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    • 3. 发明申请
    • 2-CYANO-1,3-DIONE DERIVATIVES, THE PRODUCTION OF SAME AND THEIR USE AS HERBICIDES
    • 2-氰基-1,3-二酮衍生物,其制备方法及其作为除草剂
    • WO1997019071A1
    • 1997-05-29
    • PCT/EP1996005065
    • 1996-11-18
    • BASF AKTIENGESELLSCHAFTOTTEN, MartinaVON DEYN, WolfgangENGEL, StefanHILL, Regina, LuiseKARDORFF, UweVOSSEN, MarcusPLATH, PeterWALTER, HelmutWESTPHALEN, Karl-OttoMISSLITZ, Ulf
    • BASF AKTIENGESELLSCHAFT
    • C07D335/06
    • C07D275/06A01N43/12A01N43/18C07D333/64C07D333/66C07D335/06
    • The disclosure relates to phenyl diketone derivatives of formula I in which the substituents have the following meanings: L, M - hydrogen, C1-C6 alkyl, C2-C6 alkenyl, C2-C6 alkinyl, C1-C4 alkoxy (these groups being optionally substituted by one to five halogen atoms or C1-C4 alkoxy), halogen, cyano, nitro, a -(A)m-S(O)nR group or a -(A)m-CO-R group; Y - a group consisting of C=O, C=N-R , CR -NR R , CR -OR , CR R , CR -OR , hydrogen- or C1-C4-alkyl-substituted 1,3-dioxanyl or 1,3-dioxolanyl, a heteroatom selected from the group comprising oxygen, sulphur and nitrogen; X consists of a chain (-CR R -), (-CR R -CR R -), (-CR =CR -), (CR R -CR =CR -), or NR ; the bond between X and Y can be saturated or unsaturated; A - O, NR ; m is 0 or 1; n is 0, 1 or 2; R is cyclopropyl, 1-methylcyclopropyl; 1-méthylthiocyclopropyl or tert. butyl; when Y = C=O, X is different from NR . R to R and R to R have the meanings indicated in claim 1. Also disclosed are processes for producing these phenyl diketone derivatives, agents containing them and the use of the derivatives or agents containing them for weed control.
    • 式(I)中,Phenyldiketonderivate其中取代基具有以下含义:L,M是氢,C1-C6烷基,C2-C6链烯基,C2-C6炔基,C1-C4烷氧基,这些基团任选地被一个取代 可以是至多5个卤素原子或C1-C4烷氧基; 卤素,氰基,硝基,基团 - (A)的M-S(O)NR <1>或基团 - (A)的M-CO-R <2>; Y是选自C = O,C = NR <3>,CR <7> -NR <5> - [R <6>,CR <7>是-OR <8>,CR <10> - [R <11>,CR基团 <7> -SR <8>; 用氢或C1-C4烷基取代的1,3-二氧杂环己烷或1,3-二氧戊环基; 选自氧,硫和氮中选择的杂原子; X包括一个链(-CR <12> - [R <13> - )的,(-CR <12> - [R <13> -CR <21> - [R <22> - ),( - CR <12> = CR <13 > - ),( - CR <12> - [R <13> -CR <12> = CR <13> - ); NR <23>是X和Y可以是饱和的或不饱和的之间的键; A为O,NR <14>; m是0或1; n是零,1或2; [R <15>环丙基,1-甲基环丙基,1- Methylthiocyclopropyl或叔丁基; 其中,在Y = C = O,X是除NR <23>,R其它事件<1>至R <14>和R <16>至R <23>具有权利要求1给出的相同含义; 一种用于制备Phenyldiketonderivate的,含有这些药剂,以及使用这些衍生物或含有它们的禾本科杂草/杂草控制组合物的过程。
    • 5. 发明申请
    • HERBICIDAL BENZOYL DERIVATIVES
    • 除草剂苯甲酰
    • WO1996026200A1
    • 1996-08-29
    • PCT/EP1996000593
    • 1996-02-13
    • BASF AKTIENGESELLSCHAFTVON DEYN, WolfgangHILL, Regina, LuiseKARDORFF, UweENGEL, StefanOTTEN, MartinaVOSSEN, MarcusPLATH, PeterRANG, HaraldHARREUS, AlbrechtRÖHL, FranzWALTER, HelmutWESTPHALEN, Karl-OttoMISSLITZ, Ulf
    • BASF AKTIENGESELLSCHAFT
    • C07D307/54
    • C07D271/06A01N43/08A01N43/10A01N43/74A01N43/80C07D261/04C07D261/08C07D263/14C07D263/32C07D277/26C07D307/46C07D333/22
