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1. 发明专利

DE60223629D1 未知
公开(公告)号：DE60223629D1
公开(公告)日：2008-01-03
申请号：DE60223629
申请日：2002-07-02
申请人： TAIHEIYO CEMENT K K , NMB CO LTD , TAKEMOTO OIL & FAT CO LTD
发明人： NAKANISHI HIROSHI , ISHIMORI MASAKI , YAGUCHI MINORU , SUGIYAMA TOMOMI , KINOSHITA MITSUO , TAMAKI SHINJI , SUGAMATA TAKUMI
IPC分类号： C08G65/32 , C04B24/26 , C04B24/32 , C04B28/02 , C04B103/32 , C04B111/76 , C08F8/14 , C08L71/02
摘要： A multi-functional cement dispersant contains a graft copolymer obtainable by: a first step of obtaining copolymers with average numerical molecular weight of from 3000 to 50000 by radical polymerisation of a mixture of radical polymerizable monomers containing maleic anhydride and monomers of form given by Formula 1 below, together in an amount of 85 molar % or more of said mixture and at molar ratio of from 50/50 to 80/20; and a second step of obtaining said graft copolymers by a graft reaction, in the presence of a basic catalyst, of 100 weight parts of said copolymers obtained in said first step and 3-35 weight parts of one or more selected from the group consisting of poly(oxyalkylene) monoalkylester, poly(oxyalkylene) monoalkylether and poly(propyleneglycol) with repetition number of oxypropylene units equal to 3-15; CH2=CH-CH2-O-A-O-R where R is an acyl group with 1-18 carbon atoms, an alkyl group with 1-3 carbon atoms or hydrogen, and A is a residual group obtained by removing all hydroxyl groups from poly(alkylene glycol) with repetition number of oxyalkylene units equal to 5-80, said oxyalkylene units consisting only of oxyethylene units or of both oxyethylene units and oxypropylene units; where said poly(oxyalkylene) monoalkylester has a block addition of a total of 2-10 moles of ethylene oxide and propylene oxide to one mole of aliphatic carboxylic acid with 1-6 carbon atoms; and where said poly(oxyalkylene) monoalkylether has a block addition of a total of 2-10 moles of ethylene oxide and propylene oxide to one mole of aliphatic alcohol with 1-6 carbon atoms. Hydraulic cement compositions produced with such a multi-functional cement dispersant have a superior fluidity with reduced loss of fluidity over time and hardened objects produced from such a composition exhibit a superior early strength and have a low dry shrinkage and a high resistance against freezing and thawing.

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