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1. 发明申请

WO2011138214A1 PREPARATION OF A SOLID CATALYST SYSTEM 审中-公开
标题翻译：固体催化剂体系的制备
公开(公告)号：WO2011138214A1
公开(公告)日：2011-11-10
申请号：PCT/EP2011/056705
申请日：2011-04-28
申请人： BOREALIS AG , KALLIO, Kalle , MUSTONEN, Marja , ELO, Pertti , DENIFL, Peter , SEVERN, John
发明人： KALLIO, Kalle , MUSTONEN, Marja , ELO, Pertti , DENIFL, Peter , SEVERN, John
IPC分类号： C08F10/00 , C08F4/659 , C08F4/6592 , B01J31/22 , B01J31/14 , C07F5/06
CPC分类号： C08F4/76 , B01J31/124 , B01J31/128 , B01J31/143 , B01J31/2295 , B01J31/26 , B01J2531/46 , B01J2531/48 , B01J2531/49 , B01J2531/90 , B01J2531/94 , C07F5/068 , C08F4/52 , C08F4/6028 , C08F4/6592 , C08F4/65922 , C08F10/00 , C08F2410/01 , Y10S526/943 , C08F4/65912
摘要： Process for the preparation of a solid catalyst system (CS) comprising the steps of preparing a liquid clathrate (LC) comprising (a) a lattice (L) being the reaction product of (i) aluminoxane (A), (ii) an organometallic compound (O) of a transition metal (M) of Group 3 to 10 of the Periodic Table (IUPAC 2007) or of an actinide or lanthanide, and (i) a compound (B) being effective to form with the aluminoxane (A) and the organometallic compound (O) the lattice (L), and (b) a guest (G) being an hydrocarbon compound (HC), and subsequently precipitating said liquid clathrate (LC) obtaining said solid catalyst system (SC).
摘要翻译：制备固体催化剂体系（CS）的方法，包括以下步骤：制备液体包合物（LC），其包含（a）格子（L），其为（i）铝氧烷（A），（ii）有机金属（IUPAC 2007）第3至10族的过渡金属（M）或锕系元素或镧系元素的化合物（O）和（i）与铝氧烷（A）形成有效的化合物（B）和有机金属化合物（O），晶格（L）和（b）作为烃化合物（HC）的客体（G），随后沉淀得到所述固体催化剂体系（SC）的所述液体包合物（LC）。

2. 发明申请

WO2011138212A1 PREPARATION OF A SOLID CATALYST SYSTEM 审中-公开
标题翻译：固体催化剂体系的制备
公开(公告)号：WO2011138212A1
公开(公告)日：2011-11-10
申请号：PCT/EP2011/056702
申请日：2011-04-28
申请人： BOREALIS AG , KALLIO, Kalle , MUSTONEN, Marja , ELO, Pertti , SEVERN, John , DENIFL, Peter
发明人： KALLIO, Kalle , MUSTONEN, Marja , ELO, Pertti , SEVERN, John , DENIFL, Peter
IPC分类号： C08F10/00 , C08F4/659 , C08F4/6592 , B01J31/22 , B01J31/14 , C07F5/06
CPC分类号： C08F4/76 , B01J31/0239 , B01J31/0268 , B01J31/124 , B01J31/128 , B01J31/143 , B01J31/2295 , B01J31/26 , B01J2531/90 , C08F4/52 , C08F4/6592 , C08F4/65922 , C08F10/00 , C08F2410/01 , C08F4/65912
摘要： Process for the preparation of a solid catalyst system comprising the steps of generating an emulsion by dispersing a liquid clathrate in a solution wherein (i) the solution constitutes the continuous phase of the emulsion and (ii) the liquid clathrate constitutes in form of droplets the dispersed phase of the emulsion, solidifying said dispersed phase to convert said droplets to solid particles and optionally recovering said particles to obtain said catalyst system, wherein the liquid clathrate comprises a lattice being the reaction product of aluminoxane, an organometallic compound of a transition metal of Group 3 to 10 of the Periodic Table (IUPAC 2007) or of an actinide or lanthanide, and a further compound being effective to form with the aluminoxane and the organometallic compound the lattice, and a guest being an hydrocarbon compound, and the solution comprises a silicon fluid and a hydrocarbon solvent.
摘要翻译：制备固体催化剂体系的方法，包括以下步骤：通过将液体包合物分散在溶液中产生乳液，其中（i）溶液构成乳液的连续相，和（ii）液体包合物以液滴的形式构成分散相，固化所述分散相，将所述液滴转化为固体颗粒，任选地回收所述颗粒以获得所述催化剂体系，其中所述液体包合物包含格子，其为铝氧烷，过渡金属的有机金属化合物周期表第3至10组（IUPAC 2007）或锕系元素或镧系元素，以及有效与铝氧烷和有机金属化合物形成晶格的另外的化合物，以及作为烃化合物的客体，该溶液包含硅液和烃溶剂。