    • The invention concerns benzoyl derivatives of formula (I) in which the substituents have the following meanings: L and M represent hydrogen, C1-C6 alkyl, C2-C6 alkenyl, C2-C6 alkinyl, C1-C4 alkoxy (these groups being optionally substituted by one to five halogen atoms or C1-C4 alkoxy), halogen, cyano, nitro, a -(Y)n-S(O)mR or -(Y)n-CO-R group; Z represents a five to six-membered heterocyclic saturated or unsaturated group containing one to three heteroatoms selected from the group comprising oxygen, sulphur and nitrogen and which can optionally be substituted by halogen, cyano, nitro, a -CO-R group, C1-C4 alkyl, C1-C4 alkyl halide, C3-C8 cycloalkyl, C1-C4 alkoxy, C1-C4 alkoxy halide, C1-C4 alkyl thio, C1-C4 alkyl thio halide, di-C1-C4 alkyl amino, phenyl optionally substituted by halogen, cyano, nitro, C1-C4 alkyl or C1-C4 alkyl halide, or an oxo group which can be present in the tautomeric form as a hydroxy group, is substituted or, together with a condensation-bound phenyl ring which is optionally substituted by halogen or, cyano, nitro, C1-C4 alkyl or C1-C4 alkyl halide, with a condensation-bound carbocycle or with a condensation-bound second heterocycle which can optionally be substituted by halogen, cyano, nitro, C1-C4 alkyl, di-C1-C4 alkyl amino, C1-C4 alkoxy, C1-C4 alkoxy halide or a C1-C4 alkyl halide, forms a bicyclic system; Y represents O or NR ; n is 0 or 1; m is 0, 1 or 2; R represents C1-C4 alkyl, C1-C4 alkyl halide or NR R ; R represents C1-C4 alkyl, C1-C4 alkyl halide, C1-C4 alkoxy or NR R ; R represents hydrogen or C1-C4 alkyl; R represents C1-C4 alkyl; Q represents a cyclohexane-1,2-dione ring connected at position 2 and of formula (II) in which R , R , R and R represent hydrogen or C1-C4 alkyl, R represents hydrogen, C1-C4 alkyl or a -COOR group, R represents hydrogen, C1-C4 alkyl, C3-C6 cycloalkyl, these groups optionally including one to three of the following substituents: halogen, C1-C4 alkyl thio, C1-C4 alkoxy, or R represents tetrahydropropanyl-3, tetrahydropropanyl-4 or tetrahydrothiopyranyl-3, or R and R together form a bond or a three to six-membered carbocyclic ring. The invention also concerns standard agricultural salts of compounds of formula (I) usually utilized in agriculture.
    • 式(I),其中取代基具有以下含义的苯甲酰衍生物:L,M是氢,C1-C6烷基,C2-C6链烯基,C2-C6炔基,C1-C4烷氧基,这些基团任选地被一个取代 可被取代到5个卤素原子或C1-C4烷氧基,卤素,氰基,硝基,基团 - (Y)N S(O)MR <7>或基团 - (Y)N-CO-R <8>,一个 5-或6-元杂环的饱和或含有选自氧,硫或氮中选择的一至三个杂原子的不饱和基团,其任选被卤素,氰基,硝基,基团-CO-R取代的<8>,C1- C4烷基,C1-C4卤代烷基,C3-C8环烷基,C1-C4烷氧基,C1-C4卤代烷氧基,C1-C4烷硫基,C1-C4卤代烷硫基,二-C 1 -C 4 - 烷基氨基,任选地被取代的 卤素,氰基,硝基,C1-C4烷基或C1-C4卤代烷基取代的苯基或氧代基团,其也可以任选地以互变异构形式作为羟基存在,或在一个被取代的 稠合的,任选地被卤素,氰基,硝基,C1-C4烷基或C1-C4卤代烷基的苯环,稠合碳环或稠合的,任选被卤素取代,氰基,硝基,C1-C4烷基,二C1-C4取代的 烷基氨基,C1-C4烷氧基,C1-C4卤代烷氧基,或C1-C4卤代烷基取代的杂环第二形成双环体系; Y是O,NR <9>; n是0或1; m是零,1或2; [R <7> C1-C4烷基,C1-C4卤代烷基,或NR <9> - [R <10>; [R <8> C1-C4烷基,C1-C4卤代烷基,C1-C4烷氧基,或NR <9> - [R <10>; [R <9>是氢或C1-C4烷基; [R <10> C1-C4烷基; Q,R <4>和R <6>表示一个在式环己烷-1,3-二酮环的2位连接(II)其中R <1>,R <2>是氢或C1-C4烷基, [R <5>是氢,C1-C4烷基或基团-COOR <10>,R <3>为氢,C1-C4烷基,C3-C6环烷基,这些基团任选地具有1至3个如下取代基取代的 可以:卤素,C1-C4烷硫基或C1-C4烷氧基,或R <3>为四氢吡喃基-3,四氢吡喃基-4或四氢噻喃基-3,或R <3>和R <5>一起代表一个键或 形成三至六元碳环,和化合物(I)的可农用常用盐。
