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    • 1. 发明申请
    • DICYANO ALKANOIC ACID AMIDES FOR COMBATING ANIMAL PESTS
    • DICYANO ALKANOIC ACIDES用于组合动物乳制品
    • WO2007014899A1
    • 2007-02-08
    • PCT/EP2006/064728
    • 2006-07-27
    • BASF AKTIENGESELLSCHAFTHOFMANN, MichaelBASTIAANS, Henricus, Maria, MartinusLANGEWALD, JürgenOLOUMI-SADEGHI, HassanCULBERTSON, Deborah, L.
    • HOFMANN, MichaelBASTIAANS, Henricus, Maria, MartinusLANGEWALD, JürgenOLOUMI-SADEGHI, HassanCULBERTSON, Deborah, L.
    • A01N37/34C07C255/19C07C253/30
    • A01N37/34C07C255/19C07C255/20C07C255/21C07C317/44
    • Dicyano alkanoic acid amides of formula (I), wherein R 1 is H, alkyl, haloalkyl, alkenyl, haloalkenyl, alkynyl, or haloalkynyl; R 2 is H, CN, alkyl, haloalkyl, alkenyl, haloalkenyl, alkynyl, haloalkynyl, cycloalkyl, halocycloalkyl, alkoxy, or haloalkoxy; R 3 and R 4 are H, alkyl, haloalkyl, alkenyl, haloalkenyl, alkynyl, haloalkynyl, cycloalkyl, halocycloalkyl, cycloalkenyl, halocycloalkenyl, or R 3 and R 4 together can be alkylene, haloalkylene, alkenylene or haloalkenylene; X is O or S; R 5 and R 6 are H, alkyl, optionally substituted with 1 to 3 groups CN, NO 2 , OH, NR 7 R 8 , alkoxy, haloalkoxy, alkylthio, haloalkylthio, cycloalkyl, halocycloalkyl and optionally substituted phenyl; or haloalkyl, cycloalkyl, halocycloalkyl, alkenyl, haloalkenyl, alkynyl, haloalkynyl, alkylsulfinyl, haloalkylsulfinyl, alkylsulfonyl, haloalkylsulfonyl, NR 7 R 8 , alkoxycarbonyl, haloalkoxycarbonyl, alkenyloxycarbonyl, haloalkenyloxycarbonyl, alkylcarbonyl, haloalkylcarbonyl, R 7 R 8 N-C(=O)-, phenylcarbonyl, benzylcarbonyl or phenyl wherein phenylcarbonyl, benzylcarbonyl and phenyl are optionally substituted; or R 5 and R 6 are a saturated, partially unsaturated or unsaturated 5- to 6-membered heterocyclic radical which may contain 1 to 4 heteroatoms selected from oxygen, nitrogen and sulfur and which radical may be bonded via a carbonyl (C(=O)) linkage, and which radical is optionally substituted; R 7 , R 8 are H, alkyl, haloalkyl, alkylcarbonyl, haloalkylcarbonyl, benzyl, phenyl, phenylcarbonyl, alkylsulfonyl, or haloalkylsulfonyl; or the enantiomers or diastereomers or salts thereof, processes for the preparation of compounds of formula (I), use of compounds of formula (I) for combating insects, acarids, or nematodes, and a method for treating, controlling, preventing or protecting animals against infestation or infection by parasites using compounds of formula (I).
