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1. 发明专利

ES2296877T3 DISPERSANTES MULTIFUNCIONALES PARA CEMENTO Y COMPOSICIONES DE CEMENTO HIDRAULICO. 未知
公开(公告)号：ES2296877T3
公开(公告)日：2008-05-01
申请号：ES02254632
申请日：2002-07-02
申请人： BASF POZZOLITH LTD , TAKEMOTO OIL & FAT CO LTD
发明人： NAKANISHI HIROSHI , ISHIMORI MASAKI , YAGUCHI MINORU , SUGIYAMA TOMOMI , KINOSHITA MITSUO , TAMAKI SHINJI
IPC分类号： C08G65/32 , C04B24/26 , C04B24/32 , C04B28/02 , C04B103/32 , C04B111/76 , C08F8/14 , C08L71/02
摘要： Dispersante que es para cemento y comprende copolímeros de injerto que pueden ser obtenidos mediante: un primer paso que es el de obtener copolímeros con un peso molecular medio en número de 3000 a 50000 mediante polimerización por radicales de una mezcla de monómeros polimerizables por radicales que consta de anhídrido maleico y monómeros de la forma que viene dada por la siguiente Fórmula 1, juntamente en una cantidad de un 85% molar o más de dicha mezcla y en una relación molar de 50/50 a 80/20; y un segundo paso que es el de obtener dichos copolímeros de injerto mediante una reacción de injerto, en presencia de un catalizador básico, de 100 partes en peso de dichos copolímeros obtenidos en dicho primer paso y 3-35 partes en peso de uno o varios miembros seleccionados de entre los del grupo que consta de monoalquiléster de poli(oxialquileno), monoalquiléter de poli(oxialquileno) y poli(propilenglicol) con un número de repeticiones de las unidades de oxipropileno igual a 4-10; CH2 = CH - CH2 - O - A - O - R (Fórmula 1) donde R es un grupo acilo con 1-18 átomos de carbono, un grupo alquilo con 1-3 átomos de carbono o hidrógeno, y A es un grupo residual obtenido retirando todos los grupos hidroxilo de poli(alquilenglicol) con un número de repeticiones de las unidades oxialquileno igual a 5-80, constando dichas unidades oxialquileno solamente de unidades oxietileno o bien tanto de unidades oxietileno como de unidades oxipropileno; donde dicho monoalquiléster de poli(oxialquileno) tiene una adición en bloque de 1-4 moles de óxido de etileno y 1-4 moles de óxido de propileno por un mol de ácido carboxílico alifático con 1-6 átomos de carbono; y donde dicho monoalquiléter de poli(oxialquileno) tiene una adición en bloque de 1-4 moles de óxido de etileno y 1-4 moles de óxido de propileno por un mol de alcohol alifático con 3-5 átomos de carbono.

2. 发明专利

DE60223629T2 未知
公开(公告)号：DE60223629T2
公开(公告)日：2008-10-30
申请号：DE60223629
申请日：2002-07-02
申请人： BASF POZZOLITH LTD , TAKEMOTO OIL & FAT CO LTD
发明人： NAKANISHI HIROSHI , ISHIMORI MASAKI , YAGUCHI MINORU , SUGIYAMA TOMOMI , KINOSHITA MITSUO , TAMAKI SHINJI , SUGAMATA TAKUMI
IPC分类号： C08G65/32 , C04B24/26 , C04B24/32 , C04B28/02 , C04B103/32 , C04B111/76 , C08F8/14 , C08L71/02
摘要： A multi-functional cement dispersant contains a graft copolymer obtainable by: a first step of obtaining copolymers with average numerical molecular weight of from 3000 to 50000 by radical polymerisation of a mixture of radical polymerizable monomers containing maleic anhydride and monomers of form given by Formula 1 below, together in an amount of 85 molar % or more of said mixture and at molar ratio of from 50/50 to 80/20; and a second step of obtaining said graft copolymers by a graft reaction, in the presence of a basic catalyst, of 100 weight parts of said copolymers obtained in said first step and 3-35 weight parts of one or more selected from the group consisting of poly(oxyalkylene) monoalkylester, poly(oxyalkylene) monoalkylether and poly(propyleneglycol) with repetition number of oxypropylene units equal to 3-15; CH2=CH-CH2-O-A-O-R where R is an acyl group with 1-18 carbon atoms, an alkyl group with 1-3 carbon atoms or hydrogen, and A is a residual group obtained by removing all hydroxyl groups from poly(alkylene glycol) with repetition number of oxyalkylene units equal to 5-80, said oxyalkylene units consisting only of oxyethylene units or of both oxyethylene units and oxypropylene units; where said poly(oxyalkylene) monoalkylester has a block addition of a total of 2-10 moles of ethylene oxide and propylene oxide to one mole of aliphatic carboxylic acid with 1-6 carbon atoms; and where said poly(oxyalkylene) monoalkylether has a block addition of a total of 2-10 moles of ethylene oxide and propylene oxide to one mole of aliphatic alcohol with 1-6 carbon atoms. Hydraulic cement compositions produced with such a multi-functional cement dispersant have a superior fluidity with reduced loss of fluidity over time and hardened objects produced from such a composition exhibit a superior early strength and have a low dry shrinkage and a high resistance against freezing and thawing.