    • 9. 发明申请
    • TRICYCLIC CYCLOHEXANEDIONE DERIVATIVES
    • 三环环己二酮衍生物
    • WO0059911A2
    • 2000-10-12
    • PCT/EP0002565
    • 2000-03-23
    • BASF AGLANGEMANN KLAUSBAUMANN ERNSTDEYN WOLFGANG VONKUDIS STEFFENMAYER GUIDOMISSLITZ ULFNEIDLEIN ULFWITSCHEL MATTHIASVOLK THORSTENOTTEN MARTINAWESTPHALEN KARL OTTOWALTER HELMUT
    • LANGEMANN KLAUSBAUMANN ERNSTVON DEYN WOLFGANGKUDIS STEFFENMAYER GUIDOMISSLITZ ULFNEIDLEIN ULFWITSCHEL MATTHIASVOLK THORSTENOTTEN MARTINAWESTPHALEN KARL-OTTOWALTER HELMUT
    • A01N43/90C07D495/04C07D498/04
    • C07D495/04A01N43/90
    • The invention relates to tricyclic cyclohexanedione derivatives of formula (I) in which the substituents have the following meaning: R is hydrogen, C1-C6 alkyl, C1-C6 haloalkyl, C1-C6 alkoxy, C1-C6 haloalkoxy, C1-C6 alkylthio, C1-C6 haloalkylthio, C1-C6 alkylsulfinyl, C1-C6 haloalkylsulfinyl, C1-C6 alkylsulfonyl, C1-C6 haloalkylsulfonyl, halogen, cyano or nitro; X is O or NR ; R is hydrogen, C1-C6 alkyl, C1-C6 alkoxy, C1-C6 haloalkyl, C1-C6 haloalkoxy, phenyl that is optionally substituted with C1-C3 alkyl, halogen, cyano, nitro or C1-C3 alkylsulfonyl or phenylsulfonyl that is optionally substituted with C1-C3 alkyl, halogen, cyano or nitro; R , R is hydrogen, C1-C6 alkyl, C1-C6 haloalkyl, C1-C6 alkoxy, C1-C6 haloalkoxy, C1-C6 alkylthio, C1-C6 haloalkylthio, C1-C6 alkylsulfinyl, C1-C6 haloalkylsulfinyl, C1-C6 alkylsulfonyl, C1-C6 haloalkylsulfonyl, NR R , C2-C6 alkoxyalkyl, C1-C6 alkoxycarbonyl, C1-C6 alkylcarbonyl, halogen, cyano, nitro, phenyl that is optionally substituted with C1-C3 alkyl, halogen, cyano or nitro; R is hydrogen or C1-C4 alkyl; R is hydrogen, C1-C6 alkyl or halogen; R is hydrogen or C1-C6 alkyl; R is C1-C6 alkyl or C1-C6 alkoxy; 1 is 0, 1 or 2; n is 1 or 2; R is substituted (3-oxo-1-cyclohexene-2-yl)carbonyl or substituted (1,3-dioxo-2-cyclohexyl)methylidene. The invention also relates to the agriculturally useful salts of the compounds (I), to methods for producing said tricyclic cyclohexanedione derivatives and to the intermediates for their production. The invention encompasses agents containing the inventive compounds and the use of said derivatives or of agents containing them for weed control.
    • (I),式三环环己二酮衍生物,其中取代基具有以下含义:R t <1>为氢,C1-C6烷基,C1-C6卤代烷基,C1-C6-烷氧基,C1-C6卤代烷氧基,C1-C6 烷硫基,C1-C6卤代烷硫基,C1-C6烷基亚磺酰基,C1-C6卤代烷基亚磺酰,C 1 -C 6 - 烷基磺酰基,C1-C6卤代烷基磺酰基,卤素,氰基或硝基; X是O或NR <2>; [R <2>的氢,C1-C6烷基,C1-C6-烷氧基,C1-C6卤代烷基,C1-C6-卤代烷氧基,任选地被C1-C3烷基,卤素,氰基,硝基或C1-C3烷基磺酰基取代的取代的 苯基或任选地被C1-C3烷基,卤素,氰基或硝基取代的苯磺酰基; [R <3>,R <4>为氢,C1-C6烷基,C1-C6卤代烷基,C1-C6-烷氧基,C1-C6卤代烷氧基,C1-C6烷硫基,C1-C6卤代烷硫基,C1-C6 烷基亚磺酰基,C1-C6-卤代烷基亚磺酰,C 1 -C 6 - 烷基磺酰基,C1-C6卤代烷基磺酰基,NR <7> - [R <8>,C2-C6烷氧基烷基,C1-C6烷氧羰基,C1-C6烷基羰基,卤素, 氰基,硝基,任选地被C1-C3烷基,卤素,氰基或硝基取代; [R <5>是氢或C1-C4烷基; [R <6>为氢,C1-C6烷基或卤素; [R <7>是氢或C1-C6烷基; [R <8> C1-C6烷基或C1-C6烷氧基; 1 0,1或2; n是1或2; [R <9>取代的(3-氧代-1-环己烯-2-基)羰基,或取代的(1,3-二氧代-2-环己基)亚甲基; 和化合物(I)的可农用盐,用于制备三环环己二酮衍生物以及中间体其制备方法,含有它们的组合物,以及使用这些衍生物或组合物的包含它们的用于控制杂草的方法。