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    • 4. 发明申请
    • CYANOPYRIDINE PESTICIDES
    • 氰基吡啶类杀虫剂
    • WO2007014913A1
    • 2007-02-08
    • PCT/EP2006/064788
    • 2006-07-28
    • BASF AKTIENGESELLSCHAFTKAISER, FlorianVON DEYN, WolfgangPOHLMAN, MatthiasBASTIAANS, Henricus, Maria, MartinusANSPAUGH, Douglas, D.CULBERTSON, Deborah, L.COTTER, Henry, Van Tuyl
    • KAISER, FlorianVON DEYN, WolfgangPOHLMAN, MatthiasBASTIAANS, Henricus, Maria, MartinusANSPAUGH, Douglas, D.CULBERTSON, Deborah, L.COTTER, Henry, Van Tuyl
    • C07D213/78A01N43/40
    • C07D213/84C07D213/85
    • The present invention relates to cyanopyridine compounds of the general formula (I) and to the agriculturally useful salts thereof and to compositions comprising such compounds. The invention also relates to the use of the cyanopyridine compounds, of their salts or of compositions comprising them for combating animal pests. In formula (I) n is 0, 1 or 2; X is N, N-O or C-R 4 ; Y is N, N-O or C-R 5 ; Z is N, N-O or C-R 6 ; with the proviso that one of the variables X, Y and Z is N or NO and the other two variables are optionally substituted carbon atoms; R 1 , R 2 are, independently of one another, selected from the group consisting of hydrogen, C(=O)-R 7 , optionally subsitutetd C 1 -C 10 -alkyl, C 2 -C 6 -alkenyl, C 2 -C 10 -alkinyl, C 1 -C 10 -alkoxy or C 3 -C 10 -cycloalkyl, or R 1 and R 2 together with the adjacent nitrogen form a 3 to 10-membered ring, optionally substituted by 1, 2 or 3 radicals selected from C 1 -C 5 -alkyl and halogen, wherein the ring may contain, in addition to the nitrogen and carbon ring members, 1, 2 or 3 heteroatoms as ring members selected from the group consisting of nitrogen, oxygen, sulfur, a group SO, SO 2 or N-R 8 ; R 3 is hydrogen, nitro, cyano, azido, amino, halogen, sulfonylamino, sulfenylamino, sulfinylamino, C(=O)R 9 , C 1 -C 6 -alkyl, C 2 -C 6 -alkenyl, C 2 -C 6 -alkinyl, C 3 -C 8 - cycloalkyl, C 1 -C 6 -alkoxy, C 1 -C 6 -alkylthio, (C 1 -C 6 -alkyl)amino, di(C 1 -C 6 -alkyl)amino, C 1 -C 6 -alkylsulfinyl, or C 1 -C 6 -alkylsulfonyl, R 4 , R 5 and R 6 are independently of one another selected from the group consisting of hydrogen, halogen, cyano, azido, nitro, C 1 -C 6 -alkyl, C 3 -C 8 -cycloalkyl, C 1 -C 4 -haloalkyl, C 1 -C 4 -alkoxy, C 1 -C 4 -alkylthio, C 1 -C 4 -alkylsulfinyl, C 1 -C 4 -alkylsulfonyl, C 1 -C 4 -haloalkoxy, C 1 -C 4 -haloalkylthio, C 2 -C 6 -alkenyl, C 2 -C 6 -alkinyl, (C 1 -C 4 -alkoxy)carbonyl, amino, (C 1 -C 4 -alkyl)amino, di(C 1 -C 4 -alkyl)amino, aminocarbonyl, (C 1 -C 4 -alkyl)aminocarbonyl, di(C 1 -C 4 -alkyl)aminocarbonyl, hydroxysulfonyl, sulfonylamino, sulfenylamino, sulfinylamino and C(=O)-R 10 .
