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    • 4. 发明申请
    • A USE OF SULFONANILIDES AS HERBICIDE
    • 磺酰二胺类作为除草剂的用途
    • WO2007031208A3
    • 2007-07-26
    • PCT/EP2006008591
    • 2006-09-02
    • BAYER CROPSCIENCE AGARAKI KOICHISATO YOSHITAKAGOMIBICHI TAKUYAENDO KEIJISHIRAKURA SHINICHINAKAMURA SHINROSINGER CHRISTOPHERFEUCHT DIETER
    • ARAKI KOICHISATO YOSHITAKAGOMIBICHI TAKUYAENDO KEIJISHIRAKURA SHINICHINAKAMURA SHINROSINGER CHRISTOPHERFEUCHT DIETER
    • A01N43/66A01N43/54A01P13/00C07D239/52C07D251/16
    • C07D251/20A01N43/54A01N43/66C07D239/52
    • Herbicidal compositions comprising containing sulfonanilides of the formula (I), wherein R 1 represents hydrogen, fluorine, chlorine, C 1-4 alkyl, C 1-4 alkoxy, C 3-6 cycloalkyl- C 1-4 alkyloxy or C 1-4 haloalkoxy, R 2 represents hydrogen, fluorine or chlorine, R 3 represents hydrogen or fluorine, R 4 represents hydrogen or C 1-4 alkyl which may be optionally C 1-4 alkoxy-substituted, C 3-6 alkenyl or C 3-6 alkynyl, R 5 represents hydrogen, R 6 represents hydroxy, fluorine or chlorine, or R 5 and R 6 may form, together with the carbon to which they are bonded, C=O, and X represents CH or N, provided that the following cases are excluded: (i) R 1 represents hydrogen, fluorine or chlorine, R 2 represents hydrogen, R 3 represents hydrogen, R 4 represents hydrogen, R 5 represents hydrogen, and R 6 represents hydroxy, (ii) R 1 represents hydrogen, fluorine or chlorine, R 2 represents hydrogen, R 3 represents hydrogen, R 4 represents hydrogen, and R 5 and R 6 form C=O together with the carbon to which they are bonded, (iii) R 1 represents C 1-4 alkyl, R 2 represents hydrogen, R 3 represents hydrogen, R 4 represents hydrogen, R 5 represents hydrogen, R 6 represents hydroxy, and X represents CH, or (iv) R 1 represents C 1-4 alkyl, R 2 represents hydrogen, R 3 represents hydrogen, R 4 represents hydrogen, R 5 and R 6 form C=O together with the carbon to which they are bonded, and X represents CH, and new compounds being embraced by the formula (I).
    • 包含式(I)磺酰苯胺的除草组合物,其中R 1代表氢,氟,氯,C 1-4烷基,C 1-4烷基, C 1-3烷氧基,C 3-6环烷基-C 1-4烷氧基或C 1-4卤代烷氧基,R 2,R 4, 代表氢,氟或氯,R 3代表氢或氟,R 4代表氢或C 1-4烷基,其可以是 任选被C 1-4烷氧基取代,C 3-6链烯基或C 3-6炔基,R 5, R 5代表氢,R 6代表羟基,氟或氯,或者R 5和R 6可以与碳原子一起形成 它们键合,C = O,并且X代表CH或N,条件是排除下列情况:(i)R 1代表氢,氟或氯,R 2 SUP 4代表氢,R 5和R 6与它们所键合的碳一起形成C = O,并且X代表CH,且新化合物 被公式(I)所包含。
    • 5. 发明申请
    • ALKALINE PROTEASE VARIANTS
    • 碱性蛋白酶变体
    • WO2010126156A3
    • 2011-01-06
    • PCT/JP2010057838
    • 2010-04-26
    • KAO CORPTOHATA MASATOSHIOKUDA MITSUYOSHISATO TSUYOSHIENDO KEIJISAEKI KATSUHISA
    • TOHATA MASATOSHIOKUDA MITSUYOSHISATO TSUYOSHIENDO KEIJISAEKI KATSUHISA
    • C12N9/54C11D3/386
    • C11D3/38618C11D3/386C11D3/38681C12N9/54
