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    • 4. 发明专利
    • ES2166489T3
    • 2002-04-16
    • ES97110934
    • 1997-07-02
    • BAYER AG
    • WAMPRECHT CHRISTIAN DRSONNTAG MICHAEL DRMARGOTTE DIETER DR
    • C08F279/02C08G18/63C09D151/04C08L51/04
    • A binder mixture (I) consists of: (A) 95-40 pts. wt. of a hydroxy functional graft copolymerised resin prepared by copolymerisation of: (A1) 0.1-10 pts. wt. of a optionally functionalised polybutadiene with a molecular wt. of 500-10000 and at least 20% 1,2-vinyl structure; (A2) 5-30 pts. wt. of a 8-16C aliphatic alpha -olefin; (A3) 0.1-35 pts.wt. of a 4-30C glycidyl ester of an alpha -alkylmonocarboxylic acid; (A4) 10-70 pts. wt. of an unsaturated aromatic monomer, preferably styrene, alpha -methylstyrene or vinyl toluene; (A5) 5-60 pts. wt. of a hydroxyalkyl ester of acrylic and/or methacrylic acid with 2-4C in the hydroxyalkyl group and containing a primary hydroxy group; (A6) 0-50 pts.wt. of a (cyclo)aliphatic ester of acrylic and/or methacrylic acid with 1-12C in the (cyclo)aliphatic group; (A7) 0.1-20 pts. wt. of 3-7C alpha , beta -unsaturated mono or dicarboxylic acid and/or a maleic acid and/or fumaric acid half ester with 1-14C in the alcohol group; (A8) 0-30 pts. wt. of a copolymerisable unsaturated compound with; (B) 5-60pts. wt. of a multi-functional crosslinking resin, preferably an aminoplast, preferably an alkoxylated melamine resin, melamine-formaldehyde condensation product, urea resin, guanidine resin, phenolic resin, resole and/or preferably optionally blocked polyfunctional isocyanates, preferably oligomeric isocyanates with biuret, allophanate, uretidione-urethane and/or isocyanate structure. Preferably (A) contains: 0.5-5 pts. wt. (A1) (molecular weight 500-3000, at least 40% 1,2-vinyl structure), 5-20 pts. wt. (A2) (1-octene and/or 1-decene), 0.5-20 pts. wt.; (A3) (glycidyl ester of an alpha -alkylmonocarboxylic acid with 5-10C in the carboxylic acid residue), 20-65 pts. wt. (A4) (styrene), 10-50 pts. wt. (A5) (hydroxyethyl acrylate and/or hydroxyethyl methacrylate, 0-35 pts. wt. (A6) (ethyl acrylate, butylacrylate, 2-ethylhexylacrylate, isobornylacrylate methyl methacrylate, ethylmethacrylate, butylmethacrylate, 2-ethylhexylmethacrylate, cyclohexylmethacrylate and/or isobornyl methacrylate) 0.5-5 pts. wt. (A7) (acrylic acid and/or methacrylic acid), 3-20 pts. wt. (A8) (vinylester of an aliphatic 3-9C monocarboxylic acid and/or di(cyclo)alkyl ester of maleic or fumaric acid containing 1-8C atoms in the alcohol residue, whereby the sum of the parts (A1)-(A8) is equal to 100 and 3-20% of the OH groups are secondary OH groups.