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1. 发明申请

WO2022035645A1 SYNERGISTIC FORMULATIONS FOR CONTROL AND REPELLENCY OF BITING ARTHROPODS 审中-公开
公开(公告)号：WO2022035645A1
公开(公告)日：2022-02-17
申请号：PCT/US2021/044340
申请日：2021-08-03
申请人： BEDOUKIAN RESEARCH, INC.
发明人： BEDOUKIAN, Robert H.
IPC分类号： A01N37/18
摘要： Control or repellency of biting arthropods, particularly biting insects, is accomplished by bringing the biting arthropods into contact with combinations of compounds identical or related to those found on human/animal skin or in plants acting synergistically with one another, or in combination with conventional repellents like N,N-diethyl-3-methylbenzamide (DEET®), para-menthane-3,8- diol (PMD), sec-butyl-2-(2-hydroxyethyl) piperidine carboxylate ("Picaridin"), or other nitrogen containing repellents selected from amines, amides and nitrogen containing heterocyclic compounds, or any synergistic combination of DEET®, PMD, Picaridin, or other nitrogen containing repellents selected from amines, amides and nitrogen containing heterocyclic compounds.

2. 发明公开

EP3254562A3 FEEDING DETERRENCE IN AGRICULTURAL PESTS SUCH AS HEMIPTERA, LEPIDOPTERA AND COLEOPTERA 审中-公开
标题翻译：农副产品如半翅目，鞘翅目和鞘翅目的摄食障碍
公开(公告)号：EP3254562A3
公开(公告)日：2018-03-28
申请号：EP17180427.1
申请日：2013-04-30
申请人： Bedoukian Research, Inc.
发明人： BEDOUKIAN, Robert H.
IPC分类号： A01N37/10 , A01N35/06 , A01N37/42 , A01N43/08 , A01N43/16 , A01N49/00 , A01N37/02 , A01N37/36
CPC分类号： A01N43/16 , A01N31/06 , A01N35/06 , A01N37/02 , A01N37/06 , A01N37/18 , A01N37/36 , A01N37/42 , A01N43/08 , A01N49/00
摘要： Compounds are used as agents that deter feeding of crops by agricultural pests such as hemiptera, lepidoptera and coleoptera, including, but not limited to, stink bugs, codling moth larvae and granary weevils. Feeeding deterrence is obtained by contact of the insects with at least one of the compounds of the structure (I)

wherein
R is -OH, =O, -OC(O)R 4 , -OR 6 , or -(OR 6 ) 2 , wherein each R 6 is independently an alkyl group containing from 1 to 4 carbon atoms and R 4 is a branched or straight chain, saturated or unsaturated, hydrocarbyl group with zero to two double bonds and from 1 to 15 carbon atoms;
X is O or CH 2 with the proviso that when X is O R can only be =O;
each Z is independently (CH) or (CH 2 );
y is a numeral selected from 1 and 2;
R 1 is H or a branched or straight chain, saturated or unsaturated hydrocarbyl group with zero to two double bonds and from 1 to 15 carbon atoms;
R 2 is H or a branched or straight chain, saturated or unsaturated hydrocarbyl group with zero to three double bonds and from 1 to 15 carbon atoms;
R 3 is selected from H, a branched or straight chain, saturated or unsaturated hydrocarbyl group with zero to three double bonds and from 1 to 15 carbon atoms, -(CH 2 ) n OH, -C(O)OR 5 , -CH 2 C(0)OR 7 , - CH 2 C(O)R 8 , -C(O)NR 9 R 10 , and -CH 2 C(O)NR 11 R 12 where each of R 5 , R 7 , R 8 , R 9 , R 10 , R 11 and R 12 is independently selected from H and a branched or straight chain, saturated or unsaturated hydrocarbyl group with zero to three double bonds and from 1 to 15 carbon atoms and n is an integer of from 1 to 12; the bond between the 2 and 3 positions in the ring structure may be a single or a double bond; and wherein the compounds of structure (I) contain from 9 to 20 total carbon atoms in the compounds.
摘要翻译：化合物被用作阻止农作物如半翅目，鳞翅目和鞘翅目，包括但不限于臭蝽，苹果蠹蛾幼虫和谷类象鼻虫的农作物的饲料摄取的试剂。通过昆虫与其中R为-OH，= O，-OC（O）R 4，-OR 6或 - （OR 6）2的结构（I）的化合物中的至少一种接触获得馈虫威慑，其中每个 R6独立地为含有1至4个碳原子的烷基并且R4为具有0至2个双键和1至15个碳原子的支链或直链，饱和或不饱和的烃基; X是O或CH2，条件是当X是O时，R只能是= O; 每个Z独立地是（CH）或（CH 2）; y是选自1和2的数字; R1是H或具有0-2个双键和1-15个碳原子的支链或直链饱和或不饱和烃基; R2是H或具有0-3个双键和1-15个碳原子的支链或直链饱和或不饱和烃基; R 3选自H，具有0-3个双键和1-15个碳原子的支链或直链，饱和或不饱和烃基， - （CH 2）n OH，-C（O）OR 5，-CH 2 C（O）OR 7 （O）R 8，-C（O）NR 9 R 10和-CH 2 C（O）NR 11 R 12，其中R 5，R 7，R 8，R 9，R 10，R 11和R 12中的每一个独立地选自H和支链或直链，具有0-3个双键和1-15个碳原子的饱和或不饱和烃基，n是1-12的整数; 环结构中2和3位之间的键可以是单键或双键; 并且其中结构（I）的化合物在化合物中含有总共9-20个碳原子。