    • 本发明涉及通式(I)的氰基吡啶化合物及其农业上有用的盐以及包含这些化合物的组合物。 本发明还涉及氰基吡啶化合物,其盐或包含它们的组合物用于对抗动物害虫的用途。 在式(I)中,n为0,1或2; X是N,N-O或C-R 4; Y是N,N-O或C-R 5; Z是N,N-O或C-R 6; 条件是变量X,Y和Z之一为N或NO,另外两个变量为任选取代的碳原子; R 1,R 2,R 2彼此独立地选自氢,C(= O)-R 7, 任选地取代C 1 -C 10 - 烷基,C 2 -C 6 - 烯基,C 1 -C 6 - C 1 -C 10 - 烷基,C 1 -C 10 - 烷氧基或C 3 - C 10 - 环烷基或R 1和R 2与相邻的氮一起形成3至10元环,任选被1个 ,选自C 1 -C 5 - 烷基和卤素的2或3个基团,其中除了氮和碳环成员之外,环可以含有1,2 或3个杂原子作为选自氮,氧,硫,SO 2,SO 2或NR 8的环成员。 R 3是氢,硝基,氰基,叠氮基,氨基,卤素,磺酰基氨基,亚磺酰氨基,亚磺酰氨基,C(= O)R 9,C 1, C 1 -C 6 - 烷基,C 2 -C 6 - 烯基,C 2-C≡S C 6 - 烷基,C 3 -C 8 - 环烷基,C 1 -C 6 - - 烷氧基,C 1 -C 6 - 烷硫基,(C 1 -C 6 - 烷基)氨基, (C 1 -C 6 - 烷基)氨基,C 1 -C 6 - 烷基亚磺酰基或C(C 1 -C 6 - C 1 -C 6烷基磺酰基,R 4,R 5和R 6, 独立地选自氢,卤素,氰基,叠氮基,硝基,C 1 -C 6 - 烷基,C 3 - C 1 -C 8 - 环烷基,C 1 -C 4 - 卤代烷基,C 1 -C 3 C 1-4烷氧基,C 1 -C 4 - 烷硫基,C 1 -C 4烷基, - 烷基亚磺酰基,C 1 -C 4 - 烷基磺酰基,C 1 -C 4 - 卤代烷氧基 ,C 1 -C 4 - 卤代烷硫基,C 2 -C 6 - 烯基,C 2 C 1 -C 6 - 炔基,(C 1 -C 4 - 烷氧基)羰基,氨基,(C 1 -C 6 - (C 1 -C 4 - 烷基)氨基,氨基羰基,(C 1 -C 4 - 氨基羰基,二(C 1 -C 4 -C 4 - 烷基)氨基羰基,羟基磺酰基,二(C 1 -C 4 - 磺酰氨基,亚磺酰基氨基,亚磺酰氨基和C(= O)-R 10。
    • 7. 发明申请
    • PYRIDAZINE COMPOUNDS FOR CONTROLLING INVERTEBRATE PESTS
    • 用于控制反相胶束的吡啶化合物
    • WO2011003793A1
    • 2011-01-13
    • PCT/EP2010/059329
    • 2010-07-01
    • BASF SEVEZOUET, Ronan LeSÖRGEL, SebastianDEFIEBER, ChristianGROß, SteffenKÖRBER, KarstenCULBERTSON, Deborah, L.ANSPAUGH, Douglas, D.
    • VEZOUET, Ronan LeSÖRGEL, SebastianDEFIEBER, ChristianGROß, SteffenKÖRBER, KarstenCULBERTSON, Deborah, L.ANSPAUGH, Douglas, D.
    • C07D413/12C07D417/12A01N43/80
    • C07D417/12A01N43/80A01N53/00C07D413/12
    • The present invention relates to pyridazine compounds of formulae (I) or (II) and the salts and N-oxides thereof, wherein A is a substituted or unsubstituted isoxazole or isothiazole radical; V is C(R v ) or N; W is C(R w ) or N; with the proviso that either V or W is N; R t , R u , R v , R w are H, halogen, C 1 -C 4 -alkyl and the like; X 1 is S, O or NR 1a , wherein R 1a is selected H, C 1 -C 10 -alkyl and the like; X 2 is OR 2a , NR 2b R 2c , S(O) m R 2d , wherein m is 0, 1 or 2, R 2a is C 1 -C 4 -alkyl, C 1 -C 4 -haloalkyl and the like, R 2b , R 2c are H, C 1 -C 4 -alkyl, C 1 -C 4 -haloalkyl and the like, or R 2b and R 2c together with the nitrogen atom to which they are bound form a heterocycle, and R 2d is C 1 -C 4 -alkyl, C 1 -C 4 -haloalkyl, C 3 -C 6 -cycloalkyl and the like; and R 1 is H, CN, C 1 -C 10 -alkyl and the like. The present invention further relates to a method for controlling invertebrate pests, to a method for protecting plant propagation material and/or the plants which grow there- from, to plant propagation material, comprising at least one compound according to the present invention, to a method for treating or protecting an animal from infestation or infection by parasites and to an agricultural composition containing at least one compound according to the present invention.