    • An alkaline protease variant derived from an alkaline protease consisting of an amino acid sequence represented by SEQ ID NO: 2 or consisting of an amino acid sequence having an identity of 90% or more therewith, which variant has mutations wherein one or more amino acid residues at positions selected from (a) position 6, (b) position 15, (c) position 16, (d) position 65, (e) position 66, (f) position 82, (g) position 83, (h) position 204, (i) position 319, and (j) position 337 of the amino acid sequence represented by SEQ ID NO: 2, or at positions corresponding thereto are substituted with the following amino acid residues: (a) or a position corresponding thereto: Typ, Leu, Val, Ile, Met, Tyr, Gln, Lys, Thr, Phe, Arg, Ser, Cys, Ala, or His; (b) or a position corresponding thereto: Glu, Met, Asp, Val, Gln, Arg, Cys, Trp, Ala, or Phe; (c) or a position corresponding thereto: Met, Glu, Arg, Val, Lys, Phe, Tyr, Ile, His, Asp, or Cys; (d) or a position corresponding thereto: Trp; (e) or a position corresponding thereto: His, Trp, Ser, or Leu; (f) or a position corresponding thereto: Ala, Glu, Gln, Ser, Cys, Gly, His, Lys, Arg, Met, or Asn; (g) or a position corresponding thereto: Ala, Ser, or Cys; (h) or a position corresponding thereto: Glu, Asp, Cys, Val, Thr, Pro, His, Ile, Trp, Ser, Asn, Lys, or Arg; (i) or a position corresponding thereto: Trp, Val, Thr, Leu, Ile, Cys, Glu, Lys, Tyr, Arg, Phe, Gln, Met, Pro, Asp, Asn, His, or Ser; and (j) or a position corresponding thereto: Arg, Gly, Ser, Lys, Gln, Thr, His, Ala, Cys, or Val.
    • 由碱性蛋白酶衍生的碱性蛋白酶变体,其由SEQ ID NO:2所示的氨基酸序列组成或由与其同一性为90%以上的氨基酸序列组成,所述变体具有突变,其中一个或多个氨基酸残基 在从(a)位置6,(b)位置15,(c)位置16,(d)位置65,(e)位置66,(f)位置82,(g)位置83,(h) 204,(i)位置319和(j)由SEQ ID NO:2表示的氨基酸序列的位置337或与其相对应的位置被以下氨基酸残基取代:(a)或与其对应的位置: Typ,Leu,Val,Ile,Met,Tyr,Gln,Lys,Thr,Phe,Arg,Ser,Cys,Ala或His; (b)或相应位置:Glu,Met,Asp,Val,Gln,Arg,Cys,Trp,Ala或Phe; (c)或对应的位置:Met,Glu,Arg,Val,Lys,Phe,Tyr,Ile,His,Asp或Cys; (d)或与之对应的位置:Trp; (e)或与之对应的位置:His,Trp,Ser或Leu; (f)或对应的位置:Ala,Glu,Gln,Ser,Cys,Gly,His,Lys,Arg,Met或Asn; (g)或对应的位置:Ala,Ser或Cys; (h)或相应位置:Glu,Asp,Cys,Val,Thr,Pro,His,Ile,Trp,Ser,Asn,Lys或Arg; (i)或对应的位置:Trp,Val,Thr,Leu,Ile,Cys,Glu,Lys,Tyr,Arg,Phe,Gln,Met,Pro,Asp,Asn,His或Ser; 和(j)或对应的位置:Arg,Gly,Ser,Lys,Gln,Thr,His,Ala,Cys或Val。
    • 6. 发明申请
    • A HERBICIDE COMPOSITION FOR PADDY FIELD
    • 一种杀虫剂的杀草剂组合物
    • WO2007079965A3
    • 2008-10-16
    • PCT/EP2006012502
    • 2006-12-22
    • BAYER CROPSCIENCE AGENDO KEIJISHIRAKURA SHINICHINAKAMURA SHINMINEGISHI NATSUKO
    • ENDO KEIJISHIRAKURA SHINICHINAKAMURA SHINMINEGISHI NATSUKO
    • A01N43/54A01N25/32A01N43/70A01P13/02
    • A01N43/54A01N43/66A01N25/32A01N37/18A01N37/22A01N39/02A01N43/08A01N43/12A01N43/56A01N43/78A01N43/80A01N43/86A01N43/90A01N47/30A01N47/36A01N47/38A01N57/14A01N2300/00