3. 发明公开

EP3257376A1 CONTROL AND REPELLENCY OF BED BUGS 审中-公开
标题翻译：对臭虫的控制和驱除
公开(公告)号：EP3257376A1
公开(公告)日：2017-12-20
申请号：EP17180969.2
申请日：2013-04-30
申请人： Bedoukian Research, Inc.
发明人： BEDOUKIAN, Robert H.
IPC分类号： A01N35/06
CPC分类号： C07C69/675 , A01N31/06 , A01N35/06 , A01N37/02 , A01N37/18 , A01N37/22 , A01N37/36 , A01N37/42 , A01N43/08 , A01N43/16 , A01N49/00 , C07C35/06 , C07C35/18 , C07C59/205 , C07C69/708 , C07C235/74 , C07C2601/08 , C07C2601/16 , C07D307/33 , C07D309/30 , A01N2300/00
摘要： Control or repellency of bed bugs is accomplished by bringing the bed bugs into contact with at least one of the compounds of the structure (I)

Wherein
R is selected from -OH, -OC(O)R 4 , -OR 6 , -(OR 6 ) 2 , wherein each R 6 is independently selected from an alkyl group containing from 1 to 4 carbon atoms and R 4 is a branched or straight chain saturated or unsaturated hydrocarbyl group with zero to two double bonds and from 1 to 15 carbon atoms;
X is O or CH 2 , with the proviso that when X is O R can only be =O;
each Z is independently selected from (CH) and (CH 2 )
y is a numeral selected from 1 and 2;
R 1 is selected from H or a branched or straight chain saturated or unsaturated hydrocarbyl group with zero to two double bonds and from 1 to 15 carbon atoms.
R 2 is selected from H and a branched or straight chain saturated or unsaturated hydrocarbyl group with zero to three double bonds and from 1 to 15 carbon atoms.
R 3 is selected from H, a branched or straight chain, saturated or unsaturated hydrocarbyl group with zero to three double bonds and from 1 to 15 carbon atoms, -(CH 2 ) n OH, -C(O)OR 5 , -CH 2 C(O)OR 7 ,-CH 2 C(O)R 8 , -C(O)NR 9 R 10 , -CH 2 C(O)NR 11 R 12 where each of R 5 , R 7 , R 8 , R 9 , R 10 , R 11 and R 12 is independently selected from H and a branched or straight chain, saturated or unsaturated hydrocarbyl group with zero to three double bonds and from 1 to 15 carbon atoms, and n is an integer of from 1 to 12; and
the bond between the 2 and 3 positions in the ring structure may be a single or a double bond, and wherein the compounds of structure (1) contain from 11 to 20 total carbon atoms, except where R is =O, X = CH 2 and y is 1 the compounds of structure (I) contain from 13 to 20 total carbon atoms in the compounds. wherein the compounds of structure (1) contain from 11 to 20 total carbon atoms, except where R is =O, X = CH 2 and y is 1 the compounds of structure (I) contain from 13 to 20 total carbon atoms in the compounds. wherein the compounds of structure (1) contain from 11 to 20 total carbon atoms, except where R is =O, X = CH 2 and y is 1 the compounds of structure (I) contain from 13 to 20 total carbon atoms in the compounds.
摘要翻译：臭虫的防治或排斥通过使臭虫与至少一种选自-OH，-OC（O）R 4，-OR 6， - （OR 6） 2，其中每个R6独立地选自含有1至4个碳原子的烷基并且R4是具有0至2个双键和1至15个碳原子的支链或直链饱和或不饱和烃基; X是O或CH2，条件是当X是O时，R只能是= O; 每个Z独立地选自（CH）和（CH2）y是选自1和2的数字; R1选自H或具有0至2个双键和1至15个碳原子的支链或直链饱和或不饱和烃基。 R2选自H和具有0-3个双键和1-15个碳原子的支链或直链饱和或不饱和烃基。 R3选自H，具有0至3个双键和1至15个碳原子的支链或直链，饱和或不饱和烃基， - （CH2）nOH，-C（O）OR5，-CH2C（O）OR7 （O）R 9，-C（O）NR 9 R 10，-CH 2 C（O）NR 11 R 12，其中R 5，R 7，R 8，R 9，R 10，R 11和R 12中的每一个独立地选自H和支链或直链饱和或具有0至3个双键和1至15个碳原子的不饱和烃基，并且n是1至12的整数; 并且环结构中2和3位之间的键可以是单键或双键，并且其中结构（1）的化合物含有11至20个总碳原子，除了其中R是= O，X = CH 2 并且y是1时，结构（I）的化合物在化合物中含有13至20个总碳原子。其中结构（1）的化合物含有11至20个总碳原子，除了其中R是= O，X = CH 2且y是1之外，结构（I）的化合物在化合物中含有13至20个总碳原子。其中结构（1）的化合物含有11至20个总碳原子，除了其中R是= O，X = CH 2且y是1之外，结构（I）的化合物在化合物中含有13至20个总碳原子。

