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    • 4. 发明申请
    • PYRAZOL-4-YL-BENZOYL DERIVATIVES AND THEIR USE AS HERBICIDES
    • 吡唑-4-基苯甲酰及其作为除草剂
    • WO1996026206A1
    • 1996-08-29
    • PCT/EP1996000635
    • 1996-02-14
    • BASF AKTIENGESELLSCHAFTVON DEYN, WolfgangHILL, Regina, LuiseKARDORFF, UweENGEL, StefanOTTEN, MartinaVOSSEN, MarcusPLATH, PeterRANG, HaraldHARREUS, AlbrechtKÖNIG, HartmannWALTER, HelmutWESTPHALEN, Karl-OttoMISSLITZ, Ulf
    • BASF AKTIENGESELLSCHAFT
    • C07D409/10
    • C07D401/10A01N43/56A01N43/74A01N43/80C07D231/24C07D403/10C07D405/10C07D409/10C07D411/10C07D413/10C07D417/10
    • Pyrazol-4-yl-benzoyl derivatives have the formula (I), in which the substituents have the following meanings: L, M are hydrogen, C1-C6 alkyl, C2-C6 alkenyl, C2-C6 alkinyl, C1-C4 alkoxy, these groups being optionally substituted by 1 to 5 halogen atoms or C1-C4 alkoxy, halogen, cyano, nitro, a group -(Y)n-S(O)mR or a group -(Y)n-CO-R ; Z is a 5 or 6-membered saturated or unsaturated heterocyclic rest, that contains 1 to 3 heteroatoms selected from the group that includes oxygen, sulphur or nitrogen, optionally substituted by halogen, cyano, nitro, a group -CO-R , C1-C4 alkyl, C1-C4 halogen alkyl, C3-C8 cycloalkyl, C1-C4 alkoxy, C1-C4 halogen alkoxy, C1-C4 alkylthio, C1-C4 halogen alkylthio, di-C1-C4-alkylamino, a phenyl optionally substituted by halogen, cyano, nitro C1-C4 alkyl or C1-C4 halogen alkyl or a twice bound oxygen that optionally in the tautomer form may also be a hydroxy group, or that forms a bicyclic system together with a condensed phenyl ring optionally substituted by halogen, cyano, nitro, C1-C4 alkyl or C1-C4 halogen alkyl, with a condensed carbon cycle or with a second condensed heterocycle optionally substituted by halogen, cyano, nitro, C1-C4 alkyl, di-C1-C4-alkylamino, C1-C4 alkoxy, C1-C4 halogen alkoxy or C1-C4 halogen alkyl; Y is O, NR ; n equals 0 or 1; m equals 0, 1 or 2; R is C1-C4 alkyl, C1-C4 halogen alkyl or NR R ; R is C1-C4 alkyl, C1-C4 halogen alkyl, C1-C4 alkoxy or NR R ; R is hydrogen or C1-C4 alkyl; R is C1-C4 alkyl; Q is a pyrazol ring linked at position 4 having the formula (II) in which R is C1-C4 alkyl; R is hydrogen or C1-C4 alkyl; and R is hydrogen, C1-C4 alkyl sulphonyl, phenyl sulphonyl or alkyl phenyl sulphonyl. Also disclosed are the salts of compounds (I) usually utilized in agriculture.
    • 吡唑-4-基 - 苯甲酰基的式(I),其中取代基具有以下含义的衍生物:L,M是氢,C1-C6烷基,C2-C6链烯基,C2-C6炔基,C1-C4烷氧基, (Y)N S(O)MR <7>或基团 - - (Y)N-CO-,其基团可被一至五个卤素原子或C1-C4烷氧基,任选,卤素,氰基,硝基,的基团取代 [R <8>; Z是5-或6-元杂环的饱和或不饱和基团含有一个,从组氧,硫或氮的选择三个杂原子,任选被卤素取代,氰基,硝基,基团-CO-R <8> C1-C4烷基,C1-C4卤代烷基,C3-C8环烷基,C1-C4烷氧基,C1-C4卤代烷氧基,C1-C4烷硫基,C1-C4卤代烷硫基,二-C 1 -C 4 - 烷基氨基, 任选被卤素取代的,氰基,硝基,C1-C4烷基或C1-C4卤代烷基取代的苯基或双键键合的氧,其也可以任选地存在于所述互变异构形式作为羟基,或与稠合的,任选被卤素取代, 氰基,硝基,C1-C4烷基或C1-C4卤代烷基取代的苯环,稠合碳环或稠合的,任选地被卤素,氰基,硝基,C1-C4烷基,二C1-C4烷基氨基,C1-C4取代的 烷氧基,C1-C4卤代烷氧基,或C1-C4卤代烷基取代的 n个第二杂环形成双环体系; Y是O,NR <9>; n是0或1; m是零,1或2; [R <7> C1-C4烷基,C1-C4卤代烷基,或NR <9> - [R <10>; [R <8> C1-C4烷基,C1-C4卤代烷基,C1-C4烷氧基,或NR <9> - [R <10>; [R <9>是氢或C1-C4烷基; [R <10> C1-C4烷基; Q为式(II)的4位连接的吡唑环,其中R <1> C1-C4烷基; [R <2>是氢或C1-C4烷基; 且R <3>为氢,C1-C4烷基磺酰基,苯基磺酰基或烷基苯基,和化合物(I)的可农用常用盐。