3. 发明申请

WO2010052239A1 PROCESS FOR THE PREPARATION OF AN UNSUPPORTED, SOLID METALLOCENE CATALYST SYSTEM AND ITS USE IN POLYMERIZATION OF OLEFINS 审中-公开
标题翻译：制备不需要的固体金属催化剂体系的方法及其在烯烃聚合中的应用
公开(公告)号：WO2010052239A1
公开(公告)日：2010-05-14
申请号：PCT/EP2009/064613
申请日：2009-11-04
申请人： BOREALIS AG , ELO, Pertti , SEVERN, John , DENIFL, Peter , RAUTIO, Soile , MUSTONEN, Marja , HONGELL, Anu-Leena
发明人： ELO, Pertti , SEVERN, John , DENIFL, Peter , RAUTIO, Soile , MUSTONEN, Marja , HONGELL, Anu-Leena
IPC分类号： C08F10/00 , C08F4/659 , C08F210/16
CPC分类号： C08F10/00 , C08F4/65925 , C08F210/16 , C08F4/65912 , C08F210/14 , C08F2500/18 , C08F2500/03 , C08F2500/12
摘要： Improved process for the preparation of an unsupported, heterogeneous olefin polymerization catalyst system, comprising an organometallic compound of a transition metal of Group 3 to 10 of the Periodic Table (IUPAC) or of an actinide or lanthanide in the form of solid particles comprising the steps of a) preparing a solution of catalyst components, including an aluminoxane, a compound being effective to form stable, liquid clathrates with aluminoxane and an organometallic compound of a transition metal of Group 3 to 10 of the Periodic Table (IUPAC 2007) or of an actinide or lanthanide, in a hydrocarbon solvent, yielding a two phase system with an upper solvent layer, which is separated, b) preparing a liquid/liquid emulsion system comprising a continuous phase in which said solution of the catalyst components forms a dispersed phase in the form of droplets, c) solidifying said dispersed phase to convert said droplets to solid particles and optionally recovering said particles to obtain said catalyst system, the catalysts system itself and its use for olefin polymerization.
摘要翻译：用于制备无支撑的非均相烯烃聚合催化剂体系的改进方法，其包含周期表（IUPAC）的第3至10族的过渡金属或固体颗粒形式的锕系元素或镧系元素的有机金属化合物，其包括步骤 a）制备催化剂组分溶液，包括铝氧烷，有效与铝氧烷和周期表第3至10族过渡金属的有机金属化合物（IUPAC 2007）形成稳定的液体包合物的化合物或锕系元素或镧系元素，在烃溶剂中，产生具有上溶剂层的两相体系，其被分离，b）制备液/液体乳液体系，其包含连续相，其中所述催化剂组分溶液形成分散相液滴的形式，c）固化所述分散相以将所述液滴转化为固体颗粒，并任选地回收所述颗粒以获得所述催化剂体系，催化剂体系本身及其在烯烃聚合中的应用。

