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    • 3. 发明申请
    • SUBSTITUTED AZOLIN-2-YL-AMINO COMPOUNDS
    • 取代的AZOLIN-2-YL-AMINO化合物
    • WO2008017649A1
    • 2008-02-14
    • PCT/EP2007/058109
    • 2007-08-06
    • BASF AKTIENGESELLSCHAFTKORADIN, ChristopherKORDES, MarkusLE VEZOUET, RonanCULBERTSON, Deborah L.ANSPAUGH, Douglas D.
    • KORADIN, ChristopherKORDES, MarkusLE VEZOUET, RonanCULBERTSON, Deborah L.ANSPAUGH, Douglas D.
    • C07D277/18C07D417/12A01N43/00
    • C07D417/12A01N43/50A01N43/76A01N43/78C07D277/18
    • The present invention relates to azolin-2-yl-amino compounds of formulae (I. a) and (l.b) and their salts which are useful for combating animal pest, in particular arthropod and nematodes. The present invention also relates to a method for combating such pests and for protecting crops against infestation or infection by such pests. Furthermore, the present invention relates to veterinary compositions for combating animal pests. Formula (I.a), formula (I.b) wherein n is 0 to 4; X is S, O or NR 5 ; A is -C(R 6a )(R 6b )-, O, NR 7 , S, S(O) or S(O) 2 ; B is a bond Or CH 2 ; R 1 is H, CN, C 1 -C 6 -alkyl, C 2 -C 6 -alkenyl, C 1 -C 6 -alkylcarbonyl, C 3 -C 6 -cycloalkyl, phenyl, benzyl, etc.; R 2a , R 2b are H, CN, C 1 -C 6 -alkyl, C 2 -C 6 -alkenyl, C 1 -C 6 -alkylcarbonyl, C 1 -C 6 -alkoxycarbonyl, (C 1 -C 6 -alkyl)thiocarbonyl, C(O)NR a R b , C(S)NR a R b , (SO 2 )NR a R b , phenyl, benzyl, 5 or 6 membered heterocyclic ring etc.; or R 1 together with R 2a is C 3 -C 5 -alkandiyl; or R 1 together with R 2b are C(O); R 3a , R 3b , R 3c , R 3d are H, halogen, CN, C 1 -C 6 -alkyl, C 1 -C 6 -alkylamino, C 3 -C 6 -cycloalkyl, phenyl, benzyl, etc.; R 4a , R 4b are H, halogen, C 1 -C 6 -alkyl, C 2 -C 6 -alkenyl, phenyl, benzyl, 5 or 6 membered hetaryl; or R 4a together with R 4b may also be =0, =NR C or =CR d R e ; or R 2a together with R 4a may form a bridging bivalent radical.
    • 本发明涉及用于对抗动物害虫,特别是节肢动物和线虫的式(Ⅰa)和(Ⅰ.B)的吡咯烷-2-基氨基化合物及其盐。 本发明还涉及一种防治这种害虫并防止作物抵抗这种害虫侵染或感染的方法。 此外,本发明涉及用于对抗动物害虫的兽用组合物。 式(Ⅰa),式(Ⅰb)其中n为0-4; X是S,O或NR 5; A是-C(R 6a)(R 6b) - ,O,NR 7,S,S(O)或S(O ) 2 ; B是键或CH 2 2; R 1是H,CN,C 1 -C 6 - 烷基,C 2 -C 3 - C 1 -C 6 - 亚烷基,C 1 -C 6 - 烷基羰基,C 3 -C 6 - 环烷基,苯基,苄基等; R 2a,R 2b是H,CN,C 1 -C 6 - 烷基,C 1 -C 6烷基, C 1 -C 6亚烷基,C 1 -C 6 - 烷基羰基,C 1 -C 6 - 烷基羰基,C 1 -C 6 - C 6 -C 6 - 烷氧基羰基,(C 1 -C 6 - 烷基)硫代羰基,C(O)NR a C C(S)NR a R b,(SO 2)NR a, 苯基,苄基,5或6元杂环等; 或R 1与R 2a一起为C 3 -C 5 - 亚烷基; 或R 1和R 2b一起是C(O); R 3a,R 3b,R 3c,R 3d是H,卤素,CN,C C 1 -C 6 - 烷基,C 1 -C 6 - 烷基氨基,C 3 - C 6 -C 6 - 环烷基,苯基,苄基等; R 4a,R 4b是H,卤素,C 1 -C 6 - 烷基,C 1 -C 4烷基, C 2 -C 6 - 烯基,苯基,苄基,5或6元杂芳基; 或R 4a与R 4b一起也可以是= 0,= NR C或= CR D, SUP>电子; 或R 2a与R 4a一起可以形成桥连二价基团。
    • 10. 发明申请
    • PESTICIDAL DIBENZO(HETERO)AZEPINE DERIVATIVES
    • 杀虫剂二苯醚(异恶唑)胺衍生物
    • WO2004056182A1
    • 2004-07-08
    • PCT/EP2003/014443
    • 2003-12-18
    • BASF AKTIENGESELLSCHAFTSTEINER, GerdSCHMIDT, ThomasKORDES, MarkusVON DEYN, WolfgangGÖTZ, NorbertHOFMANN, MichaelDE KRAMER, Jacobus JanHEFFERNAN, GavinCULBERTSON, Deborah L.TREACY, Michael, F.OLOUMI-SADEGHI, HassanEBUENGA, CecilleTEDESCHI, LivioBUCCI, ToniPARRA RAPADO, LilianaRACK, MichaelBAUMANN, ErnstPUHL, Michael