4. 发明授权

EP3183330B1 PERFUME COMPOSITIONS CONTAINING ISOMERIC ALKADIENALS 有权
公开(公告)号：EP3183330B1
公开(公告)日：2019-07-17
申请号：EP15834554.6
申请日：2015-08-19
申请人： Bedoukian Research, Inc.
发明人： BEDOUKIAN, Robert H. , SWIERCZEK, Krzysztof , PESAK, Douglas Jay , ANSARI, Hifzur R.
IPC分类号： C07C47/21 , C11B9/00

5. 发明公开

EP3254562A2 FEEDING DETERRENCE IN AGRICULTURAL PESTS SUCH AS HEMIPTERA, LEPIDOPTERA AND COLEOPTERA 审中-公开
公开(公告)号：EP3254562A2
公开(公告)日：2017-12-13
申请号：EP17180427.1
申请日：2013-04-30
申请人： Bedoukian Research, Inc.
发明人： BEDOUKIAN, Robert H.
IPC分类号： A01N37/10 , A01N35/06 , A01N37/42 , A01N43/08 , A01N43/16 , A01N49/00 , A01N37/02 , A01N37/36
CPC分类号： A01N43/16 , A01N31/06 , A01N35/06 , A01N37/02 , A01N37/06 , A01N37/18 , A01N37/36 , A01N37/42 , A01N43/08 , A01N49/00
摘要： Compounds are used as agents that deter feeding of crops by agricultural pests such as hemiptera, lepidoptera and coleoptera, including, but not limited to, stink bugs, codling moth larvae and granary weevils. Feeeding deterrence is obtained by contact of the insects with at least one of the compounds of the structure (I)

wherein
R is -OH, =O, -OC(O)R 4 , -OR 6 , or -(OR 6 ) 2 , wherein each R 6 is independently an alkyl group containing from 1 to 4 carbon atoms and R 4 is a branched or straight chain, saturated or unsaturated, hydrocarbyl group with zero to two double bonds and from 1 to 15 carbon atoms;
X is O or CH 2 with the proviso that when X is O R can only be =O;
each Z is independently (CH) or (CH 2 );
y is a numeral selected from 1 and 2;
R 1 is H or a branched or straight chain, saturated or unsaturated hydrocarbyl group with zero to two double bonds and from 1 to 15 carbon atoms;
R 2 is H or a branched or straight chain, saturated or unsaturated hydrocarbyl group with zero to three double bonds and from 1 to 15 carbon atoms;
R 3 is selected from H, a branched or straight chain, saturated or unsaturated hydrocarbyl group with zero to three double bonds and from 1 to 15 carbon atoms, -(CH 2 ) n OH, -C(O)OR 5 , -CH 2 C(0)OR 7 , - CH 2 C(O)R 8 , -C(O)NR 9 R 10 , and -CH 2 C(O)NR 11 R 12 where each of R 5 , R 7 , R 8 , R 9 , R 10 , R 11 and R 12 is independently selected from H and a branched or straight chain, saturated or unsaturated hydrocarbyl group with zero to three double bonds and from 1 to 15 carbon atoms and n is an integer of from 1 to 12; the bond between the 2 and 3 positions in the ring structure may be a single or a double bond; and wherein the compounds of structure (I) contain from 9 to 20 total carbon atoms in the compounds.

