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1. 发明申请

WO2010049169A1 CROSS-LINKABLE POLYETHYLENE RESIN FOR PIPES MADE BY A SINGLE-SITE CATALYST 审中-公开
标题翻译：用于单壁催化剂的管道的交联聚乙烯树脂
公开(公告)号：WO2010049169A1
公开(公告)日：2010-05-06
申请号：PCT/EP2009/007785
申请日：2009-10-30
申请人： BOREALIS AG , KOKKO, Esa , PAKKANEN, Anneli , VAHTERI, Markku , PALMLÖF, Magnus , ODERKERK, Jeroen
发明人： KOKKO, Esa , PAKKANEN, Anneli , VAHTERI, Markku , PALMLÖF, Magnus , ODERKERK, Jeroen
IPC分类号： C08F10/02 , C08F297/08
CPC分类号： C08F110/02 , B29D23/001 , C08F4/65912 , C08F4/65916 , C08F10/00 , C08F297/08 , C08F297/083 , C08L23/04 , C08L2205/02 , F16L9/12 , F16L11/04 , Y10T428/139 , C08F4/65925 , C08F2/001 , C08L2666/06 , C08F2500/03 , C08F2500/12 , C08F2500/19
摘要： An ethylene polymer with a density of less than 955 kg/m 3 obtained by polymerisation with a single-site catalyst and having a shear thinning index SHI 2.7/210 of less than 5 wherein ethylene polymer comprises two components.
摘要翻译：密度小于955kg / m 3的乙烯聚合物通过用单中心催化剂聚合获得，并且具有小于5的剪切稀化指数SHI2.7 / 210，其中乙烯聚合物包含两种组分。

2. 发明申请

WO2010052266A1 PROCESS FOR THE PREPARATION OF POLYETHYLENE 审中-公开
标题翻译：制备聚乙烯的方法
公开(公告)号：WO2010052266A1
公开(公告)日：2010-05-14
申请号：PCT/EP2009/064673
申请日：2009-11-05
申请人： BOREALIS AG , SEVERN, John , PAKKANEN, Anneli , MUSTONEN, Marja , KOKKO, Esa , TURPEINEN, Tarja-Tuulikki , AUMO, Jeanette , REKONEN, Petri , VAHTERI, Markku , MAARANEN, Janne , KRAJETE, Alexander , DRENG, Tore , DIX, Albrecht
发明人： SEVERN, John , PAKKANEN, Anneli , MUSTONEN, Marja , KOKKO, Esa , TURPEINEN, Tarja-Tuulikki , AUMO, Jeanette , REKONEN, Petri , VAHTERI, Markku , MAARANEN, Janne , KRAJETE, Alexander , DRENG, Tore , DIX, Albrecht
IPC分类号： C08F210/16 , C08F4/6592
CPC分类号： C08F110/02 , C08F4/65925 , C08F10/00 , C08F210/16 , C08F4/65912 , C08F210/14 , C08F2500/12 , C08F2500/18 , C08F2500/24
摘要： Process for the preparation of a polyethylene comprising the steps • prepolymerizing a solid metallocene catalyst system in the presence of ethylene and/or (a) C3 to C10 α-olefm(s) at a temperature above 75 °C, and subsequently polymerizing in the presence of the prepolymerized solid metallocene catalyst system ethylene and optionally C3 to C10 α-olefm(s) obtaining a polyethylene, and wherein the solid metallocene catalyst system used in step (a) has surface area measured according to ASTM D 3663 of less than 25.0 m 2 /g and comprises a cocatalyst (Co) and an organo-transition metal compound of formula (I) L 2 R n MX 2 (I) wherein M is a transition metal of groups 4 to 10 of the periodic table (IUPAC) L is an organic η 5 -ligand, R is a bridging group linking the organic ligands (L), X is a ligand with a σ-bond to the transition metal (M) n is 0, 1 or 2.
摘要翻译：制备聚乙烯的方法包括以下步骤：在乙烯和/或（a）C 3 -C 10α-烯烃存在下，在高于75℃的温度下预固化固体茂金属催化剂体系，随后在存在预聚合的固体金属茂催化剂体系乙烯和任选的C 3 -C 10α-烯烃获得聚乙烯，并且其中步骤（a）中使用的固体茂金属催化剂体系具有根据ASTM D 3663测量的表面积小于25.0 m 2 / g，并且包含助催化剂（Co）和式（I）的有机过渡金属化合物L2RnMX2（I）其中M是周期表第4至10族的过渡金属（IUPAC），L是有机α5 - 配体，R是连接有机配体（L）的桥连基团，X是与过渡金属（M）的s键的配体，n为0,1或2。