    • 6. 发明申请
    • ISOXAZOLYL-BENZOYL DERIVATIVES
    • 异恶唑基苯甲酰
    • WO1996026192A1
    • 1996-08-29
    • PCT/EP1996000592
    • 1996-02-13
    • BASF AKTIENGESELLSCHAFTVON DEYN, WolfgangHILL, Regina, LuiseKARDORFF, UweENGEL, StefanOTTEN, MartinaVOSSEN, MarcusPLATH, PeterRANG, HaraldHARREUS, AlbrechtRÖHL, FranzWALTER, HelmutWESTPHALEN, Karl-OttoMISSLITZ, Ulf
    • BASF AKTIENGESELLSCHAFT
    • C07D261/08
    • C07D413/10A01N43/80C07D261/08C07D417/10
    • The invention concerns isoxazol-4-yl-benzoyl derivatives of formula (I) in which the substituents have the following meanings: L and M represent hydrogen, C1-C6 alkyl, C2-C6 alkenyl, C2-C6 alkinyl, C1-C4 alkoxy (these groups being optionally substituted by one to five halogen atoms or C1-C4 alkoxy), halogen, cyano, nitro, a -(Y)n-S(O)mR or -(Y)n-CO-R group; Z represents a five to six-membered heterocyclic saturated or unsaturated group which contains one to three heteroatoms selected from the group comprising oxygen, sulphur or nitrogen and can optionally be substituted by halogen, cyano, nitro, an -CO-R group, C1-C4 alkyl, C1-C4 alkyl halide, C3-C8 cycloalkyl, C1-C4 alkoxy, C1-C4 alkoxy halide, C1-C4 alkyl thio, C1-C4 alkyl thio halide, di-C1-C4 alkyl amino, phenyl optionally substituted by halogen, cyano, nitro, C1-C4 alkyl or C1-C4 alkyl halide, or an oxo group which can be present in the tautomeric form as a hydroxy group, is substituted or, together with a condensation-bound phenyl ring which is optionally substituted by halogen, cyano, nitro, C1-C4 alkyl or C1-C4 alkyl halide, with a condensation-bound carbocycle or with a condensation-bound second heterocycle which can optionally be substituted by halogen, cyano, nitro, C1-C4 alkyl, di-C1-C4 alkyl amino, C1-C4 alkoxy, C1-C4 alkoxy halide, or a C1-C4 alkyl halide, form a bicyclic system; Y represents O or NR ; n is 0 or 1; m is 0, 1 or 2; R represents C1-C4 alkyl, C1-C4 alkyl halide or NR R ; R represents C1-C4 alkyl, C1-C4 alkyl halide, C1-C4 alkoxy or NR R ; R represents hydrogen or C1-C4 alkyl; R represents C1-C4 alkyl; Q represents an isoxazole ring connected at position 4 and of formula (II) in which R represents hydrogen or -CO2R , R represents hydrogen, C1-C4 alkyl or C3-C6 cycloalkyl which can optionally be substituted by one or more halogen atoms or C1-C4 alkyl, R representing a C1-C4 alkyl; J represents a carbonyl group CO or a -CHR group, R representing an OH group, a hydroxyl group optionally acylated with C2-C4 acyl, or a chlorine atom. The invention also concerns salts of compounds of formula (I) usually utilized in agriculture.