3. 发明专利

AU776089B2 Multi-functional cement dispersants and hydraulic cement compositions 未知
公开(公告)号：AU776089B2
公开(公告)日：2004-08-26
申请号：AU4892902
申请日：2002-06-25
申请人： TAIHEIYO CEMENT KABUSHIKI KAIS , NMB CO LTD , TAKEMOTO OIL & FAT CO LTD
发明人： NAKANISHI HIROSHI , ISHIMORI MASAKI , YAGUCHI MINORU , SUGAMATA TAKUMI , SUGIYAMA TOMOMI , KINOSHITA MITSUO , TAMAKI SHINJI
IPC分类号： C04B24/26 , C04B24/32 , C04B28/02 , C04B103/32 , C04B111/76 , C08F8/14 , C08L71/02 , C04B24/24 , C08F267/04 , C08F283/00 , C08F299/04
摘要： A multi-functional cement dispersant contains a graft copolymer obtainable by: a first step of obtaining copolymers with average numerical molecular weight of from 3000 to 50000 by radical polymerisation of a mixture of radical polymerizable monomers containing maleic anhydride and monomers of form given by Formula 1 below, together in an amount of 85 molar % or more of said mixture and at molar ratio of from 50/50 to 80/20; and a second step of obtaining said graft copolymers by a graft reaction, in the presence of a basic catalyst, of 100 weight parts of said copolymers obtained in said first step and 3-35 weight parts of one or more selected from the group consisting of poly(oxyalkylene) monoalkylester, poly(oxyalkylene) monoalkylether and poly(propyleneglycol) with repetition number of oxypropylene units equal to 3-15; CH2=CH-CH2-O-A-O-R where R is an acyl group with 1-18 carbon atoms, an alkyl group with 1-3 carbon atoms or hydrogen, and A is a residual group obtained by removing all hydroxyl groups from poly(alkylene glycol) with repetition number of oxyalkylene units equal to 5-80, said oxyalkylene units consisting only of oxyethylene units or of both oxyethylene units and oxypropylene units; where said poly(oxyalkylene) monoalkylester has a block addition of a total of 2-10 moles of ethylene oxide and propylene oxide to one mole of aliphatic carboxylic acid with 1-6 carbon atoms; and where said poly(oxyalkylene) monoalkylether has a block addition of a total of 2-10 moles of ethylene oxide and propylene oxide to one mole of aliphatic alcohol with 1-6 carbon atoms. Hydraulic cement compositions produced with such a multi-functional cement dispersant have a superior fluidity with reduced loss of fluidity over time and hardened objects produced from such a composition exhibit a superior early strength and have a low dry shrinkage and a high resistance against freezing and thawing.

