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    • 8. 发明申请
    • CYANOPYRIDINE PESTICIDES
    • 氰基吡啶类杀虫剂
    • WO2007014913A1
    • 2007-02-08
    • PCT/EP2006/064788
    • 2006-07-28
    • BASF AKTIENGESELLSCHAFTKAISER, FlorianVON DEYN, WolfgangPOHLMAN, MatthiasBASTIAANS, Henricus, Maria, MartinusANSPAUGH, Douglas, D.CULBERTSON, Deborah, L.COTTER, Henry, Van Tuyl
    • KAISER, FlorianVON DEYN, WolfgangPOHLMAN, MatthiasBASTIAANS, Henricus, Maria, MartinusANSPAUGH, Douglas, D.CULBERTSON, Deborah, L.COTTER, Henry, Van Tuyl
    • C07D213/78A01N43/40
    • C07D213/84C07D213/85
    • The present invention relates to cyanopyridine compounds of the general formula (I) and to the agriculturally useful salts thereof and to compositions comprising such compounds. The invention also relates to the use of the cyanopyridine compounds, of their salts or of compositions comprising them for combating animal pests. In formula (I) n is 0, 1 or 2; X is N, N-O or C-R 4 ; Y is N, N-O or C-R 5 ; Z is N, N-O or C-R 6 ; with the proviso that one of the variables X, Y and Z is N or NO and the other two variables are optionally substituted carbon atoms; R 1 , R 2 are, independently of one another, selected from the group consisting of hydrogen, C(=O)-R 7 , optionally subsitutetd C 1 -C 10 -alkyl, C 2 -C 6 -alkenyl, C 2 -C 10 -alkinyl, C 1 -C 10 -alkoxy or C 3 -C 10 -cycloalkyl, or R 1 and R 2 together with the adjacent nitrogen form a 3 to 10-membered ring, optionally substituted by 1, 2 or 3 radicals selected from C 1 -C 5 -alkyl and halogen, wherein the ring may contain, in addition to the nitrogen and carbon ring members, 1, 2 or 3 heteroatoms as ring members selected from the group consisting of nitrogen, oxygen, sulfur, a group SO, SO 2 or N-R 8 ; R 3 is hydrogen, nitro, cyano, azido, amino, halogen, sulfonylamino, sulfenylamino, sulfinylamino, C(=O)R 9 , C 1 -C 6 -alkyl, C 2 -C 6 -alkenyl, C 2 -C 6 -alkinyl, C 3 -C 8 - cycloalkyl, C 1 -C 6 -alkoxy, C 1 -C 6 -alkylthio, (C 1 -C 6 -alkyl)amino, di(C 1 -C 6 -alkyl)amino, C 1 -C 6 -alkylsulfinyl, or C 1 -C 6 -alkylsulfonyl, R 4 , R 5 and R 6 are independently of one another selected from the group consisting of hydrogen, halogen, cyano, azido, nitro, C 1 -C 6 -alkyl, C 3 -C 8 -cycloalkyl, C 1 -C 4 -haloalkyl, C 1 -C 4 -alkoxy, C 1 -C 4 -alkylthio, C 1 -C 4 -alkylsulfinyl, C 1 -C 4 -alkylsulfonyl, C 1 -C 4 -haloalkoxy, C 1 -C 4 -haloalkylthio, C 2 -C 6 -alkenyl, C 2 -C 6 -alkinyl, (C 1 -C 4 -alkoxy)carbonyl, amino, (C 1 -C 4 -alkyl)amino, di(C 1 -C 4 -alkyl)amino, aminocarbonyl, (C 1 -C 4 -alkyl)aminocarbonyl, di(C 1 -C 4 -alkyl)aminocarbonyl, hydroxysulfonyl, sulfonylamino, sulfenylamino, sulfinylamino and C(=O)-R 10 .
    • 本发明涉及通式(I)的氰基吡啶化合物及其农业上有用的盐以及包含这些化合物的组合物。 本发明还涉及氰基吡啶化合物,其盐或包含它们的组合物用于对抗动物害虫的用途。 在式(I)中,n为0,1或2; X是N,N-O或C-R 4; Y是N,N-O或C-R 5; Z是N,N-O或C-R 6; 条件是变量X,Y和Z之一为N或NO,另外两个变量为任选取代的碳原子; R 1,R 2,R 2彼此独立地选自氢,C(= O)-R 7, 任选地取代C 1 -C 10 - 烷基,C 2 -C 6 - 烯基,C 1 -C 6 - C 1 -C 10 - 烷基,C 1 -C 10 - 烷氧基或C 3 - C 10 - 环烷基或R 1和R 2与相邻的氮一起形成3至10元环,任选被1个 ,选自C 1 -C 5 - 烷基和卤素的2或3个基团,其中除了氮和碳环成员之外,环可以含有1,2 或3个杂原子作为选自氮,氧,硫,SO 2,SO 2或NR 8的环成员。 R 3是氢,硝基,氰基,叠氮基,氨基,卤素,磺酰基氨基,亚磺酰氨基,亚磺酰氨基,C(= O)R 9,C 1, C 1 -C 6 - 烷基,C 2 -C 6 - 烯基,C 2-C≡S C 6 - 烷基,C 3 -C 8 - 环烷基,C 1 -C 6 - - 烷氧基,C 1 -C 6 - 烷硫基,(C 1 -C 6 - 烷基)氨基, (C 1 -C 6 - 烷基)氨基,C 1 -C 6 - 烷基亚磺酰基或C(C 1 -C 6 - C 1 -C 6烷基磺酰基,R 4,R 5和R 6, 独立地选自氢,卤素,氰基,叠氮基,硝基,C 1 -C 6 - 烷基,C 3 - C 1 -C 8 - 环烷基,C 1 -C 4 - 卤代烷基,C 1 -C 3 C 1-4烷氧基,C 1 -C 4 - 烷硫基,C 1 -C 4烷基, - 烷基亚磺酰基,C 1 -C 4 - 烷基磺酰基,C 1 -C 4 - 卤代烷氧基 ,C 1 -C 4 - 卤代烷硫基,C 2 -C 6 - 烯基,C 2 C 1 -C 6 - 炔基,(C 1 -C 4 - 烷氧基)羰基,氨基,(C 1 -C 6 - (C 1 -C 4 - 烷基)氨基,氨基羰基,(C 1 -C 4 - 氨基羰基,二(C 1 -C 4 -C 4 - 烷基)氨基羰基,羟基磺酰基,二(C 1 -C 4 - 磺酰氨基,亚磺酰基氨基,亚磺酰氨基和C(= O)-R 10。