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    • 4. 发明申请
    • METHOD FOR PRODUCING PROPENE FROM PROPANE
    • 用于生产丙烯丙烷
    • WO2007113085A3
    • 2008-03-13
    • PCT/EP2007052354
    • 2007-03-13
    • BASF AGSCHUBERT MARKUSMUELLER ULRICHKIENER CHRISTOPHTEICH FRIEDHELMCRONE SVENSIMON FALKPASTRE JOERG
    • SCHUBERT MARKUSMUELLER ULRICHKIENER CHRISTOPHTEICH FRIEDHELMCRONE SVENSIMON FALKPASTRE JOERG
    • C07C7/12C07C7/13
    • C07C5/333C07C7/12C07C7/13C07C11/06
    • The invention relates to a method for producing propene from propane. Said method comprises the following steps: A) a feed gas stream (a) containing propane is prepared; B) the feed gas stream (a) containing propane, is introduced with optionally water vapour and optionally, an oxygen-containing gas stream into a dehydrogenation zone and then the propane is dehydrogenated to form propene, and a product gas stream (b) containing propane, propene, methane, ethane, ethene, hydrogen, optionally carbon monoxide, carbon dioxide, water vapour and oxygen, is obtained; C) the product gas stream (b) is cooled, optionally compressed and then water vapour is separated by condensation and a product gas stream (c) depleted in water vapour is obtained; D) the product gas stream (c) is brought into contact with a selectively active adsorber which selectively adsorbs propene in the selected adsorption conditions, and an adsorber charged with propene and a gas stream (d2) depleted in propene and containing propane, methane, ethane, ethene and hydrogen, carbon monoxide and carbon dioxide are obtained; E) a gas stream (e1) containing propene is released from the adsorber charged with propene by reducing the pressure and/or heat of the adsorber.
    • 本发明涉及用于由丙烷制备丙烯的方法,包括步骤:A)(a)中,提供了一种含丙烷的原料气流; B)包含(a),任选的蒸汽和任选的含氧气体流中的丙烷进料气流被送入脱氢区和丙烷经受脱氢成丙烯,得到产物气流b包括丙烷,丙烯,甲烷,乙烷,乙烯,氢气,任选的一氧化碳 ,二氧化碳,获得水蒸汽和氧气; C)的产物气流(B)被冷却,冷凝,任选地,这将允许水蒸气通过冷凝分离,得到一个蒸汽贫化产物气流(获得的C); D)的产物气流(c)的具有选择性作用的吸附剂选择性吸附所选择的吸附条件下丙烯,与一个装有丙烯吸附剂和贫丙烯气流(D2)的包含丙烷,甲烷,乙烷,乙烯接触接触 和氢,得到一氧化碳和二氧化碳; E)从载有丙烯吸附剂通过减压和/或吸附剂的加热,气体流包含丙烯(E1)释放。
    • 5. 发明申请
    • METHOD FOR PRODUCING PROPENE FROM PROPANE
    • 用于生产丙烯丙烷
    • WO2006094938A3
    • 2006-11-02
    • PCT/EP2006060436
    • 2006-03-03
    • BASF AGCRONE SVENMACHHAMMER OTTOSCHINDLER GOETZ-PETERBORGMEIER FRIEDER
    • CRONE SVENMACHHAMMER OTTOSCHINDLER GOETZ-PETERBORGMEIER FRIEDER
    • C07C5/48C07C11/06
    • C07C5/327C07C5/48C07C11/06
    • The invention concerns a method for producing propene from propane, said method consisting in: A) preparing an input gas stream (a) containing propane; B) introducing the input gas stream (a), containing propane, optionally water vapour and optionally an oxygen-containing gas stream, into a dehydrogenation zone then dehydrogenating propane to form propene, a product gas stream (b), containing propane, propene, methane, ethane, ethene, nitrogen, carbon monoxide, carbon dioxide, water vapour, optionally hydrogen and optionally oxygen, being obtained; C) cooling and optionally compressing the product gas stream (b) then separating water vapour by condensing a product gas stream (c) depleted in water vapour (c) being obtained; D) separating the non-condensable gas constituents or with low boiling point by contacting the product gas stream (c) with an inert absorbent then by desorbing the gases dissolved in said inert absorbent, a C 3 hydrocarbon stream (d1) and a residual gas stream (d2) containing methane, ethane, ethene, nitrogen, carbon monoxide, carbon dioxide, optionally hydrogen and optionally oxygen, being obtained; E) cooling and optionally compressing the C 3 hydrocarbon stream (d1), a gaseous or liquid C 3 hydrocarbon stream (e1) being obtained; F) optionally introducing the C 3 hydrocarbon stream (e1) into a first distillation zone then separating same by distillation into a propane and propene stream (f1) and a stream (f2) containing ethane and ethene; G) introducing the stream (e1) or (f1) into a (second) distillation zone then separating by distillation into a propene stream (g1) and a propane stream (g2), the stream (g2) being recycled at least partly to the dehydrogenation zone.
    • 本发明涉及一种方法,用于从丙烷制备丙烯的方法,包括以下步骤:提供一种含丙烷的原料气流的A); B)包含(a),任选的蒸汽和任选的含氧气体流中的丙烷进料气流被送入脱氢区和丙烷经受脱氢成丙烯,得到产物气流(b)包含丙烷,丙烯,甲烷,乙烷,乙烯,氮气, 一氧化碳,二氧化碳,水蒸汽,任选的氢气和任选的氧获得; C)的产物气流(B)被冷却,冷凝,任选地,这将允许水蒸气通过冷凝分离,得到一个蒸汽贫化产物气流(获得的C); D)不可冷凝的或低沸点的气体成分是通过产物气体流(c)与的溶解在惰性吸收介质气体的惰性吸收剂和随后解吸分离,由此一个C 3 烃流(d1)和一个接触制备 废气流的含甲烷,乙烷,乙烯,氮气,一氧化碳,二氧化碳,任选的氢气和任选的氧(D2)得到; E)与c 3 烃流(D1)被冷却和任选地被压缩,其特征在于,气态或液C 3 得到烃流(E1); F)的C 3 烃流(E1)任选地进料至丙烷和丙烯以及包含乙烷和乙烯流(F2)中的第一蒸馏区和蒸馏(在流F1); 电源(E1)或(F1)的G)被供给到蒸馏区中的(第二)和蒸馏分离成从丙烷中分离丙烯的产物料流(GL)和流(G2),所述电流(G2)至少部分地在 脱氢区返回。