    • 式(I)的二氰基链烷酸酰胺,其中R 1是H,烷基,卤代烷基,烯基,卤代烯基,炔基或卤代炔基; R 2是H,CN,烷基,卤代烷基,烯基,卤代烯基,炔基,卤代炔基,环烷基,卤代环烷基,烷氧基或卤代烷氧基。 R 3和R 4是H,烷基,卤代烷基,烯基,卤代烯基,炔基,卤代炔基,环烷基,卤代环烷基,环烯基,卤代环烯基或R 3, SO 2和R 4一起可以是亚烷基,卤代亚烷基,亚烯基或卤代亚烯基; X是O或S; R 5和R 6是H,烷基,任选被1至3个基团CN,NO 2,OH,NR 7取代 烷氧基,卤代烷氧基,烷硫基,卤代烷硫基,环烷基,卤代环烷基和任意取代的苯基; 或卤代烷基,环烷基,卤代环烷基,烯基,卤代烯基,炔基,卤代炔基,烷基亚磺酰基,卤代烷基亚磺酰基,烷基磺酰基,卤代烷基磺酰基,NR 8 R 8,烷氧基羰基,卤代烷氧基羰基,烯氧基羰基,卤代链烯氧基羰基, 烷基羰基,卤代烷基羰基,R 7 R 8 NC(= O) - ,苯基羰基,苄基羰基或苯基,其中苯基羰基,苄基羰基和苯基任选被取代; 或R 5和R 6是饱和的,部分不饱和的或不饱和的5至6元杂环基,其可以含有1至4个选自氧,氮和硫的杂原子 并且该基团可以通过羰基(C(= O))键键合,并且该基团任选被取代; R 7,R 8是H,烷基,卤代烷基,烷基羰基,卤代烷基羰基,苄基,苯基,苯基羰基,烷基磺酰基或卤代烷基磺酰基; 或其对映体或非对映异构体或其盐,式(I)化合物的制备方法,式(I)化合物用于防治昆虫,螨虫或线虫的用途,以及用于治疗,控制,预防或保护动物的方法 使用式(I)化合物对寄生虫的感染或感染。
    • 5. 发明申请
    • CYANOPYRIDINE PESTICIDES
    • 氰基吡啶类杀虫剂
    • WO2007014913A1
    • 2007-02-08
    • PCT/EP2006/064788
    • 2006-07-28
    • BASF AKTIENGESELLSCHAFTKAISER, FlorianVON DEYN, WolfgangPOHLMAN, MatthiasBASTIAANS, Henricus, Maria, MartinusANSPAUGH, Douglas, D.CULBERTSON, Deborah, L.COTTER, Henry, Van Tuyl
    • KAISER, FlorianVON DEYN, WolfgangPOHLMAN, MatthiasBASTIAANS, Henricus, Maria, MartinusANSPAUGH, Douglas, D.CULBERTSON, Deborah, L.COTTER, Henry, Van Tuyl
    • C07D213/78A01N43/40
    • C07D213/84C07D213/85
    • The present invention relates to cyanopyridine compounds of the general formula (I) and to the agriculturally useful salts thereof and to compositions comprising such compounds. The invention also relates to the use of the cyanopyridine compounds, of their salts or of compositions comprising them for combating animal pests. In formula (I) n is 0, 1 or 2; X is N, N-O or C-R 4 ; Y is N, N-O or C-R 5 ; Z is N, N-O or C-R 6 ; with the proviso that one of the variables X, Y and Z is N or NO and the other two variables are optionally substituted carbon atoms; R 1 , R 2 are, independently of one another, selected from the group consisting of hydrogen, C(=O)-R 7 , optionally subsitutetd C 1 -C 10 -alkyl, C 2 -C 6 -alkenyl, C 2 -C 10 -alkinyl, C 1 -C 10 -alkoxy or C 3 -C 10 -cycloalkyl, or R 1 and R 2 together with the adjacent nitrogen form a 3 to 10-membered ring, optionally substituted by 1, 2 or 3 radicals selected from C 1 -C 5 -alkyl and halogen, wherein the ring may contain, in addition to the nitrogen and carbon ring members, 1, 2 or 3 heteroatoms as ring members selected from the group consisting of nitrogen, oxygen, sulfur, a group SO, SO 2 or N-R 8 ; R 3 is hydrogen, nitro, cyano, azido, amino, halogen, sulfonylamino, sulfenylamino, sulfinylamino, C(=O)R 9 , C 1 -C 6 -alkyl, C 2 -C 6 -alkenyl, C 2 -C 6 -alkinyl, C 3 -C 8 - cycloalkyl, C 1 -C 6 -alkoxy, C 1 -C 6 -alkylthio, (C 1 -C 6 -alkyl)amino, di(C 1 -C 6 -alkyl)amino, C 1 -C 6 -alkylsulfinyl, or C 1 -C 6 -alkylsulfonyl, R 4 , R 5 and R 6 are independently of one another selected from the group consisting of hydrogen, halogen, cyano, azido, nitro, C 1 -C 6 -alkyl, C 3 -C 8 -cycloalkyl, C 1 -C 4 -haloalkyl, C 1 -C 4 -alkoxy, C 1 -C 4 -alkylthio, C 1 -C 4 -alkylsulfinyl, C 1 -C 4 -alkylsulfonyl, C 1 -C 4 -haloalkoxy, C 1 -C 4 -haloalkylthio, C 2 -C 6 -alkenyl, C 2 -C 6 -alkinyl, (C 1 -C 4 -alkoxy)carbonyl, amino, (C 1 -C 4 -alkyl)amino, di(C 1 -C 4 -alkyl)amino, aminocarbonyl, (C 1 -C 4 -alkyl)aminocarbonyl, di(C 1 -C 4 -alkyl)aminocarbonyl, hydroxysulfonyl, sulfonylamino, sulfenylamino, sulfinylamino and C(=O)-R 10 .