    • A herbicide composition for paddy field characterized by containing (a) a herbicidal difluoromethanesulfonamide derivative represented by the formula (I) and (b) at least one herbicidal compound selected from the group consisting of pretilachlor, butachlor, alachlor, metolachlor, acetochlor, clomeprop, bromobutide, benfuresate, indanofan, pyrazolate, benzofenap, pyrazoxyfen, pyraclonil, oxaziclomefone, bensulfuron-methyl, azimsulfuron, imazosulfuron, pyrazosulfuron-ethyl, cyclosulfamuron, ethoxysulfuron, halosulfuron-methyl, orthosulfamuron, cinosulfuron, metsulfuron-methyl, penoxsulam, thiobencarb, pyributycarb, molinate, dimethametryn, simetryn, cafenstrole, quinclorac, anilofos, mefenacet, fentrazamide, pentoxazone, oxadiargyl, oxadiazon, benzobicyclon, mesotrione, AVH301 (code no.), cyhalof op-butyl, metamifop, bispyribac-sodium, pyriftalid, pyrimisulfan, pyrimenobac-methyl, chlormethoxynil, oxyfluorfen, dithiopyr, MCPA, MCPB, 2,4-D, dymron, cumyluron, quinoclamine and clomazone, and/or (c) one or more compounds selected from the group consisting of safeners dymron, isoxadifen(-ethyl), flurazole, fenchlorazole-ethyl, fenclorim, cloquintocet-mexyl, oxabetrinil, fluxofenim, mefenpyr-diethyl, furilazole, R-29148 (code no.), benoxacor, dichlormid and dicyclonone as effective components.
    • 一种用于稻田的除草剂组合物,其特征在于含有(a)由式(I)和(b)表示的除草二氟甲磺酰胺衍生物,至少一种选自草酰草胺,丁草胺,甲草胺,异丙甲草胺,乙草胺,氯米普, 溴替丁,苯呋喃酮,吡诺昔芬,吡唑啉,苯扎芬,吡嘧磺隆,吡嘧磺隆,恶唑磺隆,吡磺隆,吡嘧磺隆,咪唑磺隆,吡嘧磺隆,环磺胺甲磺隆,邻磺嘧磺隆, 茉莉酸,二甲基苯甲酸,西妥昔单抗,喹诺酮,氟他拉酰胺,戊唑嗪酮,恶草酮,恶二酮,苯并环己酮,甲基磺草酮,AVH301(代号),cyhalof op-butyl,metamifop,bispyribac-sodium,pyriftalid, 甲基,氯代甲氧基,氧氟芬,二硫代吡啶,MCPA,MCPB,2,4-D,胞嘧啶,枯叶红素,喹啉胺和克罗马酮, 和/或(c)一种或多种选自安息剂,多西他赛(乙基),氟尿嘧啶,芬氯唑,芬舍洛芬,氯喹毒素,恶唑胺,氟吡芬,咪芬吡啶二乙基,呋喃唑,R-29148 (代号),benoxacor,dichlormid和dicyclonone作为有效成分。
    • 10. 发明专利
    • METALLIC SCRUBBER
    • JPH09182710A
    • 1997-07-15
    • JP1927796
    • 1996-01-11
    • ENDO KEIJI
    • ENDO KEIJI
    • A47L13/10A47L17/08
    • PROBLEM TO BE SOLVED: To provide an easily holdable metallic scrubber to enable to correctly and quickly clean a metallic utensil and usable for a long period without deforming, by biding arbitrary parts of the metallic scrubber with a binding line and placing binding parts in multiple points on the metallic scrubber. SOLUTION: Arbitrary parts of this metallic scrubber 1 are bound with a binding line (a metallic line, a synthetic resin band, etc.) to make bound parts 3 (the inside of the binding line and its periphery) to be placed on several proper positions in this metallic scrubber 1. The practical example shows the metallic scrubber 1 with three binding lines 2 and three bound parts 3. Each biding line 2 passes through the central part of the metallic scrubber 1 and bound parts 3 are set with an angle of 120 deg. to each other. If the metallic line has high density, a pace part 4 cannot exist. Consequently, when plural rigidified binding parts 2 are properly arranged, an easily holdable metallic scrubber appears. Since binding parts 2 divides the metallic scrubber 1 into plural parts, deformation of the metallic scrubber 1 is prevented and it brings the function to keep the hole shape.