3. 发明申请

WO2010125022A1 LINEAR LOW DENSITY POLYETHYLENE WITH UNIFORM OR REVERSED COMONOMER COMPOSITION DISTRIBUTION 审中-公开
标题翻译：线性低密度聚乙烯具有均匀或反转的人气组合物分布
公开(公告)号：WO2010125022A1
公开(公告)日：2010-11-04
申请号：PCT/EP2010/055519
申请日：2010-04-26
申请人： BOREALIS AG , GAROFF, Thomas , WALDVOGEL, Päivi , KALLIO, Kalle , ERIKSSON, Virginie , AITTOLA, Aki , KOKKO, Esa
发明人： GAROFF, Thomas , WALDVOGEL, Päivi , KALLIO, Kalle , ERIKSSON, Virginie , AITTOLA, Aki , KOKKO, Esa
IPC分类号： C08F10/00 , C08F210/02 , C08L23/08
CPC分类号： C08F210/16 , C08L2314/02 , C08F210/08 , C08F2500/12 , C08F2500/18 , C08F2500/08 , C08F2500/10
摘要： Ziegler-Natta catalyzed linear low density polyethylene which satisfies the following conditions: a) a density, according to ISO 1183, of from 900 to 925 kg/m 3 , b) a C 4 -C 10 -comonomer content, determined by Fourier transform infrared spectroscopy, of 1 to 16 wt% c) a weight average molecular weight Mw, determined by gel permeation chromatography, of at least 200 000, d) wherein the linear low density polyethylene comprises, by Crystallisation Analysis Fractionation (CRYSTAF) an amorphous fraction soluble at a temperature below 30°C of at most 10 wt% and a fraction crystallising between 60 to 75°C of at least 35 wt% and e) by temperature rising elution fractionation (TREF) analysis, at least 70 wt% of a crystallising polymer component having an elution temperature range from 60°C to 94°C and less than 10 wt% of a crystallising polymer component having an elution temperature range from 30°C to 60° and, f) by Gel Permeation chromatography using an Fourier transform infrared spectroscopy detector (GPC-FTIR), a substantially constant short chain branching profile across the molecular weight distribution (MWD) or g) by Gel Permeation chromatography coupled with Fourier transform infrared spectroscopy instruments (GPC-FTIR), a revers short chain branching profile across the molecular weight distribution (MWD), the linear low density polyethylene being produced in the presence of a special Ziegler- Natta procatalyst and a halogenated aluminium alkyl cocatalyst of the formula (IV) (C 1 -C 4 - alkyl) m -AI-X 3-m1 , wherein X is chlorine, bromine, iodine or fluorine and m is 1 or 2.
摘要翻译：齐格勒 - 纳塔催化的线性低密度聚乙烯，其满足以下条件：a）根据ISO 1183的密度为900至925kg / m 3，b）通过傅立叶变换红外光谱测定的C 4 -C 10共聚单体含量， c）通过凝胶渗透色谱测定的至少200000重量平均分子量Mw，d）其中线性低密度聚乙烯通过结晶分析分馏（CRYSTAF）包含在温度低于30℃至多10重量％，并且在60至75℃之间结晶至少35重量％的馏分和e）通过升温洗脱分馏（TREF）分析，至少70重量％的结晶聚合物组分具有洗脱温度范围为60℃至94℃且小于10重量％的洗脱温度范围为30℃至60℃的结晶聚合物组分，f）通过使用傅里叶变换红外光谱的凝胶渗透色谱法（GPC-FTIR），通过凝胶渗透色谱与傅立叶变换红外光谱仪（GPC-FTIR）结合，分子量分布（MWD）基本恒定的短链支化谱，或g），反向短链支化谱分子量分布（MWD），线性低密度聚乙烯是在特殊的齐格勒 - 纳塔前催化剂和式（Ⅳ）的卤化烷基铝助催化剂（C1-C4烷基）m-AI-X3- m1，其中X是氯，溴，碘或氟，m是1或2。