4. 发明专利

DE60223629D1 未知
公开(公告)号：DE60223629D1
公开(公告)日：2008-01-03
申请号：DE60223629
申请日：2002-07-02
申请人： TAIHEIYO CEMENT K K , NMB CO LTD , TAKEMOTO OIL & FAT CO LTD
发明人： NAKANISHI HIROSHI , ISHIMORI MASAKI , YAGUCHI MINORU , SUGIYAMA TOMOMI , KINOSHITA MITSUO , TAMAKI SHINJI , SUGAMATA TAKUMI
IPC分类号： C08G65/32 , C04B24/26 , C04B24/32 , C04B28/02 , C04B103/32 , C04B111/76 , C08F8/14 , C08L71/02
摘要： A multi-functional cement dispersant contains a graft copolymer obtainable by: a first step of obtaining copolymers with average numerical molecular weight of from 3000 to 50000 by radical polymerisation of a mixture of radical polymerizable monomers containing maleic anhydride and monomers of form given by Formula 1 below, together in an amount of 85 molar % or more of said mixture and at molar ratio of from 50/50 to 80/20; and a second step of obtaining said graft copolymers by a graft reaction, in the presence of a basic catalyst, of 100 weight parts of said copolymers obtained in said first step and 3-35 weight parts of one or more selected from the group consisting of poly(oxyalkylene) monoalkylester, poly(oxyalkylene) monoalkylether and poly(propyleneglycol) with repetition number of oxypropylene units equal to 3-15; CH2=CH-CH2-O-A-O-R where R is an acyl group with 1-18 carbon atoms, an alkyl group with 1-3 carbon atoms or hydrogen, and A is a residual group obtained by removing all hydroxyl groups from poly(alkylene glycol) with repetition number of oxyalkylene units equal to 5-80, said oxyalkylene units consisting only of oxyethylene units or of both oxyethylene units and oxypropylene units; where said poly(oxyalkylene) monoalkylester has a block addition of a total of 2-10 moles of ethylene oxide and propylene oxide to one mole of aliphatic carboxylic acid with 1-6 carbon atoms; and where said poly(oxyalkylene) monoalkylether has a block addition of a total of 2-10 moles of ethylene oxide and propylene oxide to one mole of aliphatic alcohol with 1-6 carbon atoms. Hydraulic cement compositions produced with such a multi-functional cement dispersant have a superior fluidity with reduced loss of fluidity over time and hardened objects produced from such a composition exhibit a superior early strength and have a low dry shrinkage and a high resistance against freezing and thawing.

5. 发明专利

AU4892902A Multi-functional cement dispersants and hydraulic cement compositions 未知
公开(公告)号：AU4892902A
公开(公告)日：2003-01-09
申请号：AU4892902
申请日：2002-06-25
申请人： TAIHEIYO CEMENT KABUSHIKI KAIS , TAKEMOTO OIL & FAT CO LTD , NMB CO LTD
发明人： NAKANISHI HIROSHI , TAMAKI SHINJI , SUGIYAMA TOMOMI , KINOSHITA MITSUO , SUGAMATA TAKUMI , YAGUCHI MINORU , ISHIMORI MASAKI
IPC分类号： C04B24/26 , C04B24/32 , C04B28/02 , C04B103/32 , C04B111/76 , C08F8/14 , C08L71/02 , C04B24/24 , C08F267/04 , C08F283/00 , C08F299/04
摘要： A multi-functional cement dispersant contains a graft copolymer obtainable by: a first step of obtaining copolymers with average numerical molecular weight of from 3000 to 50000 by radical polymerisation of a mixture of radical polymerizable monomers containing maleic anhydride and monomers of form given by Formula 1 below, together in an amount of 85 molar % or more of said mixture and at molar ratio of from 50/50 to 80/20; and a second step of obtaining said graft copolymers by a graft reaction, in the presence of a basic catalyst, of 100 weight parts of said copolymers obtained in said first step and 3-35 weight parts of one or more selected from the group consisting of poly(oxyalkylene) monoalkylester, poly(oxyalkylene) monoalkylether and poly(propyleneglycol) with repetition number of oxypropylene units equal to 3-15; CH2=CH-CH2-O-A-O-R where R is an acyl group with 1-18 carbon atoms, an alkyl group with 1-3 carbon atoms or hydrogen, and A is a residual group obtained by removing all hydroxyl groups from poly(alkylene glycol) with repetition number of oxyalkylene units equal to 5-80, said oxyalkylene units consisting only of oxyethylene units or of both oxyethylene units and oxypropylene units; where said poly(oxyalkylene) monoalkylester has a block addition of a total of 2-10 moles of ethylene oxide and propylene oxide to one mole of aliphatic carboxylic acid with 1-6 carbon atoms; and where said poly(oxyalkylene) monoalkylether has a block addition of a total of 2-10 moles of ethylene oxide and propylene oxide to one mole of aliphatic alcohol with 1-6 carbon atoms. Hydraulic cement compositions produced with such a multi-functional cement dispersant have a superior fluidity with reduced loss of fluidity over time and hardened objects produced from such a composition exhibit a superior early strength and have a low dry shrinkage and a high resistance against freezing and thawing.

