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    • 6. 发明申请
    • CYANOPYRIDINE PESTICIDES
    • 氰基吡啶类杀虫剂
    • WO2007014913A1
    • 2007-02-08
    • PCT/EP2006/064788
    • 2006-07-28
    • BASF AKTIENGESELLSCHAFTKAISER, FlorianVON DEYN, WolfgangPOHLMAN, MatthiasBASTIAANS, Henricus, Maria, MartinusANSPAUGH, Douglas, D.CULBERTSON, Deborah, L.COTTER, Henry, Van Tuyl
    • KAISER, FlorianVON DEYN, WolfgangPOHLMAN, MatthiasBASTIAANS, Henricus, Maria, MartinusANSPAUGH, Douglas, D.CULBERTSON, Deborah, L.COTTER, Henry, Van Tuyl
    • C07D213/78A01N43/40
    • C07D213/84C07D213/85
    • The present invention relates to cyanopyridine compounds of the general formula (I) and to the agriculturally useful salts thereof and to compositions comprising such compounds. The invention also relates to the use of the cyanopyridine compounds, of their salts or of compositions comprising them for combating animal pests. In formula (I) n is 0, 1 or 2; X is N, N-O or C-R 4 ; Y is N, N-O or C-R 5 ; Z is N, N-O or C-R 6 ; with the proviso that one of the variables X, Y and Z is N or NO and the other two variables are optionally substituted carbon atoms; R 1 , R 2 are, independently of one another, selected from the group consisting of hydrogen, C(=O)-R 7 , optionally subsitutetd C 1 -C 10 -alkyl, C 2 -C 6 -alkenyl, C 2 -C 10 -alkinyl, C 1 -C 10 -alkoxy or C 3 -C 10 -cycloalkyl, or R 1 and R 2 together with the adjacent nitrogen form a 3 to 10-membered ring, optionally substituted by 1, 2 or 3 radicals selected from C 1 -C 5 -alkyl and halogen, wherein the ring may contain, in addition to the nitrogen and carbon ring members, 1, 2 or 3 heteroatoms as ring members selected from the group consisting of nitrogen, oxygen, sulfur, a group SO, SO 2 or N-R 8 ; R 3 is hydrogen, nitro, cyano, azido, amino, halogen, sulfonylamino, sulfenylamino, sulfinylamino, C(=O)R 9 , C 1 -C 6 -alkyl, C 2 -C 6 -alkenyl, C 2 -C 6 -alkinyl, C 3 -C 8 - cycloalkyl, C 1 -C 6 -alkoxy, C 1 -C 6 -alkylthio, (C 1 -C 6 -alkyl)amino, di(C 1 -C 6 -alkyl)amino, C 1 -C 6 -alkylsulfinyl, or C 1 -C 6 -alkylsulfonyl, R 4 , R 5 and R 6 are independently of one another selected from the group consisting of hydrogen, halogen, cyano, azido, nitro, C 1 -C 6 -alkyl, C 3 -C 8 -cycloalkyl, C 1 -C 4 -haloalkyl, C 1 -C 4 -alkoxy, C 1 -C 4 -alkylthio, C 1 -C 4 -alkylsulfinyl, C 1 -C 4 -alkylsulfonyl, C 1 -C 4 -haloalkoxy, C 1 -C 4 -haloalkylthio, C 2 -C 6 -alkenyl, C 2 -C 6 -alkinyl, (C 1 -C 4 -alkoxy)carbonyl, amino, (C 1 -C 4 -alkyl)amino, di(C 1 -C 4 -alkyl)amino, aminocarbonyl, (C 1 -C 4 -alkyl)aminocarbonyl, di(C 1 -C 4 -alkyl)aminocarbonyl, hydroxysulfonyl, sulfonylamino, sulfenylamino, sulfinylamino and C(=O)-R 10 .