4. 发明申请

WO2011076618A1 PREPARATION OF SINGLE-SITE CATALYSTS 审中-公开
标题翻译：单壁催化剂的制备
公开(公告)号：WO2011076618A1
公开(公告)日：2011-06-30
申请号：PCT/EP2010/069634
申请日：2010-12-14
申请人： BOREALIS AG , KALLIO, Kalle , MUSTONEN, Marja , CASTRO, Pascal , DENIFL, Peter
发明人： KALLIO, Kalle , MUSTONEN, Marja , CASTRO, Pascal , DENIFL, Peter
IPC分类号： C08F10/00 , C08F4/6592
CPC分类号： C08F10/00 , C08F4/65927 , C08F110/06 , C08F2410/01 , C08F4/65912
摘要： Process for the preparation of a catalyst system comprising the steps of (a) preparing a solution (A) comprising (i) a transition metal compound of formula (I) L m R n M q wherein "M" is a transition metal of anyone of the groups 3 to 10 of the periodic table (IUPAC), each "X" is independently a monovalent σ-ligand, each "L" is independently an organic ligand which coordinates to the transition metal (M), "R" is a bridging group linking said organic ligands (L), "m" is 2 or 3, preferably 2, "n" is 0, 1 or 2, preferably 1, "q" is 1, 2 or 3, preferably 2, m+q is equal to the valency of the transition metal (M), (ii) a cocatalyst (Co) comprising an element (E) of group 13 of the periodic table (IUPAC), preferably a cocatalyst (Co) comprising a compound of A1, (iii) a solvent (A'), (b) generating an emulsion by dispersing the solution (A) in a solvent (B) and in the presence of a surfactant (S) wherein (i) the solvent (B) constitutes the continuous phase of the emulsion and (ii) the solution (A) constitutes in form of droplets the dispersed phase of the emulsion, (iii) the transition metal compound of formula (I) and the cocatalyst (Co) are present in the droplets, and (iv) the surfactant (S) is a reaction product (RP) of at least one compound of formula (II) and a compound (C) comprising an element (E) of group 13 of the periodic table (IUPAC), preferably a compound comprising A1, the formula (II) is wherein R 1 is a semi-, highly- or perfluorinated hydrocarbon residue, and R 2 is a residue selected from the group consisting of -C(R 3 )=C(R 3' )-R 4 , wherein R 3 , R 4 , R 3' , are independently from each other selected from the group consisting of H, C 1 to C 20 alkyl, C 2 to C 20 alkenyl, C 2 to C 20 alkinyl, (c) solidifying said dispersed phase to convert said droplets to solid particles and (d) optionally recovering said particles to obtain said catalyst system.
摘要翻译：制备催化剂体系的方法，包括以下步骤：（a）制备溶液（A），其包含（i）式（I）的过渡金属化合物LmRnMq，其中“M”是3至 10的周期表（IUPAC）中，每个“X”独立地是一价s配体，“L”分别是与过渡金属（M）配位的有机配体，“R”是连接所述有机物配体（L），“m”为2或3，优选2，“n”为0,1或2，优选1，“q”为1,2或3，优选2，m + q等于的过渡金属（M），（ii）包含周期表第13族元素（E）的助催化剂（Co）（IUPAC），优选包含A1化合物的助催化剂（Co），（iii）溶剂（A'），（b）通过将溶液（A）分散在溶剂（B）中并在表面活性剂（S）的存在下产生乳液，其中（i）溶剂（B）构成乳液的连续相和（ii）溶液（A ）构成液滴的形式，乳液的分散相，（iii）式（I）的过渡金属化合物和助催化剂（Co）存在于液滴中，和（iv）表面活性剂（S）是反应产物（II）的至少一种化合物和包含元素周期表第13族元素（E）的化合物（I）的（RP），优选包含A1，式（II）的化合物，其中R1 是一个半，高度或全氟化的烃残基，R2是选自-C（R 3）= C（R 3'）-R 4的残基，其中R 3，R 4，R 3'彼此独立地是选自H，C1至C20烷基，C2至C20烯基，C2至C20炔基，（c）固化所述分散相以将所述液滴转化为固体颗粒，和（d）任选地回收所述颗粒以获得所述催化剂体系。

5. 发明申请

WO2011076617A1 PREPARATION OF SINGLE-SITE CATALYSTS 审中-公开
标题翻译：单壁催化剂的制备
公开(公告)号：WO2011076617A1
公开(公告)日：2011-06-30
申请号：PCT/EP2010/069633
申请日：2010-12-14
申请人： BOREALIS AG , DENIFL, Peter , CASTRO, Pascal , RAUTIO, Soile , HUHTANEN, Lauri , OKSMAN, Marita , MUSTONEN, Marja
发明人： DENIFL, Peter , CASTRO, Pascal , RAUTIO, Soile , HUHTANEN, Lauri , OKSMAN, Marita , MUSTONEN, Marja
IPC分类号： C08F10/00 , C08F4/6592
CPC分类号： C08F10/00 , C08F4/65927 , C08F110/06 , C08F2410/01 , C08F4/65912
摘要： The formula (II) is (formula (II)) wherein R 1 is a semi-, highly- or perfluorinated hydrocarbon residue, and R 2 is a residue selected from the group consisting of -C(R 3 )=C(R 3' )-R 4 , wherein R 3 , R 4 , R 3' , are independently from each other selected from the group consisting of H, C 1 to C 20 alkyl, C 2 to C 20 alkenyl, C 2 to C 20 alkinyl.
摘要翻译：式（II）是（式（II）），其中R 1是半，高度或全氟化的烃残基，R 2是选自-C（R 3）= C（R 3'）-R 4 其中R3，R4，R3'彼此独立地选自H，C1至C20烷基，C2至C20烯基，C2至C20炔基。