4. 发明申请

WO2010052264A1 SOLID CATALYST COMPOSITION 审中-公开
标题翻译：固体催化剂组合物
公开(公告)号：WO2010052264A1
公开(公告)日：2010-05-14
申请号：PCT/EP2009/064670
申请日：2009-11-05
申请人： BOREALIS AG , MANSNER, Erik , KOKKO, Esa , KAUHANEN, Jyrki , SEVERN, John
发明人： MANSNER, Erik , KOKKO, Esa , KAUHANEN, Jyrki , SEVERN, John
IPC分类号： B01J31/16 , B01J31/22 , B01J31/12 , B01J31/14
CPC分类号： B01J31/2295 , B01J31/128 , B01J31/143 , B01J31/165 , B01J2231/122 , B01J2531/46 , B01J2531/48 , B01J2531/49 , C08F4/65925 , C08F10/00 , C08F110/06 , C08F4/65912
摘要： Solid catalyst composition comprising a polymer matrix (A) and distributed therein a solid catalyst system (B), wherein (a) the solid catalyst system (B) comprises • a transition metal compound of formula (I) L m R n MX q , (I) wherein "M" is a transition metal of anyone of the groups 3 to 10 of the periodic table (IUPAC), each "X" is independently a monovalent anionic σ-ligand, each "L" is independently an organic ligand which coordinates to the transition metal (M), "R" is a bridging group linking two organic ligands (L), said organic ligands (L) and said bridging groups (R) do not comprise polymerizable olefϊnic groups, "m" is 2 or 3, "n" is 0, 1 or 2, "q" is 1, 2 or 3, m+q is equal to the valency of the transition metal (M), and • a cocatalyst (Co) comprising a compound of Al, and (b) the polymer matrix (A) is not covalent bonded to anyone of the organic ligands (L) and/or to anyone of the bridging groups (R) of the transition metal compound.
摘要翻译：固体催化剂组合物，其包含聚合物基体（A）并分布在其中的固体催化剂体系（B），其中（a）所述固体催化剂体系（B）包含：式（I）的过渡金属化合物LmRnMXq，（I）其中“ M“是元素周期表（IUPAC）中的任何3至10族的过渡金属，每个”X“独立地是一价阴离子S-配体，”L“分别是与过渡金属配位的有机配体（M）中，“R”是连接两个有机配体（L），所述有机配体（L）和所述桥连基团（R）的桥连基团不包含可聚合的烯基，“m”为2或3， n“为0,1或2，”q“为1,2或3，m + q等于过渡金属（M）的化合价，和a为包含Al化合物的助催化剂（Co）和（ b）聚合物基质（A）不与任何有机配体（L）和/或任何过渡金属化合物的桥连基团（R）键合。