    • 本发明涉及通式(I)的氰基吡啶化合物及其农业上有用的盐以及包含这些化合物的组合物。 本发明还涉及氰基吡啶化合物,其盐或包含它们的组合物用于对抗动物害虫的用途。 在式(I)中,n为0,1或2; X是N,N-O或C-R 4; Y是N,N-O或C-R 5; Z是N,N-O或C-R 6; 条件是变量X,Y和Z之一为N或NO,另外两个变量为任选取代的碳原子; R 1,R 2,R 2彼此独立地选自氢,C(= O)-R 7, 任选地取代C 1 -C 10 - 烷基,C 2 -C 6 - 烯基,C 1 -C 6 - C 1 -C 10 - 烷基,C 1 -C 10 - 烷氧基或C 3 - C 10 - 环烷基或R 1和R 2与相邻的氮一起形成3至10元环,任选被1个 ,选自C 1 -C 5 - 烷基和卤素的2或3个基团,其中除了氮和碳环成员之外,环可以含有1,2 或3个杂原子作为选自氮,氧,硫,SO 2,SO 2或NR 8的环成员。 R 3是氢,硝基,氰基,叠氮基,氨基,卤素,磺酰基氨基,亚磺酰氨基,亚磺酰氨基,C(= O)R 9,C 1, C 1 -C 6 - 烷基,C 2 -C 6 - 烯基,C 2-C≡S C 6 - 烷基,C 3 -C 8 - 环烷基,C 1 -C 6 - - 烷氧基,C 1 -C 6 - 烷硫基,(C 1 -C 6 - 烷基)氨基, (C 1 -C 6 - 烷基)氨基,C 1 -C 6 - 烷基亚磺酰基或C(C 1 -C 6 - C 1 -C 6烷基磺酰基,R 4,R 5和R 6, 独立地选自氢,卤素,氰基,叠氮基,硝基,C 1 -C 6 - 烷基,C 3 - C 1 -C 8 - 环烷基,C 1 -C 4 - 卤代烷基,C 1 -C 3 C 1-4烷氧基,C 1 -C 4 - 烷硫基,C 1 -C 4烷基, - 烷基亚磺酰基,C 1 -C 4 - 烷基磺酰基,C 1 -C 4 - 卤代烷氧基 ,C 1 -C 4 - 卤代烷硫基,C 2 -C 6 - 烯基,C 2 C 1 -C 6 - 炔基,(C 1 -C 4 - 烷氧基)羰基,氨基,(C 1 -C 6 - (C 1 -C 4 - 烷基)氨基,氨基羰基,(C 1 -C 4 - 氨基羰基,二(C 1 -C 4 -C 4 - 烷基)氨基羰基,羟基磺酰基,二(C 1 -C 4 - 磺酰氨基,亚磺酰基氨基,亚磺酰氨基和C(= O)-R 10。
    • 9. 发明公开
    • NOVEL 2-CYANO-3-(HALO)ALKOXY-BENZENESULFONAMIDE COMPOUNDS FOR COMBATING ANIMAL PESTS
    • 新型2-氰基-3-(卤代)烷氧基苯磺酰胺化合物用于防治动物病虫害
    • EP1819668A2
    • 2007-08-22
    • EP05810670.9
    • 2005-11-24
    • BASF AKTIENGESELLSCHAFT
    • VON DEYN, WolfgangBASTIAANS, Henricus, Maria, MartinusPOHLMAN, MatthiasRACK, MichaelBAUMANN, ErnstPUHL, MichaelHOFMANN, MichaelTEDESCHI, LivioKORDES, MarkusKORADIN, ChristopherANSPAUGH, Douglas, D.CULBERTSON, Deborah, L.COTTER, Henry, Van TuylOLOUMI-SADEGHI, Hassan
    • C07C311/16C07C311/29C07C311/39C07C323/32C07C319/20A01N41/06
    • C07C319/20A01N41/06C07C311/29C07C323/62
    • The invention relates to 2-cyano-3-(halo)alkoxy-benzenesulfonamide compounds (I), where the variables Alk and R1 to R5 are as defined in claim 1, and/or to their agriculturally useful salts. Moreover, the present invention relates to: the use of compounds (I) and/or their salts for combating animal pests; agricultural compositions comprising such an amount of at least one compound of the general formula (I) and/or at least one agriculturally useful salt of (I) and at least one inert liquid and/or solid agronomically acceptable carrier that it has a pesticidal action and, if desired, at least one surfactant; and a method of combating animal pests which comprises contacting the animal pests, their habit, breeding ground, food supply, plant, seed, soil, area, material or environment in which the animal pests are growing or may grow, or the materials, plants, seeds, soils, surfaces or spaces to be protected from animal attack or infestation with a pesticidally effective amount of at least one2-cyano-3-(halo)alkoxy-benzenesulfonamide compound of the formula (I) and/or at least one agriculturally acceptable salt thereof; a method for the for the protection of seeds from soil insects and of the resulting plant's roots and shoots from soil and foliar insects comprising contacting the seeds before sowing and/or after pregermination with a 2-cyano-3-(halo)alkoxy-benzenesulfonamide compound of the general formula (I).
    • 本发明涉及2-氰基-3-(卤代)烷氧基 - 苯磺酰胺化合物(I),其中变量Alk和R1-R5如权利要求1中所定义,和/或其可农用盐。 此外,本发明涉及:化合物(I)和/或其盐用于对抗动物害虫的用途; 包含这种量的至少一种通式(I)的化合物和/或至少一种(I)的农业上有用的盐和至少一种惰性液体和/或固体农艺上可接受的载体的农业组合物,其具有杀虫作用 和如果需要的话,至少一种表面活性剂; 以及防治动物害虫的方法,其包括使动物害虫,其习性,繁殖场,食物供应,植物,种子,土壤,面积,动物害虫正在生长或可能生长的材料或环境,或材料,植物 (I)的至少一种2-氰基-3-(卤代)烷氧基 - 苯磺酰胺化合物和/或至少一种农业上受到保护的种子,土壤,表面或空间免于动物攻击或侵染 其可接受的盐; 一种用于保护种子免受土壤昆虫以及所得植物的根和茎由土壤和叶面昆虫引起的方法,包括在播种之前和/或在萌芽后使种子与2-氰基-3-(卤代)烷氧基 - 苯磺酰胺 通式(I)的化合物。