6. 发明申请

WO2003051934A3 PRODUCTION OF OLEFIN POLYMERISATION CATALYSTS 审中-公开
公开(公告)号：WO2003051934A3
公开(公告)日：2003-06-26
申请号：PCT/EP2002/014461
申请日：2002-12-18
申请人： BOREALIS TECHNOLOGY OY , DENIFL, Peter , VAN PRAET, Erik , BARTKE, Michael , OKSMAN, Marita , MUSTONEN, Marja , GAROFF, Thomas , PESONEN, Kari
发明人： DENIFL, Peter , VAN PRAET, Erik , BARTKE, Michael , OKSMAN, Marita , MUSTONEN, Marja , GAROFF, Thomas , PESONEN, Kari
IPC分类号： C08F10/00
摘要： The invention provides a process for producing an olefin polymerisation catalyst, comprising an organometallic compound of a transition metal or of an actinide or lanthanide, in the form of solid catalyst particles, comprising forming a liquid/liquid emulsion system which comprises a solution of one or more catalyst components dispersed in a solvent immiscible therewith; and solidifying said dispersed phase to convert said droplets to solid particles comprising the catalyst and optionally recovering said particles.

7. 发明申请

WO2013030206A1 POWER CABLE COMPRISING POLYPROPYLENE 审中-公开
标题翻译：包含聚丙烯的电力电缆
公开(公告)号：WO2013030206A1
公开(公告)日：2013-03-07
申请号：PCT/EP2012/066724
申请日：2012-08-29
申请人： BOREALIS AG , VESTBERG, Torvald , DENIFL, Peter , HAGSTRAND, Per-Ola , ENGLUND, Villgot , NILSSON, Ulf , NYMARK, Anders
发明人： VESTBERG, Torvald , DENIFL, Peter , HAGSTRAND, Per-Ola , ENGLUND, Villgot , NILSSON, Ulf , NYMARK, Anders
IPC分类号： C08F110/06 , C08L23/12 , H01B3/44
CPC分类号： H01B3/303 , C08F10/06 , C08F110/06 , C08F210/06 , C08L23/0815 , C08L23/10 , C08L23/16 , C08L2314/02 , C08L2314/06 , H01B3/441 , H01B9/00 , C08F4/6555 , C08F4/025 , C08F4/6465 , C08F2/02 , C08F210/16 , C08F2500/12 , C08F2/001
摘要： Power cable comprising a conductor surrounded by at least one layer comprising a polypropylene, wherein the polypropylene comprises nanosized catalyst fragments being evenly distributed in said polypropylene.
摘要翻译：电力电缆包括由包括聚丙烯的至少一层包围的导体，其中所述聚丙烯包括均匀分布在所述聚丙烯中的纳米尺寸的催化剂碎片。

8. 发明申请

WO2012007430A1 CATALYST COMPONENT 审中-公开
标题翻译：催化剂组分
公开(公告)号：WO2012007430A1
公开(公告)日：2012-01-19
申请号：PCT/EP2011/061770
申请日：2011-07-11
申请人： BOREALIS AG , HAIKARAINEN, Anssi , DENIFL, Peter , LEINONEN, Timo
发明人： HAIKARAINEN, Anssi , DENIFL, Peter , LEINONEN, Timo
IPC分类号： C08F10/00 , C08F4/651
CPC分类号： C08F4/6494 , C08F10/00 , C08F4/651 , C08F4/6546 , C08F4/02
摘要： The invention refers to a process for preparing a Group 2 metal/transition metal olefin polymerisation catalyst component in particulate form free of conventional phthalate electron donors and the use thereof in a process for polymerising olefins.
摘要翻译：本发明涉及一种制备不含常规邻苯二甲酸酯电子给体的颗粒形式的第2族金属/过渡金属烯烃聚合催化剂组分的方法及其在烯烃聚合方法中的用途。