5. 发明申请

WO2010125020A1 IMPROVED MULTI-STAGE PROCESS FOR PRODUCING MULTI-MODAL LINEAR LOW DENSITY POLYETHYLENE 审中-公开
标题翻译：用于生产多模式线性低密度聚乙烯的改进的多级方法
公开(公告)号：WO2010125020A1
公开(公告)日：2010-11-04
申请号：PCT/EP2010/055517
申请日：2010-04-26
申请人： BOREALIS AG , GAROFF, Thomas , WALDVOGEL, Päivi , KALLIO, Kalle , ERIKSSON, Virginie , AITTOLA, Aki , KOKKO, Esa
发明人： GAROFF, Thomas , WALDVOGEL, Päivi , KALLIO, Kalle , ERIKSSON, Virginie , AITTOLA, Aki , KOKKO, Esa
IPC分类号： C08F210/16 , C08F2/00 , C08F4/655
CPC分类号： C08F210/16 , C08F2/14 , C08F4/6555 , C08F2/001 , C08F2/34 , C08F210/08 , C08F2500/18 , C08F2500/12 , C08F2500/05 , C08F2500/07 , C08F2500/02 , C08F2500/08 , C08F2500/01 , C08F210/14
摘要： Multi-stage polymerization process for the production of a multi-modal linear low density polyethylene in at least two staged reactors connected in series comprising at least (i) polymerizing in a first slurry phase stage ethylene monomers and optionally one or more alpha- olefine comonomers, in the presence of a Ziegler-Natta polymerization catalyst system to obtain a first polyethylene fraction component (A) (ii) polymerizing in a second gas or slurry phase stage ethylene monomers and one or more alpha- olefine comonomers, in the presence of a Ziegler-Natta polymerization catalyst system to obtain a second polyethylene fraction component (B), whereby the Ziegler-Natta polymerisation catalyst system comprises C) a procatalyst, which procatalyst comprises a) an Al compound having the formula AI(alkyl) x CI 3-x (l), where alkyl is an alkyl group with 1 to 12 and 0 1 ) 2-n (R 2 ) n (II), wherein each R 1 and R 2 is independently a C 1-20 hydrocarbon residue which may optionally be substituted with halogen and O y Ti(OR 3 ) 4-y (III), wherein R 3 is a C 2-20 hydrocarbon residue and y is 1, 2, 3 or 4 and compounds a), b) and c) being deposited on a particulate inorganic support and D) a halogenated aluminium alkyl cocatalyst of the formula (IV) (C 1 -C 4 -alkyl) m -AI-X 3-m , wherein X is chlorine, bromine, iodine or fluorine and m is 1 or 2, and yielding a multimodal linear low density polyethylene with a narrow molecular weight distribution, whereby the process shows a higher comonomer conversion compared to multi-stage processes using non-halogenated cocatalysts.
摘要翻译：用于在串联连接的至少两个阶段反应器中生产多模式线性低密度聚乙烯的多级聚合方法，包括至少（i）在第一浆料相阶段聚合乙烯单体和任选的一种或多种α-烯烃共聚单体在齐格勒 - 纳塔聚合催化剂体系的存在下，获得第一聚乙烯级分组分（A）（ⅱ）在第二气体或浆料相阶段聚合乙烯单体和一种或多种α-烯烃共聚单体，在齐格勒 - 纳塔聚合催化剂体系，以获得第二聚乙烯级分组分（B），其中齐格勒 - 纳塔聚合催化剂体系包含C）前催化剂，其主催化剂包含a）具有式AI（烷基）xCI3-x（其中烷基是具有1至12和0 1）2-n（R2）n（II）的烷基，其中每个R 1和R 2独立地为可任选被卤素和O yTi（OR 3）4-y（III），其中R 3是C 2-20烃残基，y是1,2,3或4，并且化合物a），b）和c）沉积在颗粒状无机载体上和D）式（Ⅳ）（C1-C4烷基）m-Al-X3-m的卤化烷基铝助催化剂，其中X是氯，溴，碘或氟，m是1或2，并产生多峰具有窄分子量分布的线性低密度聚乙烯，由此与使用非卤化助催化剂的多阶段方法相比，该方法显示出更高的共聚单体转化率。