6. 发明专利

CA2394113C MULTI-FUNCTIONAL CEMENT DISPERSANTS AND HYDRAULIC CEMENT COMPOSITIONS 未知
公开(公告)号：CA2394113C
公开(公告)日：2010-12-07
申请号：CA2394113
申请日：2002-07-18
申请人： TAIHEIYO CEMENT KABUSHIKI KAISHA , NMB CO LTD , TAKEMOTO OIL & FAT CO LTD
发明人： NAKANISHI HIROSHI , ISHIMORI MASAKI , YAGUCHI MINORU , SUGAMATA TAKUMI , SUGIYAMA TOMOMI , KINOSHITA MITSUO , TAMAKI SHINJI
IPC分类号： C04B24/24 , C04B7/00
摘要： A multi-functional cement dispersant contains a graft copolymer obtained by a graft reaction of one or more selected from polyoxyalkylene monoalkylester, polyoxyalkylene monoalkylether and polypropyleneglycol of specified kinds to a copolymer obtained by radical polymerization of a mixture of radical polymerizable monomers containing maleic anhydride and monomers of a specified kind at a specified ratio. Hydraulic cement compositions produced with such a multi-functional cement dispersant have a superior fluidity with reduced loss over time and hardened objects produced from such a composition exhibit a superior early strength and have a low dry shrinkage and a high resistance against freezing and thawing.

7. 发明专利

CA2394113A1 MULTI-FUNCTIONAL CEMENT DISPERSANTS AND HYDRAULIC CEMENT COMPOSITIONS 未知
公开(公告)号：CA2394113A1
公开(公告)日：2003-09-27
申请号：CA2394113
申请日：2002-07-18
申请人： TAIHEIYO CEMENT KABUSHIKI KAIS , NMB CO LTD , TAKEMOTO OIL & FAT CO LTD
发明人： KINOSHITA MITSUO , SUGAMATA TAKUMI , SUGIYAMA TOMOMI , NAKANISHI HIROSHI , ISHIMORI MASAKI , YAGUCHI MINORU , TAMAKI SHINJI
IPC分类号： C04B7/00 , C04B24/24
摘要： A multi-functional cement dispersant contains a graft copolymer obtained by a graft reaction of one or more selected from polyoxyalkylene monoalkylester, polyoxyalkylene monoalkylether and polypropyleneglycol of specified kinds to a copolymer obtained by radical polymerization of a mixture of radical polymerizable monomers containing maleic anhydride and monomers of a specified kind at a specified ratio. Hydraulic cement compositions produced with such a multi-functional cement dispersant have a superior fluidity with reduced loss over time and hardened objects produced from such a composition exhibit a superior early strength and have a low dry shrinkage and a high resistance against freezing and thawing.

