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    • 4. 发明申请
    • METHOD FOR THE DIRECT AMINATION OF HYDROCARBONS INTO AMINO HYDROCARBONS, INCLUDING ELECTROCHEMICAL SEPARATION OF HYDROGEN
    • 直接处理烃与氢的电化学分离AMINOKOHLENWASSERSTOFFEN
    • WO2011003934A3
    • 2011-05-05
    • PCT/EP2010059711
    • 2010-07-07
    • BASF SEKUBANEK PETRPANCHENKO ALEXANDERFISCHER ANDREASHEIDEMANN THOMAS
    • KUBANEK PETRPANCHENKO ALEXANDERFISCHER ANDREASHEIDEMANN THOMAS
    • C07C209/02C07C211/04
    • C07C209/02B01D53/326B01D2257/108C25B3/00C07C211/46
    • Disclosed is a method for the direct amination of hydrocarbons into amino hydrocarbons by reacting a feedstock stream E containing at least one hydrocarbon and at least one amination reagent so as to obtain a reaction mixture R containing amino hydrocarbon and hydrogen in a reaction zone RZ, and electrochemically separating at least some of the hydrogen produced during the reaction from the reaction mixture R by means of a gas-tight membrane-electrode assembly comprising at least one membrane selectively conducting protons and at least one electrode catalyst on each side of the membrane, wherein at least some of the hydrogen is oxidized to protons on the anode catalyst on the retentate side of the membrane, and after penetrating the membrane, some of the protons on the permeate side are b1) reduced to hydrogen on the cathode catalyst by applying a voltage, and some of the protons b2) are reacted with oxygen on the cathode catalyst to obtain water, thereby generating electricity, the oxygen being fed from an oxygen-containing stream O that is brought in contact with the permeate side of the membrane.
    • 一种用于通过反应物料流E反应烃Aminokohlenwasserstoffen的直接胺化过程中,含有至少一种烃和至少一种胺化试剂,含有在反应区RZ氨基烃和氢气的反应混合物的R,并将该反应氢期间形成的至少一部分的电化学分离 将反应混合物R包括气密膜电极组件,所述至少一个选择性质子传导膜和在所述膜的至少一个电极催化剂的每一侧,其中,在所述阳极催化剂至少一个氢的一部分被氧化成质子在膜和质子的滞留物侧 在部分根据b1)通过阴极催化剂的渗透侧上的膜之后在施加电压下并且部分地根据b2)被还原成氢气以产生电流mi t氧转化成水,其中氧来自与膜的渗透侧接触的含氧流O.
    • 6. 发明申请
    • METHOD FOR DIRECT AMINATION OF HYDROCARBONS TO FORM AMINO HYDROCARBONS WITH THE ELECTROCHEMICAL SEPARATION OF HYDROCARBON
    • 直接处理烃与氢的电化学分离AMINOKOHLENWASSERSTOFFEN
    • WO2011003964A2
    • 2011-01-13
    • PCT/EP2010059771
    • 2010-07-08
    • BASF SEKUBANEK PETRPANCHENKO ALEXANDERFISCHER ANDREASHEIDEMANN THOMAS
    • KUBANEK PETRPANCHENKO ALEXANDERFISCHER ANDREASHEIDEMANN THOMAS
    • C07C209/02
    • C07C209/02C25B3/00Y02P20/582C07C211/46
    • The invention relates to a method for the direct amination of hydrocarbons to form amino hydrocarbons, comprising the following steps: conversion of an educt flow E containing at least one hydrocarbon and at least one amination reagent into a reaction mixture R containing amino hydrocarbons and hydrogen, and b) electrochemical separation of at least part of the hydrogen created during the conversion, from the reaction mixture R, by means of a gas-tight membrane electrode assembly comprising at least one selectively proton-conducting membrane and at least one electrode catalyst on each side of the membrane. On the retenate side of the membrane, at least part of the hydrogen is oxidised on the anode catalyst to form protons and, after passing through the membrane, on the permeate side, on the cathode catalyst, the protons are b1) reduced to hydrogen and/or b2) converted to water with oxygen, the oxygen originating from a flow O containing oxygen, brought into contact with the permeate side of the membrane.
    • 一种包括以下步骤Aminokohlenwasserstoffen烃的直接胺化过程:a)在反应物料流E反应,将含有在反应中至少一种烃和至少一种胺化试剂,)将得到的含有Aminokohlenwasserstoffe和氢气的反应混合物的R的至少一部分的电化学分离,和b 氢在从反应混合物中 - [R用气密膜电极组件,所述至少一个选择性质子传导膜和在膜的每一侧上的装置的至少一个电极催化剂,其特征在于,在阳极催化剂质子氢的至少一部分上的Retenatseite膜和氧化 质子B1)的,穿过在阴极催化剂的渗透侧膜后,根据还原成氢气和/或b2)中的与氧形成水,其特征在于,含有选自氧的氧反应 流O与膜的渗透侧接触。
    • 7. 发明公开
    • 시클릭 이소시아네이트의 제조 방법
    • 生产环状异氰酸酯的方法
    • KR20180030657A
    • 2018-03-23
    • KR20187004553
    • 2016-07-20
    • BASF SE
    • BREUER KLAUSBAUMANN ROBERTPANCHENKO ALEXANDERLORENZ MICHAELHETTCHE FRANKGUTFRUCHT NORBERTFENLON THOMAS
    • C07C263/10C07C263/20C07C265/14
    • C07C263/10C07B2200/09C07C2601/14C07C265/14
    • 본발명은적어도 4개의고리탄소원자를갖는적어도하나의시클로알칸고리를갖는적어도하나의성분 (A)를갖는조성물 (Z)를기재로하는시클릭이소시아네이트 (B)를제조하는방법에관한것이다. 시클로알칸고리는, 서로에대해β-위치또는γ-위치에있는 2개의 NH기를치환기로서가지며, 성분 (A)의총량의 50 몰% 초과에서, 서로에대해β-위치또는γ-위치에있는 2개의 NH기가서로에대해트랜스-배위를취한다. 조성물 (Z)를본 발명에따른방법으로포스겐과반응시켜, 이소시아네이트기를갖는적어도하나의시클릭이소시아네이트 (B)를갖는조성물 (ZP)를수득한다. 추가로본 발명은중합체를제조하는방법, 특히폴리우레탄및 폴리우레아를제조하는방법에서단량체로서의이소시아네이트혼합물 (M)의용도에관한것이다.
    • 本发明涉及基于具有至少一种具有至少一个具有至少四个环碳原子的环烷烃环的组分(A)的组合物(Z)制备环状异氰酸酯(B)的方法。 环烷环具有作为取代基的相对于彼此为α位或α位的两个NH基团,并且其超过组分(A)总量的50mol% 两个NH组彼此进行反式协调。 根据本发明的方法使组合物(Z)与光气反应以获得具有至少一种具有异氰酸酯基团的环状异氰酸酯(B)的组合物(ZP)。 本发明进一步涉及异氰酸酯混合物(M)在制备聚合物的方法中作为单体的用途,特别是在制备聚氨酯和聚脲中的用途。