)结构的三嗪环的式R7-NR8部分,其中R2,R3,R4和R6彼此独立地表示H,Q1或R7和R8意味着 彼此独立地H,Q1或R10和R11彼此独立地表示R7或R8; R5是指可以被一个或多个氧原子,硫原子,取代和未取代的氮原子间隔的直链或支链C2-C20-烷基,Rx,Ry彼此独立地表示H,OH,Q1, - [C1- C18] -OH或其中Q1表示直链或支链C1-C20-烷基,直链或支链C2-C20-链烯基,直链或支链C2-C20-炔基,C3-C10-环烷基,C5-C7-环烯基, 可以被一个或多个氧原子,硫原子,取代或未取代的氮原子和/或一个或多个-C(O)O - , - OC(O) - ,-C(= O) - , - NHC(O)O-,-OC(O)NH-和/或-OC(O)O-。 并且其中n = 0-10,优选1-8,最优选1-5和m = 0-8,优选1-7,最优选1-5或其混合物。
    • 8. 发明公开
    • METHOD FOR ALKYLATING AN AMINO COMPOUND
    • EP3327009A1
    • 2018-05-30
    • EP16200228.1
    • 2016-11-23
    • Borealis Agrolinz Melamine GmbH
    • GABRIEL, HerbertDICKE, René
    • C07D251/70C07C275/06
    • C07D251/70C07C273/1863C07C275/06
    • The invention relates to a method for alkylating an amino compound, characterized in that at least one triazine derivative of general formula (I)

      or at least one urea or urea derivative of the general formula (II)

      wherein
      • R 4 and R 5 mean independently from each other Q 1 or a moiety of the formula R 6 -N-R 7 or R 8 -N-R 9 bound with its central nitrogen atom to the triazine ring of the structure of formula (I), whereat
      - Q 1 means a linear or branched C 1 -C 30 -alkyl or a cyclic substituent in form of a C 5 -C 20 -cycloalkyl, a C 5 -C 20 -aryl, a C 1 -C 20 -alkylsubstituted C 5 -C 20 -aryl or an amide of a cyclic unsaturated carboxylic acid, whereat the C 1 -C 30 -alkyl or the cyclic substituent can be interrupted by one or multiple oxygen atoms, sulphur atoms, substituted nitrogen atoms and/or by one or multiple groups of the type -C(O)O-, -OC(O)-, -C(O)- and/or -OC(O)O-,

      • R 1 , R 2 , R 3 , R 6 , R 7 , R 8 and R 9 mean independently from each other H, linear or branched C 1 -C 20 -alkyl, C 5 -C 20 -cyclo alkyl, C 5 -C 20 -aryl, C 1 -C 20 -alkylsubstituted C 5 -C 20 -aryl, which in each case can be interrupted by one or multiple oxygen atoms, sulphur atoms and/or substituted nitrogen atoms and/or by one or multiple groups of the type -C(O)O-, - OC(O)-, -C(O)- and/or -OC(O)O- and/or can be functionalized by one or multiple hydroxyl groups and/or mercapto groups, and
      • X means O or S,
      is reacted with at least one alcohol of the general formula (III)

               R 10 -OH

      wherein R 10 means a linear or branched C 1 -C 20 -alkyl, C 5 -C 20 -cycloalkyl, or C 1 -C 20 -alkylsubstituted C 5 -C 20 -aryl, which can be in each case interrupted by one or multiple oxygen atoms, sulphur atoms, substituted nitrogen atoms and/or by one or multiple groups of the type -C(O)O-, -OC(O)-, -C(O)- and/or -OC(O)O- and/or can be functionalized by one or multiple hydroxyl groups and/or mercapto groups, wherein the reaction is carried out in the presence of at least one Ruthenate of the general formula (IV) M n (RuO 4 ) and/or at least one Perruthenate of the general formula (V) M(RuO 4 )n wherein the cation M is selected from a group comprising an alkali, earth alkali or substituted or non-substituted ammonium cation.
    • 9. 发明公开
    • NOVEL TRIAZINE PRECONDENSATE AND METHOD FOR OBTAINING THE SAME
    • 新的三嗪前体及其获得方法
    • EP3263561A1
    • 2018-01-03
    • EP16176878.3
    • 2016-06-29
    • Borealis Agrolinz Melamine GmbH
    • GABRIEL, HerbertDICKE, RenéPUCHINGER, Helmut
    • C07D251/70
    • C07D251/70
    • The present invention relates to a triazine precondensate according to the general formula (I)

      wherein R 1 means Q 1 or a moiety of the formula R 3 -N-R 4 connected with the nitrogen atom to the triazine ring of the structure of formula (I), wherein R 9 means Q 1 or a moiety of the formula R 7 -N-R 8 connected with the nitrogen atom to the triazine ring of the structure of formula (I),
      wherein R 2 , R 3 , R 4 and R 6 mean independently from each other H, Q1 or R 8 mean independently from each other H, Q 1 ,

      R 7 and

      or

      R 10 and R 11 mean independently from each other R 7 or R 8 ; R 5 means linear or branched C 2 -C 20 -alkyl that can be interrupted by one or more oxygen atoms, sulphur atoms, substituted or non-substituted nitrogen atoms, R x , Ry mean independently from each other H, OH, Q 1 , -[C 1 -C 18 ]-OH or

      wherein Q 1 means linear or branched C 1 -C 20 -alkyl, linear or branched C 2 -C 20 -alkenyl, linear or branched C 2 -C 20 -alkinyl, C 3 -C 10 -cycloalkyl, C 5 -C 7 -cycloalkenyl, which in each case can be interrupted by one or more oxygen atoms, sulphur atoms, substituted or non-substituted nitrogen atoms and/or by one or more groups of the type -C(O)O-, -OC(O)-, -C(O)-, -NHC(O)O-, -OC(O)NH- and/or -OC(O)O-; and wherein n = 0-10, preferably 1-8, most preferably 1 - 5, and m = 0-8, preferably 1-7, most preferably 1 - 5 or mixtures thereof.
    • 本发明涉及根据通式(I)的三嗪预缩合物,其中R 1是指Q1或式R3-N-R4与氮原子连接至式(I)结构的三嗪环的部分,其中 R9是指Q1或式R7-NR8的与氮原子连接的式(I)结构的三嗪环的部分,其中R2,R3,R4和R6彼此独立地表示H,Q1或R8 彼此独立地表示H,Q1,R7和/或R10和R11彼此独立地表示R7或R8; R5是指可被一个或多个氧原子,硫原子,取代或未取代的氮原子间隔的直链或支链C2-C20-烷基,Rx,Ry彼此独立地表示H,OH,Q1, - [C1- C18] -OH或其中Q1表示直链或支链C1-C20-烷基,直链或支链C2-C20-链烯基,直链或支链C2-C20-炔基,C3-C10-环烷基,C5-C7-环烯基, 可以被一个或多个氧原子,硫原子,取代或未取代的氮原子和/或一个或多个-C(O)O - , - OC(O) - ,-C(= O) - , - NHC(O)O-,-OC(O)NH-和/或-OC(O)O-。 并且其中n = 0-10,优选1-8,最优选1-5和m = 0-8,优选1-7,最优选1-5或其混合物。