8. 发明专利

JP2003081670A Multifunctional cement dispersant, and hydraulic cement composition 有权
标题翻译：多功能水泥分散剂和液压水泥组合物
公开(公告)号：JP2003081670A
公开(公告)日：2003-03-19
申请号：JP2002087683
申请日：2002-03-27
申请人： Nmb Co Ltd , Taiheiyo Cement Corp , Takemoto Oil & Fat Co Ltd , 太平洋セメント株式会社 , 株式会社エヌエムビー , 竹本油脂株式会社
发明人： NAKANISHI HIROSHI , ISHIMORI MASAKI , YAGUCHI MINORU , SUGAMATA TAKUMI , SUGIYAMA TOMOMI , KINOSHITA MITSUO , TAMAKI SHINJI
IPC分类号： C04B24/26 , C04B24/32 , C04B28/02 , C04B103/32 , C04B111/76 , C08F8/14 , C08L71/02
CPC分类号： C04B24/267 , C04B2103/006 , C04B2103/408 , C08L71/02 , C08L2205/05 , C08L2666/04
摘要： PROBLEM TO BE SOLVED: To provide a multifunctional cement dispersant which can simultaneously impart multifunctions that a hydraulic cement composition to be prepared has excellent fluidity reduced in deterioration with time, and a hardened body to be obtained exhibits excellent initial strength, has a low dry shrinkage percentage and high resistance to freezing fusing action, and to provide a hydraulic cement composition simultaneously having the same multifunctions.
SOLUTION: As the multifunctional cement dispersant, a graft copolymer in which one or more selected from a specified polyoxyalkylene monoalkyl ester, polyoxyalkylene monoalkyl ether and polypropylene glycol is brought into graft reaction in a prescribed ratio with a copolymer obtained by radical- polymerizing a radical-polymerizable monomer mixture containing maleic anhydride and a specified monomer in a prescribed ratio is used.
COPYRIGHT: (C)2003,JPO
摘要翻译：要解决的问题：提供一种多功能水泥分散剂，其能够同时赋予待制备的水硬性水泥组合物随着时间劣化而具有优异的流动性降低的多功能，并且所得到的硬化体显示出优异的初始强度，具有低的干缩率百分比和高抗冻融融合作用，并提供同时具有相同多功能的水硬性水泥组合物。解决方案：作为多功能水泥分散剂，将选自规定的聚氧化烯单烷基酯，聚氧化烯单烷基醚和聚丙二醇中的一种以上的接枝共聚物与通过使自由基聚合反应获得的共聚物以规定的比例进行接枝反应，使用含有马来酸酐和规定比例的特定单体的可聚合单体混合物。

9. 发明专利

JP2001294466A ADMIXTURE FOR HYDRAULIC COMPOSITION AND HYDRAULIC COMPOSITION 失效
公开(公告)号：JP2001294466A
公开(公告)日：2001-10-23
申请号：JP2000111845
申请日：2000-04-13
申请人： TAIHEIYO CEMENT CORP , NMB KK , TAKEMOTO OIL & FAT CO LTD
发明人： NAKANISHI HIROSHI , OGAWA SHOICHI , MATSUO SHIGEMI , SUGIYAMA TOMOMI , KINOSHITA MITSUO , MIURA TOYOJI
IPC分类号： C04B24/02 , C04B24/32 , C04B28/02 , C04B103/50 , C04B111/34 , C08K5/00 , C08K5/06 , C08L71/02
摘要： PROBLEM TO BE SOLVED: To provide an admixture used for a hydraulic composition, which has an excellent shrinkage reduction effect and excellent frost damage resistance, and to provide the hydraulic composition. SOLUTION: This admixture contains a compound (s) represented by the formula (A-1) and/or the formula (A-2), and another compound (s) represented by the formula (B-1) and/or the formula (B-2) (in these formula each of R1-R9 is an alkyl group or the like; each of A, B, X, Y and Z is an alkylene group; each of, n, m, p and r is numeral of 0-20; and p is numeral of 20-200).

10. 发明专利

JP2002003257A DISPERSING AGENT FOR GYPSUM 失效
公开(公告)号：JP2002003257A
公开(公告)日：2002-01-09
申请号：JP2000179410
申请日：2000-06-15
申请人： TAIHEIYO CEMENT CORP , TAKEMOTO OIL & FAT CO LTD
发明人： NAKANISHI HIROSHI , ISHIMORI MASAKI , KINOSHITA MITSUO , IIDA MASAHIRO , TAKAHASHI TOMOO
IPC分类号： B01F17/52 , C04B24/26 , C04B28/14 , C04B103/40 , C08F290/06
摘要： PROBLEM TO BE SOLVED: To offer a dispersing agent for gypsum with the small amount of water used, therefore which can grant sufficient flowability with the small amount used even for the gypsum slurry in low water/gypsum ratio. SOLUTION: It is provided with the water-soluble vinyl copolymer of the weight-avarage molecular weight 1,000-100,000 obtained by copolymerizing 1 sort of specific vinyl monomer having in its molecule the polyoxyalkylene group which is composed of a oxyethylene unit and a oxypropylene unit and two other sorts of specific vinyl monomers in the specified ratio respectively.

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