6. 发明公开

EP3183330A1 PERFUME COMPOSITIONS CONTAINING ISOMERIC ALKADIENALS 有权
标题翻译：含有异构醇的香料组合物
公开(公告)号：EP3183330A1
公开(公告)日：2017-06-28
申请号：EP15834554.6
申请日：2015-08-19
申请人： Bedoukian Research, Inc.
发明人： BEDOUKIAN, Robert H. , SWIERCZEK, Krzysztof , PESAK, Douglas Jay , ANSARI, Hifzur R.
IPC分类号： C11D3/50
CPC分类号： C07C47/21 , C11B9/0015
摘要： A perfume composition comprising an effective amount of at least one alkadienal selected from 4,8-undecadienal and isomers thereof, 4,9-dodecadienal and isomers thereof, and 4,10-tridecadienal and isomers thereof. The isomers of 4,8-undecadienal comprise Z,Z-4,8-undecadienal, E,E-4,8-undecadienal, and mixed Z/E isomers of 4,8-undecadienal; the isomers of 4,9-dodecadienal comprise Z,Z-4,9-dodecadienal, E,E-4,9-dodecadienal, and mixed Z/E isomers of 4,9-dodecadienal; and the isomers of 4,10-tridecadienal comprise Z,Z-4,10-tridecadienal, E,E-4,10-tridecadienal, and mixed Z/E isomers of 4,10-tridecadienal. A composition comprising an effective amount of at least one alkadienal selected from 4,8-undecadienal and isomers thereof, 4,9-dodecadienal and isomers thereof, and 4,10-tridecadienal and isomers thereof. Processes for the preparation of the isomer mixtures of alkadienals are provided. The isomeric alkadienals have a range of fresh, watery, ozone, grapefruit, tangerine, orange peel, aldehydic notes of exceptional strength.
摘要翻译：包含有效量的至少一种选自4,8-十一碳二烯醛及其异构体，4,9-十二碳二烯醛及其异构体，和4,10-十三碳二烯醛及其异构体的链二烯醛的香料组合物。 4,8-十一碳二烯醛的异构体包括Z，Z-4,8-十一碳二烯醛，E，E-4,8-十一碳二烯醛和4,8-十一碳二烯醛的混合Z / E异构体; 4,9-十二碳二烯醛的异构体包含Z，Z-4,9-十二碳二烯醛，E，E-4,9-十二碳二烯醛和4,9-十二碳二烯醛的混合Z / E异构体; 并且4,10-十三碳二烯醛的异构体包含4,10-十三碳二烯醛的Z，Z-4,10-十三碳二烯醛，E，E-4,10-十三碳二烯醛和混合的Z / E异构体。包含有效量的至少一种选自4,8-十一碳二烯醛及其异构体，4,9-十二碳二烯醛及其异构体和4,10-十三碳二烯醛及其异构体的链二烯醛的组合物。提供了制备链烷二烯异构体混合物的方法。异构的alkadienals有一系列新鲜，含水，臭氧，葡萄柚，橘子，橙皮，具有非凡强度的醛类香味。