    • 本发明涉及式(I)或(II)的哒嗪化合物及其盐和N-氧化物,其中A是取代或未取代的异恶唑或异噻唑基; V是C(Rv)或N; W是C(Rw)或N; 条件是V或W为N; R 1,R u,R v,R w为H,卤素,C 1 -C 4 - 烷基等; X1是S,O或NR1a,其中R1a选自H,C1-C10-烷基等; X2是OR2a,NR2bR2c,S(O)mR2d,其中m是0,1或2,R2a是C1-C4-烷基,C1-C4-卤代烷基等,R2b,R2c是H,C1-C4-烷基, C1-C4卤代烷基等,或R2b和R2c与它们所结合的氮原子一起形成杂环,R2d是C1-C4-烷基,C1-C4卤代烷基,C3-C6-环烷基等 ; R1为H,CN,C1-C10-烷基等。 本发明还涉及一种控制无脊椎害虫的方法,一种用于保护植物繁殖材料和/或在其上生长的植物的方法,包括至少一种根据本发明的化合物的植物繁殖材料, 用于治疗或保护动物免受寄生虫感染或感染的方法以及含有至少一种本发明化合物的农药组合物。
    • 9. 发明申请
    • PYRIDINE COMPOUNDS FOR CONTROLLING INVERTEBRATE PESTS III
    • 用于控制反相胶束的吡啶化合物
    • WO2012034959A2
    • 2012-03-22
    • PCT/EP2011/065708
    • 2011-09-12
    • BASF SESÖRGEL, SebastianDEFIEBER, ChristianLE VEZOUET, RonanGROß, SteffenKÖRBER, KarstenCULBERTSON, Deborah, L.ANSPAUGH, Douglas, D.
    • SÖRGEL, SebastianDEFIEBER, ChristianLE VEZOUET, RonanGROß, SteffenKÖRBER, KarstenCULBERTSON, Deborah, L.ANSPAUGH, Douglas, D.
    • A01N43/40A01N43/54A01N43/58A01N43/60A01N25/00
    • The present invention relates to a method for controlling invertebrate pests, in particular arthropod pests and nematodes, by using pyridine compounds of formulae (I) or (II) and the salts thereof, the tautomers thereof, the N-oxides thereof and the salts of the tautomers or N-oxides thereof, where the radical A is of the formula (A), wherein # denotes the point of attachment to the remainder of formulae (I) or (II), and wherein A 1 is N or C-R A1 , A 2 is N or C-R A2 , A 3 is N or C-R A3 , A 4 is N or C-R A4 and A 5 is N or C-R A5 , provided that one or two of the variables A 1 , A 2 , A 3 , A 4 or A 5 is N; R A1 , R A5 , if present, are H, halogen, CN, NO 2 , C 1 -C 6 -alkyl, C 1 -C 6 -haloalkyl and the like; R A2 , R A4 , if present, are H, halogen, CN, NO 2 , C 1 -C 10 -alkyl, C 1 -C 10 -haloalkyl and the like; R A3 , if present, is H, halogen, CN, NO 2 , C 1 -C 10 -alkyl, C 1 -C 10 -haloalkyl and the like; R 1 is H, CN, C 1 -C 10 - alkyl, C 1 -C 10 -haloalkyl and the like; R 2 is H, halogen, methyl, C 1 -haloalkyl and the like; R 3 is H, halogen, C 1 -C 4 -alkyl, C 1 -C 3 -haloalkyl and the like; X 1 is S, O or NR 1a , wherein R 1a is H, C 1 -C 10 -alkyl and the like; X 2 is OR 2a , NR 2b R 2c or S(O) m R 2d , wherein m is 0, 1 or 2, R 2a is C 1 -C 4 -alkyl, C 1 -C 4 -haloalkyl and the like, R 2b and R 2c are H, C 1 -C 4 -alkyl, C 1 -C 4 - haloalkyl and the like, or R 2b and R 2c together with the nitrogen atom to which they are bound form a heterocycle, and R 2d is C 1 -C 4 -alkyl, C 1 -C 4 -haloalkyl, C 3 -C 6 -cycloalkyl and the like. The present invention further relates to a method for protecting plant propagation material and/or the plants which grow therefrom, to plant propagation material, comprising at least one compound of formulae (I) or (II), their salts or N-oxides, and to an agricultural composition containing at least one compound of formulae (I) or (II), their salts or N-oxides.