6. 发明申请

WO2010097352A1 IMPROVED MULTI-STAGE PROCESS FOR PRODUCING MULTI-MODAL ETHYLENE POLYMER COMPOSITION 审中-公开
标题翻译：用于生产多模式乙烯聚合物组合物的改进的多阶段方法
公开(公告)号：WO2010097352A1
公开(公告)日：2010-09-02
申请号：PCT/EP2010/052173
申请日：2010-02-22
申请人： BOREALIS AG , GAROFF, Thomas , WALDVOGEL, Päivi , KALLIO, Kalle , ERIKSSON, Virginie , AITTOLA, Aki , KOKKO, Esa
发明人： GAROFF, Thomas , WALDVOGEL, Päivi , KALLIO, Kalle , ERIKSSON, Virginie , AITTOLA, Aki , KOKKO, Esa
IPC分类号： C08F10/00 , C08F4/685
CPC分类号： C08F10/00 , C08F110/02 , C08F210/16 , Y02P20/52 , C08F4/6357 , C08F4/685 , C08F2/001 , C08F2500/07 , C08F2500/12 , C08F2500/05 , C08F2500/18 , C08F210/14 , C08F2500/08
摘要： Multi-stage polymerization process for the production of a multi-modal linear low density polyethylene in at least two staged reactors connected in series comprising at least (i) polymerizing in a first slurry phase stage ethylene monomers and optionally one or more alpha-olefine comonomers, in the presence of a Ziegler-Natta polymerization catalyst system to obtain a first polyethylene fraction component (A) (ii) polymerizing in a second gas or slurry phase stage ethylene monomers and one or more alpha-olefine comonomers, in the presence of a Ziegler-Natta polymerization catalyst system to obtain a second polyethylene fraction component (B), whereby the Ziegler-Natta polymerization catalyst system comprises 1) a solid procatalyst formed by contacting at least: a) a Mg-alcoholate complex of the formula (I): Mg(OR 1 ) 2-n (R 1 ) n , wherein each R 1 independently represents a C 1 -C 20 hydrocarbyl group and 0 ≤ n 2 ) m X 3-m , wherein each R 2 independently represents an alkyl of up to 6 carbon atoms; each X is independently a halogen; 0 ≤ m 1 -C 20 -alkyl group, 0 ≤ x ≤ 2; 1 ≤ y ≤ 3; 0 ≤ z ≤ 2 and x + y + z = 3; x, y and z may or may not be an integer, yielding a multi-modal polyethylene, whereby the process shows a reduced change of comonomer response with polymerization time and a more stable comonomer conversion with polymerization time compared to multistage processes using Ziegler-Natta catalysts with 100% Ti.
摘要翻译：用于在至少两个串联反应器中连续串联生产多模式线性低密度聚乙烯的多级聚合方法，包括至少（i）在第一浆料相阶段聚合乙烯单体和任选的一种或多种α-烯烃共聚单体在齐格勒 - 纳塔聚合催化剂体系存在下，得到第一聚乙烯级分组分（A）（ⅱ）在第二种气相或淤浆相阶段中聚合乙烯单体和一种或多种α-烯烃共聚单体，在齐格勒 - 纳塔聚合催化剂体系，得到第二聚乙烯组分（B），其中齐格勒 - 纳塔聚合催化剂体系包括：1）通过使至少与下列物质接触而形成的固体前催化剂：a）式（I）的Mg-醇化物络合物，：Mg（OR1）2-n（R1）n，其中每个R1独立地表示C1-C20烃基，0 = n2）mX3-m，其中每个R2独立地表示至多6个碳原子的烷基; 每个X独立地是卤素; 0 = m <3和m，并且可以是或不是整数，c）钒化合物和钛化合物，以提供V:Ti的摩尔比为10:90至90:10，以产生固体前催化剂和2）式（III）的一种或多种有机金属助催化剂，其中每个R独立地为C 1 -C 20 - 烷基，0 = x = 2; 1 = y = 3; 0 = z = 2，x + y + z = 3; x，y和z可以是或不是整数，产生多峰聚乙烯，由此与使用齐格勒 - 纳塔（Ziegler-Natta）的多阶段方法相比，该方法显示了聚合时间下共聚单体响应的变化减小和聚合时间的更稳定的共聚单体转化具有100％Ti的催化剂。

7. 发明申请

WO2010097351A1 MULTI-STAGE PROCESS FOR PRODUCING MULTI-MODAL LINEAR LOW DENSITY POLYETHYLENE 审中-公开
标题翻译：用于生产多模式线性低密度聚乙烯的多级方法
公开(公告)号：WO2010097351A1
公开(公告)日：2010-09-02
申请号：PCT/EP2010/052172
申请日：2010-02-22
申请人： BOREALIS AG , GAROFF, Thomas , WALDVOGEL, Päivi , KALLIO, Kalle , ERIKSSON, Virginie , AITTOLA, Aki , KOKKO, Esa
发明人： GAROFF, Thomas , WALDVOGEL, Päivi , KALLIO, Kalle , ERIKSSON, Virginie , AITTOLA, Aki , KOKKO, Esa
IPC分类号： C08F10/00 , C08F4/685 , C08F2/00
CPC分类号： C08F10/00 , C08F110/02 , C08F210/16 , C08F2410/03 , Y10T428/139 , C08F4/6357 , C08F4/685 , C08F2/001 , C08F2500/07 , C08F2500/12 , C08F2500/05 , C08F2500/18 , C08F210/14 , C08F2500/08
摘要： Multi-stage polymerization process for the production of a multi-modal linear low density polyethylene in at least two staged reactors connected in series comprising at least (i) polymerizing in a first slurry phase stage ethylene monomers and optionally one or more alpha-olefine comonomers, in the presence of a Ziegler-Natta polymerization catalyst system to obtain a first polyethylene fraction component (A) (ii) polymerizing in a second gas or slurry phase stage ethylene monomers and one or more alpha-olefine comonomers, in the presence of a Ziegler-Natta polymerization catalyst system to obtain a second polyethylene fraction component (B), whereby the Ziegler-Natta polymerization catalyst system comprises: 1) a solid procatalyst formed by contacting at least: a) a Mg-alcoholate complex of the formula (I): Mg(OR 1 ) 2-n (R 1 ) n , wherein each R 1 independently represents a C 1 -C 20 hydrocarbyl group and 0 2 ) m X 3-m , wherein each R 2 independently represents an alkyl of up to 6 carbon atoms; each X is independently a halogen; 0 1 -C 20 -alkyl group, 0
摘要翻译：用于在至少两个串联反应器中连续串联生产多模式线性低密度聚乙烯的多级聚合方法，包括至少（i）在第一浆料相阶段聚合乙烯单体和任选的一种或多种α-烯烃共聚单体在齐格勒 - 纳塔聚合催化剂体系存在下，得到第一聚乙烯级分组分（A）（ⅱ）在第二种气相或淤浆相阶段中聚合乙烯单体和一种或多种α-烯烃共聚单体，在齐格勒 - 纳塔聚合催化剂体系，以获得第二聚乙烯部分组分（B），由此齐格勒 - 纳塔聚合催化剂体系包括：1）通过使至少与下式接触形成的固体前催化剂：a）式）：Mg（OR 1）2-n（R 1）n，其中每个R 1独立地表示C 1 -C 20烃基和O 2）m X 3-m，其中每个R 2独立地表示至多6个碳原子的烷基; 每个X独立地是卤素; 0