    • STEINER, GerdSCHMIDT, ThomasKORDES, MarkusVON DEYN, WolfgangGÖTZ, NorbertHOFMANN, MichaelDE KRAMER, Jacobus JanHEFFERNAN, GavinCULBERTSON, Deborah L.TREACY, Michael, F.OLOUMI-SADEGHI, HassanEBUENGA, CecilleTEDESCHI, LivioBUCCI, ToniPARRA RAPADO, LilianaRACK, MichaelBAUMANN, ErnstPUHL, Michael
    • A01N43/72
    • C07D267/20A01N43/72C07D223/20C07D243/38C07D267/18C07D281/14C07D281/16C07D413/12
    • Use of compounds of formula (I): wherein X is S, O, S=O, SO 2 , NR a , or CR b R c ;R 1 ,R 2 are halogen, OH, SH, NH 2 , CN, NO 2 , alkyl, alkoxy, alkylamino, dialkylamino, alkylthio, alkenyl, alkenyloxy, alkenylamino, alkenylthio, alkynyl, alkynyloxy, alkynylamino, alkynylthio, alkylsulfonyl, alkylsulfoxyl, alkenylsulfonyl, alkynylsulfoxyl, formyl, alkylcarbonyl, hydroxycarbonyl, alkoxycarbonyl, carbonyloxy, alkylcarbonyloxy, phenyloxy, alkylcarbonylamino, C(O)NR d R e , or (SO 2 )NR d R e , or C=NOR f )-G p -R f' , ora mono- or bicyclic 5- to 10-membered aromatic or heteroaromatic ringsystem, optionally substituted, which is unfused or fused to the aromatic group to which it is bonded and which, when unfused, is bonded directly or through an O, S, alkyl, or alkoxy linkage, or cycloalkyl, wherein the carbon atoms in these groups may be substituted.R 3 ,R 4 are each independently H, alkyl, haloalkyl, alkylamino, alkoxy, cycloalkyl, wherein the carbon atoms in these groups may be substituted, or R 3 and R 4 together with the nitrogen atom to which they are attached form a saturated or partially saturated mono- or bicyclic 5- to 10-membered ringsystem or 5-membered hetaryl, phenyl or benzyl, wherein the rings are optionally sub-stituted, or R 3 and R 4 together form the chains -(CH 2 ) 2 N + (O - )(CH 2 ) 2 - or -(CH 2 ) 3 N + (O - )(CH 2 ) 2 -;and R a , R b , R c , R d , R e , R f ', R f , G, and p are as defined in the description;m is 0, 1, 2, 3 or 4;n is 0, 1, 2, 3 or 4;or the enantiomers or diastereomers, salts or esters thereof for combatting insects, arachnids, or nematodes, methods for the control of these pests and of protecting growing plants from attack or infestation by these pests by applying a pesticidally effective amount of compounds of formula ( I), compounds of formula (I), processes for preparing them, and compositions comprising them.
    • 式(I)化合物的用途:其中X是S,O,S = O,SO 2,NR a或CR R c; R 1,R 2是卤素,OH ,烷基磺酰基,烷基磺酰基,烯基磺酰基,炔基磺酰基,甲酰基,烷基羰基,羟基羰基,烷氧基羰基,烷氧基羰基,烷氧基羰基,烷基氨基, ,羰基氧基,烷基羰基氧基,苯氧基,烷基羰基氨基,C(O)NR d R e或(SO 2)NR d R e或C = NOR f)-Gp-R f' ,或单环或双环5-至10-元芳族或杂芳族环系统,任选取代的,其未被结合或与其键合的芳族基团稠合,当未被融合时,直接或通过O,S ,烷基或烷氧基键或环烷基,其中这些基团中的碳原子可以被取代.R 3,R 4各自独立地为H,烷基,卤代烷基,烷基氨基,烷氧基,环烷基,其中 这些基团可以被取代,o r R 3和R 4与它们所连接的氮原子一起形成饱和或部分饱和的单环或双环5-至10-元环系或五元杂芳基,苯基或苄基,其中环 任选被取代,或R 3和R 4一起形成链 - (CH 2)2 N +(O - )(CH 2)2 - 或 - (CH 2)3 N + (CH 2)2 - ;和R a,R b,R c,R d,R e,R f',R f,G和 p如说明书中所定义; m为0,1,2,3或4; n为0,1,2,3或4;或用于对抗昆虫,蜘蛛或线虫的对映异构体或非对映体,其盐或酯 用于控制这些害虫的方法和通过施用杀虫有效量的式(I)化合物,式(I)化合物,其制备方法和包含它们的组合物来保护生长植物免受这些害虫的侵袭或侵扰 。