7. 发明公开

EP3183231A1 PERFUME COMPOSITONS CONTAINING ISOMERIC ALKADIENENITRILES 有权
标题翻译：含有异构化阿卡地尼的香料复合物
公开(公告)号：EP3183231A1
公开(公告)日：2017-06-28
申请号：EP15834026.5
申请日：2015-08-19
申请人： Bedoukian Research, Inc.
发明人： BEDOUKIAN, Robert H. , SWIERCZEK, Krzysztof , PESAK, Douglas Jay , ANSARI, Hifzur R.
IPC分类号： C07C255/07 , A61Q13/00 , C11B9/00
CPC分类号： C07C253/30 , C07B2200/09 , C07C255/07 , C11B9/0023
摘要： A perfume composition comprising an effective amount of at least one alkadienenitrile selected from 4,8-undecadienenitrile and isomers thereof, 4,9-dodecadienenitrile and isomers thereof, and 4,10-tridecadienenitrile and isomers thereof. The isomers of 4,8-undecadienenitrile comprise Z,Z-4,8-undecadienenitrile, E,E-4,8-undecadienenitrile, and mixed Z/E isomers of 4,8-undecadienenitrile; the isomers of 4,9-dodecadienenitrile comprise Z,Z-4,9-dodecadienenitrile, E,E-4,9-dodecadienenitrile, and mixed Z/E isomers of 4,9-dodecadienenitrile; and the isomers of 4,10-tridecadienenitrile comprise Z,Z-4,10-tridecadienenitrile, E,E-4,10-tridecadienenitrile, and mixed Z/E isomers of 4,10-tridecadienenitrile. A composition comprising an effective amount of at least one alkadienenitrile selected from 4,8-undecadienenitrile and isomers thereof, 4,9-dodecadienenitrile and isomers thereof, and 4,10-tridecadienenitrile and isomers thereof. Processes for the preparation of the isomeric alkadienenitriles are provided. The isomeric alkadienenitriles have a range of fresh, citric, ozonic and floral notes of exceptional strength.
摘要翻译：一种香料组合物，其中含有有效量的至少一种选自4,8-十一碳二烯腈及其异构体，4,9-十二碳烯二腈及其异构体和4,10-十三碳二烯腈及其异构体的亚氨二腈。 4,8-十一碳烯腈的异构体包括Z，Z-4,8-十一碳烯腈，E，E-4,8-十一碳烯腈和4,8-十一碳二烯腈的混合Z / E异构体; 4,9-十二碳烯腈的异构体包括Z，Z-4,9-十二碳烯二腈，E，E-4,9-十二碳烯二腈和4,9-十二碳烯腈的混合Z / E异构体; 并且4,10-十三碳烯腈的异构体包括Z，Z-4,10-十三碳烯腈，E，E-4,10-十三碳烯二腈和4,10-十三碳烯腈的混合Z / E异构体。包含有效量的至少一种选自4,8-十一碳二烯腈及其异构体，4,9-十二碳烯二腈及其异构体和4,10-十三碳二烯腈及其异构体的链二烯腈的组合物。提供了制备异构体链二烯腈的方法。异构体烯二腈具有一系列具有优异强度的新鲜柠檬酸，臭氧和花香香料。

8. 发明授权

EP3183231B1 PERFUME COMPOSITIONS CONTAINING ISOMERIC ALKADIENENITRILES 有权
公开(公告)号：EP3183231B1
公开(公告)日：2019-10-09
申请号：EP15834026.5
申请日：2015-08-19
申请人： Bedoukian Research, Inc.
发明人： BEDOUKIAN, Robert H. , SWIERCZEK, Krzysztof , PESAK, Douglas Jay , ANSARI, Hifzur R.
IPC分类号： C07C255/07 , A61Q13/00 , C11B9/00

9. 发明公开

EP3068221A1 SYNERGISTIC FORMULATIONS FOR CONTROL AND REPELLENCY OF BITING ARTHROPODS 审中-公开
标题翻译：协同配方战斗和节肢动物咬甩
公开(公告)号：EP3068221A1
公开(公告)日：2016-09-21
申请号：EP14861892.9
申请日：2014-11-13
申请人： Bedoukian Research, Inc.
发明人： BEDOUKIAN, Robert H.
IPC分类号： A01N37/10 , A01N35/00
CPC分类号： A01N37/18 , A01N31/02 , A01N31/06 , A01N35/02 , A01N37/30 , A01N37/36 , A01N37/40 , A01N37/42 , A01N43/08 , A01N43/16 , A01N49/00 , A01N37/10
摘要： Control or repellency of biting arthropods, particularly biting insects, is accomplished by bringing the biting arthropods into contact with combinations of compounds identical or related to those found on human/animal skin or in plants acting synergistically with one another, or in combination with conventional repellents like DEET®, para-menthane-3,8-diol (PMD),
sec -butyl-2-(2-hydroxyethyl) piperidine carboxylate ("Picaridin"), or other nitrogen containing repellents selected from amines, amides and nitrogen containing heterocyclic compounds, or any synergistic combination of DEET®, PMD, Picaridin, or other nitrogen containing repellents selected from amines, amides and nitrogen containing heterocyclic compounds.
摘要翻译：控制或咬节肢动物，尤其叮咬昆虫的驱避性通过使咬节肢动物接触到相同的或相关的那些对人/动物的皮肤或与彼此协同作用植物中发现的化合物的组合，或与常规驱虫剂组合来实现 DEET®等，对 - 薄荷烷-3,8-二醇（PMD），仲 - 丁基-2-（2-羟乙基）哌啶羧酸酯（“picaridin”），或其它含氮的驱虫剂从胺，酰胺和杂环氮含选择化合物，或从cardamines，酰胺和含氮杂环化合物中选择DEET®，PMD，Picaridin，或其它含氮驱避剂的任何协同组合。

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