    • Fomel(I)的异恶唑-4-基 - 苯甲酰基衍生物,其中取代基具有以下含义:L,M是氢,C1-C6烷基,C2-C6链烯基,C2-C6炔基,C1-C4烷氧基, (Y)N S(O)MR <7>或基团 - - (Y)N-CO-,其基团可被一至五个卤素原子或C1-C4烷氧基,任选,卤素,氰基,硝基,的基团取代 [R <8>; Z是5-或6-元杂环的饱和或不饱和基团含有一个,从组氧,硫或氮的选择三个杂原子,任选被卤素取代,氰基,硝基,基团-CO-R <8> C1-C4烷基,C1-C4卤代烷基,C3-C8环烷基,C1-C4烷氧基,C1-C4卤代烷氧基,C1-C4烷硫基,C1-C4卤代烷硫基,二-C 1 -C 4 - 烷基氨基, 任选被卤素,氰基,硝基,C1-C4烷基或C1-C4卤代烷基取代的苯基或氧代基团,其也可以任选地以互变异构形式作为羟基存在,或与稠合的,任选被卤素取代,氰基取代的 ,硝基,C1-C4烷基或C1-C4卤代烷基取代的苯环,稠合碳环或稠合的,任选地被卤素,氰基,硝基,C1-C4烷基取代,二C1-C4烷基氨基,C1-C4- 烷氧基,C1-C4卤代烷氧基,或C1-C4卤代烷基取代的第二Heterocycl 美国形成双环体系; Y是O,NR <9>; n是0或1; m是零,1或2; [R <7> C1-C4烷基,C1-C4卤代烷基,或NR <9> - [R <10>; [R <8> C1-C4烷基,C1-C4卤代烷基,C1-C4烷氧基,或NR <9> - [R <10>; [R <9>是氢或C1-C4烷基; [R <10> C1-C4烷基; Q在位置相连4式的异恶唑(II)其中R <1>是氢或-CO 2 R <3>; [R <2>为氢,可以被一个或多个卤素原子或C1-C4烷基,R是任选取代的C1-C4烷基或C3-C6环烷基<3>是C1-C4烷基; J是羰基或CO基团-CHR <4>; [R <4>为OH基团,任选地被C 2 -C 4酰基羟基或氯原子酰化; 化合物(I)的和农业上常用盐。
    • 9. 发明申请
    • 2-CYANO-1,3-DIONE DERIVATIVES, THE PRODUCTION OF SAME AND THEIR USE AS HERBICIDES
    • 2-氰基-1,3-二酮衍生物,其制备方法及其作为除草剂
    • WO1997019071A1
    • 1997-05-29
    • PCT/EP1996005065
    • 1996-11-18
    • BASF AKTIENGESELLSCHAFTOTTEN, MartinaVON DEYN, WolfgangENGEL, StefanHILL, Regina, LuiseKARDORFF, UweVOSSEN, MarcusPLATH, PeterWALTER, HelmutWESTPHALEN, Karl-OttoMISSLITZ, Ulf
    • BASF AKTIENGESELLSCHAFT
    • C07D335/06
    • C07D275/06A01N43/12A01N43/18C07D333/64C07D333/66C07D335/06
    • The disclosure relates to phenyl diketone derivatives of formula I in which the substituents have the following meanings: L, M - hydrogen, C1-C6 alkyl, C2-C6 alkenyl, C2-C6 alkinyl, C1-C4 alkoxy (these groups being optionally substituted by one to five halogen atoms or C1-C4 alkoxy), halogen, cyano, nitro, a -(A)m-S(O)nR group or a -(A)m-CO-R group; Y - a group consisting of C=O, C=N-R , CR -NR R , CR -OR , CR R , CR -OR , hydrogen- or C1-C4-alkyl-substituted 1,3-dioxanyl or 1,3-dioxolanyl, a heteroatom selected from the group comprising oxygen, sulphur and nitrogen; X consists of a chain (-CR R -), (-CR R -CR R -), (-CR =CR -), (CR R -CR =CR -), or NR ; the bond between X and Y can be saturated or unsaturated; A - O, NR ; m is 0 or 1; n is 0, 1 or 2; R is cyclopropyl, 1-methylcyclopropyl; 1-méthylthiocyclopropyl or tert. butyl; when Y = C=O, X is different from NR . R to R and R to R have the meanings indicated in claim 1. Also disclosed are processes for producing these phenyl diketone derivatives, agents containing them and the use of the derivatives or agents containing them for weed control.
    • 式(I)中,Phenyldiketonderivate其中取代基具有以下含义:L,M是氢,C1-C6烷基,C2-C6链烯基,C2-C6炔基,C1-C4烷氧基,这些基团任选地被一个取代 可以是至多5个卤素原子或C1-C4烷氧基; 卤素,氰基,硝基,基团 - (A)的M-S(O)NR <1>或基团 - (A)的M-CO-R <2>; Y是选自C = O,C = NR <3>,CR <7> -NR <5> - [R <6>,CR <7>是-OR <8>,CR <10> - [R <11>,CR基团 <7> -SR <8>; 用氢或C1-C4烷基取代的1,3-二氧杂环己烷或1,3-二氧戊环基; 选自氧,硫和氮中选择的杂原子; X包括一个链(-CR <12> - [R <13> - )的,(-CR <12> - [R <13> -CR <21> - [R <22> - ),( - CR <12> = CR <13 > - ),( - CR <12> - [R <13> -CR <12> = CR <13> - ); NR <23>是X和Y可以是饱和的或不饱和的之间的键; A为O,NR <14>; m是0或1; n是零,1或2; [R <15>环丙基,1-甲基环丙基,1- Methylthiocyclopropyl或叔丁基; 其中,在Y = C = O,X是除NR <23>,R其它事件<1>至R <14>和R <16>至R <23>具有权利要求1给出的相同含义; 一种用于制备Phenyldiketonderivate的,含有这些药剂,以及使用这些衍生物或含有它们的禾本科杂草/杂草控制组合物的过程。