    • 本发明涉及通过使用式(I)或(II)的吡啶化合物及其盐,其互变异构体,其N-氧化物和其盐的方法来控制无脊椎害虫,特别是节肢动物害虫和线虫的方法 其中基团A为式(A)的互变异构体或N-氧化物,其中#表示与式(I)或(II)的其余部分的连接点,其中A1为N或C-RA1, A2是N或C-RA2,A3是N或C-RA3,A4是N或C-RA4,A5是N或C-RA5,条件是变量A1,A2,A3,A4或A5中的一个或两个是 N; RA1,RA5如果存在,是H,卤素,CN,NO 2,C 1 -C 6 - 烷基,C 1 -C 6 - 卤代烷基等; RA2,RA4如果存在,是H,卤素,CN,NO 2,C 1 -C 10 - 烷基,C 1 -C 10 - 卤代烷基等; 如果存在,RA 3是H,卤素,CN,NO 2,C 1 -C 10 - 烷基,C 1 -C 10 - 卤代烷基等; R1是H,CN,C1-C10-烷基,C1-C10-卤代烷基等; R 2是H,卤素,甲基,C 1 - 卤代烷基等; R3是H,卤素,C1-C4烷基,C1-C3-卤代烷基等; X1是S,O或NR1a,其中R1a是H,C1-C10-烷基等; X2是OR2a,NR2bR2c或S(O)mR2d,其中m是0,1或2,R2a是C1-C4-烷基,C1-C4-卤代烷基等,R2b和R2c是H,C1-C4-烷基, C1-C4卤代烷基等,或R2b和R2c与它们所连接的氮原子一起形成杂环,R2d是C1-C4-烷基,C1-C4卤代烷基,C3-C6-环烷基等 。 本发明还涉及一种保护植物繁殖材料和/或从其生长的植物的方法,包括至少一种式(I)或(II)化合物,其盐或N-氧化物的植物繁殖材料,以及 涉及含有至少一种式(I)或(II)化合物,其盐或N-氧化物的农业组合物。
    • 10. 发明申请
    • PYRIDAZINE COMPOUNDS FOR CONTROLLING INVERTEBRATE PESTS
    • 用于控制反相胶束的吡啶化合物
    • WO2011003796A1
    • 2011-01-13
    • PCT/EP2010/059333
    • 2010-07-01
    • BASF SELe VEZOUET, RonanSÖRGEL, SebastianDEFIEBER, ChristianGROß, SteffenKÖRBER, KarstenCULBERTSON, Deborah, L.ANSPAUGH, Douglas, D.
    • Le VEZOUET, RonanSÖRGEL, SebastianDEFIEBER, ChristianGROß, SteffenKÖRBER, KarstenCULBERTSON, Deborah, L.ANSPAUGH, Douglas, D.
    • C07D403/12C07D413/12C07D417/12A01N43/58A01N43/76A01N43/78
    • C07D417/12A01N43/58A01N43/76A01N43/78C07D403/12C07D413/12
    • The present invention relates to pyridazine compounds of formulae (I) or (Il) and the salts and N-oxides thereof, wherein A is a substituted or unsubstituted oxazole or thiazole or imidazole radical; V is C(R V ) or N; W is C(R W ) or N; with the proviso that either V or W is N; R t , R u , R v , R w are H, halogen, C 1 -C 4 -alkyl and the like; X 1 is S, O or NR 1a , wherein R 1a is selected H, C 1 -C 10 -alkyl and the like; X 2 is OR 2a , NR 2b R 2c , S(O) m R 2d , wherein m is 0, 1 or 2, R 2a is C 1 -C 4 -alkyl, C 1 -C 4 -haloalkyl and the like, R 2b , R 2c are H, C 1 -C 4 -alkyl, C 1 -C 4 -haloalkyl and the like, or R 2b and R 2c together with the nitrogen atom to which they are bound form a heterocycle, and R 2d is C 1 -C 4 -alkyl, C 1 -C 4 -haloalkyl, C 3 -C 6 -cycloalkyl and the like; and R 1 is H, CN, C 1 -C 10 -alkyl and the like. The present invention further relates to a method for controlling invertebrate pests, to a method for protecting plant propagation material and/or the plants which grow therefrom, to plant propagation material, comprising at least one compound according to the present invention, to a method for treating or protecting an animal from infestation or infection by parasites and to an agricultural composition containing at least one compound according to the present invention.
    • 本发明涉及式(I)或(II)的哒嗪化合物及其盐和N-氧化物,其中A是取代或未取代的恶唑或噻唑或咪唑基; V为C(RV)或N; W为C(RW)或N; 条件是V或W为N; R 1,R u,R v,R w为H,卤素,C 1 -C 4 - 烷基等; X1是S,O或NR1a,其中R1a选自H,C1-C10-烷基等; X2是OR2a,NR2bR2c,S(O)mR2d,其中m是0,1或2,R2a是C1-C4-烷基,C1-C4-卤代烷基等,R2b,R2c是H,C1-C4-烷基, C1-C4卤代烷基等,或R2b和R2c与它们所结合的氮原子一起形成杂环,R2d是C1-C4-烷基,C1-C4卤代烷基,C3-C6-环烷基等 ; R1为H,CN,C1-C10-烷基等。 本发明还涉及一种控制无脊椎害虫的方法,一种用于保护植物繁殖材料和/或从其生长的植物的方法,包括至少一种根据本发明的化合物的植物繁殖材料的方法, 治疗或保护动物免受寄生虫侵袭或感染,以及含有至少一种本发明化合物的农药组合物。