8. 发明申请

WO2009027075A2 CATALYSTS 审中-公开
标题翻译：催化剂
公开(公告)号：WO2009027075A2
公开(公告)日：2009-03-05
申请号：PCT/EP2008/007007
申请日：2008-08-27
申请人： BOREALIS TECHNOLOGY OY , VOSKOBOYNIKOV, Alexander Zelmanovich , ASACHENKO, Andrei Fyodorovich , KONANOVICH, Dmitry , NIKULIN, Mikhail V. , TZAREV, Alexey , MAARANEN, Janne , VANNE, Tiina , KAUHANEN, Jyrki , MANSNER, Erik , KOKKO, Esa , SAARINEN, Laura
发明人： VOSKOBOYNIKOV, Alexander Zelmanovich , ASACHENKO, Andrei Fyodorovich , KONANOVICH, Dmitry , NIKULIN, Mikhail V. , TZAREV, Alexey , MAARANEN, Janne , VANNE, Tiina , KAUHANEN, Jyrki , MANSNER, Erik , KOKKO, Esa , SAARINEN, Laura
IPC分类号： C08F4/656 , C08F10/00 , C07F17/00 , C07C13/465
CPC分类号： C07F17/00 , C08F4/65912 , C08F4/65916 , C08F10/00 , C08F110/02 , C08F210/16 , C08F4/65927 , C08F2500/07 , C08F2500/12 , C08F2500/03 , C08F2500/18 , C08F210/14
摘要： A complex comprising a ligand of formula (I), wherein each R 1 , which may be the same or different, is hydrogen, an optionally substituted C 1-20 hydrocarbyl group, N(R 5 ) 2 , silyl, siloxy; an optionally substituted heteroaryl group, an optionally substituted heterocyclyl group or two R 1 groups on adjacent carbon atoms taken together may form an optionally substituted 5- to 8-membered fused ring; each R 2 , which may be the same or different is hydrogen, is hydrogen, an optionally substituted C 1-20 hydrocarbyl group, N(R 5 ) 2 , silyl, siloxy; an optionally substituted heteroaryl group, or an optionally substituted heterocyclyl group; R 3 , which binds to the 6-membered ring of the indenyl group, is -(Si(R 5 ) 2 ) p -, where p is 1 or 2, -(C(R 5 ) 2 )n- where n is an integer of 2 or more; each R 4 which may be the same or different, is hydrogen, an optionally substituted C 1-20 hydrocarbyl group, N(R 5 ) 2 , silyl, siloxy, an optionally substituted heteroaryl group, an optionally substituted heterocyclyl group or two R 4 groups on adjacent carbon atoms taken together can form an optionally substituted 5- to 8-membered fused carbon ring; each R 5 , which may be the same or different, is hydrogen, an optionally substituted C 1-20 hydrocarbyl group, or two R 5 groups taken together can form an optionally substituted 5- to 8-membered ring; a is 0 to 3; b is 0 to 3; c is 0 to 4; complexed to a metal ion, M.
摘要翻译：包含式（I）的配体的络合物，其中每个R 1可以相同或不同，为氢，任选取代的C 1-20烃基，N（R 5）2，甲硅烷基，甲硅烷氧基; 任选取代的杂芳基，任选取代的杂环基或相邻碳原子上的两个R 1基团可以一起形成任选取代的5-至8-元稠环; 每个R 2可以相同或不同，为氢，为氢，任选取代的C 1-20烃基，N（R 5）2，甲硅烷基，甲硅烷氧基; 任选取代的杂芳基，或任选取代的杂环基; 结合茚基的6元环的R 3为 - （Si（R 5）2）p - ，其中p为1或2， - （C（R 5）2）n - ，其中n为 2以上; 每个R 4可以相同或不同，为氢，任选取代的C 1-20烃基，N（R 5）2，甲硅烷基，甲硅烷氧基，任选取代的杂芳基，任选取代的杂环基或相邻碳上的两个R 4基团一起取代的原子可以形成任选取代的5至8元稠合碳环; 每个R 5可以相同或不同，为氢，任选取代的C 1-20烃基或两个R 5基团可以形成任选取代的5至8元环; a是0到3; b为0〜3; c为0〜4; 与金属离子络合