    • 本发明涉及通式(I)的氰基吡啶化合物及其农业上有用的盐以及包含这些化合物的组合物。 本发明还涉及氰基吡啶化合物,其盐或包含它们的组合物用于对抗动物害虫的用途。 在式(I)中,n为0,1或2; X是N,N-O或C-R 4; Y是N,N-O或C-R 5; Z是N,N-O或C-R 6; 条件是变量X,Y和Z之一为N或NO,另外两个变量为任选取代的碳原子; R 1,R 2,R 2彼此独立地选自氢,C(= O)-R 7, 任选地取代C 1 -C 10 - 烷基,C 2 -C 6 - 烯基,C 1 -C 6 - C 1 -C 10 - 烷基,C 1 -C 10 - 烷氧基或C 3 - C 10 - 环烷基或R 1和R 2与相邻的氮一起形成3至10元环,任选被1个 ,选自C 1 -C 5 - 烷基和卤素的2或3个基团,其中除了氮和碳环成员之外,环可以含有1,2 或3个杂原子作为选自氮,氧,硫,SO 2,SO 2或NR 8的环成员。 R 3是氢,硝基,氰基,叠氮基,氨基,卤素,磺酰基氨基,亚磺酰氨基,亚磺酰氨基,C(= O)R 9,C 1, C 1 -C 6 - 烷基,C 2 -C 6 - 烯基,C 2-C≡S C 6 - 烷基,C 3 -C 8 - 环烷基,C 1 -C 6 - - 烷氧基,C 1 -C 6 - 烷硫基,(C 1 -C 6 - 烷基)氨基, (C 1 -C 6 - 烷基)氨基,C 1 -C 6 - 烷基亚磺酰基或C(C 1 -C 6 - C 1 -C 6烷基磺酰基,R 4,R 5和R 6, 独立地选自氢,卤素,氰基,叠氮基,硝基,C 1 -C 6 - 烷基,C 3 - C 1 -C 8 - 环烷基,C 1 -C 4 - 卤代烷基,C 1 -C 3 C 1-4烷氧基,C 1 -C 4 - 烷硫基,C 1 -C 4烷基, - 烷基亚磺酰基,C 1 -C 4 - 烷基磺酰基,C 1 -C 4 - 卤代烷氧基 ,C 1 -C 4 - 卤代烷硫基,C 2 -C 6 - 烯基,C 2 C 1 -C 6 - 炔基,(C 1 -C 4 - 烷氧基)羰基,氨基,(C 1 -C 6 - (C 1 -C 4 - 烷基)氨基,氨基羰基,(C 1 -C 4 - 氨基羰基,二(C 1 -C 4 -C 4 - 烷基)氨基羰基,羟基磺酰基,二(C 1 -C 4 - 磺酰氨基,亚磺酰基氨基,亚磺酰氨基和C(= O)-R 10。