9. 发明申请

WO2012007427A1 CATALYST COMPONENT 审中-公开
标题翻译：催化剂组分
公开(公告)号：WO2012007427A1
公开(公告)日：2012-01-19
申请号：PCT/EP2011/061765
申请日：2011-07-11
申请人： BOREALIS AG , DENIFL, Peter , ERIKSSON, Mikaela , LEINONEN, Timo , HAIKARAINEN, Anssi
发明人： DENIFL, Peter , ERIKSSON, Mikaela , LEINONEN, Timo , HAIKARAINEN, Anssi
IPC分类号： C08F10/06 , C08F4/651 , C08F4/02 , C08F4/654
CPC分类号： C08F4/50 , C08F110/06 , C08F2500/18 , C08F2500/12 , C08F4/6555 , C08F4/02 , C08F4/6546 , C08F4/651
摘要： The invention refers to a process for preparing a Group 2 metal/transition metal olefin polymerisation catalyst component in particulate form for polymerising olefins, especially ethylene or propylene or comonomers thereof.
摘要翻译：本发明涉及制备用于聚合烯烃，特别是其乙烯或丙烯或其共聚单体的颗粒形式的第2族金属/过渡金属烯烃聚合催化剂组分的方法。

10. 发明申请

WO2010127997A2 PREPARATION OF PRECIPITATED ZN PP CATALYSTS WITH INTERNAL PORE STRUCTURE USING NANOPARTICLES 审中-公开
标题翻译：用纳米颗粒制备内部孔结构的沉淀ZN PP催化剂
公开(公告)号：WO2010127997A2
公开(公告)日：2010-11-11
申请号：PCT/EP2010/055885
申请日：2010-04-30
申请人： BOREALIS AG , HAIKARAINEN, Anssi , DENIFL, Peter , LEINONEN, Timo
发明人： HAIKARAINEN, Anssi , DENIFL, Peter , LEINONEN, Timo
IPC分类号： C08F10/06 , C08F4/651 , C08F4/654 , C08F4/02
CPC分类号： C08F4/643 , C08F10/06 , C08F210/06 , C08L23/12 , Y10T428/2982 , C08F4/651 , C08F4/02 , C08F2/001 , C08F4/6548 , C08F4/6546 , C08F4/025 , C08L23/16 , C08F210/16 , C08F2500/05 , C08F2500/12 , C08F2500/18 , C08F2500/24
摘要： Process for the preparation of a catalyst being in the form of solid particles comprising the steps of •preparing a solution of a complex of a metal which is selected from one of the groups 1 to 3 of the periodic table (IUPAC) and an electron donor by reacting a compound of said metal with said electron donorin an organic liquid reaction medium; •adding to said solution solid material obtaining a suspension, said solid material -does not comprise catalytically active sites, -has a specific surface area below 500 m 2 /g, and -has a mean particle size below 200 nm; •combining said suspension at a temperature of at least 50°C with at least one transition metal compound resulting in a precipitation of said catalyst being in the form of a solid particle, wherein said transition metal compound is selected from one of the groups 4 to 10 of the periodic table (IUPAC) or a compound of actinide or lanthanide; and •optionally separating said catalyst; said catalyst being in the form of solid particles, which -have a specific surface area of less than 20 m 2 /g, and -contain said solid material.
摘要翻译：用于制备固体颗粒形式的催化剂的方法包括以下步骤：·制备选自周期表第1至3族之一的金属络合物的溶液通过使所述金属的化合物与所述电子供体在有机液体反应介质中反应来制备表（IUPAC）和电子供体; ·向所述溶液中添加固体材料以获得悬浮液，所述固体材料不包含催化活性位点， - 具有低于500m 2 / g的比表面积和 - 具有低于500m 2 / g的平均粒度 200纳米; ·将所述悬浮液在至少50℃的温度下与至少一种过渡金属化合物结合，导致所述催化剂沉淀为固体颗粒形式，其中所述过渡金属化合物选自组4至组4 周期表（IUPAC）的10或act系元素或镧系元素的化合物; 和·任选分离所述催化剂; 所述催化剂为固体颗粒形式，其具有小于20m 2 / g的比表面积，并且包含所述固体材料。

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