9. 发明申请

WO2008043388A1 SURFACE-MODIFIED POLYMERIZATION CATALYSTS FOR THE PREPARATION OF LOW-GEL POLYOLEFIN FILMS 审中-公开
标题翻译：用于制备低凝胶聚菲膜的表面改性聚合催化剂
公开(公告)号：WO2008043388A1
公开(公告)日：2008-04-17
申请号：PCT/EP2006/012612
申请日：2006-12-29
申请人： BOREALIS TECHNOLOGY OY , KOKKO, Esa , MAARANEN, Janne , SEVERN, John , LOMMI, Marjaana , KRAJETE, Alexander , DRENG, Tore
发明人： KOKKO, Esa , MAARANEN, Janne , SEVERN, John , LOMMI, Marjaana , KRAJETE, Alexander , DRENG, Tore
IPC分类号： C08F10/00 , C08F2/00
CPC分类号： C08F10/00 , C08F4/65916 , C08F4/65925 , C08F210/16 , C08F2410/01 , C08F4/65912 , C08F4/651 , C08F210/14 , C08F2500/12 , C08F2500/03 , C08F2500/26
摘要： Use of a catalyst composition treated with a surface modifier in the polymerization of olefins for lowering the gel content in the resulting polyolefin, wherein the surface modifier has a polar residue capable of interacting with the surface of the catalyst composition and a lipophilic residue and is selected from carboxylate metal salts, nitrogen containing catalyst surface modifiers, phosphorus containing catalyst surface modifiers, oxygen containing catalyst surface modifiers, sulfur containing catalyst surface modifiers, fluoro containing polymeric catalyst surface modifiers or mixtures thereof and wherein the gel content is determined by using pressed plate gel analysis method.
摘要翻译：在烯烃聚合中用表面改性剂处理的催化剂组合物用于降低所得聚烯烃中凝胶含量的用途，其中表面改性剂具有能够与催化剂组合物的表面相互作用的极性残基和亲脂性残基，并被选择含羧基金属盐，含氮催化剂表面改性剂，含磷催化剂表面改性剂，含氧催化剂表面改性剂，含硫催化剂表面改性剂，含氟聚合物催化剂表面改性剂或其混合物，其中凝胶含量通过使用压板凝胶分析方法。

10. 发明申请

WO2020016370A1 PROCESS FOR THE PREPARATION OF AN UHMWPE HOMOPOLYMER 审中-公开
公开(公告)号：WO2020016370A1
公开(公告)日：2020-01-23
申请号：PCT/EP2019/069397
申请日：2019-07-18
申请人： BOREALIS AG
发明人： SAEED, Irfan , KOKKO, Esa , SALO, Mika , RASTOGI, Sanjay , ROMANO, Dario , RONCA, Sara
IPC分类号： C08F110/02 , C08F4/655 , C08F4/654 , C08F4/02
摘要： A process for the preparation of an ultra-high molecular weight ethylene homopolymer having a MFR 21 of 0.01 g/10min or less, said process comprising: (I) prepolymerising at least ethylene at a temperature of 0 to 90°C in the presence of a heterogeneous Ziegler Natta catalyst to prepare an ethylene prepolymer having an Mw of 40,000 to 600,000 g/mol; and thereafter in the presence of the prepolymer and said catalyst; (II) polymerising ethylene at a temperature of 55 °C or less, such as 20 to 55 °C, to prepare said UHMW ethylene homopolymer; wherein the UHMW ethylene homopolymer comprises up to 8 wt.% of said prepolymer.

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